Artificial Gemstones - A Collection of Historical Articles on the Production of Synthetic Gemstones
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Artificial Gemstones - A Collection of Historical Articles on the Production of Synthetic Gemstones - Read Books Ltd.
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Artificial Production of real Precious Stones. Results obtained. Becquerel. Ebelman. Gaudin. Henri Sainte-Claire Deville. De Sénarmont. Daubrée. Durocher. Sainte-Claire Deville and Caron, &c.
"Beset with emeralds
And diamonds, with sparkling rubies red
In checkerwise, by strange invention."
We have seen that the elementary constituents of precious stones must have existed once in a condition that allowed them to move freely; and that this condition was obtained by one of three general methods—
1st.—Direct fusion of the substance by a sufficient heat.
2d.—Dissolution at variable temperatures of the mineral substance in a foreign body, and complete or partial volatilization of the dissolvent; or crystallization without evaporation under the influence of natural forces, either alone or aided by heat, electricity, &c.
3d.—Prior reduction into vapour of substances destined to react upon each other.
To the first method belong the results of the observations of Mitscherlich upon the mineral species which are naturally produced in furnaces where metals are reduced; the direct reproduction of several minerals by Berthier; and, above all, the fusion of alumina and of silica, by M. Gaudin.
The second method comprehends the remarkable results of Ebelman; that which M. de Sénarmont has employed, but in which intervenes a new element, that of a very strong compression; and lastly, that of M. Becquerel, but with still another element, the action of a feeble electric current.
The third method includes the results obtained by MM. Daubrée, Ebelman, Durocher, Henri Sainte-Claire Deville and Caron, &c.
FIRST METHOD.
If any one should say—I am going to produce a fire of enormous power, without employing any substance but water, he would run the risk of being considered a fool, since fire and water have always been considered the antipodes of one another. Even modifying the announcement, and saying—I am about to produce an intense fire by means of elements derived exclusively from water, hardly makes the proposition appear more plausible, yet nothing can be more rigorously exact.
Water is composed of two bodies, which, in the present state of knowledge, are considered simple: they are two gases—one called oxygen, the other hydrogen. If a mixture of these two gases is made, and if to this mixture an ignited body is applied, the two gases combine and form water; but at the same time there is a production of vivid light, and a development of a great quantity of heat. These two effects attain their maximum when the mixture is formed of one volume of oxygen and two of hydrogen.
If, instead of forming the mixture immediately, we arrange so that the two gases arrive separately, in two uniform and continuous streams, at an orifice of small diameter, and if an ignited body is applied to this orifice where the gases meet and combine, the mixture takes fire. As the two gases are constantly renewed at the orifice, the combustion is not interrupted; and a jet of flame is attained analogous to that of a gas-burner. It gives out little light, but develops an exceedingly elevated temperature. The contrivance is called the oxyhydrogen blowpipe, and is in common use among chemists and others.
By aid of this instrument M. Gaudin melted silica and alumina, and artificially reproduced the corundum.
The corundum, as we have seen, is crystallized alumina. To obtain it M. Gaudin heated ammonia alum and potash alum: the enormous heat developed by his apparatus volatilized the potash, and the alumina crystallized. Rubies were obtained in this manner; and M. Dufrénoy has found in these productions the rhombohedral form, and the triple cleavage proper to the corundum. Finally, M. Malaguti has established, by the analysis of these crystals, that they contain 97 to 100 parts of alumina, and 2 of silicate of lime; a composition analogous to that of the ruby.
The experiments of M. Gaudin date back to 1837; this date gives the priority to this ingenious physicist for the artificial production of the corundum.
It should nevertheless be noted that more than ten years before the work of M. Gaudin, a man who has left a deep impress on science, Berthier, basing his experiments upon chemical proportions, reproduced a great number of minerals, such as peridote, pyroxene, &c., by bringing their elements together at a high temperature.
SECOND METHOD.
In the year 1823 M. Becquerel, one of the most eminent of French physicists, formed the idea of using the currents of the voltaic pile to determine combinations, and not merely decompositions.
Instead of employing powerful currents, such as were used to produce decomposition, he applied to his purpose very feeble currents, and the results obtained surpassed his expectations.
The simple apparatus which he used is shown in Fig. 90. It is a tube curved in the form of the letter U. The curved part is filled with clay, to prevent the liquids contained in the branches from flowing together, without interfering with the production of molecular actions and transports. The two liquids are, moreover, placed in direct communication by means of a metallic wire.
Fig. 90.—Voltaic Apparatus of M. Becquerel for the Production of Crystals.
One of the substances reproduced by