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6.14;
6.15;
6.16;
6.17;
6.19;
6.20;
6.24;
6.25;
6.26.
Incio Slido
Final
X = solubilidade
Kps = [Cu+].[Br-]
5.10-9=x.x
S=5.10-9=7,07.10-5 mol/L
b)
S em g/100 mL:
7,07.10-5 mol
1000mL
y
100 mL
145,45g
S
a)
S em mol/L:
Ag4Fe(CN)6(s) 4Ag+(aq) + Fe(CN)64-(aq)
Incio
Slido
Final
4X
Kps=[Ag+]4.[Fe(CN)64-]=8,5.10-45
Kps=(4x)4.x
Kps=256x5
S=5(8,5.10-45)/256
S= 5,06.10-10 mol/L
b)
643,42g
[Ag+]=0,22 ppb
AgCl(s)
Ag+(aq)+Cl-(aq) Kps=1,8.10-10
Incio
Slido
Final
Kps=[Ag+].[Cl-]=1,8.10-10
Kps=x.x
kps=x
x=[Ag+]=1,8.10-10=1,34.10-5 mol/L
1,34.10-5 mol Ag+
1000mL
y
1mL
y= 1,34.10-8 mol Ag+/mL
z=1,4.10-6 g de Ag+/mL
1 ng
w
10-9g
1,4.10-6g
w= 1400 ng/mL
z
107,87
AgBr(s)
Ag+(aq)+Br-(aq) Kps=5,0.10-13
Incio
Slido
Final
Kps=[Ag+][Br-]=5,0.10-13
Kps=x=5,0.10-13
x=[Ag+]=5,0.10-13=7,07.10-7 mol/L
7,07.10-7mol Ag+
1000mL
y
1mL
y=7,07.10-10 mol Ag+/mL
1 mol Ag+
107,87g
7,07.10-10mol
z
z= 7,63.10-8 g Ag+/mL
7,63.10-8g Ag+
10-9g
w=76ng/mL
[Ag+]=76 ppb
w ng
1 ng
AgI(s)Ag+(aq)+I-(aq)
Incio Slido
Final
kps=8,3.10-17
Kps=[Ag+][I-]=8,3.10-17
Kps=x
[Ag+]=x=8,3.10-17=9,11.10-9 mol/L
9,11.10-9 mol Ag+
1000mL
y
1mL
y=9,11.10-12mol Ag+/mL
1 mol Ag+
107,87g
9,11.10-12 mol
z
z=9,83.10-10 g de Ag+/mL
1g Ag+
9,83.x10-10g
109 ng
w
w=0,98ng de Ag+/mL
[Ag+]=0,98 ppb
Cu4(OH)6(SO4)(s)4Cu2+(aq)+6OH-(aq)+SO42-(aq)
Incio
Slido
1,0.10-6
Final
4X
1,0.10-6
Kps=[Cu2+]4.[OH-]6.[SO42-]=2,3.10-69
Kps=(4x)4.(1,0.10-6)6.x=2,3.10-69
256x5=2,3.10-33
x=9,79.10-8
[Cu2+]=4x=4.(9,79.10-8)=3,9.10-7M
Incio Slido
Final
Kps=[Ca2+].[SO42-]=2,4.10-5
Kps=x.x
x=2.4.10-5
x=S
S=4,9.10-3M
4,9.10-3 mol/L
y
1mol/L
136,14g
y=0,67g/L
S=0,67g/L
Incio Slido
Final
0,5
X+0,5
Kps=[Ca2+].[SO42-]
Kps=(x+0,5).x
Como x<<0,5, podemos considerar:
Kps=0,5x
2,4.10-5=0,5x
x=4,8.10-5
x=S
S=4,8.10-5M
4,8.10-5 mol/L
1 mol/L
y=6,5.10-3g/L
S=6,5.10-3g/L
y
136,14g
AgIO3(s)Ag+(aq)+IO3-(aq)
Incio Slido
Final
x
X
KIO3(aq)K+(aq)+IO3-(aq)
0,01M
0,01M 0,01M
Em gua pura:
Kps=[Ag+].[IO3-]=3,1.10-8
Kps=x
x=3,1.10-8
x=1,76.10-4
x=S
S=1,76.10-4M
S=3,1.10-6M
Incio
0,10
Final
slido
1.10-4 (0,1%)
Kps=[Zn2+].[CO32-]
1.10-10=1.10-4.x
x=1.10-6
[CO32-]=x=1.10-6M
Dados:
AgCl
AgBr
AgI
Ag2CrO4
Como
kps=1,8.10-10
kps=5,0.10-13
kps=8,3.10-17
kps=1,2.10-12
Para
O,10M
Final
slido
2x
0,10M-x
Kps=[Ag+].[CrO42-]
Kps=(2x)2.(0,10-x)=4x.(0,10-x)
S= 1,73.10-6M
Clculo
da solubilidade do AgCl:
AgCl(s)Ag+(aq)+Cl-(aq)
Incio
O,10M
Final
slido
0,10M-x
Kps=[Ag+][Cl-]
Kps=x.(0,10-x)
-Como x<<0,10, podemos considerar:
Kps=x.0,10
1,8.10-10=x.0,10
x=1,8.10-9
x=S
S=1,8.10-9M
Como 1,8.10-9<1,73.10-6:
I-<Br-<Cl-<CrO42-
Para o CaSO4:
CaSO4(s)Ca2+(aq)+SO42-(aq)
Incio
0,05
Final
slido
5.10-4(1%)
Kps=[Ca2+].[SO42-]
2,4.10-5=5.10-4.x
x=[SO42-]=0,048M
kps=2,4.10-5
Para o AgSO4:
-Considerando [SO42-]=0,048M:
Ag2SO4(s)2Ag+(aq)+SO42-(aq) kps=1,5.10-5
0,03M 0,048M
Q=[Ag+].[SO42-]
Q=0,03.0,048=4,32.10-5
[Ca2+] quando
Ag2SO4:
Q=Kps
comear
Kps=[Ag+].[SO42-]
1,5.10-5=0,03.[SO42-]
[SO42-]=0,017M
Kps=[Ca2+].[SO42-]
2,4.10-5=[Ca2+].0,017
[Ca2+]=0,014M
precipitao
de