Академический Документы
Профессиональный Документы
Культура Документы
12 of H2 and 11.2 of Cl2 are mixed and exploded. The composition by volume of mixture is (A) 24 of HCl (g) (B) 0.8 Cl2 and 20.8 HCl(g) (C) 0.8 H2 and 22.4 HCl(g) (D) 22.4 HCl(g) Copper metal reacts with nitric acid, according to the reaction 3Cu(s) + 8HNO3(aq) 3Cu(NO3)2(aq) + 2NO(g) + 4H2O() If 18.75 g Cu(NO3)2 is eventually obtained, then how many grams of nitric oxide, would have also formed according to the preceeding equation ? (A) 2g (B) 4g (C) 6g (D) 8g A spherical ball of radius 10 cm contains 56% iron. If density is 1.2 g/cm3 , number of mol of Fe present approximately is (A) 24 (B) 20 (C) 50 (D) 25 On heating O3 its volume : (A) remains unchanged (B) becomes doubled 3 (C) becomes half (D) becomes times 2 Number of water molecules in the drop of water, if 1 ml of water has 20 drops and A is Avogadros number is (A) 0.5 A/18 (B) 0.05 A (C) 0.5 A (D) 0.05A/18 N2 + 3H2 2NH3, molecular weight of NH3 and N2 are x1 and x2, their equivalent weight are y1 and y2. Then (y1 y2) is -
4.
5.
6.
7.
8.
2 x1 x 2 (B) x1 x2 (C) 3x1 x2 (D) x1 3x2 6 Read the following passage carefully and answer the questions given after the passage. Milk of sulphur is soluble in CS2 and mainly used in medicine. A doctor wants to produce 6.4 kg milk of sulphur , so he went to laboratory and took milk of lime [Ca(OH)2] with sulphur and again decomposing the products formed with HCl, milk of sulphur i.e. , white sulphur is formed. Reaction involving in the production of white sulphur are (A)
2CaS5 + CaS2O3 + 6HCl 9. Doctor wants to produce (A) 1. 2046 1026 sulphur atom (C) 6.023 1023 sulphur atom
3CaCl2 + 3H2O + 12S (white) (B) 1.2046 1023 white sulphur atom (D) 1. 2046 1026 white sulphur atom
10.
How many mole of Ca(OH)2 is used for the production of 6.4 kg of milk of sulphur ? (A) 0.50 mole (B) 0.80 mole (C) 50 mole (D) 80 mole How many mole of HCl is used in this process ? (A) 100 mole (B) 200 mole (C) 10 mole
11.
(D) 20 mole
12.
When milk of lime is reacted with sulphur, the oxidation state of sulphur changes from zero to (A) 2/5 (B) 2/5 and +2 (C) +2 (D) +2 and +4
2.
3.
4.
5.
6.
300 ml of 3M NaCl is added to 200 ml of 4M BaCl2 solution. The concentration of Cl ions in the resulting solution is (A) 7 M (B) 1.6 M (C) 1.8 M (D) 5 M The volume of water to be added to 100 cm3 of 0.5 N H2SO4 to get deci normal concentration is : (A) 100 cm3 (B) 450 cm3 (C) 500 cm3 (D) 400 cm3 Salt solution of sodium bicarbonate is (A) Basic (C) Neutral
7.
8.
9.
Which of the following will released hydrogen when reacts with sodium ? (A) HCl (B) C2H5OH (C) C2H2
10.
pH of a solution prepared by mixing 25 ml of 0.05 M solution of HCl, 10 mL of 0.5 NaOH, 50 mL of 0.05 M solution of H2SO4 and 15 ml of water will be (A) 12.903 (B) 1.903 (C) 12.097 (D) 1.097 The pH of a solution of 0.1 M CH3COOH increases when which of the following substance is added ? (A) NaHSO4 (B) HClO4 (C) NH4NO3 (D) K2CO3 105 M NaOH solution at 25C is diluted 1000 times. The pH of the solution will (A) be equal to 8 (B) lie between 7 and 8 (C) lie between 6 and 7 (D) remain unchanged The number of H+ ions present in 1 ml of a solution having pH = 13 is (A) 1013 (B) 6.023 1013 (C) 6.023 107
11.
12.
13.
14.
The pH of aqueous solutions of three acids A, B and C respectively is 3, 2 and 1. What will be the ratio of their [H+] ? (A) 1 : 2 : 3 (B) 300 : 200 : 10 (C) 100 : 10 : 1 (D) 1 : 10 : 100 10 mL of 0.1 N HCl is added to 990 mL solution of NaCl. The pH of the resulting solution is(A) zero (B) 3 (C) 7 (D) 10
15
The function of flux during the smelting of the ore is (A) to make the ore porous (C) to facilitate reduction (B) to remove gangue (D) to facilitate oxidation
4.
(C) leaching
The incorrect statement is (A) Calamine and siderite are carbonates (C) Zinc blende and iron pyrites are sulphides (B) Argentite and cuprite are oxides. (D) Malachite and azurite are ores of copper.
6.
Aluminium oxide reacts with sodium hydroxide to form (A) Sodium meta aluminate and hydrogen (C) Aluminium hydroxide and sodium oxide. (B) Sodium meta aluminate and water (D) Sodium -aluminium alloy and water.
7.
(D) Liquation
In the commercial electro chemical process for aluminium extraction, the electrolyte used is (A) Al(OH)3 in NaOH solution (C) A molten mixture of Al2O3 and Na3AlF6 (B) An aqueous solution of Al2(SO4)3 (D) A molten mixture of Al2O3 and Al(OH)3
9.
Leaching of silver from argentite is done by Mac-Arthur forest cyanide process which involves following reaction.
[A] Ag2S + NaCN
[A] + Zn [B] [B] is a metal . Hence [A] and [B] are (A) Na2[Zn(CN)4], Zn 10. Azurite is (A) 2CuCO3. Cu(HCO3)2 (B) CuCO3.2Cu(OH)2 (C) 2CuCO3. Cu(OH)2 (D) Cu(HCO3)2. Cu(OH)2 (B) Na[Ag(CN)2], Ag (C) Na2[Ag(CN)4], Ag (D) Na3[Ag(CN)4], Ag
2.
3.
4.
5.
6.
7.
8.
For the energy levels in an atom which one of the following statement is correct ? (A) The 4s sub-energy level is at a higher energy than the 3d sub-energy level. (B) The M- energy level can have maximum of 32 electrons. (C) The second principal energy level can have four orbitals and contain a maximum of 8 electrons. (D) The 5th main energy level can have maximum of 50 electrons.
9.
The order of increasing energies of the orbitals follows (A) 3s, 3p, 4s, 3d, 4p (C) 3s, 3p, 4s, 4p, 3d (B) 3s, 3p, 3d, 4s, 4p (D) 3s, 3p, 3d, 4p, 4s
10.
The number of electrons in an atom with atomic number 105 having ( n+ )=8 is (A) 15 (B) 17 (C) 19 (D) 21
11.
In Cu ( Atomic no. 29 ) (A) 13 electrons have spin in one direction and 16 electrons in other direction. (B) 14 electrons have spin one direction and 15 electrons in other direction. (C) one electron can have spin only in the clockwise direction. (D) none of the above is correct.
12.
Consider the ground state of Cr atom.The number of electrons with the azumithal quantum numbers = 1 and 2 are respectively(A) 12 and 4 (B) 12 and 5 (C) 16 and 4 (D) 16 and 5
05
DPP :
2.
(C) Be Al
(D) Li Na
3.
Which of the following series of elements have nearly the same atomic radii ? (A) F, Cl, Br, I (B) Na, K, Rb, Cs (C) Li, Be, B, C (D) Fe, Co, Ni, Cu The elements having highest ionization enthalpies within their periods are called (A) halogens (B) noble gases (C) alkali metals (D) transition elements The correct order of size among Cl, Cl+ and Cl is (A) Cl+ < Cl < Cl (B) Cl+ > Cl > Cl (C) Cl+ < Cl < Cl Which of the following properties generally decreases along a period ? (A) Ionisation energy (B) Atomic radii (C) Electron affinity The correct order of increasing atomic radius of the following elements is (A) S < O < Se < C (B) O < C < S < Se (C) O < S < Se < C
4.
5.
6.
(D) Valency
7.
8.
The electron affinities of halogens are : F = 332, Cl = 349, Br = 324, I = 295 kJ mol1 The higher value of Cl as compared to that of F is due to : (A) higher atomic radius of F (B) smaller electronegativity of F (C) weaker electron repulsion in Cl (D) more vacant p-subshell in Cl In the modern periodic table which one of the following does not have appropriate position ? (A) Inert gases (B) Inner-transition elements (C) Transition elements (D) Fluorine Element of which of the following atomic nos. has lowest EN? (A) 37 (B) 55 (C) 87 Match the following : Column-I (element / elements) (A) (B) (C) (D) An element whose fourth shell contains two p-electrons An element whose valence shell contains one unpaired p-electron An element which receives last electron in (n 1) d-subshell An element with the ground-state electron configurationa [Ar]4s23d10
9.
10.
(D) 105
11
Column-II (group number) (p) 8th group (q) 12th group (r) 14th group (s) 17th group
12.
Arrange the following in increasing radii (a) Li+, Na+, K+ (c) Mg, Mg+, Mg2+ (e) O, O, O2 (g) Na+, Ne
(b) K+, Ca2+, Ar (d) O2, N3, F (f) Mg2+, Ca2+ (h) P3, N3
-rays have ionisation power because they possess (A) lesser kinetic energy (C) lesser penetration power (B) higher kinetic energy (D) higher penetration power
3.
A magnet will cause greatest deflection of (A) -rays (B) -rays (C) -rays (D) neutrons
4.
The ionising power of , and rays is in the decreasing order (A) > > (B) > > (C) > > (D) > >
5.
Which of the following radiation have least effect on both the photographic plate and zinc sulphide screen ? (A) -rays (B) -rays (C) - rays (D) All have equal effect
6.
7.
emits an alpha particle, the product has mass number and atomic number (B) 234,90
235 92 U
(C) 238, 90
207 82 Pb
9.
When
an -particle , the new element formed belongs to (B) zero group (C) fourth group (D) second group
10.
The
disintegrates to give 4 and 6 particles. The atomic no. of the end product is (B) 96 (C) 84 (D) 90
(A) 92