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12-15

12.13 We are asked to calculate the theoretical density of NiO. This density may be computed using Equation (12.1) as
n' ANi + AO VC N A

Since the crystal structure is rock salt, n' = 4 formula units per unit cell. Using the ionic radii for Ni2+ and O2- from Table 12.3, the unit cell volume is computed as follows:
3 VC = a 3 = 2r 2+ + 2r 2- = [2 (0.069 nm) + 2 (0.140 nm)]3 Ni O cm 3 nm3 = 7.30 x 10-23 unit cell unit cell

= 0.0730

Thus,
=

(4 formula units/unit cell)(58.69 g/mol + 16.00 g/mol) 7.30 x 10-23 cm3/unit cell 6.023 x 1023 formula units/mol

)(

= 6.79 g/cm3

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