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, ,

VI
( )
9


O2
S
, 0
-219
113

Se
221

Te
450

, 0
,

-183

444,6

688

1390

45

81

92

111

1 XXI
http://www.webelements.com



() CaSO4*2H2O

CuFeS2
( )
1 XXI

:-

http://demons.fatal.ru/hell/muki.htm

http://www.webelements.com

.. , .1,
.: , 1974, 656 ., . 321

+, . 17. , . 236


Fe + S = FeS

1 XXI
D:\DATA\VIDEO\080154.mpg

Zn + S = ZnS

1: .
VID\s09_3vo3

S + 2 H2SO4 = 3 SO2 + 2 H2O

1: .
VID\s09_3vo4

3 S + 6 NaOH = Na2SO3 + 2 Na2S + 3 H2O


() H2S23 :

Na2S + S = Na2S2



2 Ag + H2S = Ag2S + H2 (???)
Ag+ + e = Ag

H2S (1 = 1*107)

0 = + 0,80

E = E0 + 0,058 lg [Ag+]
Ag2S = 2*1050

[Ag+] = 1,7*1017 1017

E = 0,8 - 0,058*17 = 0,8 - 0,986 = 0,186

SF4 (6+4=10, 5 -) SF6 (6+6=12, 6 -)

http://www.webelements.com

..
, 12, 1999, .16-20

..
, 12, 1999, .16-20

Picrophilus
oshimae


(--)


., 0

0,6 - 0,7 - ?

85

Sulfurisphaera
ohwakuensis

1,0 - 2,0 - 5,0

84

Acidianus
infernus

1,0 - 2,0 - 5,5

90

Stigiolobus
azoricus

1,0 - 2,3 - 5,5

80

- .. .
.
//, 1999, . 68, . 398-406

..
, 12, 1999, .16-20

. .

H2S2O3

H2S3O6

H2SO3

H2SO4

+6, -2

+6, -2

+4

+6

Na2SO4
Na2SO3
Na2S

Na2SO3 + S = Na2S2O3
:
Na2S2O3 + 4 Cl2 + 5 H2O = Na2SO4 + H2SO4 + 8 HCl
2 Na2S2O3 + I2 = Na2S4O6 + 2 NaI
H2S2O3 = S + SO2 + H2O
prosto-s

IV

SO2 :
SO2 + 2 H2S = 3 S + 2 H2O
3 S + 6 NaOH = Na2SO3 + 2 Na2S + 3 H2O
SO2 + Cl2 = SO2Cl2
4 Na2SO3 = 3 Na2SO4 + Na2S

. -

2 Ag + 2 H2SO4 (>95%) = Ag2SO4 + SO2 + 2 H2O


4 Zn + 5 H2SO4 (>95%) = 4 ZnSO4 + H2S + 4 H2O
1: .
VID\s09_5vo1

H2S2O7 H2S4O13
H2S2O8 ( )

VI
S

Se

Te

2,0

2,0

0,01

H2S

H2Se

H2Te

(8 ), /3

10

0,1

, /3

<0,1

1 - 3 , /3

800

20

SO2

SeO2

TeO2

-72,7

340-390

.450

( 8 . ), /3

10

0,1

0,0005

, /3

0,2

0,003

( 8 . ), /3

, 0

, /3

20-50

1 - 3 , /3

5000


1990 .
20 , 150 . .
1973-1974 .;
2,4,
2,7.
1 .
3 . ,
100000 .

:
O3 + SO2 = SO3 + O2

CD: IUPAC DIDAC project - 2003 Agfa-Gevaert N.V.


http://www.iupac.org/didac/index.html

CD: IUPAC DIDAC project - 2003 Agfa-Gevaert N.V.


http://www.iupac.org/didac/index.html

1-
2-
3-
""
4-
5-

6-
7-

http://compcraft.narod.ru/vneshnie/laser.htm

.
, ().
( )

CD: IUPAC DIDAC project - 2003 Agfa-Gevaert N.V.


http://www.iupac.org/didac/index.html


- ( )

CD: IUPAC DIDAC project - 2003 Agfa-Gevaert N.V.


http://www.iupac.org/didac/index.html

-
-( .. . -XXI, 1998, 2)


() ..

CD: IUPAC DIDAC project - 2003 Agfa-Gevaert N.V.


http://www.iupac.org/didac/index.html

-
( .. . -XXI, 1998, 2)

http://alchimia.chat.ru/1.htm

.
.
, ,
. - , - .
, .


. 1 XXI
. 1: .

(. 5)

Ag + H+ = Ag+ + H2
E = 0 0,80 - (0,058)lg([Ag+]/[ H+]

( ), ,
[Ag+] 1 ( [ H+] 1).
( + )
:
E = E0 + 0,058 lg [Ag+]
, E < 0 ,
.. ( 0).