22

UV filters cyclosiloxanes glycol ethers octinoxate benzophenone3 benzophenone1 benzophenone dodecamethylcyclohexylsiloxane decamethylcyclopentasiloxane octamethylcyclotetrasiloxane 2,2butoxyethoxyethanol 2,2methoxyethoxyethanol 2phenoxyethanol 2butoxyethanol phenethyl alcohol musk xylene musk ketone methyl ionone isobornyl acetate HHCB DPMI diphenyl ether bucinal AHTN terpineol pinene methyl salicylate methyl eugenol linalool limonene hexyl cinnemal eugenol benzylacetate nonylphenol diethoxylate nonylphenol monoethoxylate 4tnonylphenol octylphenol diethoxylate octylphenol monoethoxylate 4toctylphenol diethanolamine monoethanolamine triclosan triclocarban bisphenol A diethyl phthalate dinpropyl phthalate dinoctyl phthalate dinhexyl phthalate dinbutylphthalate diisononyl phthalate diisobutyl phthalate dicyclohexyl phthalate benzylbutyl phthalate bis(2ethylhexyl) phthalate bis(2ethylhexyl) adipate butyl paraben ethyl paraben methyl paraben

18

17

10

fragrances

alkylphenols ethanolamines antimicrobials bisphenol A

phthalates

parabens

Calculated alternative composite

Alternative sample 1

Alternative sample 2

Alternative sample 3

Alternative sample 4

Conventional >1,000 g/g >1001,000 g/g >1100 g/g Not detected Not analyzed

Alternative >1,000 g/g >1001,000 g/g >1100 g/g Not detected Not analyzed

Figure S1. Concentrations of target compounds in sunscreen samples. Compounds are grouped by chemical class, with natural and synthetic fragrances distinguished by a dashed horizontal line. Horizontal (xaxis) shows the conventional sunscreen sample, which was a composite of 4 sunscreens; the calculated composite of 5 alternative sunscreens that were analyzed individually; and then results for each of the 5 alternative sunscreens. Numbers in the top margin count the number of chemicals detected in each sample; numbers in the right margin count number of products containing each compound.

R.E. Dodson, M. Nishioka, L.J. Standley, L.J. Perovich, J.G. Brody, R.A. Rudel. 2012. Endocrine Disruptors and Asthma-Associated Chemicals in Consumer Products. Environmental Health Perspectives. http://dx.doi.org/10.1289/ehp.1104052

Conventional composite (4)

Alternative sample 5