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Uses of metals in our daily lives Uses related to properties of metals Occurrence of metals in nature Extraction of metals from their ores Discovery of metals Conserving metals
1 1 4 4 8 10 11 12
13
Different reactivities of metals Comparing reactivity of common metals The metal reactivity series Chemical equations Metal reactivity series and the tendency of metals to form positive ions Displacement reactions of metals in aqueous solution Ionic equations Extraction of metals from their ores
13 13 20 21 26 27 28 31 34 35
Chapter 12
Reacting masses
37
The mole concept in general Percentage by mass of an element in a compound Chemical formulae of compounds Determination of empirical formulae Determination of molecular formulae Calculations based on equations
37 42 44 47 49 53 58 59
Chapter 13
61
Corrosion of metals Rusting Factors that speed up rusting To observe rusting using rust indicator Protecting iron from rusting Socio-economic implications of rusting Corrosion resistance of aluminium
61 61 63 64 66 70 70 71 72
10.1
( )
10.2
10.1
Metal
Iron construction, transport
Uses
water pipes
Note 3 (a) Aluminium is more than twice as conductive of electricity as the same mass of copper.
cooking utensils
(b) Aluminium cables are much lighter than copper cables, thus the pylons supporting them can be less sturdily built, with a saving in cost.
Aluminium
(c) Aluminium is not used in plumbing because it is difficult to weld aluminium pipes by ordinary welding.
very good conductor of electricity, low density, ductile; cheaper than copper
N2 & N3
aircraft body
Metal
Aluminium saucepans, kitchen foil
Uses
non-poisonous, low density (hence convenient to carry), corrosion resistant, very malleable ( ) corrosion resistant, strong light but very strong, very corrosion resistant, malleable
N4
N4
Titanium
N5
Gold
Note 5 (a) Titanium weighs only 60% as the same volume of steel. Both are equally strong. (b) At high temperatures, titanium remains strong and its shape is not distor ted. (When speeding through air, a supersonic aircraft becomes heated up by friction with air.)
jewellery, coins
Note 6 Today, tiny drops or thin sheets of gold can be found in nearly every telephone, computer, late-model car, automatic teller machine, video camera and liquid-crystal display.
attractive golden yellow colour, extremely corrosion resistant (so always shiny), most malleable and ductile, quite soft when pure ( )
N6
Mercury
thermometers
liquid at room temperature, expands on heating, does not wet walls of tubes
Silver
jewellery, coins
attractive silvery colour, corrosion resistant, malleable and ductile, moderately soft
Table 10.1 Uses of some metals and their properties related to the uses. 2
N7
10.1
( A E )
Metal
Relative price
Density (g cm )
3
Other characteristics
most expensive
19.3
1063
cheapest
7.9
1540
hard and strong attractive silvery colour, quite soft, corrosion resistant
very expensive
10.5
961
very expensive
4.5
1933
11
11
medium
9.2
420
Refer to the above information to answer the questions below: (a) Which is the most widely used metal? Why? (b) Which two metals are widely used in jewellery? Why? (c) Which metal is the best conductor of heat? Give a reason why we do not use this metal to make cooking utensils. (d) Which metal is used to make aircraft bodies? Give a reason for the choice. (e) Which two metals are the best conductors of electricity? Give a reason why one of these is used much more than the other. (a) (b) (c)
(d)
(e)
A10.1 (a) B. It is hard and strong, yet very cheap. (b) A and C. They have a beautiful shiny appearance. A is chemically inert, and C is also corrosion resistant. They are both very expensive metals. (c) C. It is very expensive. (d) D. It is light (with a low density) but strong and corrosion resistant. (e) A and C. C is more widely used because it is cheaper.
10.3
Four important ores found in nature. (a) Bauxite the main ore of aluminium. It is mostly N9 aluminium oxide
Note 9 Al2O3. Pure aluminium oxide is white. The bauxite ore shown is brown because it contains appreciable amounts of iron(III) oxide.
(a) Al2O3 (b) CuFeS2 (c) (III) Fe2O3 (d) (II) PbS ( )
(b) Copper pyrite the main ore of copper. It is mostly CuFeS2. (c) Haematite the main ore of iron. It is mostly iron(III) oxide Fe2O3. (d) Galena the main ore of lead. It is mostly lead(II) sulphide PbS. A few metals (e.g. gold and platinum) are so unreactive that they occur in the Earth in free state, as pure metal.
10.4
1. 2. 3.
Some unreactive metals, mercury and silver, for example, can be extracted from their ores by this method. Mercury(II) oxide and silver oxide decompose on heating to produce the metal and oxygen. We can use a glowing splint N10 to test for any oxygen evolved. mercury(II) oxide
red
(II)
mercury + oxygen
silvery
(II) +
silver oxide
brownish black
silver + oxygen
silvery
( )
( (III))
(II))
(PbS)
(II) + (II)
The lead(II) oxide formed in the reaction is then heated with carbon and is changed to lead. lead(II) oxide + carbon lead + carbon dioxide (II) + +
10.1)
aluminium oxide
(from bauxite)
aluminium + oxygen
( )
Note 11 There is a competition for oxygen. At high temperatures, carbon holds on to oxygen more tightly than lead does, hence carbon can take oxygen away from lead(II) oxide. Besides carbon, carbon monoxide and hydrogen can also reduce oxides of metals low in the reactivity series. For example, CuO(s) + CO(g) Cu(s) + CO2(g); PbO(s) + H2(g) Pb(s) + H2O( ) Note 12 Bunsen flame is not hot enough to give an obvious result in the extraction reaction. However, trace of iron can be detected when a magnet is placed near the resultant reaction mixture.
negative () electrode ()
Learning tip Aluminium oxide has a very high melting point (2047C). Cryolite (Sodium aluminium fluoride, Na3AlF6) is added to lower the melting point to about 950C. (2047C) Na3AlF6)
( 950C
Common ores of some metals and their methods of N13 extraction are listed in Table 10.2.
10.2
Most difficult
Metal
Year of discovery
Potassium
in deposits and sea 1807 A.D. water common salt in sea 1807 A.D. water; rock salt 1808 A.D. limestone 1808 A.D. magnesite 1827 A.D. bauxite zinc blende
heat in air
oxide metal
Ease of extraction
1000 A.D.
Note 14 Copper and mercury are quite unreactive. Therefore in the controlled heating of their sulphides in air, the sulphur par t will be oxidized to sulphur dioxide, leaving the metals behind, e.g. HgS + O2 Hg + SO2
Note 15 Much silver and some gold are also recovered from by-products in the extraction of other metals.
oxide
3000 B. C. Iron
metal
3000
sulphide
metal
N14
) cinnabar
silver glance (or as free element) ( )
displacement from solution Ag2S ( ) mechanical separation (to get rid of impurities) ) (
N15
5000
Au
10.2
(d) silver
aluminium + oxygen
electrolysis
sodium chloride
sodium + chlorine
10.5
10.2
haematite
(d) Displacement from solution containing silver. (e) Physical separation. (f) Electrolysis.
electrolysis
magnesium chloride
heat in air
magnesium + chlorine
oxygen 46.6%
iron
(g) Heating the metal ore in air and then with carbon lead(II) sulphide Lead(II) oxide Lead(II) oxide + sulphur dioxide lead + carbon dioxide
5.0%
all other elements 1.5% magnesium 2.1% potassium 2.6% sodium 2.8% calcium 3.6%
Note 16 If all the gold available in the world today were melted to make a cube, the cube would be 15 18 m on each side. It has been estimated that the total gold resource not yet extracted is only 50% of the existing amount.
Although gold and silver are the earliest metals discovered N16 by humans, they are not massively used. This is because of the low abundance of gold and silver in the Earths crust.
the ease of extracting the metal from its ore and the cost of N18 3. Note 18 extraction
Another factor affecting the price of a metal is its supply and demand.
10.1
(a) A B C D
(i) Arrange the metals in the order of ease of extraction from their ores, the easiest first. (ii) Arrange the reactivity of the metals in ascending order. (iii) Deduce the order of discovery of the metals, the earliest first. (b) Aluminium is the most abundant metal in the Earths crust, yet it is more expensive than iron. Explain. Solution (a) (i) A, D, B, C (ii) The extraction methods are indication of the reactivity of metals. Thus, the ascending order of reactivity of the four metals is the same as the order of ease of extraction of these metals. That is, A, D, B, C. (iii) The order of discovery of metals relates directly to the reactivity and hence the ease of extraction of the metals. Therefore, the correct order is A, D, B, C. (b)
( A (iii) A C
cont'd
) C
(b) Though aluminium is the most abundant metal, much N19 of it exists in clay (mainly silicates). It is not economical to extract aluminium from clay. In fact, we extract aluminium from bauxite by electrolysis. Much electricity is needed and electricity is expensive. On the other hand, we extract iron from haematite by heating haematite with carbon in a blast furnace. The cost is relatively low.
(b) ( )
Note 19 Up till now, there is no economically feasible, largescale method for extracting aluminium from clay.
21
10.6
PVC (
1.
Metal resources are limited. However, demand for metals N21 keeps on increasing. Recycling is an effective way of conserving metals. 2. ) (
2.
Recycling saves energy and other resources (e.g. electricity, water, fuels). Thus, recycling also reduces the cost of metals. 3.
3.
Recycling helps to reduce pollution. Recycling of metals can reduce pollution due to metal waste. Also, recycling would cause less metal ores to be mined. This would minimize the environmental problems arising from mining N22 and extraction from ores.
4.
4.
Key terms
1. bauxite 2. copper pyrite 3. extraction 4. galena 5. haematite 6. recycling 7. replacing 8. reusing
Note 22 Mining would produce a lot of harmful chemicals, rocks, mud and dust, and noise at the same time. The extraction of metals also produces pollutants. For example, extracting copper from copper pyrites (mainly CuFeS2) releases sulphur dioxide. Besides, mining leaves very large holes on the ground, which are unsightly and wasteful of land.
Page 4 4 4 4 4 10 10 10
11
Summary
10.1 Uses of metals in our daily lives 1. Metals are very useful to us and they are used in many different ways in our daily lives.
10.3 Occurrence of metals in nature 3. Only a few metals (e.g. silver, in nature. Most metals exist as
gold compounds
and in ores.
platinum
10.4 Extraction of metals from their ores 4. 5. Metals can be obtained from
ores
by a process called
extraction
Metals can be extracted from their ores by alone (a) heating the metal ore carbon (b) heating the metal ore with electrolysis (c)
10.5 Discovery of metals 6. Different metals were discovered at different time in human history. Factors affecting the discovery and uses of a metal include abundance (a) of the metal in the Earths crust ease (b) of extraction of the metal.
availability Factors affecting the of a metal include (a) abundance of the metal in the Earths crust (b) ease of mining its ore and the cost (c) ease of extracting the metal from its ore and the cost
7.
10.6 Conserving metals 8. 9. Metal resources are limited and there is a need for Four methods are used to conserve metals: Reusing (a) metal articles Replacing (b) metals by other materials Reducing (c) the use of metal articles Recycling (d) used metals
Recycling conservation
10.
metals means melting down used metals and using them again.
12
11.1
The lowest temperature at which the reaction starts The rate (speed) of reaction
Add a magnesium ribbon to water at 25C; add iron powder to dilute hydrochloric acid at 80C; observe which metal gives out gas bubbles faster.
1. 2. 3.
11.2
Most metals combine with oxygen to form oxides when they are heated in air. The reactions of some common metals with air are summarized in Table Metal
Potassium
(b) The equations provided in Section 11.2 only appear in the Teachers 11.1. Edition. After learning equations, students should, in Activity, turn all the word equations in Section 11.2 into chemical equations.
11.1
Observation
It burns vigorously with a lilac (pale purple) flame to produce an orange powder.
Word equation
potassium + oxygen potassium superoxide (KO2) (KO2)
K(s) + O2(g) KO2(s)
Sodium
B U R N
gentle heating
Calcium
strong heating
Note 3 A little magnesium nitride Mg3N2 (pale yellow) is also formed. This
N2
Magnesium
strong heating
point need not be mentioned to students.
N3
13
Metal Metal
Aluminium
Observation Observation
Aluminium powder burns to give out much heat; a white powder forms.
Zinc
U R N
strong heating
Zinc powder burns to give out some heat; a powder (yellow when hot, white when cold) forms. ( )
zinc + oxygen
N4
2Zn(s) + O2(g)
Iron
strong heating
Iron powder burns with yellow showery sparks to produce a black solid.
Lead
D O N O T B U R N
strong heating
It melts to silvery balls; a powder (orange when hot, yellow when cold) is seen on the surface. ( )
N4
Copper
copper + oxygen 2Cu(s) + O2(g) copper(II) oxide (CuO) 2CuO(s) (II) (CuO) mercury + oxygen 2Hg( ) + O2(g) 2HgO(s) mercury(II) oxide (HgO) (II) (HgO)
Mercury
A red powder forms on the surface. No apparent change even on very strong heating.
Silver
N O R E A C T I O N
Platinum
Gold
14
Figure 11.1 summarizes the reactivity of common metals with air (oxygen). ( )
11 . 1
Metal
Potassium Sodium Calcium ,K , Na , Ca , Mg , Al
burn
Iron Lead
Platinum Gold
, Au
The resultant solution is alkaline because potassium hydroxide is formed. It will turn red litmus blue.
15
When we add a small piece of sodium to water, it moves N6 about on the surface of water. It burns with a golden yellow flame and becomes smaller and smaller. The resultant solution is alkaline because sodium hydroxide is formed: sodium + water
2Na(s) + 2H2O( )
hydrogen gas
hydrogen gas
A milky suspension is produced as the white calcium hydroxide formed is only slightly soluble in water. calcium + water
Ca(s) + 2H2O( )
+
16
( + +
With steam, however, the reaction is vigorous. We can carry out the experiment using a set-up as shown in Figure 11.3.
wet sand magnesium ribbon delivery tube heat
11.3
hydrogen water
trough
With strong heating, the water in the wet sand turns into steam. The steam then reacts with magnesium to give an intense white light. A white solid product, magnesium oxide, is formed. magnesium + steam
Mg(s) + H2O(g)
Zinc and iron do not react with cold or hot water. Heated zinc or iron reacts with steam in a similar way as magnesium does. However, the reaction is less vigorous for zinc, and even less for iron.
Zn(s) + H2O(g) ZnO(s) + H2(g)
+ (II
+ III) +
Aluminium does not seem to react with steam. This is because aluminium metal is usually covered with a very thin N7 layer of aluminium oxide. The oxide layer protects the metal N8 from reaction. If the protective oxide layer is removed by some method, the aluminium obtained would be more reactive than zinc, but less reactive than magnesium. Lead, copper, mercury, silver and gold, even if heated strongly, have no reaction with steam. Figure 11.4 summarizes the reactivity of common metals towards water.
17
11.4
Metal
Potassium Sodium Calcium ,K , Na , Ca , Mg , Al
Equation
metal + water metal hydroxide + hydrogen
Magnesium
Note 9 Point out to students that heated magnesium, aluminium, zinc and iron react with steam to form metal oxides, not hydroxides.
N9
, Hg , Ag , Pt
Silver
Platinum Gold
, Au
A11.1 Rubidium hydroxide. As can be seen from Figure 11.4, very reactive metals (e.g. K, Na, Ca) react with water to form a metal hydroxide and hydrogen; fairly reactive metals form a metal oxide and hydrogen. Rubidium should be more reactive than potassium, since it is lower than potassium in Group I. (The reactivity of Group I elements increases down the group.) Thus rubidium should form rubidium hydroxide, not rubidium oxide.
11.1
Reactions of metals with dilute hydrochloric acid and dilute sulphuric acid
11.5 Figure 11.5 shows the reactivity of common metals towards N10 dilute hydrochloric acid or dilute sulphuric acid.
Learning tip Potassium or sodium reacts with dilute acids explosively, so NEVER attempt to perform this experiment in a school laboratory.
Note 10 Dilute sulphuric acid forms insoluble sulphates (such as CaSO4, PbSO4) which would stop the reaction after a short while; dilute nitric acid is not a typical acid towards metals (as it has oxidizing properties).
18
Metal
Potassium Sodium Calcium
Reactivity of metals towards dilute hydrochloric /sulphuric acid decreases
Equation
metal + hydrochloric acid metal chloride + hydrogen or metal + sulphuric acid metal sulphate + hydrogen
explosive reaction
Figure 11.5 The reactivity of common metals towards dilute hydrochloric acid/dilute sulphuric acid.
Mercury Silver
, Hg , Ag , Pt no reaction
Platinum Gold
, Au
Reactive metals react with dilute hydrochloric acid and sulphuric acid to give salts and hydrogen.
Zinc reacts with both concentrated and dilute sulphuric acid to give out hydrogen gas. Zinc reacts with concentrated sulphuric acid to give out sulphur dioxide rather than hydrogen gas. (Details will be discussed in Chapter 31.)
( )
19
11.3
( 11.6)
,K , Na , Ca , Mg , Al
most reactive
, Zn , Fe , Pb , Cu , Hg , Ag , Pt
decreasing reactivity
Iron Lead
N12
Platinum Gold
, Au
least reactive
Metals at the top of the series are the most reactive; those at the bottom are the least reactive.
20
11.2
Metal A burns with a brick-red flame B forms a black powder C burns with a lilac flame D burns with a dazzling white flame
moderate reaction
no reaction
no reaction
fast reaction
no reaction
fast reaction
(a) Arrange the four metals in decreasing order of reactivity. (b) Give possible names of the four metals.
(a)
(b)
11.4
( When magnesium burns in air (or oxygen), magnesium oxide is formed. We can represent this reaction by a word equation: magnesium + oxygen
reactants (reacting substances)
) ) +
magnesium oxide
product (the substance produced)
11.7)
O O Note 13 A cation is smaller than the atom from which it is derived; an anion is larger than the atom from which it is derived.
Mg
Mg
2 magnesium atoms 2
Mg
2+
Mg
2+
N13
Figure 11.7 The formation of magnesium oxide in terms of particles 2 atoms of Mg react with 1 molecule of O22 form to 2+ 2 formula units of MgO. (1 formula unit of magnesium oxide consists of 1 magnesium ion, Mg and 1 oxide ion, O .) Mg O2 2+ 2 MgO ( MgO (Mg ) (O ) )
21
We may also represent the reaction by writing a chemical equation: 2Mg(s) + O2(g)
reactants
2MgO(s)
product
2Mg(s) + O2(g)
2MgO(s)
Mg
O2 MgO
22
11.3
SO2(g) + 2NaOH(aq)
A11.3 1 molecule of sulphur dioxide gas reacts with 2 formula units of aqueous sodium hydroxide, to produce 1 formula unit of aqueous sodium sulphite and 1 molecule of liquid water. Note 17 Point out to students that it is often simpler to represent a reaction by a chemical equation than written description (as shown in Q11.3). An equation also gives information about the composition of the substances involved, from their formulae.
Generally, an equation must be balanced with respect to (1) the number of atoms of any kind and (2) the net ionic charges. The numbers before the formulae of reactants and products in a balanced equation are called stoichiometric coefficients. 2Mg(s) + O 2 (g) 2MgO(s) is a balanced equation. The 2Mg(s) + O2(g) 1 O2 1O2 2MgO(s) 2 1 stoichiometric coefficients are 2, 1 and 2 respectively. Note that 1 is understood and should be left out thus O2 is written instead of 1O2. (2)
(1)
11.4
2CO(g) + O2(g) (a) (i) (b) (i) (c) (ii) (ii) 2CO2(g)
(b) How many oxygen atoms are on the (i) left-hand side (c) Is it a balanced equation? (ii) right-hand side of the arrow?
indicates that the reaction goes one way only. At the end, all reactants react to form products.
23
is used in some equations, e.g. means that the reaction N18 ( 2NH 3 (g))
N 2 (g) + 3H 2 (g) ( )
2NH3(g). The
is reversible, that is, both forward (left to right) and backward (right to left) reactions occur at the same time. At the end, both reactants and products are present. )
The steps in writing an equation are shown below, with an example for illustration. hydrogen + oxygen water +
In balancing equations, stoichiometric coefficients must be placed in front of formulae where necessary. The formulae themselves must not be changed. Thus, for the above reaction, it would be incorrect to write H2(g) + O2(g) or H2(g) + O(g) H2O2( ), H2O( ).
H2O2( ) H2O( )
Learning tip It is a common practice to write an equation in which coefficients are the smallest possible whole numbers. That is why the equation 2H2(g) + O2(g) 2H2O( ) is shown here.
2H2(g) + O2(g)
2H2O( )
24
Problem-solving strategy
Writing a chemical equation Step 1 Find out what the reactants and products are. Write down the word equation for the reaction. hydrogen + oxygen water ( ) 2 H2 + O2
(
(After some practice, you will be able to skip this step.) Step 2 Write the equation by replacing names of reactants and products with their correct formulae. H2 + O2 H2O
(unbalanced)
H2O
)
Step 3 Balance the equation with respect to atoms of any kind. To balance the number of oxygen atoms: 2 oxygen atoms on the left-hand side, only 1 oxygen atom on the right-hand side, so put 2 before H2O; the equation is still unbalanced H2 + O2 2H2O To balance the number of hydrogen atoms: 2 hydrogen atoms on the left-hand side, 4 hydrogen atoms on the right-hand side, so put 2 before H2; the equation is now balanced 2H2 + O2 2H2O Step 4 Write the state symbol after each formula to give the complete balanced equation. 2H2(g) + O2(g) 2H2O( )
N19
H 2O 2 H2 + O2 2H2O
H2 2 2H2 + O2 4 2H2O
Note 19 In public examinations, candidates usually need not write state symbols in equations, unless they are instructed to do so in the question.
A11.5 1. (a) 2 Cl atoms, 7 O atoms (b) 2 N atoms, 8 H atoms, 2 Cr atoms, 7 O atoms (c) 6 Fe atoms, 9 S atoms, 36 O atoms (d) 6 Na atoms, 3 C atoms, 39 O atoms, 60 H atoms 2. 2Pb3O4(s) 6PbO(s) + O2(g)
2H2(g) + O2(g)
(
2H2O( )
)
11.5
N20
2.
(a) Cl2O7 (b) (NH4)2Cr2O7 (c) 3Fe2(SO4)3 (d) 3Na2CO3 10H2O 2. __________ Pb3O4(s)
__________ Pb3O4(s)
Note 20 Students may get confused about (1) the subscript after an atomic symbol, e.g. 3Fe 2 (SO 4 )3 (2) the subscript after brackets, e.g. 3Fe2(SO4) 3 and (3) the stoichiometric coefficient in front of a formula, e.g. 3 Fe2(SO4)3. Explain to students how to calculate the number of atoms of each kind.
11.5 Metal reactivity series and the tendency of metals to form positive ions
Metals react by losing electrons
Metals react by losing electrons to form positive ions.
11.5
11.8
Figure 11.8 Readiness to lose electrons (and hence reactivity of metals) decreases across a period and increases down a group. ( )
A metal higher in the reactivity series has a higher reactivity, and its atoms would lose outermost shell electrons to form cations more easily.
26
11.6
Cu(NO3)2(aq) + 2Ag(s)
pale blue
Cu(s) + 2AgNO3(aq)
Cu(NO3)2(aq) + 2Ag(s)
We say that copper displaces the silver metal from the silver nitrate solution.
(II)
(II)
FeSO4(aq) + Cu(s)
pale green reddish brown
Fe(s) + CuSO4(aq)
FeSO4(aq) + Cu(s)
On the other hand, if we put a piece of copper into iron(II) sulphate solution, no reaction occurs.
(II)
A metal (M1) higher in the reactivity series will displace any metal (M 2 ) lower in the series from the solution of a compound of M2. (M 2 )
(M 1 )
We may use the reactivity series to explain this rule. A metal higher in the reactivity series is more reactive, so its atoms lose electrons more readily to form cations. The cations of the less reactive metal would accept these electrons, forming back the atoms of the less reactive metal.
Note 22 Suppose a student is asked to describe a simple experiment to compare the reactivity of copper and iron. The displacement reaction here can be quoted. However, it would be wrong to quote the example of setting up an electrolytic cell. With an external electric current applied, the relative reactivity of the two metals cannot be compared. Note 23 Remind students to write the appropriate equations in examinations. If the question asks for a balanced chemical equation, either the full equation or ionic equation (if applicable) can be put down. But if it asks for an ionic equation, only the ionic equation will be accepted.
27
Example 11.1 Predicting chemical reactions based on the metal reactivity series
Predict, with reasoning, whether a reaction takes place in each of the following: (a) Zinc is added to magnesium chloride solution. (b) Magnesium is added to lead(II) nitrate solution. (c) Silver is added to dilute sulphuric acid. State what type of reaction (if any) takes place and write an appropriate equation for the reaction. Solution (a) No reaction occurs. Zinc is lower than magnesium in the metal reactivity series. (b) Displacement reaction occurs. Magnesium is higher than lead in the metal reactivity series. It can displace lead from lead(II) nitrate solution. Mg(s) + Pb(NO3)2(aq) (c) Mg(NO3)2(aq) + Pb(s) No reaction occurs. All metals lower than copper in the metal reactivity series would have no reaction with dilute sulphuric acid. (a) (b)
11.1
19
11.7
Consider the reaction between copper metal and aqueous silver nitrate solution. The equation for the reaction is: Cu(s) + 2AgNO3(aq) Cu(NO3)2(aq) + 2Ag(s) Cu(s) + 2AgNO3(aq) Cu(NO3)2(aq) + 2Ag(s)
28
Cu (aq) + 2Ag(s)
2+
Cu (aq) + 2Ag(s)
2+
shows more clearly what has happened. Note that the nitrate ions (NO3 ) remain unchanged in the reaction. These ions, which do not actually take part in a reaction, are called spectator ions. They do not appear in ionic equations. (NO3 )
Problem-solving strategy
Writing an ionic equation Step 1 Write the full balanced equation for the reaction. Cu(s) + 2AgNO3(aq) Step 2 Rewrite the equation: Cu(NO3)2(aq) + 2Ag(s) 1 Cu(s) + 2AgNO3(aq) Cu(NO3)2(aq) + 2Ag(s) 2 Cu(NO 3) 2 AgNO 3
AgNO 3 and Cu(NO 3) 2 are electrolytes in aqueous solution. Cu(s) + 2Ag (aq) + 2NO3 (aq) 2+ Cu (aq) + 2NO3 (aq) + 2Ag(s) Step 3 Cancel out the spectator ions on both sides of the equation. Cu(s) + 2Ag (aq) + 2NO3 (aq) 2+ Cu (aq) + 2NO3 (aq) + 2Ag(s) Step 4 Check that the ionic charge is balanced in the ionic equation. Cu(s) + 2Ag (aq)
net charge = +2
+ + +
Cu(s) + 2Ag (aq) + 2NO3 (aq) Cu (aq) + 2NO3 (aq) + 2Ag(s) 3 Cu(s) + 2Ag (aq) + 2NO3 (aq) Cu (aq) + 2NO3 (aq) + 2Ag(s) 4 Cu(s) + 2Ag (aq)
= +2
+ 2+ + 2+ +
Cu (aq) + 2Ag(s)
net charge = +2
2+
Cu (aq) + 2Ag(s)
= +2
2+
29
11.2
(a) Pb(s) + CuSO4(aq) PbSO4(aq) + Cu(s) (b) Zn(s) + 2AgNO3(aq) Zn(NO3)2(aq) + 2Ag(s)
2+
Cancel out the spectator ions on both sides of the equation: Pb(s) + Cu (aq) + SO4 (aq)
2+ 2
2+
The ionic charge is balanced on both sides of the equation. Thus, the ionic equation is: Pb(s) + Cu (aq)
net charge = +2
2+
Pb (aq) + Cu(s)
net charge = +2
2+
2+
Pb (aq) + Cu(s)
= +2
2+
= +2
(b) Zn(s) + 2Ag (aq) + 2NO3 (aq) Zn (aq) + 2NO3 (aq) + 2Ag(s)
+ 2+ +
Cancel out the spectator ions on both sides of the equation: Zn(s) + 2Ag (aq) + 2NO3 (aq)
+
2+
The ionic charge is balanced on both sides of the equation. Thus, the ionic equation is: Zn(s) + 2Ag (aq)
net charge = +2
+
Zn (aq) + 2Ag(s)
net charge = +2
= +2
2+
Zn (aq) + 2Ag(s)
= +2
2+
30
11.3
6 ClO3
A11.6 + (a) Mg(s) + 2Ag (aq) 3+ (b) 3Mg(s) + 2Al (aq) Mg (aq) + 2Ag(s) 2+ 3Mg (aq) + 2Al(s)
2+
11.6
(a) Mg(s) + 2AgNO3(aq) Mg(NO3)2(aq) + 2Ag(s) (b) 3Mg(s) + 2Al(NO3)3(aq) 3Mg(NO3)2(aq) + 2Al(s)
11.8
31
10.2 ( )
latest
,K , Na , Ca , Mg , Al
most reactive
Magnesium Aluminium Order of discovery Zinc Iron Lead Copper Mercury Silver earliest , Zn , Fe , Pb , Cu
Reactivity
, Hg , Ag , Pt least reactive
Platinum Gold
, Au
32
Example 11.4 Relating the extraction method of a metal to its position in the metal reactivity series
Some information about the extraction methods of five different metals A, B, C, D and E are listed as follows:
11.4
Metal A B C D
Extraction method Mechanical separation Carbon reduction Electrolysis Displacement from solution by metal E
E D
Arrange the positions of metals in the metal reactivity series based on the above information, from the lowest to the highest. Explain your answer. Solution Mechanical separation is the easiest way to extract a metal from its ore. Thus, metal A must be the least reactive (i.e. the lowest in the metal reactivity series). Metal D should be in a position higher than that of A, but lower than that of E as it can be displaced out from its solution by E. Metal C should be in the highest position among the five metals since it is the most difficult to be extracted. Metal B should be in a position higher than that of E since it is extracted by carbon reduction. The positions of five metals in the metal reactivity series should be: A<D<E<B<C A<D<E<B<C A ( D A E ) E
C B E
33
11.7
(
(b)
(III) +
(b)
A11.7 1. (a) (b) 2. (a) (b) Yes. Magnesium is more reactive than iron. No. Magnesium is much more expensive than iron. 4Fe(s) + 3CO2(g) 2Fe2O3(s) + 3C(s) 2AgO(s) 2Ag(s) + O2(g)
Key terms
Page 1. balanced equation 2. chemical equation 3. displacement reaction 4. ionic equation 5. one-way reaction 6. reactivity 7. reversible reaction 8. spectator ion 9. stoichiometric coefficient ( ) 23 22 27 28 23 13 23 29 23
34
Summary
11.1 Different reactivities of metals 1.
Reactivity
11.2 Comparing reactivity of common metals 2. The reactivity of metals can be found by comparing their reactions with air, water and dilute acids. Refer to p.13 19 for the results of the reactions.
The following table summarizes the appearances and reactions of metals in the reactivity series. Reaction of metal with
Metal
Appearance of metal
dull (stored under paraffin oil)
air
burns violently, forming oxide (Example 1)
water/steam
Displacement reactions
not applicable these 3 metals react with water in aqueous solution to give H2 gas
K Na Ca Mg Al
metal + water reacts explosively, forming metal metal chloride and hydroxide hydrogen (Example 6) + hydrogen no reaction (Example 4) reacts with decreasing vigour: metal + hydrochloric acid metal chloride + hydrogen reduced with increasing ease: (Example 7) metal oxide + carbon metal + carbon dioxide (Example 8) no reaction decomposed to metal and oxygen by heating alone (Example 9)
generally dull
Zn Fe Pb Cu Hg
generally shiny
reacts with metal + steam decreasing metal oxide vigour, forming + hydrogen oxide (Example 2) (Example 5)
a metal displaces any other metal lower in the series from a solution of its compound (Example 10)
no reaction
Ag Au
no reaction
4Na(s) + O2(g) 2Ca(s) + O2(g) 2Cu(s) + O2(g) 2Na(s) + 2H2O( ) Zn(s) + H2O(g) 2K(s) + 2HCl(aq)
2Na2O(s) 2CaO(s) 2CuO(s) 2NaOH(aq) + H2(g) ZnO(s) + H2(g) 2KCl(aq) + H2(g) (NEVER attempt this experiment!)
35
2Hg( ) + O2(g)
6. 7.
reversible
The steps in writing a chemical equation are shown in Problem-solving strategy on p.25.
11.5 Metal reactivity series and the tendency of metals to form positive ions 8.
losing Metals react by electrons to form cations. Different metals have different reactivities because they have different tendencies to lose electrons. Atoms of a reactive metal lose electrons readily.
in the reactivity series will displace any one (M2) in the series from the solution of a compound of M2. This is because a more reactive metal loses electrons more easily.
higher
as
11.8 Extraction of metals from their ores 12. 13. The ease of extracting a metal from its ores is related to the reactivity series.
position
lower The a metal in the reactivity series, the earlier it was first discovered. This is less because less reactive metals form stable compounds, from which the metals can be extracted more easily.
36
12.1
MgCl2
Mg
2+
Cl
Chemists use a very special unit, called mole (abbreviation: mol) to show the number of formula units. One mole contains a N1 large number of particles, 6.02 10 . This number is called 10 mol .
23 1 23
N2
10 (L)
23
L = 6.02
To count by weighing
We can count indirectly by weighing.
Note 2 (a) Determination of L using different methods leads to values which are very close to each other. 23 23 The most recent values lie between 6.022 24 10 and 6.022 80 10 . By approximation, 23 1 we take L = 6.02 10 mol . (b) At one time, L was referred to as the Avogadro number. Now the term Avogadro constant is used as its value is constant.
12.1
(Given that the mass of a $1 coin = 7.08 g; the mass of one 22 copper atom = 1.05 10 g) Solution (a) Weigh out 7.08 coins. (b) Weigh out 1.05 copper metal. 50 000 = 354 000 g or 354 kg of $1 10
22
(3.01
10 ) = 316 g of pure
24
(a) (b)
(3.01
10 ) =
37
24
12.1
1 1.204
23
108 g 10
23
silver atoms.
= 1.204 10 23 6.02 10 = 0.200 mol Molar mass of silver (Ag) 1 = 108 g mol
Defining mole
A12.1 1 mole of silver contains 6.02 23 10 silver atoms. number of moles of silver atoms = number of atoms/L
One mole (mol) of a substance (or species) represented by a formula is the amount containing the same number of formula units as the number of atoms in exactly 12.0 g of carbon-12.
mass of pure silver metal to be weighed out (for counting indirectly) = number of moles molar mass = 0.200 108 g = 21.6 g
( ) 12.0 g -12
Note 3 Species has a broader sense than substance. Sodium chloride is a species and also a substance, but chloride ion is a species, not a substance. Chloride ions alone cannot be isolated.
One mole of a substance (or species) has a mass corresponding N3 to its formula mass expressed in gram unit. The molar mass of a substance is the mass in grams of one mole of the substance. (Unit of molar mass: g mol )
Note 4 Remind students that the abbreviation of mole is mol (not m); that of gram is g (not gm).
1
N4
( g mol )
1
For example, the molar mass of carbon dioxide is 44.0 g mol ; that of water (H2O) is 18.0 g mol . Note: (a) The unit of molar mass is g mol . (b) The relative molecular mass (or formula mass) of carbon dioxide is just 44.0, not 44.0 g mol . We should notice that the mole can relate the mass of a substance to the number of formula units contained in the substance.
1 1 1 1
44.0 g mol
1 1
(H2O)
18.0 g mol
(a) mol
1
g ( 44.0 g mol
1
(b) 44.0
mass
NUMBER OF MOLES
(mol) = (mol )
1
38
12.2
1. (a) Fe2(SO4)3
A12.2 1. (a) 55.8 2 + (32.1 + 16.0 4) 3 = 399.9 1 (b) 399.9 g mol (c) 399.9 0.2000 = 79.98 g
2.
27.0 g
= 0.250 mol Number of silver atoms = number of moles L 23 = 0.250 (6.02 10 ) 23 = 1.51 10
Based on definition of mole, we can get the following important relationships: (1) Mass of 1 mole of a substance or species (g) formula mass expressed in gram unit mass (g) molar mass (g mol ) number of formula units Avogadro constant (mol )
1 1
(1) =
N5
(g)
(2) Number of moles (mol) = (3) Number of moles (mol) = (4) Mass of 1 formula unit (g) = molar mass (g mol )
1
(2) = (3) =
12.2
44.44 g (a) CaCl2 (b) CaCl2 (c) (d) (e) CaCl2 CaCl2 Cl
CaCl 2
39
Solution (a) Formula mass of CaCl2 = 40.1 + 35.5 (b) Molar mass of CaCl2 = 111.1 g mol (c)
1
2 = 111.1
N6 N7
2
1
Number of moles of CaCl2 = 1 molar mass (g mol ) 44.44 = mol 111.1 = 0.4000 mol = number of moles (mol) = 0.4000 = 2.41 10 6.02
23
mass (g)
= 111.1 g mol
10
23
= 0.4000 mol
(e)
Since 1 formula unit of CaCl2 contains 2 Cl ions, number of Cl ions = 2.41 = 4.82 10 10
23 23
10
23
Note 6 (a) Remind students again that formula mass has no unit, while molar mass has the 1 unit of g mol . (b) Tell students not to use as the multiplication sign . Thus it is 35.5 2, not 35.5 2.
Note 7 (a) Remind students to write the subject of an expression clearly. Thus it is Molar 1 mass of CaCl 2 = 111.1 g mol , not 1 CaCl2 = 111.1 g mol . (b) Do not write gm for g, m or M for mol.
Cl
12.3
( )
(
N8
g g
cont'd
(g mol ) (mol )
1
Note 8 It is a good practice to write a unit for each separate line (if applicable).
g g
40
(b) Mass of 1 H2O molecule = 1.0 2 + 16.0 g 23 6.02 10 = 2.99 (c) Mass of 1 formula unit of NaCl = 10
23
(b) = g g (c) =
g 10 10
23
= 2.99
10
g g
g (d)
= 9.72 SO4 =
A12.3 1. (a) 0.200 35.5 = 7.10 g (b) 0.200 (35.5 2) = 14.2 g (c) 1.20 mol of chlorine (Cl 2) contains the same number of molecules as 1.20 mol of water (H2O). Mass of chlorine = 1.20 (35.5 2) g = 85.2 g 2. (a) Molar mass of sodium hydroxide (NaOH) 1 = 23.0 + 16.0 + 1.0 g mol 1 = 40.0 g mol Mass of NaOH = 0.250 40.0 = 10.0 g
Number of formula units of NaOH 23 = 0.250 6.02 10 23 = 1.51 10 (b) Since helium is monoatomic, molar mass of 1 He = 4.0 g mol . 0.20 Number of moles of He molecules = mol 4.0 = 0.050 mol Number of He molecules = 0.050 6.02 22 = 3.0 10 10
23
4 g
= 1.60
10
12.3
Mass
(g)
23
(c) Molar mass of sulphur dioxide (SO2) 1 = 32.1 + 16.0 2 g mol 1 = 64.1 g mol Number of moles of SO2 = 3.01 1023 mol 6.02 10 = 5.00 mol
24
(d) Number of moles of X 23 = 3.01 1023 mol 6.02 10 = 0.500 mol Molar mass of X 23.0 1 = g mol 0.500 = 46.0 g mol
1
41
12.2
A A = A
Percentage by mass of element A in a compound relative atomic mass of A no. of atoms of A in formula = formula mass of the compound
A A 100% = A 100%
12.4
(II) CuSO4 5H2O
CuSO4 5H2O Cu S O4 = 63.5 + 32.1 + 16.0 4 + 5 + 16.0) = 249.6 Cu Cu 100% = = Cu CuSO4 5H2O 63.5 249.6 100% 100% 5H2O (1.0 2
= 25.4%
Calculate the percentage by mass of sulphur, oxygen and hydrogen in copper(II) sulphate-5-water, CuSO4 5H2O.
42
12.5
15.0 g (II)
= CuSO4 5H2O CuSO4 5H2O = CuSO4 5H2O 5 H2O CuSO4 5H2O = 15.0 g = 5.41 g 5 (1.0 2 + 16.0) 249.6
= 15.0 g = 5.41 g
2 + 16.0)
Self-Test 12.5 Mass of water crystallization 4 (1.0 2 + 16.0) = 20 g (55.8 + 35.5 2) + 4 (1.0 2 + 16.0) = 7.24 g
249.6
Self-Test 12.5
20 g
FeCl 2 4H 2 O
12.6
M M M MCl3 34.4%
a 1 a a + 35.5 3 55.8
43
a = 55.8
a = 55.8
Self-Test 12.6
Self-Test 12.6 Let the relative atomic mass of X be a. relative atomic mass X 1 Fraction by mass of X in XBr2 = formula mass of XBr2 25.6 a = 100 a + 79.9 2 a = 55.0
The bromide of a metal X has the formula XBr2 and contains 25.6% by mass of X. Find the relative atomic mass of X.
A12.4 1. Number of moles of Na number of moles of NaNO3 = 4.35 mol 100 = mol = 4.35 mol Mass of NaNO3 23 Since number of moles of Na : number of moles of NaNO3 = 1 : 1 = 4.35 (23.0 + 14.0 + 16.0 3) g = 369.75 g % by mass of N in NaNO3 14.0 100% = 16.5% = Class practice 12.4 23.0 + 14.0 + 16.0 3 Mass of N = 369.75 g 16.5% = 61.0 g
X X 25.6%
XBr 2 X
12.4
1. 2. 100 g 4.6 g (Na2CO3 10H2O) 3. MO 79.87% 4.
100%
1. 2.
What is the mass of nitrogen present in the sample of sodium nitrate (NaNO3) which contains 100 g of sodium? What is the mass of water of crystallization present in the sample of sodium carbonate-10-water (Na2CO3 10H2O) which contains 4.6 g of sodium? A metal oxide MO contains 79.87% by mass of the metal M. Find the relative atomic mass of M. 26.88 g of a metal chloride MCl contains 5.68 g of chlorine. Find the relative atomic mass of the metal M.
% by mass of H2O in Na2CO3 10H2O = (23.0 10 (1.0 2 + 16.0) 2 + 12.0 + 16.0 3 + 10 (1.0 2 + 16.0))
(NaNO3)
3. 4.
M M MCl M
2. Number of moles of Na =
4.6 mol = 0.2 mol 23.0 Since number of moles of Na : number of moles of Na2CO3 10H2O = 2 : 1 number of moles of Na2CO3 10H2O = 0.1 mol Mass of Na2CO3 10H2O = 0.1 (23.0 2 + 12.0 + 16.0 3 + 10 (1.0 2 + 16.0)) g = 28.6 g
26.88 g 5.68 g
3. Let the relative atomic mass of M be a. Fraction by mass of M in MO relative atomic mass of M 1 = formula mass of MO
12.3
Ionic formula
N9
The ionic formula of an ionic compound is the formula which shows the simplest whole number ratio of the ions present, and also the charges carried by them.
but not + Mg(s) + 2Ag NO3 (aq) Mg (NO3 )2(aq) + 2Ag(s)
2+
Molecular formula
The molecular formula of a substance shows the actual number of each kind of atoms in one molecule of the substance. It is only applicable to molecular compounds and elements consisting of molecules.
44
4. % by mass of Cl in MCl = 5.68 100% = 21.13% 26.88 % by mass of M in MCl = 100% 21.13% = 78.87% Let the relative atomic mass of M be a. Fraction by mass of M in MCl relative atomic mass of M 1 = formula mass of MCl 78.87 a = 100 a + 35.5 a = 132.5
Structural formula
The structural formula of a molecular substance is the formula which shows how the constituent atoms are joined up in one molecule of the substance. The following flow chart (Figure 12.1) shows the sequence and methods by which the various types of formulae are found.
Example magnesium chloride (an ionic compound) ( ) qualitative analysis Example ethanoic acid (a molecular compound) ( )
12.1)
Mg, Cl
C, H, O
quantitative analysis (to find composition by mass) ( ) MgCl2 for ionic compounds Empirical formula CH2O for molecular compounds
Mg (Cl )2
2+
Ionic formula
Molecular formula
C2H4O2
Structural formula
H H C H
O C O H
Some examples of empirical, ionic, molecular and structural formulae of a few substances are given in Table 12.1.
12.1
45
Substance
Nitrogen Carbon dioxide
Empirical formula
CO2 CH2
Ionic formula
Molecular formula
N2 CO2 C2H4
Structural formula
N N O=C=O
H H H C C H
Ethene
H H H
Propene
CH2
C3H6
H C H
H H
Ethanol
C2H6O
C2H6O
H C
O H
H H H H O C H H
Methoxymethane
C2H6O
C2H6O
H C H
NH4Cl
NH4 Cl
FeSO11H14
2 2+ Fe SO4 . 7H2O
K2Cr2O7 SiO2
(K )2Cr2O7
We should note that the empirical and molecular formulae of a compound may be the same (e.g. carbon dioxide) or different (e.g. ethene). The molecular formula is the empirical formula multiplied by some whole number (1, 2, 3, etc.). Even different compounds may have the same empirical formula and same molecular formula (e.g. ethanol and methoxymethane). But they have different structural formulae. ( ) ) ( 1 2 3 ) ( ) (
46
12.5
-1H H C H H C H H C H C H
C H
Write down its (a) molecular formula and (b) empirical formula.
(a)
(b)
12.4
hole in test tube copper oxide town gas supply excess town gas burns here
heat
Figure 12.2 To find the empirical formula of copper oxide by passing town gas over the heated compound.
47
The empirical formula is worked out by changing the composition by mass to the simplest whole number mole ratio, as illustrated below: Specimen results Mass of test tube = 18.100 g = 18.100 g + + = 18.701 g = 18.579 g = (18.579 18.100) g = 0.479 g = (18.701 18.579) g = 0.122 g
Mass of test tube + copper oxide = 18.701 g Mass of test tube + copper Mass of copper in oxide = 18.579 g = (18.579 18.100) g = 0.479 g Mass of oxygen in oxide = (18.701 18.579) g = 0.122 g Calculations
Cu
O 0.122
Masses (in g)
mass in g ) molar mass
0.479
0.479
(mol)
63.5
= 0.007 54
0.122 16.0
= 0.007 63
0.007 54 0.007 54
0.007 63 =1 0.007 54
= 1.01 1
CuO
Example 2
( (
48
Figure 12.3 To find the empirical formula of magnesium oxide by heating magnesium in air.
tripod
From the experimental results, the empirical formula of magnesium oxide can be worked out to be MgO. Try the experiment yourselves.
2. Masses (in g) C 0.857 0.857 12.0 = 0.07142 H 0.143 0.143 1.0 = 0.143
MgO
12.6
1. 1.200 g 1.173 g 2. 1.000 g 0.857 g
empirical formula of the compound is CH2.
1.200 g of a compound containing only carbon, hydrogen and oxygen gave 1.173 g of carbon dioxide and 0.240 g of water on complete combustion. Find the empirical formula of the compound. A compound has the empirical formula CxHy. On analysis, 1.000 g of the compound is found to contain 0.857 g of carbon. Find the values of x and y.
Relative number of moles 0.07142 0.07142 =1 0.143 0.07142 2
0.240 g C xH y x y
2.
12.5
Example 12.7 Determining empirical formula and molecular formula using percentage by mass
Compound X was found to contain carbon and hydrogen only. Experiments showed that it contained 80% carbon and 20% hydrogen by mass. If its relative molecular mass was 30.0, find its empirical formula and molecular formula.
12.7
cont'd
49
Solution Assume there were 100 g of X, then there would be 80 g of carbon and 20 g of hydrogen.
C Masses (in g)
mass in g ) molar mass
100 g 20 g
H 20
80 g
80
(mol)
(= (g) )
80 = 6.7 12.0
20 = 20 1.0
6.7 =1 6.7
20 = 2.98 6.7
the empirical formula of X is CH3. Note: Experimental errors would probably result in a small difference from whole numbers. In calculating relative number of moles, it is an accepted practice to round off these values to the nearest whole numbers. However, care must be taken in doing so, e.g. 2.98 can be taken to be 3, but 2.8 is usually not taken as 3. Let its molecular formula be (CH3)n, where n is the whole number. Relative molecular mass of (CH3)n = 30.0 n(12.0 + 1.0 3) = 30.0 n=2 15.0n = 30.0 molecular formula of X is C2H6.
CH3
2.98 3 3 (CH3)n n (CH3)n n(12.0 + 1.0 = 30.0 3) = 30.0 15.0n = 30.0 n=2 X C2H6 2.8
Example 12.8 Determining empirical formula and molecular formula using masses of combustion products
A compound Y containing only carbon, hydrogen and oxygen burned completely in air to form carbon dioxide and water as the only products. 2.43 g of Y gave 3.96 g of carbon dioxide and 1.35 g of water. Find the empirical formula of Y. If its relative molecular mass was 160, find also its molecular Note 10 formula. N10
Refer to Supplementary information: Combustion analysis of organic compounds in the Teachers Guide.
12.8
3.96 g Y
cont'd
50
Solution Since all the C in CO 2 and H in H 2 O came from the compound, 12.0 mass of C in the compound = 3.96 g 12.0 + 16.0 2 = 1.08 g; 1.0 2 mass of H in the compound = 1.35 g 1.0 2 + 16.0 = 0.15 g The rest of mass of the compound must come from oxygen. mass of O in compound = (2.43 1.08 0.15) g = 1.20 g Now go on to find the empirical formula as follows: CO 2 C = 3.96 g H = 1.35 g 1.0 1.0 2 2 + 16.0 O = (2.43 1.08 0.15) g = 1.20 g = 0.15 g 12.0 12.0 + 16.0 2 = 1.08 g C H 2O H
C Masses (in g)
mass in g ) molar mass
H 0.15
O 1.20
1.08
(mol)
(= (g) )
0.15 =2 0.075
0.075 =1 0.075
(multiplied by the smallest possible whole number (5 here) to turn all values into whole numbers) ( ( ) )
1.2
5=6
5 = 10
5=5
Note: We should not take 1.2 to be equal to 1, because we cannot allow for so large an experimental error. empirical formula of compound is C6H10O5. Let its molecular formula be (C6H10O5)n, where n is a whole number. Relative molecular mass of (C6H10O5)n = 160 n(12.0 6 + 1.0 10 + 16.0 5) = 160 162n = 160 n = 0.988 1 molecular formula of compound Y is C6H10O5. n (C6H10O5)n n(12.0 6 + 1.0
1.2
1 C6H10O5 (C 6 H 10 O 5 ) n
Example 12.9 Determining molecular formula using empirical formula and relative molecular mass
A compound has an empirical formula CH2 and a relative molecular mass of 42. Find its molecular formula. Solution Let the molecular formula of the compound be (CH 2) n, where n is a whole number. Relative molecular mass of (CH2)n = 42 n(12.0 + 1.0 2) = 42 n=3 the molecular formula is (CH2)3, i.e. C3H6. C3H6
A12.7 Since all the C in CO2 and H in H2O came from the compound, 12.0 = 0.36 g mass of C in the compound = 1.32 g 12.0 + 16.0 2 mass of H in the compound = 0.45 g 1.0 2 = 0.05 g 1.0 2 + 6.0
12.9
CH2 42
The rest of the compound must be oxygen. Mass of O in compound = (0.81 0.36 0.05) g = 0.40 g
12.7
1.32 g
12.10
5.60 g nH 2 O) (II) (a) (b) n (a)
cont'd
Let its molecular formula be (C6H10O5)n, where n is a whole number. Relative molecular mass of (C6H10O5)n = 320 n(12.0 6 + 1.0 10 + 16.0 5 ) = 320 162n = 320 n =2 molecular formula of compound is C12H20O10.
(II) (CuSO 4
3.59 g
52
5 = 10
Solution (a) Mass of water of crystallization = (5.60 3.59) g = 2.01 g Formula mass of CuSO4 = 63.5 + 32.1 + 16.0 = 159.6 4 (a) CuSO4 = (5.60 3.59) g = 2.01 g = 63.5 + 32.1 + 16.0 4 = 159.6 = 1.0 2 + 16.0 = 18.0
H2O 2.01
H2O
3.59
(mol)
(= (g) )
0.0225 =1 0.0225
n should be a whole number. A reasonable value of n would therefore be 5. (b) The experimental value of n (4.98) is lower than 5. This might be due to two reasons: (1) (2) Not all water of crystallization has been removed in the heating process. Self-Test 12.10 crystallization = (9.99 5.41) g = 4.58 g Mass of water of Weighing had been delayed, so that the anhydrous salt had absorbed some moisture from the atmosphere. Formula mass of FeCl2 = 55.8 + 35.5 2 = 126.8
FeCl2 H2O 4.58 Mass (in g) 5.41
Self-Test 12.10
When 9.99 g of hydrated iron(II) chloride (FeCl2 nH2O) was heated in a crucible, 5.41 g of anhydrous iron(II) chloride was left. Find the value of n. Number of moles 5.41 4.58
126.8
= 0.0427
18.0
= 0.2544
0.0427 =1 0.0427
0.2544 6 0.0427
12.6
53
Problem-solving strategy
Calculating the reacting masses Step 1 Write down the balanced equation for the reaction. 2Mg(s) + O2(g) 2MgO(s) 2 ( Mg mass (g)
1
Step 2 Convert the amounts of given substances into mole quantities. (Assume that the mass of Mg is 2.43 g.) Molar mass of Mg = 24.3 g mol Number of moles of Mg =
1
Mg
2.43 g
)
1
Step 3 Calculate the mole quantities of the required substances using the ratio, as given by the stoichiometric coefficients of the equation. Since oxygen is in excess, all the Mg is changed to MgO. (Mg is called the limiting reactant in this case, as it is all used up. Obviously, amounts of products formed depend on the amount of the limiting reactant only.) From the equation, mole ratio of Mg : MgO = 2 : 2 = 1 : 1 Hence number of moles of MgO formed = 0.100 mol Step 4 Change the mole quantities of the required substances back into mass as required by the question. Molar mass of MgO = (24.3 + 16.0) g mol = 40.3 g mol mass of MgO formed = 0.100 = 4.03 g The steps taken are illustrated below: Given information of A Number of moles of A by ratio Number of moles of B Required information of B A
1 1
Mg Mg MgO ( Mg =2:2=1 1 MgO 0.100 mol 4 MgO 1 = (24.3 + 16.0) g mol 1 = 40.3 g mol MgO = 0.100 40.3 g = 4.03 g ) MgO = Mg
40.3 g
54
Study the following examples. Example 12.11 Calculations based on equation (with limiting reactant)
Calculate the mass of magnesium oxide formed when 2.43 g of magnesium are burnt with 1.28 g of oxygen. Solution Step 1: 2Mg(s) + O2(g) 2MgO(s)
1
12.11
2.43 g
1.28 g
1 2
2Mg(s) + O2(g) Mg Mg
= 2.43 mol 24.3 = 0.100 mol = 32.0 g mol = 1.28 mol 32.0 = 0.0400 mol Mg =2 1 2 O2
1
O2 O2
= 0.0400 mol Step 3: From the equation, mole ratio of Mg : O2 = 2 : 1. 0.0400 mol of O2 would react with 0.0400 0.0800 mol of Mg Since 0.100 mol of Mg is used, Mg is in excess. O2 is the limiting reactant in this case, as it is all used up. From the equation, mole ratio of O2 : MgO = 1 : 2, number of moles of MgO = 0.0400 mass of MgO formed = 0.0800 = 3.22 g 2 mol =1 = 0.0800 mol 40.3 g Mg
0.0400 mol O2 0.0400 = 0.0800 mol Mg 0.100 mol Mg O2 O2 O2 2 MgO = 0.0400 2 mol = 0.0800 mol MgO = 0.0800 40.3 g = 3.22 g MgO
Note 11 This example illustrates what to do if the mass given is not in g unit. Some students may just divide 1.59 by 79.5 to calculate number of moles of CuO.
12.12
N11
(II) ( kg
Cu(s) + H2O( )
cont'd
55
Solution The only substances involved in calculations here are CuO and Cu.
First method Step 1: CuO(s) + H2(g) 1 CuO(s) + H2(g) Cu(s) + H2O( ) Cu(s) + H2O( )
CuO Cu
Second method Since 1 mole of CuO produces 1 mole of Cu, 79.5 g of CuO produces 63.5 g of Cu, or 79.5 kg of CuO produces 63.5 kg of Cu. 1.59 79.5 )
Step 2: Mass of CuO = 1.59 kg = 1.59 1000 g = 1590 g Molar mass of CuO = (63.5 + 16.0) g mol 1 = 79.5 g mol Number of moles of CuO = 2 CuO CuO CuO = = 1.59 kg = 1.59 1000 g = 1590 g
1 1
1.59 kg of CuO produces (63.5 = 1.27 kg of Cu. 1 mol CuO 1 mol Cu 63.5 g Cu 63.5 kg Cu (63.5 1.59 79.5 )
1590 mol = 20.0 mol 79.5 Step 3: From equation, mole ratio of CuO : Cu = 1 : 1. number of moles of Cu = 20.0 mol mass of Cu produced = 20.0 63.5 g = 1270 g = 1.27 kg 3 Cu Cu CuO Cu =1 1 = 20.0 mol = 20.0 63.5 g = 1270 g = 1.27 kg
22
Example 12.13 Calculations based on equation (actual yield and theoretical yield)
5.91 g of iron was dissolved in excess dilute hydrochloric 2+ acid to give a solution containing Fe ions. The solution was 2+ then boiled with concentrated nitric acid to oxidize all Fe 3+ ions into Fe ions. Excess sodium hydroxide solution was 3+ added to precipitate all Fe ions as iron(III) hydroxide, Fe(OH)3. The precipitate was filtered off, washed, dried and finally heated to convert all into iron(III) oxide, Fe2O3.
12.13
Fe
3+
(III)
56
(a) Calculate the theoretical mass of iron(III) oxide obtained (the theoretical yield). (b) The mass of iron(III) oxide actually obtained from experiment (actual yield) was 7.95 g. Compare this with the theoretical mass in (a) and give two possible reasons for the difference. Solution (a) Step 1: The whole process may be represented by a sequence of steps: Fe 5.91 g Fe
2+
(a) ( (b) ( ) )
(a)
(a)
1
2+
Fe
3+
Fe(OH)3
Fe2O3 ?g
Fe Fe 5.91 g
Fe
3+
Fe(OH)3
Fe2O3 ?g
Step 2: To get the answer, one method is to write balanced equations for each of the reactions. 2+ 3+ From these, we can calculate masses of Fe , Fe and Fe(OH)3 in turn, and finally that of Fe2O3. A much simpler method is to write the overall expression representing the mole ratio of the given substance (Fe) and the required substance (Fe2O3), without writing any equations: 2Fe Fe 2O 3 (the 2 before Fe is added to balance number of Fe atoms) Thus mole ratio of Fe : Fe2O3 = 2 : 1. Molar mass of Fe = 55.8 g mol
1
Fe Fe(OH) 3 Fe2O3
2+
Fe
3+
(Fe) (Fe 2 O 3 )
Fe2O3 (Fe Fe Fe 2 O 3
Number of moles of Fe used = 5.91 mol 55.8 = 0.106 mol 0.106 mol Step 3: Number of moles of Fe2O3 formed = 2 = 0.0530 mol theoretical mass of Fe2O3 formed = 0.0530 159.6 g = 8.46 g (b) The actual yield (7.95 g) is smaller than the theoretical yield (8.46 g). Possible reasons are: (1) Iron used might be impure. (2) There was loss of materials during the various experimental processes, e.g. filtration. (b) g) (1) (2) )
=
1
Fe 5.91 = 55.8 mol = 0.106 mol Fe2O3 3 0.106 = mol = 0.0530 mol 2 Fe2O3 = 0.0530 159.6 g = 8.46 g (7.95 g) (8.46
(
57
12.8
1.5 g
Key terms
1. actual yield
Number of moles of Ca(OH)2 formed = 0.0374 mol theoretical mass of Ca(OH)2 formed = 0.0374 74.1 g = 2.77 g (c) (1) Calcium used might be impure. (2) There was loss of material during the various experimental processes, e.g. filtration.
Page 56 37 47 44 42 44 54 38 37 44 42 45 56
2. Avogadro constant 3. composition by mass 4. empirical formula 5. fraction by mass 6. ionic formula 7. limiting reactant 8. molar mass 9. mole 10. molecular formula 11. percentage by mass 12. structural formula 13. theoretical yield
58
Summary
12.1 The mole concept in general 1. 2. 3. 4. 5. Chemists use The equal to 6.02
mole One containing 6.02
23
(abbreviation: mol) to show the number of formula units. is the number of atoms in exactly 12 g of carbon-12. It is
10 mol . 10
23
molar mass The of a substance (or species) is the mass in grams of one 1 mole of it. The unit of molar mass is g mol .
Mass of 1 mole of a substance (or species) = formula mass expressed in gram unit Number of moles (mol) = Number of moles (mol) =
mass ______________ (g)
12.2 Percentage by mass of an element in a compound 6. The percentage by mass of an element in a compound can be found by the equation: Percentage by mass of element A in a compound =
relative atomic ______________________________ mass of A
100%
12.3 Chemical formulae of compounds 7. are part of language of chemistry. They give information about the substances concerned and are not just short-hand representation. Some common empirical ionic chemical formulae include formula, formula, molecular structural formula and formula.
Chemical formulae
59
12.4 Determination of empirical formulae 8. 9. formula of a compound is the formula which shows the simplest whole number ratio of the atoms or ions present. The empirical formula of a compound can be calculated from its composition by mass . The composition of a compound has to be determined by experiment.
Empirical
12.5 Determination of molecular formulae 10. may be determined from empirical formula and relative molecular mass. This is because molecular formula is a whole number multiple of empirical formula.
Molecular formula
60
13.1
Most metals corrode. Generally, a metal higher in the metal reactivity series will corrode more rapidly. Rusting refers to the corrosion of iron. As iron is the most N1 widely used metal, rusting is the most common type of corrosion.
Note 1 We can say corrosion of copper but not rusting of copper.
Corrosion of copper is also called rusting. Rusting refers to the corrosion of iron only. We can say corrosion of copper, but not rusting of copper.
13.2 Rusting
Conditions for rusting
We can use the set-up shown in Figure 13.1 to find whether both water and air are involved in rusting. We have to leave the test tubes to stand for several days.
13.2
13.1
Learning tip Anhydrous calcium chloride is a drying agent. It removes water (moisture) from the air.
61
cotton wool
iron nail
distilled water
Figure 13.1 Iron rusts only in the presence of both water and air. ( )
Tube 1 1 no rusting
Tube 2 2
For rusting to occur, two things must be present: water and oxygen.
A13.1 1. In Tube 1, moisture in air has been absorbed by anhydrous calcium chloride. In Tube 2, dissolved air in water has been driven out by boiling. Besides, the oil layer on top prevents air from dissolving in water again.
13.1
1. 3 2. 13.1 2 1
Refer to Figure 13.1. Explain why Tube 1 has no water, Tube 2 has no air, while Tube 3 has both water and air. Iron rusts on the Earth. Will a piece of iron rust on the Moon?
Iron nail is immersed in distilled water in Tube 3. Distilled water contains dissolved air. 2. No; there is no air on the Moon. (In March 1998, NASA revealed that there was strong evidence for the existence of a large quantity of ice at the poles of the Moon. Thus the old idea that there was no water on the Moon might have to be changed.)
Note 2 The theory of rusting is beyond the scope of the HKDSE syllabus.
2+
Then a series of reactions follow. The overall reaction can be represented by an equation: 4Fe(s) + 3O2(g) + 2nH2O( ) 2Fe2O3 nH2O(s)
rust (reddish brown)
2Fe2O3 nH2O(s)
( )
Rust is in fact hydrated iron(III) oxide (Fe 2O 3 nH 2O), where n is a variable number.
62
13.1
13.2)
13.3)
13.3
63
High temperature
An increase in temperature always increases the rate of chemical reactions, including rusting.
Other factors
Other factors that speed up rusting include the presence of
13.4
N6
13.4)
head
nail
shank
Figure 13.4 Detecting rusting by a rust indicator solution. Blue patches around the iron nail appear in a few minutes.
tip
Petri dish
13.2
13.5
1 2 3
cont'd
64
(a) What do you observe in each case? (b) Explain the observed results. (c) From your answers in (a) and (b), suggest a method to protect iron from rusting.
Solution (a) Dish 1: A blue colour appears, mainly around the head and tip of the nail. Dish 2: Gas bubbles appear around magnesium. No blue colour appears. Dish 3: A blue colour appears, mainly around the head and tip of the nail. The blue patches are larger than those observed in dish 1. (b) Dish 1: A blue colour appears, showing that the iron nail rusts. (The blue patches are formed mainly around the head and tip of the nail. This is because these regions are sharply pointed; iron there 2+ can change into Fe (aq) ions more easily.) Dish 2: A blue colour does not appear, indicating that the iron nail does not rust. This is because magnesium, being more reactive, loses electrons more easily than iron. Because of this, iron is prevented from losing electrons. Iron 2+ therefore cannot form Fe (aq) ions and does not rust. (Magnesium reacts with hot water to form hydrogen. This accounts for the appearance of gas bubbles around magnesium.) 2 (b) (a) 1 2 3 1 1 ( Fe (aq)
2+
Fe (aq) ( )
cont'd
2+
65
Dish 3: A blue colour appears, showing that the iron nail rusts. The iron nail wrapped with a copper strip rusts more quickly than the iron nail alone. This is because copper is less reactive than iron, causing iron to lose electrons more easily. This speeds up the rusting of the iron nail. (c) Join iron to a more reactive metal (e.g. magnesium or zinc). (c)
( )
15
13.5
Iron can be coated with a thin layer of corrosion-resistant metal to avoid direct contact with air and oxygen. There are three common ways to achieve this goal: 1. Galvanizing: Iron coated with zinc is called galvanized N9 iron. Some roofs and buckets are made from galvanized iron.
66
Note 9 Zinc and tin are resistant to corrosion because they form a protective oxide layer on the surface.
1.
2.
Tin-plating: Tin-plate is iron coated with tin. Tin is an unreactive metal. It can protect iron from air and oxygen and hence prevent rusting. Tin-plating is commonly used in making food cans since tin and tin ions are not poisonous.
Learning tip Tin is a less reactive metal than iron.
2.
3.
Electroplating: Electroplating is a process in which a thin layer of metal is plated on an object, for example iron object. Chromium is a common metal to be electroplated on iron. Iron coated with electroplated chromium has a beautiful shiny appearance, but is quite expensive. Examples are bathroom fittings, car bumpers and motor cycle parts.
3. )
Cathodic protection
Electricity can also prevent rusting. For example, the negative terminal of a car battery is always connected to the car body. This supplies electrons to the iron body, preventing it from losing electrons. Cathodic protection is often used to protect water/fuel pipelines and storage tanks, ships, offshore oil platforms and onshore oil well casings.
Learning tip The negative terminal of a car battery is called the cathode. So this kind of electrical protection is known as cathodic protection. More details about the meaning of cathode will be discussed in Chapter 31.
Sacrificial protection
During rusting, iron (Fe(s)) loses electrons to form iron(II) ions (Fe (aq)). If we connect iron to a more reactive metal, that metal will lose electrons in preference to iron. This would prevent Fe(s) from forming Fe (aq) ions.
2+ 2+
Galvanizing (zinc-plating) provides a good example. When the zinc coating is undamaged, the iron is protected from rusting. In case the coating is partly damaged, the exposed iron is still protected. Zinc, being more reactive than iron, will form zinc ions. Thus, iron will not rust but zinc corrodes instead zinc is sacrificed to save iron (Figure 13.6). This kind of protection against rusting is called sacrificial protection. N10 13.6) Galvanizing is not used in making food cans because zinc ions are toxic.
Note 10 (a) Zinc offers sacrificial protection even when the zinc coating is damaged. Thus galvanized iron can be used for making objects that are often scratched or knocked about during use (e.g. buckets). (b) About one-third of all the zinc produced in the world is used for galvanizing iron.
zinc
iron
iron
Tin-plating is a kind of sacrificial protection. Tin is resistant to corrosion. As long as the tin coating remains completely undamaged, the underlying iron does not rust. However, if the coating is damaged (even only partly), iron will rust more quickly than it does without tin-plating. This is because tin is less reactive than iron.
68
13.2
Stainless steel does not rust, yet it is seldom used to make large objects. Why?
Table 13.1 summarizes the advantages and disadvantages of different methods of rust prevention with some examples.
13.1
Simple chemistry
Advantages
economical
Disadvantages
fall off easily
Examples
window frames, car bodies coat hangers
the added layer prevents the iron object from contact with air and water
not once and for moving parts of machines all dirt would stick to oil or grease when the tin coating is damaged, rusting will occur more quickly than iron alone tin cans for storing food
(d) Tin-plating
(e) Galvanizing
(f) Chromiumplating
expensive
the negative terminal of an electric source is connected to the iron object, supplying electrons to prevent it from rusting
convenient
69
Simple chemistry
a more reactive metal (e.g. magnesium, zinc) in contact is sacrificed to form ions; this would prevent iron from forming iron(II) ions
Advantages
Disadvantages
Examples
zinc blocks attached to the hull of a ship
an effective way of the sacrificed metal needs protection replacement from time to time
(II) (i) Alloying iron is alloyed with chromium, nickel and manganese which are corrosion resistant has a beautiful appearance a very effective way of protection expensive cutlery, scissors
13.6
13.7
13.7)
aluminium
aluminium
Key terms
Page 1. alloying 2. anodizing (anodization) 3. cathodic protection 4. corrosion 5. electroplating 6. galvanized 7. potassium hexacyanoferrate(III) 8. protective layer 9. rust indicator 10. rusting 11. sacrificial protection 12. tin-plating (III) 68 71 67 61 67 66 64 66 64 61 67 67
71
Summary
13.1 Corrosion of metals 1. 2. is the gradual deterioration of a metal due to reaction with air, water or other substances in the surroundings. In general, a metal
higher Corrosion
13.2 Rusting 3. is the corrosion of iron. Rusting requires the exposure of iron to both water and air. Rust is in fact hydrated iron(III) oxide, Fe2O3 nH2O.
Rusting
13.3 Factors that speed up rusting 4. Factors that speed up rusting include:
acidic Presence of solutions or soluble salts High temperature less A reactive metal in contact with iron Uneven or sharply pointed regions in the iron piece
13.4 To observe rusting using rust indicator 5. We can observe rusting conveniently using a colour where rusting occurs.
rust indicator
. It shows a blue
13.5 Protecting iron from rusting 6. To prevent rusting, we can make use of a suitable method. Refer to Table 13.1 on p.69 for different methods of rust prevention.
13.6 Socio-economic implications of rusting 7. Rusting causes enormous socio-economic problems and extensive corrosion protection has to be developed.
13.7 Corrosion resistance of aluminium 8. 9. Aluminium is resistant to corrosion because it has a protective
Anodizing oxide
layer.
is an electrolysis process used to thicken the aluminium oxide layer on aluminium. Anodized aluminium is even more corrosion-resistant, and can be easily dyed to give attractive colours.
72