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(11)

2 399 589

(13)

C2

(51)

C01G
C03C
A61K
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B82B

23/053 (2006.01)
17/25 (2006.01)
8/29 (2006.01)
53/86 (2006.01)
1/00 (2006.01)

(12)

(30) :
06.12.2004 IT FI2004A000252

(73) ():
... (IT)

(43) : 20.01.2009

2 3 9 9 5 8 9

(45) : 20.09.2010 . 26

2 3 9 9 5 8 9
R U

(85) PCT
: 06.07.2007
(86) PCT:
EP 2005/056478 (05.12.2005)
(87) PCT:
WO 2006/061367 (15.06.2006)
:
103735, , . , 5/2,
"", .. ..
(54) TiO2 , ,
, TiO2


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,

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(56) ,
: 0770579 1, 02.05.1997. JP 11322338 ,
24.11.1999. RU 2144505 1, 20.01.2000. WO
9962822 1, 09.12.1999. JP 2003119024 ,
23.04.2003. FELDMANN ., Polyol-Mediated
Synthesis of Nanoscale Functional Materials,
Advanced Functional Materials, 2003, Vol.13, No.
2, p.101-107.

(57) :


,

R U

(24) :
05.12.2005

(72) ():
(IT),
(IT),
(IT)

(21), (22) : 2007125485/15, 05.12.2005

.
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,
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.

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.: 2

RUSSIAN FEDERATION

(19)

RU

(11)

2 399 589

(13)

C2

(51) Int. Cl.

C01G
C03C
A61K
B01D
B82B

23/053 (2006.01)
17/25 (2006.01)
8/29 (2006.01)
53/86 (2006.01)
1/00 (2006.01)

FEDERAL SERVICE
FOR INTELLECTUAL PROPERTY,
PATENTS AND TRADEMARKS

(12) ABSTRACT

OF INVENTION

(30) Priority:
06.12.2004 IT FI2004A000252

(73) Proprietor(s):
KOLOROBBIJa ITALIJa S.P.A. (IT)

(43) Application published: 20.01.2009

2 3 9 9 5 8 9

(45) Date of publication: 20.09.2010 Bull. 26


(85) Commencement of national phase: 06.07.2007
(86) PCT application:
EP 2005/056478 (05.12.2005)

2 3 9 9 5 8 9
R U

Mail address:
103735, Moskva, ul. Il'inka, 5/2, OOO
"Sojuzpatent", pat.pov. O.I.Vol'
(54) METHOD OF PREPARING TiO2 DISPERSIONS IN FORM OF NANOPARTICLES, DISPERSIONS
PREPARED USING SAID METHOD, AND USE OF TiO2 DISPERSIONS TO ENDOW SURFACES WITH
CERTAIN PROPERTIES
(57) Abstract:
FIELD: chemistry.
SUBSTANCE: invention can be used to prepare
dispersions of titanium dioxide nanoparticles
suitable for photocatalytic coatings on surfaces, for
photocatalytic disinfection of gases and liquids and
for preparing cosmetic compositions with high degree
of skin protection from the sun. The method of
preparing dispersions of anatase nanoparticles
involves the following steps: i) reaction of titanium
alkoxide with a complexing solvent selected from a
group consisting of ethylene glycol, diethylene
glycol or polyethylene glycol; ii) distillation of
the solution obtained at step i) to a small volume;

iii) addition of water of to the solution obtained at


step ii) together with the above mentioned
complexing
solvent
and
one
or
more
polycondensation inhibitors, and then heating the
reaction mixture with a reflux condenser. The
polycondendation inhibitor consists of a mixture
which contains at least one inorganic acid and one
organic acid. The amount of inorganic acid ranges
from 0.1 to 10% of the total volume of the reaction
mixture and the amount of organic acid ranges from 1
to 20 vol %.
EFFECT: invention increases stability of
dispersions of anatase nanoparticles.
3 dwg, 2 tbl, 12 ex

.: 3

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(87) PCT publication:


WO 2006/061367 (15.06.2006)

en

R U

(24) Effective date for property rights:


05.12.2005

(72) Inventor(s):
BALDI Dzhovanni (IT),
BITOSSI Marko (IT),
BARTsANTI Andrea (IT)

(21), (22) Application: 2007125485/15, 05.12.2005

RU 2 399 589 C2

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WO 99/62822).
,

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.: 5

RU 2 399 589 C2

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RU 2 399 589 C2

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/

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.
.: 7

RU 2 399 589 C2

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TiO2 /
.
20- 5,53 ,
5,54 .
5 , 120
. 11,1 , 125
32-33%- , 2,07 125
. 180
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,
, Philips X'Pert
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2
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, 130 .
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125 .
180 2 .
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100 80 1% -100 .
50. 1,280 Ti.
24 50.
.: 8

RU 2 399 589 C2

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35

.
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, ,
100 12 .
,
, Philips X'Pert
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4
TiO2 /
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.

, 30,20.
.: 9

RU 2 399 589 C2

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15

20

25

30

35

40

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7
TiO2 /
-
.
, ,
1,
5%
.
,
700, :
SiO2

48,32%

CaO

6,95%

Al2O3

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MgO

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Li2O

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.: 10

RU 2 399 589 C2

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.: 11

RU 2 399 589 C2

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.
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1. TiO2
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.: 12

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RU 2 399 589 C2

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18. TiO2, .9-11,
.

35

40

45

50

.: 13

RU 2 399 589 C2

.: 14

DR

RU 2 399 589 C2

.: 15

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