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Old Theory
nucleus
Highest energy level
Electromagnetic Spectrum
Radio Micro Infrared waves waves . Ultra- Xviolet Rays
Electronic transition
Energy
n= 1
Absorption Spectra
Energy , Example heat or electricity
n=2
n= 1
When an atom is excited by absorbing energy, an electron jumps up to a higher energy level.
+
nucleus
Spectrum of hydrogen
Emission Spectra
Radiation
Energy is emitted when an electron falls from a higher to a lower energy level.
+
nucleus
Lyman series is a spectral series resulting from transitions back to the first energy level (n=1). This is in the ultraviolet region.
Paschen series is a spectral series resulting from transitions back to the third energy level (n=3). This is in the infrared region.
See previous slide for illustration
Convergence limit
Is the frequency at which the spectral lines come together at the highest energy level (n = ) It corresponds to the point at which ionization takes place if an electron is excited beyond this level Electron is lost from atom!
n= n=4 n=3 n=2 An + n=1
Convergence limit
Note
All substances give emission spectra when they are excited in some way either by heat or the passage of an electric current.
energy
En=2
E
emission
En=1
The small amount of energy absorbed or emitted when an electron undergoes a transition between energy levels is called a quantum ( plural = quanta) of energy
Quantum, E
Quantum, E = En=2 - En=1 = h
E = h
Where h = Plancks constant (6.63 x 10-34Js) = frequency of radiation C = speed of light = wavelength V is a Greek letter called nu
=
Plancks Equation
Subshells
Bohrs model explains the emission spectrum of the H atom in terms of electronic transition between shells. The emission spectrum of the other elements eg sodium(Na) is much more complex. This could not be explained by the Bohrs model To explain the spectrum there must be subdivisions of the Bohr shells, called subshells.
Subshells contd
It was found that: shell n=1 n=2 n=3 n=4 Number of subshells 1 2 3 4 subshells s s, p s, p, d s, p, d, f
New Theory
Orbital
Quantum Numbers
Four(4) quantum numbers determine the orbitals (not orbits) and gives information about energy levels available to an atom. 1. Principal quantum number, n n = 1, 2, 3, 4, , (shells) 2. Subsidiary quantum number, l l = 0, 1, 2, 3, , (n-1) (subshells) 3. Magnetic quantum number, m m = , -1, 0, 1, 2, 4. Spin quantum number, s s=
s atomic Orbital
Is spherically symmetric about the nucleus There is one (1) s orbital for each principal quantum number
p Atomic Orbitals
Pairs of dumb-bells aligned along the x, y, z axis at 90 to each other There are three(3) p orbitals for each principal quantum number from n = 2 onwards denoted by 2p, 3p, 4p, etc Can hold a maximum 6 electrons, 2 in each p orbital. z z y y
x z y
Energy Levels
Hunds Rule
Spin
Electrons act as if they were spinning around an axis, in much the same way that the earth spins. This spin can have two orientations, denoted as up and down
up
down
Filling Order
O= 8
Increasing Energy
or 1s22s22p4
= 20
Increasing Energy
or []
Ca
or []
Neon (Ne)
1s22s22p63s23px23py23pz1
Cl
likewise
Can be written as
[Ne]3s23px23py23pz1
Activities
1. Write the electronic configuration of the first 20 elements in the periodic table using spdf notation. Use the table in the next slide. 2. Illustrate the electronic configuration of phosphorus and potassium using boxes to show the different energy levels and using spdf notation