1-2 mL ( ), 5 mL

(K2Cr2O7)
(H2SO4) .
,
,
. (
)
2- (
) ,
( acetone).

.
(KMnO4)
.
, .
,
(CuO).
.
, .
.
,
.

.
:
5 CH3CH2OH + 2 KMnO4 + 3 H2SO4 5 CH3CH=O + 2 MnSO4 + K2SO4 + 8 H2O

.

.
CH3CH2OH + CuO CH3CH=O + Cu + H2O
:

: , (, )

()
.

.:
K2Cr2O7 ( Cr2O72-)
Cr3+ , :
Mn4 ( MnO4-)
( Mn2+ )

:
C3C2 +|| C3C= + H2O ( )
C3C=+|| CH3COOH ( )
:
C3C()C3 +|| C3CC3 + H2O ( )
:



.
.
,
[1] Tollens Fehling,
(RC=+|| RCOOH)
(g+Ag) Cu2+ Cu2).

[2].

K2Cr2O7 KMnO4

, ,

2- 2

 10 ml

(2S4)

(K2Cr2O7)

250 ml

(KMnO4)

1.

150 ml .

2.

1ml .

3.
4.
5.

1 ml K2Cr2O7 1 ml
.
.

K2Cr2O7 KMnO4

.

.

, ,

2- 2

10 ml

(2S4)

(K2Cr2O7)

250 ml

(KMnO4)

1.

150 ml .

2.

1ml .

3.
4.
5.

1 ml K2Cr2O7 1 ml
.
.

Fehling Tollens

.

.

(AgNO3)

(3)

, ,

(H3CHO)

10 ml

(CH3COCH3)

Fehling [3]

250 ml

Fehling B[4]

1.

150 ml .

2.

1 ml Fehling 1 ml
Fehling B .

3.

, .
.

4.

1 ml Fehling 1 ml
Fehling B .

5.

, .
. .

6.

3 ml

7.

1 ml .
.

,
>C=O.
[1]

.
[2]

[3]

Fehling 35 gr 100 mL

[4]

Fehling 35 gr 10 gr
100 mL

.


1.
1.

2
2

2.

H2SO4 K2Cr2O7
;
.

3.

;
; ...
..
..

4.

 :
........
.
..

2. Fehling
1.

Fehling
;

..

2.

;
..

3.

: HCH=O + |O|
.
3. Tollens

1.

Tollens;
..

..

2.

1 min
;
4.

1.

, ;...

2.

; ..

3.

..