ATilVAC CH EMIC/IL CORPORAT'IOII NUVET 2OO EC

Pagc

t of t0

AltlVAC |'{SDS No.: 3322

MATERIAL SAFETY DATA SHEET

I.@r
PRODLTCT NAME: NUVET 200 EC

LlDl1aluEledrioN

CIIBMICAL NAME: Nor applicrblc (btend)

GENERAL USB: Emulsifiable Concentrntc insecticittc PRODUCT DBSCRIPTION: Amber liquid llPA tlegistration Nrrmber: Not rcgistercrl in U.S. For Bxport Onl1,.
Revision Date:
1.5

MSDS No.: 332 2

December, 2005

MANUF'ACTURER:

AMVAC CITEMICAL CORPORA'I'ION

4100 E. \,trashington Blvd. l,os Angelcs, CA USA 90023-4406

EMBIICENCY TI,LI]PIIONB tr'UMBERS: TRANSPORTATION (24 ITOURS)

ilTANIJFACTTIRBR: 323-264-391 0

Ph: J23-264-3910

CIIEl\lTReC:

liAX: 321-268-1028

oTtrnR (24 nolitrs)

800-424-9300 323-264_3910

r\MVAC:

CONIPONI'N'T
l)imr:tlryl 2,2-tliclrlorovi rrylphosphlte ( I)l)Vl,; [)i0lrlorvos)
20n,i,

62-73-1

Inelt ingredients:
lncluclcs the follor.ving compounrJs: ,2-benzenedicarboxvl ic acid, dibutyl ester (Dibut1,l phthalate) Acelic arrhydride Mixed nonionic/anioniq en4liifiers in solvenrs
I

80r'o 69.',|%

84-'t4-2
I

0.5%
_ o QO/ a.r\ /O

08-24-7

osltA HAZARDOUS

CONTpoN0NTS (29 CFII. 1910. t200) coMpoNENT

IIAZAB])

mg/nrr 5.0 mglm'

@ffi/#*r6ry,ffi .-.-.--.-AsClig
5nonr : ru
Exposurc Limits g lrrs. TWA

;;.-;"* _ 5_-ppm

,ro-ro-r; cNS ncpression 5 0 qdudrldC l0g:24-i\ Corrosive

AMVAC CHEMICAL CORPORATION

NUVET 2OO EC

Psge 2 ol 10 AMVAC tISDS No.: 3322

Ynunt-*
EMERGENCY OVEITVIEW:
DANGER! POISON! Poisonous if sivallorved, inhalecl or absorbei ilrrough skin and eyes. Rapidly absorbed through skin. Repeated inhalation or skin contact ntay, without symptoms, progressively increase susceptibility to Dichlorvos (DDVP) poisoning. CAUTION! FLAMMABLE! Keep away from sources of ignition. CAUTION! WATER REAC'IIVE! TOXIC to fish! Do not contaminate bodies of water.

KEEP AWAY FROM CHII-DREN!

POIEI\ffir\L IIEALTI{ EFFECTS

ROUTE(S) OF ENffRY May be fatal if absorbed through thc eye or sl<in, is ingested or is inhalcd.
SIGNS

OFACLffE OVEREXPOSURE: r\crrtc cholincstcr:rsc rlcprcssioo may bc cvirlcncccl

bv hcadache, nausca, vomiting, diarrhca, abdominal cramps, cxcessive sweating, salivalion and tearing, constricted pupil.-, blurrccl vision, tightncss in chest, weakncss, musclc trvitchirrg and confusion; irr extreme cases, unconsciousrrcss, convulsions, sevcre tespittt<;q'depression and clcath may occur. It should also bc notcd that br:carrsc of thc prescncc oFthc othcr c()1nl)()lrcnts, thc product may also havc thc following hcnltl.r hazards: in:iratin11 to thc skin and cvcs, mav causc ctntral nervous system tlcprcsr;ion, ma)'catrsc skin scnsitization, amv causo harm to rn unlx;tn tlrild, and rnny irtctcasc thc possiblc tisl< oI inrpnirccl lcttiliq'..

SIGNS OF CFIROMC OVEREXPOSURII: llcpe'atecl exlx)surcs to small closcs of Dl)V? ancl othcr organ<lplrosplratcs nray lorvct thc cholinc"-tcrar-c to levtls tirr:rr: tlre alrovc svmpt()nrs of :rcrrtc ()vcrcxp()i^urc lrc,rbscfvctl. Irr rtltlitiorr, llrr-'rc is cvitlcrrr:c tltrt cltrrlric cxp()surc t0 thc solvr:nt rnat' c,r, rs(: c('ntritl ilr:rv()us systcnr tlltnrtllc.

CARCINOGENICI'IY: lil)r\ untlcr its

19!X) proposcrl (iuirlclirrt's f<rr ()arcirrollcn ltisk r\sscs.rnrcrrt has classificcl I)l)VI'!ls lravirrg "sulgcstivc cvirlcncc of carcinoecnir:ity, bLrt not sufficir:rrt t() lsscss human carcinogcn'ic potcntial." lAlt(l lists l)I)Vl) (l)ichlorvos) as bcing possibly carcirrog<'rric to htrrnans ((irorrJr 213). CARII SI{O[[,D BE IXI]RCISED IN I

IAM)IING I)DVP N ND

TTS

I()TIMT]I/\I'IONS.

MBDICALCONDITIONSAGGRAVATED BYEXPOSURE: Prcexisting conditiors rvhlch loscr

cholincstcrasc lcvcls incrcasc vulncrability to cht>lirrcstcrar-c dcprcssion,'l'hc"-c inclrrdc: (for plnsrna) gcnetic cholincstt:tasc dc6cicrrcy; rdvalccd livr:r tliscasc; chronic alcoholisrn; nr:rlntrtritirn; dennatomvositis; cxisting toxicity frrm exT)()i^urc to carbon disulfidc; benzalkonium salts, organic rncrcury compounds, ciguatoxins or solanincs; and (for ltl3C) hemolytic anemias.

\
4. FIRST AID MIIASUITES
DDVP IS A CI{OI,INESTERASE INI-III]If'OIT. A PI{\SICIAN STIOULD l]E CONIACI'ED IN EXPOSURE TO DDVP AND N'S FOiITTLA I'IONS.

ALL

CASES OF

CAUTION: Pcrsons atrcnding victim should avoid clircct contact with hcavih contaminatcd clothing ot vominrs. Rubber gkrvcs should bc wom bv the cmcrgcncy rcsJronrlcr or mc<.tic:rl pcrsrrnnci whilc washing thi pcsticiclc from skin and harr of tht cxposcd vicrirn.

E\T'S:

Immcdiatcly flush thc cycs rvith copious amolrrlts of clcirr, cool nrnnir:g rvater tirr a miniurum o[: 15 minutcs. I]old thecyrliclsaPartduringtlrcflushingtocnsurcrinsingofthccrrtircsurfaccofthccycs and lids u.ith watcr. Contact a physician irnmcdiatcly. I f thcrc will bc a dclay in gcttirrg rne dical rttcntitxr, rinsc thc cves for at lcast alother I 5
lr inutr:s.

INHAI-ATIO}.I:
Rcmovc vi<:tim ar:tificial rcspiration.

to frcsh air. If brcnthirrg has ceasctl, clcar the victim's ainvay nnd startrnouth-

If

breathing is difFrcult, givc oxygcn. (lontact a physicinn immccliatcly.

to-moutll

INGESTION:
DO NOT induce vomiting. lf victim is consciorrs, adrninistcr xn I oz. glass of water containing 2 charcoal. l'Iave person lic on thr:ir left sidc to slorv down absorption of the ingested material. Ncvcr m()uth t() An unconscious lte rs()tl- (lontact a physician immcdiatclv.
tbsp. activated

givc anvthing bv

SKIN:

Imnrcdiatcly flush rrll affcctcll arcrts rvith largc afir()rrnts of ciclr rvirtcr ftrr at lcist 15
ir

nrinutcs.

I{cm1rvc

pl rysi<'i:rrr

rrrrrctlirrtt.ly.

NOIETOPFTY$CIANS:
'fhis is nn C)rgaoophttsphatc (Ol') lnsccticidc. l)o not rvait tirr laboratorv confirnation to trcar paticnrs with strong clinical evidencc ofpoisorring. Contact your local poison control centet for further recornmendatioos regatding control of poisoning, emcrgency trcatment, aud other infonnation regatding the toxiciry of DD\? (Dichlorvos)' A possible method of treatorent is given bclorv. I)o Not handle the patient rvithout the foLlowing protective equipmeot in place chemical resistlnt gloves and apron (prcfcrably nitrile). ltcmove contamiiatcd clothing ani do notreusc without tlrorough. cleaning with cletctgent and hot watcr. f)ispose of heavilr. c()ntalninated clot-hirrg, including shocs, as a hazlrdous waste. Iistablish airway and oxyeenation. I lt Atropi.c s^ulf-ate is- the antidote of cl.roicc against patasymPathetic !]ewous stimulation. If thcrc arc signs of parasymplthctic stimr:latiol, ,/\tropine Sulfate should bc infccted at 10 minutc intcrvals in doscs of i to 2 milligrams u.rtil compl;rc atropinizarion has occurrcd. Pralidoxime chloride (2-P,'\tr'f cliloride) mav also bc uscd as an eftective antiiote i' a.'i.lition to and rvhile maintaining full atropinizatiot. In adults, an initial rlose of I gmm of 2-PAIVI should be injcctecl, prcferably as an irrfusion, in250 cc of saline oveta 15 to 20 mimrte pcriocl. IFthis is notpractical,2l)r\M may bc r&rinistered slorvly by intravcrious injection as a 59lo solution in rvatct over not lcss than 2 mirrutcs. Aftcr about an hour, a second dose of I sram of 2- PAM rvill be inclicatcd if muscle rvcakncss has not bcen tclicvcd. For infants and chiidrcn, thc dose of 2I)AM is 0.25 grirms..i\voi,l morphine, aminophyllinc, phcnothiazine, reserpinc, furoscmidc ancl ethacrvnic acid. clear chcst by postural drai'ngc. oxygcn administration nray bc neccssary. Observe p^tient cofltinuously for 48 hours. Rcpeated exposure to cholinesterasc inhibitors may rvithout warning cause ptolongcd susccptibiliry to vcry small doses of anv cholinestcrasc inhibitor. All,,ru no further cxposurc until time f<rr cholincsterasc tegencration has becn attaincd as detcrmincd by a |lood tcst. Ilathe and sharnpoo contnminatcd skin antl hait. If irrgcstccl, crnpty stonrach. Activatcd c6atcoal is trsctirl to tlrtl.rcr limit absorption.

6.

ACCIDBNTALRIILEASBIYIBASURIiS.-gon1't!
absr>rbctrt (clav, salrcl, oil city, kiny lincr, ctc..) to absorb the liquid. Srveep into art opcn plastic tlrum. I)econtaminatc tlrc arcr rrrd cr.luipmcnt with clilutc ali<ali <>r amm6nia (iess than 570 solution) antl clctctgcnt. FIush thc arc:r rvith watcr. i\bsotb arrd -srvccp into thc sarnc opcn plastic Jmm. Close

SMALL SPILL: Covcr with nonflanrmablc

thc dnrnr arrcl rlisposc oFas a hazardous \\'astc.

LAlt(;E SPILL: l)ikc

thc spill to prcvcnt cotttitntirtatiorr of locul rvatcr s()urccs. SiJrlron thc maioritv of thc lirluitl i11t6 clrrtrrts l'rrr ust: or dislrosal, dcpcndinll on thc circrrmstanccs. (,lcan thc arca as dcscribcci f<rr a snrall spill.

T.gaNpLtNG ANp

STORAGE

FIANDLING: l)rcvcnt

sl<in contact. I)o not breathe fumes. Wcar approl:riatc personal protcctive ccluipmenr (PPE, Scction 8). Wash thoroughlv aod chanse clothcs aftcr hanclling. Wash clothes .epnr"t"lv; do .,ot rvash heavily contrminated clothint. Disposc of hcavily c()ntalninatecl clothing as a hazarclr>us rvaste. Kccp prtxluct rrrvay fronl frlod, clrirrk, c<>sntctic"-, ancl tobacco prorlucts. Scc prodr:ct labcl firr ororc dcttiicd harrdling proccclurcs.

of childrcn. Storc irr oriqinli containcr.

Ii. BXPOSU RIt CONTROLS/PE Ii.SONA I, PROT BCT'I ON

ENGINEEIUNGCOI\I.rIiOIS r\ wcll-vt:rrtilatctl
arca is rcconrrncrrrlctl fot hanrlling NL]V;\NG) 200 I.l(1. Usc mcchanical or local cxbaust svstcm-s is rccomntclrclcrl. Scc labr:l ()r cont:lct vour distributr>r tbr r.norc complctc instructions.

of

RESPIRATORY PITOTECTION: r\ NIOSI i/ivfSI L'\ approvr:d airlurili,ing rcspiraror ccluippccl rvith r>rganic vapgr cartriclgcs or canir-tcts is requircd g'hcn rnvonc is workinr *,itlr or ncar opcrl colltiin;rs of this piodrct. ,\ nta;:jmtrrn usc oFcighr hours is rccommcrrclctl. llor crncrecncv arrrl otlrcr iondrtions q,hcrc. thc c,xPcisurc lintit nray l>c grcatlv cxccctlcrl, usc an al)llr()\'ctl positivc-prt:sstrrc, scl f'-corttainctl l;rcathint1 al)p:rratlls 6r pgsitiycl)rcssrtrc airlinc rvitlr atrxiliatv sc]f-contlirtt'cl rir strpplv. Scc l;rbcl ()r c()nt:tct vour,listribrrt<>. f,r. nr,r." cornpft:tc
in s lrrrctiorr s.

SKIN PnOTECIION: I)rcvcttt:rkirt c.tttitct. (lh<:rnrcrl rcsistant glovc"-(prcfcr:rblv nitrilc), covcralls iorrr-slccvcci 'r sllirr altrl 1t:tltt:r, rtrtl cht:tttir::t] rc'sislrurl shr,< s or llor,rs, art: ncc(-,ss:rrv t() l)r(.vcrrt skin (:(),)tlnrir):rrirl1. .\
risk oisIillrr11t'or slllrrslrirrll. l(ttrtovr: c()nt;ln);rr;rl((l r:lotlrirrt:ts s(xrn rls possilrlc. \\/lslr tii16.9r r:onl:rrnirr:rtttl clothing scparatt.lr, tionr ofltcr r.lotirrs. \\,cirr clr:rtrr clrithcs tlailr.. Wrrslr t,cl] *ith so.rp

rr':ttcr;ttitr harrrllirt!'this Ir,rrltrct. St'r'thc lal;tl tirr

arrcl

rrrort.sJ.(.'cill(: irrstrur:rir,rrs.

[!BE

FIEUTLN G M II,.\sURII:5.

FI-AMMABLD PROPERTIES Flash Point I 156 1t/65.5oO (Pensliv-l\'fartcns c,c.) '\utoisnitiort '['cmpcraturc: Not availablc lilammablc l,imits: l,orvcr flammablc limit: not available Uppcr flarnmablc limit: not availablc . lilammability: 'l his is a nonflamnnblc liqtncl that will burn rvhcn hcatcd S',lltl?,'\ rating =1) EXPLOSTVITY
Vapor-tirmixturcs <>f onc of thc (:()mp()ncr)ts);\cctic anhytlriclc, art: l<nt>rvtt trr bc cxplosivc rvlrcn thc ct>rnpt>uncl is rvithin the tlarnmablc limits li--tcd abo.'e an<l thc tcmpcraturc is abovc the flaslrpoint.,\lsr>, a violent cxgthcrmic rcrcti6n occurs rvlrcrr .\cctic arrhyrltidc rctcts rvitlt rvrtcr. ']'his hcat may bc sufficicnt trr i.O";r" comltustiblc matcritls. r\cctjc :rnhvcl ridc is sc:nsitivc t() stxtic cl isclra rtlc.

HAZARDOUS COMBUSTION PRODI]CIS: T'his pr6dqct will crnit toxic furncs rvhcn llurncil, irrclucling carb<ttr nronrrxidc. \rapors of thc r:nbtrrtrcd prgduct mry also bc hazarclous. (lorltact rvith thc fumcs and vapors shottld be avoidcd bv stavirrg upu'ind
and by wearing imperviotrs clothing and positivc prcssutc sclf-containecl brcathing aPParanrs.

DCTINGUISFIINGMEDIA Foam, dry chemical, carbon dioxide, watcr spray (fog). Usc rvatcr .x'ith caution as one of thc components.
Acctic anhydride, reacts with watcr. FIRE FIGFITING INSTRUCITONS: l:ivacuatc rlonessr:fltial pcrsonncl from thc arca. Kccp upwincl. Wcar self-containcd btcathing apParatus ancl inrpenious clothing, including glovcs antl cvc protection. Clcan all clothing bcfbrc rettse. Sevcrelv contaminatcd clotl-ring cannot bc adcquatcly dccrxrt'lrninated, :rnd rmrst be disposbd as a hazarrlous waste. Shower rvith -soap and water nftct contact with tlris procluct.

6.

ACCI
GENERAL:
rtpirronrirtte l;',vncuatc pcrsolurcl antl tlroroughlv vcntilafc tlrc rrcr. Usc lrlt:titrirtc vcntilatiotr anrl arvrtv tiom thc spill. pcrsonal protcctivc e<pipnrer.rt (l)l)l:,), Scction 8). l(ccp bysturtdcrs upwind ancl