Name: Teo Zhi Yuan

Class: M04M

Date: July 6, 2005

Chemistry Practical 18
Title: Bond Energy Methodology: Refer to Chemistry HL Practical Handbook pg. 71

Data Collection: Results: Initial T (C) Trichloromethane, CCl3 Ethyl ethanoate, C2H5OOCCH3 29.0 26.0 Final T (C) 37.0 37.0 T 8.0 12.5 % 11.0 9.09 %

Data Processing: Trichloromethane RMM Density (g cm-3) Specific heat capacity (Jg-1K-1) Number of moles used 119.5 1.48 0.96 0.1 Ethyl ethanoate 88 0.90 1.92 0.1

Volume =

number of moles molar mass density

Volume of trichloromethane =

0.1 mol 119.5 g mol -1 1.48 g cm -3

= 8.10 0.05 cm 3 = 8.10 0.617 % cm 3

Volume of ethyl ethanoate =

0.1 mol 88 g mol -1 0.90 g cm -3

= 9.80 0.05 cm 3

Density =

mass ; Mass = Density Volume volume

= 9.80 0.510 % cm 3

Mass of trichloromethane =1.48 g cm -3 8.10 cm 3 =12.0 0.617 % g

Mass of ethyl ethanoate =0.90 g cm -3 9.80 cm 3 =8.82 0.510 % g

Volume (cm ) Mass (g) Temperature change, T (C) Specific heat capacity,c (Jg-1K-1)

Trichloromethane 8.10 0.617 % 12.0 0.617 % 8.0 12.5 % 0.96

Ethyl ethanoate 9.80 0.510 % 8.82 0.510 % 11.0 9.09 % 1.92

Amount of heat liberated in the reaction, q = m1c1T1 + m2c2T2 = (12.0 g 0.96 Jg-1K-1 8.0K) + (8.82 g 1.92 Jg-1K-1 11.0K) = (92.2 13.1 %) J + (186 9.60 %) J = (92.2 12.1) J + (186 17.9) J = 278.2 30.0 J = 278.2 10.8 % J
The equivalent mixture of 0.1 mole of trichloromethane and 0.1 mole of ethyl ethanoate evolved 278.2 10.8 % J of heat.

If 1 mole of each liquid was used, The amount of heat energy that would have been liberated
278.2 0.1 =2782 10.8 % J =
The strength of the hydrogen bond between trichloromethane and ethyl ethanoate is 2782 10.8 % J

Conclusion: The strength of the hydrogen bond between trichloromethane and ethyl ethanoate is 2782 10.8 % J.