vol of

S2 = CA
extent of conc of
NaOH(ml) conc of
reaction ethanol
ln CA
*
acid
Ce
11.3
4.52
1.78
9.22 1.508512
10.6
4.24
2.06
8.94 1.444563
10.1
4.04
2.26
8.74 1.396245
8.9
3.56
2.74
8.26 1.269761
8.3
3.32
2.98
8.02 1.199965
7.9
3.16
3.14
7.86 1.150572
7.6
3.04
3.26
7.74 1.111858
7.3
2.92
3.38
7.62 1.071584
5.9
2.36
3.94
7.06 0.858662

ln(K *CA- CP)

CP=*
1.752395
1.613589
1.50114
1.164774
0.941725
0.759497
0.597077
0.403062
-6.72543

K for first order= at infinite time/ Ca at infinite time

K for second order= ^2/(Ca at infinity Ce at infinity)
m= {(K-1)(-)-K(CA+Ce)+(C(water)+C(ester))+-
or, m= {(0.932-1)(-3.94)-*0.932(2.36+7.06)+(3.94+3.94)+-3.94
or m =(-0.068*(-3.94)-16.66)*3.94

n=(-),(K-1)+K(CA+Ce)+(C(water)+C(ester))or n= (-3.94),(-0.068)*3.94+0.932(2.36+7.06)+(3.94+3.94)or Q= (-3.94)16.39

M= (m/n)

1/CA
0.221239
0.235849
0.247525
0.280899
0.301205
0.316456
0.328947
0.342466
0.423729

ln(Ce/CA)
0.712863
0.745972
0.771665
0.841664
0.881974
0.911215
0.934544
0.959193
1.095783

m
-65.0617
-65.1367
-65.1903
-65.3189
-65.3832
-65.4261
-65.4582
-65.4904
-65.6404

n
-35.4024
-30.8132
-27.5352
-19.668
-15.7344
-13.112
-11.1452
-9.1784
-7.3E-15

M
1.837776
2.113922
2.367526
3.321075
4.15543
4.989785
5.87322
7.13527
9.02E+15

ln(M)
0.608556
0.748545
0.861845
1.200288
1.424416
1.607393
1.770403
1.96505
36.73803

concentration of acetic aci

5
4.5
4
3.5
3

(mol/L)

0
31
42
52
71
81
91
101
1440

S2 = CA
conc of
acid
4.52
4.24
4.04
3.56
3.32
3.16
3.04
2.92
2.36

concentration of acetic acid ,CA

time t
(min)

2.5
2
0

cumulative time t

ln(CA) vs. cumulative time graph for

1.8
1.6
1.4
1.2

0
31
42
52
71
81
91
101

ln CA
1.508512
1.444563
1.396245
1.269761
1.199965
1.150572
1.111858
1.071584

0.8

ln(CA )

time t
(min)

0.6
0.4
0.2
0
0

20

1440

20

0.858662
cumulative time t

concentration of acetic acid vs. cumulative time

Series1

500

1000

1500

2000

cumulative time t (min)

vs. cumulative time graph for 1st-order irriversible reaction

y = -0.0047x + 1.5468
R = 0.9623

Series1
Linear (Series1)

40

60

80

100

120

40

60

cumulative time t (min)

80

100

120

0
31
42
52
71
81
91
101
1440

ln(K *CA- CP)

CP=*
1.752395
1.613589
1.50114
1.164774
0.941725
0.759497
0.597077
0.403062
-6.72543

ln(K*CA
2.5

ln(K *CA- CP)

time t
(min)

1.5

0.5

0
0

0
31
42
52
71
81

1/CA

(1/CA) vs. cumulative time

(type-1)

0.221239
0.235849
0.247525
0.280899
0.301205
0.316456

0.4
0.35
0.3
0.25

1/CA

time t
(min)

0.2

0.328947
0.342466
0.423729

1/CA

91
101
1440

0.2
0.15
0.1
0.05
0
0

ln(Ce/CA) vs. cumulat

0
31
42
52
71
81
91
101
1440

ln(Ce/CA

0.712863
0.745972
0.771665
0.841664
0.881974
0.911215
0.934544
0.959193
1.095783

ln(Ce/CA)

time t
(min)

ln(M) vs.cumulative time fo

2.5

0
31
42
52
71
81
91
101
1440

lnM
0.608556
0.748545
0.861845
1.200288
1.424416
1.607393
1.770403
1.96505
36.73803

1.5

ln(M)

time t
(min)

0.5

0
0

ln(K*CA-CP) vs. cumulative time for 1st-orser reversible reaction

y = -0.0143x + 1.932
R = 0.9502

Series1
Linear (Series1)

20

40

60

80

100

120

cumulative time t (min)

A)

vs. cumulative time for 2nd order irrerversible reaction

-1)

y = 0.0013x + 0.2075

y = 0.0013x + 0.2075
R = 0.9574

20

40

60

80

100

120

cumulative time t (min)

ln(Ce/CA) vs. cumulative time for 2nd order irreversible reaction(type-2)

1.2
y = 0.0027x + 0.6884
R = 0.9606

0.8

0.6

0.4

0.2

0
0

20

40

60

cumulative time t (min)

80

100

120

vs.cumulative time for 2nd order reversible reaction

y = 0.0144x + 0.4285
R = 0.9504

20

40

60

cumulative time t (min)

80

100

120