1.

Sebelum penambahan
0.1 N NaBr

(0.1 N = 0.1 M)

[Br-]

= 0.1

P Br

= -log [Br-]
= -log 0.1
=1

2. Penambahan AgN03
Vol NaBr

=10 ml

[NaBr]

=0.1 M

Br-

=V.M
=10 mL x 0.1 mol/L
=1 mmol

a. Vol AgNO3

= 2 ml

[AgNO3]

=0.1 M

Ag+

=2 ml x 0.1 mol/L
Ag+

Br -

Mula-mula

0.2 mmol

1 mmol

Reaksi

0.2 mmol -

0.2 mmol

Sisa

[Br -] sisa

=
= 0.07 M
pBr

= -log [Br -]
= -log 0.07
= 1.2

0.8 mmol

AgBr

b. Vol AgNO3

= 4 ml

[AgNO3]

=0.1 M

Ag+

=4 ml x 0.1 mol/L
=0.4 mmol
Ag+

Br -

Mula-mula

0.4 mmol

1 mmol

Reaksi

0.4 mmol -

0.4 mmol

Sisa

[Br -] sisa

AgBr

0.6 mmol

=
= 0.0428 M
pBr

= -log [Br -]
= -log 0.0428
= 1.368

c. Vol AgNO3

= 6 ml

[AgNO3]

=0.1 M

Ag+

= 6 ml x 0.1 mol/L
=0.6 mmol
Ag+

Br -

Mula-mula

0.6 mmol

1 mmol

Reaksi

0.6 mmol -

0.6 mmol

Sisa

[Br -] sisa

0.4 mmol

AgBr

=
= 0.025 M
pBr

= -log [Br -]
= -log 0.025
= 1.60

d. Vol AgNO3

= 8 ml

[AgNO3]

=0.1 M

Ag+

=8 ml x 0.1 mol/L
Ag+

Br -

Mula-mula

0.8 mmol

1 mmol

Reaksi

0.8 mmol -

0.8 mmol

Sisa

[Br -] sisa

AgBr

0.2 mmol

=
= 0.01 M
pBr

= -log [Br -]
= -log 0.01
=2

e. Vol AgNO3

= 10 ml

[AgNO3]

=0.1 M

Ag+

=10 ml x 0.1 mol/L

=1 mmol
Ag+

Br -

Mula-mula

1 mmol

1 mmol

Reaksi

1 mmol -

1 mmol

AgBr

Sisa

Pada saat titik ekuivalen

Ksp= [Ag +] [Br-]
4 x 10 -16 = [Br-]
[Br-]

= 2 x 10 -8

P Br

= -log 2 x 10-8
=7.699

f. Vol AgNO3

= 12 ml

[AgNO3]

=0.1 M

Ag+

=12 ml x 0.1 mol/L

=1.2
Ag+

Br -

Mula-mula

1.2mmol

1 mmol

Reaksi

1 mmol -

1 mmol

Sisa

0.2 mmol

[Ag+] sisa

=
= 0.009 M
pAg

= -log [Ag +]
= -log 0.009
= 2.045

g. Vol AgNO3

= 14 ml

[AgNO3]

=0.1 M

Ag+

=14 ml x 0.1 mol/L

=1.4

AgBr

Ag+

Br -

Mula-mula

1.4mmol

1 mmol

Reaksi

1 mmol -

1mmol

Sisa
[Ag+] sisa

0.4
=

AgBr

=
= 0.016 M
pAg

= -log [Ag+]
= -log 0.016
= 1.795

h. Vol AgNO3

= 16 ml

[AgNO3]

=0.1 M

Ag+

=6 ml x 0.1 mol/L
= 1.6
Ag+

Br -

Mula-mula

1.6 mmol

1 mmol

Reaksi

1 mmol -

1 mmol

Sisa

[Ag+] sisa

0.6

=
= 0.023 M
P Ag

= -log [0.023]
= -log 0.23
= 1.63

i. Vol AgNO3

= 18 ml

AgBr

[AgNO3]

=0.1 M

Ag+

=18 ml x 0.1 mol/L

=1.8
Ag+

Br -

Mula-mula

1.8 mmol

1 mmol

Reaksi

1 mmol -

1 mmol

Sisa

[Ag +] sisa

0.8 mmol

AgBr

=
= 0.028 M
pAg

= -log [0.028]
= -log 0.028
= 1.553

j. Vol AgNO3

= 20 ml

[AgNO3]

=0.1 M

Ag+

=20 ml x 0.1 mol/L

=2
Ag+

Br -

Mula-mula

2 mmol

1 mmol

Reaksi

1 mmol -

1 mmol

Sisa

[Ag +] sisa

1 mmol

=
= 0.033 M

AgBr

pAg

= -log [Ag+]
= -log 0.033
= 1.481

vol Ag NO3 brpbr

pag
d
d2
0
0.1
1.00
14.40
2
0.07
1.20
14.20
0.1
-0.008
4
0.0428
1.37
14.03
0.084
0.016
6
0.025
1.60
13.80
0.116
0.042
8
0.01
2.00
13.40
0.2 1.32475
10 0.00000002
7.70
7.70
2.8495
0.01075
12
13.36
2.05
2.828 -1.3515
14
13.61
1.80
0.125
0.02125
16
13.77
1.63
0.0825
-0.022
18
13.85
1.55
0.0385
0.00125
20
13.92
1.48
0.036
0.0018

Y-Values
16
14
12
10
8

Y-Values

6
4
2
0
0

10

15

20

25

Y-Values
3.5
3
2.5
2
1.5

Y-Values

1
0.5
0
0

10

15

20

25

20

25

-0.5

Y-Values
1.5
1
0.5
0

Y-Values
0

-0.5
-1
-1.5

10

15