B GIO DC V O TO

CHNH THC

( thi c 6 trang)

THI TUYN SINH I HC NM 2013 Mn: HA HC; Khi A Thi gian lm bi: 90 pht, khng k thi gian pht M thi 463

H, tn th sinh:.......................................................................... S bo danh:............................................................................

Cho bit nguyn t khi ca cc nguyn t: H = 1; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; P = 31; S = 32; Cl = 35,5; Ca = 40; Cr = 52; Fe = 56; Cu = 64; Zn = 65; Br = 80; Ag = 108; Ba = 137. I. PHN CHUNG CHO TT C TH SINH (40 cu, t cu 1 n cu 40) Cu 1: Cho hn hp X gm 0,01 mol Al v a mol Fe vo dung dch AgNO3 n khi phn ng hon ton, thu c m gam cht rn Y v dung dch Z cha 3 cation kim loi. Cho Z phn ng vi dung dch NaOH d trong iu kin khng c khng kh, thu c 1,97 gam kt ta T. Nung T trong khng kh n khi lng khng i, thu c 1,6 gam cht rn ch cha mt cht duy nht. Gi tr ca m l A. 3,24. B. 8,64. C. 6,48. D. 9,72. Cu 2: Cho 0,1 mol tristearin ((C17H35COO)3C3H5) tc dng hon ton vi dung dch NaOH d, un nng, thu c m gam glixerol. Gi tr ca m l A. 27,6. B. 9,2. C. 4,6. D. 14,4. Cu 3: trng thi c bn, cu hnh electron ca nguyn t Na (Z = 11) l A. 1s22s22p53s2. B. 1s22s22p63s2. C. 1s22s22p63s1. D. 1s22s22p43s1. Cu 4: Ln men m gam glucoz to thnh ancol etylic (hiu sut phn ng bng 90%). Hp th hon ton lng kh CO2 sinh ra vo dung dch Ca(OH)2 d, thu c 15 gam kt ta. Gi tr ca m l A. 45,0. B. 7,5. C. 18,5. D. 15,0. Cu 5: Cho m gam Fe vo bnh cha dung dch gm H2SO4 v HNO3, thu c dung dch X v 1,12 lt kh NO. Thm tip dung dch H2SO4 d vo bnh thu c 0,448 lt kh NO v dung dch Y. Bit trong c hai trng hp NO l sn phm kh duy nht, o iu kin tiu chun. Dung dch Y ha tan va ht 2,08 gam Cu (khng to thnh sn phm kh ca N+5). Bit cc phn ng u xy ra hon ton. Gi tr ca m l A. 4,20. B. 2,40. C. 3,92. D. 4,06. Cu 6: Cht no sau y khng to kt ta khi cho vo dung dch AgNO3? A. KBr. B. K3PO4. C. HCl. D. HNO3. Cu 7: Trong iu kin thch hp, xy ra cc phn ng sau: (a) 2H2SO4 + C 2SO2 + CO2 + 2H2O. (b) H2SO4 + Fe(OH)2 FeSO4 + 2H2O. (c) 4H2SO4 + 2FeO Fe2(SO4)3 + SO2 + 4H2O. (d) 6H2SO4 + 2Fe Fe2(SO4)3 + 3SO2 + 6H2O. Trong cc phn ng trn, phn ng xy ra vi dung dch H2SO4 long l A. (c). B. (a). C. (d). D. (b). Cu 8: Phenol phn ng c vi dung dch no sau y? A. NaHCO3. B. KOH. C. HCl. D. NaCl. Cu 9: ng vi cng thc phn t C4H10O c bao nhiu ancol l ng phn cu to ca nhau? A. 3. B. 2. C. 5. D. 4. Cu 10: Hn hp X cha ba axit cacboxylic u n chc, mch h, gm mt axit no v hai axit khng no u c mt lin kt i (C=C). Cho m gam X tc dng va vi 150 ml dung dch NaOH 2M, thu c 25,56 gam hn hp mui. t chy hon ton m gam X, hp th ton b sn phm chy bng dung dch NaOH d, khi lng dung dch tng thm 40,08 gam. Tng khi lng ca hai axit cacboxylic khng no trong m gam X l A. 9,96 gam. B. 15,36 gam. C. 12,06 gam. D. 18,96 gam.
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Cu 11: Cho cc cn bng ha hc sau: 2HI (k). (a) H2 (k) + I2 (k) 2NH3 (k). (c) 3H2 (k) + N2 (k)

N2O4 (k). (b) 2NO2 (k) 2SO3 (k). (d) 2SO2 (k) + O2 (k)

nhit khng i, khi thay i p sut chung ca mi h cn bng, cn bng ha hc no trn khng b chuyn dch? A. (d). B. (c). C. (a). D. (b). Cu 12: Cho s cc phn ng:
t X + NaOH (dung dch) Y + Z;
o

t ,CaO Y + NaOH (rn) T + P;

o

1500 C t , xt T Q + H2O Q + H2 ; Z. Trong s trn, X v Z ln lt l: A. HCOOCH=CH2 v HCHO. B. CH3COOCH=CH2 v HCHO. C. CH3COOCH=CH2 v CH3CHO. D. CH3COOC2H5 v CH3CHO. Cu 13: Khi c chiu sng, hirocacbon no sau y tham gia phn ng th vi clo theo t l mol 1 : 1, thu c ba dn xut monoclo l ng phn cu to ca nhau? A. butan. B. neopentan. C. pentan. D. isopentan. Cu 14: Ha tan hon ton m gam Al bng dung dch HNO3 long, thu c 5,376 lt (ktc) hn hp kh X gm N2, N2O v dung dch cha 8m gam mui. T khi ca X so vi H2 bng 18. Gi tr ca m l A. 21,60. B. 17,28. C. 18,90. D. 19,44. Cu 15: Thc hin cc th nghim sau: (a) Cho dung dch HCl vo dung dch Fe(NO3)2. (b) Cho FeS vo dung dch HCl. (c) Cho Si vo dung dch NaOH c. (d) Cho dung dch AgNO3 vo dung dch NaF. (e) Cho Si vo bnh cha kh F2. (f) Sc kh SO2 vo dung dch H2S. Trong cc th nghim trn, s th nghim c xy ra phn ng l A. 6. B. 5. C. 4. D. 3. Cu 16: iu kin thch hp xy ra cc phn ng sau: (a) 2C + Ca (b) C + 2H2 CaC2. CH4. (c) C + CO2 (d) 3C + 4Al 2CO. Al4C3. Trong cc phn ng trn, tnh kh ca cacbon th hin phn ng A. (c). B. (d). C. (a). D. (b). Cu 17: Bit X l axit cacboxylic n chc, Y l ancol no, c hai cht u mch h, c cng s nguyn t cacbon. t chy hon ton 0,4 mol hn hp gm X v Y (trong s mol ca X ln hn s mol ca Y) cn va 30,24 lt kh O2, thu c 26,88 lt kh CO2 v 19,8 gam H2O. Bit th tch cc kh o iu kin tiu chun. Khi lng ca Y trong 0,4 mol hn hp trn l A. 9,0 gam. B. 11,4 gam. C. 17,7 gam. D. 19,0 gam. Cu 18: Dung dch axit axetic phn ng c vi tt c cc cht trong dy no sau y? A. NaOH, Cu, NaCl. B. Na, NaCl, CuO. C. Na, CuO, HCl. D. NaOH, Na, CaCO3. Cu 19: Hp cht X c thnh phn gm C, H, O, cha vng benzen. Cho 6,9 gam X vo 360 ml dung dch NaOH 0,5M (d 20% so vi lng cn phn ng) n phn ng hon ton, thu c dung dch Y. C cn Y thu c m gam cht rn khan. Mt khc, t chy hon ton 6,9 gam X cn va 7,84 lt O2 (ktc), thu c 15,4 gam CO2. Bit X c cng thc phn t trng vi cng thc n gin nht. Gi tr ca m l A. 11,4. B. 12,3. C. 13,2. D. 11,1. Cu 20: Hn hp X gm 3,92 gam Fe, 16 gam Fe2O3 v m gam Al. Nung X nhit cao trong iu kin khng c khng kh, thu c hn hp cht rn Y. Chia Y thnh hai phn bng nhau. Phn mt tc dng vi dung dch H2SO4 long (d), thu c 4a mol kh H2. Phn hai phn ng vi dung dch NaOH d, thu c a mol kh H2. Bit cc phn ng u xy ra hon ton. Gi tr ca m l A. 7,02. B. 4,05. C. 5,40. D. 3,51.

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Cu 21: Cht no sau y khi un nng vi dung dch NaOH thu c sn phm c anehit? A. CH3COOCH2CH=CH2. B. CH3COOCH=CHCH3. C. CH2=CHCOOCH2CH3. D. CH3COOC(CH3)=CH2. Cu 22: Oxi ha hon ton 3,1 gam photpho trong kh oxi d. Cho ton b sn phm vo 200 ml dung dch NaOH 1M n khi phn ng xy ra hon ton, thu c dung dch X. Khi lng mui trong X l A. 11,1 gam. B. 12,0 gam. C. 14,2 gam. D. 16,4 gam. Cu 23: Dy cc cht u tc dng c vi dung dch Ba(HCO3)2 l: A. HNO3, Ca(OH)2 v KNO3. B. HNO3, NaCl v Na2SO4. C. NaCl, Na2SO4 v Ca(OH)2. D. HNO3, Ca(OH)2 v Na2SO4. Cu 24: Trong mt bnh kn cha 0,35 mol C2H2; 0,65 mol H2 v mt t bt Ni. Nung nng bnh mt thi gian, thu c hn hp kh X c t khi so vi H2 bng 8. Sc X vo lng d dung dch AgNO3 trong NH3 n phn ng hon ton, thu c hn hp kh Y v 24 gam kt ta. Hn hp kh Y phn ng va vi bao nhiu mol Br2 trong dung dch? A. 0,20 mol. B. 0,10 mol. C. 0,15 mol. D. 0,25 mol. Cu 25: Hn hp X gm Na, Ba, Na2O v BaO. Ha tan hon ton 21,9 gam X vo nc, thu c 1,12 lt kh H2 (ktc) v dung dch Y, trong c 20,52 gam Ba(OH)2. Hp th hon ton 6,72 lt kh CO2 (ktc) vo Y, thu c m gam kt ta. Gi tr ca m l A. 15,76. B. 21,92. C. 39,40. D. 23,64. Cu 26: Cho 100 ml dung dch amino axit X nng 0,4M tc dng va vi 80 ml dung dch NaOH 0,5M, thu c dung dch cha 5 gam mui. Cng thc ca X l A. (NH2)2C4H7COOH. B. NH2C2H4COOH. C. NH2C3H5(COOH)2. D. NH2C3H6COOH. Cu 27: Tin hnh in phn dung dch cha m gam hn hp CuSO4 v NaCl (hiu sut 100%, in cc tr, mng ngn xp), n khi nc bt u b in phn c hai in cc th ngng in phn, thu c dung dch X v 6,72 lt kh (ktc) anot. Dung dch X ha tan ti a 20,4 gam Al2O3. Gi tr ca m l A. 23,5. B. 51,1. C. 25,6. D. 50,4. Cu 28: Tin hnh cc th nghim sau: (a) Sc kh etilen vo dung dch KMnO4 long. (b) Cho hi ancol etylic i qua bt CuO nung nng. (c) Sc kh etilen vo dung dch Br2 trong CCl4. (d) Cho dung dch glucoz vo dung dch AgNO3 trong NH3 d, un nng. (e) Cho Fe2O3 vo dung dch H2SO4 c, nng. Trong cc th nghim trn, s th nghim c xy ra phn ng oxi ha - kh l A. 5. B. 3. C. 4. D. 2. Cu 29: Kim loi st tc dng vi dung dch no sau y to ra mui st(II)? A. MgSO4. B. CuSO4. D. HNO3 c, nng, d. C. H2SO4 c, nng, d. Cu 30: Lin kt ha hc gia cc nguyn t trong phn t HCl thuc loi lin kt A. cng ha tr khng cc. B. ion. C. cng ha tr c cc. D. hiro. Cu 31: Dung dch no sau y lm phenolphtalein i mu? A. glyxin. B. alanin. C. axit axetic. D. metylamin. Cu 32: Cho bt Fe vo dung dch gm AgNO3 v Cu(NO3)2. Sau khi cc phn ng xy ra hon ton, thu c dung dch X gm hai mui v cht rn Y gm hai kim loi. Hai mui trong X v hai kim loi trong Y ln lt l: A. Cu(NO3)2; Fe(NO3)2 v Ag; Cu. B. Cu(NO3)2; AgNO3 v Cu; Ag. C. Fe(NO3)2; Fe(NO3)3 v Cu; Ag. D. Cu(NO3)2; Fe(NO3)2 v Cu; Fe. Cu 33: T nilon-6,6 l sn phm trng ngng ca A. axit aipic v etylen glicol. B. etylen glicol v hexametyleniamin. C. axit aipic v hexametyleniamin. D. axit aipic v glixerol.
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Cu 34: Ha tan hon ton 1,805 gam hn hp gm Fe v kim loi X bng dung dch HCl, thu c 1,064 lt kh H2. Mt khc, ha tan hon ton 1,805 gam hn hp trn bng dung dch HNO3 long (d), thu c 0,896 lt kh NO (sn phm kh duy nht). Bit cc th tch kh u o iu kin tiu chun. Kim loi X l A. Mg. B. Cr. C. Zn. D. Al. Cu 35: Khi lng Ag thu c khi cho 0,1 mol CH3CHO phn ng hon ton vi lng d dung dch AgNO3 trong NH3, un nng l A. 43,2 gam. B. 21,6 gam. C. 16,2 gam. D. 10,8 gam. Cu 36: Hn hp X gm Ba v Al. Cho m gam X vo nc d, sau khi cc phn ng xy ra hon ton, thu c 8,96 lt kh H2 (ktc). Mt khc, ha tan hon ton m gam X bng dung dch NaOH, thu c 15,68 lt kh H2 (ktc). Gi tr ca m l A. 19,1. B. 24,5. C. 29,9. D. 16,4. Cu 37: Cho 1,37 gam Ba vo 1 lt dung dch CuSO4 0,01M. Sau khi cc phn ng xy ra hon ton, khi lng kt ta thu c l A. 3,31 gam. B. 1,71 gam. C. 2,33 gam. D. 0,98 gam. Cu 38: Cc cht trong dy no sau y u to kt ta khi cho tc dng vi dung dch AgNO3 trong NH3 d, un nng? A. vinylaxetilen, glucoz, anehit axetic. B. vinylaxetilen, glucoz, axit propionic. C. vinylaxetilen, glucoz, imetylaxetilen. D. glucoz, imetylaxetilen, anehit axetic. Cu 39: Cho X l hexapeptit AlaGlyAlaValGlyVal v Y l tetrapeptit GlyAlaGlyGlu. Thy phn hon ton m gam hn hp gm X v Y thu c 4 amino axit, trong c 30 gam glyxin v 28,48 gam alanin. Gi tr ca m l A. 87,4. B. 73,4. C. 83,2. D. 77,6. Cu 40: Tn thay th (theo IUPAC) ca (CH3)3CCH2CH(CH3)2 l A. 2,2,4-trimetylpentan. B. 2,4,4-trimetylpentan. C. 2,4,4,4-tetrametylbutan. D. 2,2,4,4-tetrametylbutan. II. PHN RING (10 cu)
Th sinh ch c lm mt trong hai phn (Phn A hoc Phn B)

A. Theo chng trnh Chun (10 cu, t cu 41 n cu 50) Cu 41: Cho cc cp oxi ha - kh c sp xp theo th t tng dn tnh oxi ha ca cc ion kim loi: Al3+/Al; Fe2+/Fe; Sn2+/Sn; Cu2+/Cu. Tin hnh cc th nghim sau: (a) Cho st vo dung dch ng(II) sunfat. (b) Cho ng vo dung dch nhm sunfat. (c) Cho thic vo dung dch ng(II) sunfat. (d) Cho thic vo dung dch st(II) sunfat. Trong cc th nghim trn, nhng th nghim c xy ra phn ng l: A. (a) v (c). B. (a) v (b). C. (b) v (d). D. (b) v (c). Cu 42: Cho 25,5 gam hn hp X gm CuO v Al2O3 tan hon ton trong dung dch H2SO4 long, thu c dung dch cha 57,9 gam mui. Phn trm khi lng ca Al2O3 trong X l A. 20%. B. 60%. C. 40%. D. 80%. Cu 43: t chy hon ton hn hp X gm 0,07 mol mt ancol a chc v 0,03 mol mt ancol khng no, c mt lin kt i, mch h, thu c 0,23 mol kh CO2 v m gam H2O. Gi tr ca m l A. 2,34. B. 8,40. C. 5,40. D. 2,70. Cu 44: Cho cc pht biu sau: (a) Trong bng tun hon cc nguyn t ha hc, crom thuc chu k 4, nhm VIB. (b) Cc oxit ca crom u l oxit baz. (c) Trong cc hp cht, s oxi ha cao nht ca crom l +6. (d) Trong cc phn ng ha hc, hp cht crom(III) ch ng vai tr cht oxi ha. (e) Khi phn ng vi kh Cl2 d, crom to ra hp cht crom(III). Trong cc pht biu trn, nhng pht biu ng l: A. (a), (b) v (e). B. (b), (d) v (e). C. (b), (c) v (e). D. (a), (c) v (e).
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Cu 45: Trong cc dung dch: CH3CH2NH2, H2NCH2COOH, H2NCH2CH(NH2)COOH, HOOCCH2CH2CH(NH2)COOH, s dung dch lm xanh qu tm l A. 1. B. 2. C. 4. D. 3. Cu 46: Th nghim vi dung dch HNO3 thng sinh ra kh c NO2. hn ch kh NO2 thot ra t ng nghim, ngi ta nt ng nghim bng: (a) bng kh. (b) bng c tm nc. (c) bng c tm nc vi. (d) bng c tm gim n. Trong 4 bin php trn, bin php c hiu qu nht l A. (d). B. (c). C. (b). D. (a). Cu 47: Cho X v Y l hai axit cacboxylic mch h, c cng s nguyn t cacbon, trong X n chc, Y hai chc. Chia hn hp gm X v Y thnh hai phn bng nhau. Phn mt tc dng ht vi Na, thu c 4,48 lt kh H2 (ktc). t chy hon ton phn hai, thu c 13,44 lt kh CO2 (ktc). Phn trm khi lng ca Y trong hn hp l A. 42,86 %. B. 57,14%. C. 85,71%. D. 28,57%. Cu 48: Cho phng trnh phn ng aAl + bHNO3 cAl(NO3)3 + dNO + eH2O. T l a : b l A. 2 : 3. B. 1 : 3. C. 1 : 4. D. 2 : 5. Cu 49: Dy cc cht u c kh nng tham gia phn ng thy phn trong dung dch H2SO4 un nng l: A. saccaroz, tinh bt v xenluloz. B. glucoz, saccaroz v fructoz. C. fructoz, saccaroz v tinh bt. D. glucoz, tinh bt v xenluloz. Cu 50: Hn hp X gm H2, C2H4 v C3H6 c t khi so vi H2 l 9,25. Cho 22,4 lt X (ktc) vo bnh kn c sn mt t bt Ni. un nng bnh mt thi gian, thu c hn hp kh Y c t khi so vi H2 bng 10. Tng s mol H2 phn ng l A. 0,050 mol. B. 0,075 mol. C. 0,070 mol. D. 0,015 mol. B. Theo chng trnh Nng cao (10 cu, t cu 51 n cu 60) Cu 51: Cho 13,6 gam mt cht hu c X (c thnh phn nguyn t C, H, O) tc dng va vi dung dch cha 0,6 mol AgNO3 trong NH3, un nng, thu c 43,2 gam Ag. Cng thc cu to ca X l A. CH C[CH2]2CHO. B. CH2=C=CHCHO. C. CH CCH2CHO. D. CH3C CCHO.
+ dungdch NaOH, d 2 Cu 52: Cho s phn ng Cr X Y. to +Cl , d

Cht Y trong s trn l B. Cr(OH)3. A. Na[Cr(OH)4].

C. Na2Cr2O7.

D. Cr(OH)2.

Cu 53: Hn hp X gm ancol metylic, ancol etylic v glixerol. t chy hon ton m gam X, thu c 15,68 lt kh CO2 (ktc) v 18 gam H2O. Mt khc, 80 gam X ha tan c ti a 29,4 gam Cu(OH)2. Phn trm khi lng ca ancol etylic trong X l A. 16%. B. 8%. C. 46%. D. 23%. Cu 54: Cho cc pht biu sau: (a) x l thy ngn ri vi, ngi ta c th dng bt lu hunh. (b) Khi thot vo kh quyn, freon ph hy tng ozon. (c) Trong kh quyn, nng CO2 vt qu tiu chun cho php gy ra hiu ng nh knh. (d) Trong kh quyn, nng NO2 v SO2 vt qu tiu chun cho php gy ra hin tng ma axit. Trong cc pht biu trn, s pht biu ng l A. 1. B. 3. C. 2. Cu 55: Trng hp no sau y khng xy ra phn ng? (a) CH2=CHCH2Cl + H2O (b) CH3CH2CH2Cl + H2O
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to

D. 4.

 (c) C6H5Cl + NaOH (c)

to

t o cao, p cao

; (vi C6H5 l gc phenyl)

(d) C2H5Cl + NaOH A. (b). B. (c). C. (a). D. (d). Cu 56: Cho phng trnh phn ng aFeSO4 + bK2Cr2O7 + cH2SO4 dFe2(SO4)3 + eK2SO4 + fCr2(SO4)3 + gH2O. T l a : b l A. 2 : 3. B. 3 : 2. C. 6 : 1. D. 1 : 6. Cu 57: Cho 12 gam hp kim ca bc vo dung dch HNO3 long (d), un nng n phn ng hon ton, thu c dung dch c 8,5 gam AgNO3. Phn trm khi lng ca bc trong mu hp kim l A. 55%. B. 45%. C. 65%. D. 30%. Cu 58: Peptit X b thy phn theo phng trnh phn ng X + 2H2O 2Y + Z (trong Y v Z l cc amino axit). Thy phn hon ton 4,06 gam X thu c m gam Z. t chy hon ton m gam Z cn va 1,68 lt kh O2 (ktc), thu c 2,64 gam CO2; 1,26 gam H2O v 224 ml kh N2 (ktc). Bit Z c cng thc phn t trng vi cng thc n gin nht. Tn gi ca Y l A. lysin. B. axit glutamic. C. alanin. D. glyxin. Cu 59: Cho cc pht biu sau: (a) Glucoz c kh nng tham gia phn ng trng bc. (b) S chuyn ha tinh bt trong c th ngi c sinh ra mantoz. (c) Mantoz c kh nng tham gia phn ng trng bc. (d) Saccaroz c cu to t hai gc -glucoz v -fructoz. Trong cc pht biu trn, s pht biu ng l A. 1. B. 2. C. 4. D. 3. Cu 60: Trng hp no sau y, kim loi b n mn in ha hc? A. Thp cacbon trong khng kh m. B. t dy st trong kh oxi kh. C. Kim loi st trong dung dch HNO3 long. D. Kim loi km trong dung dch HCl.
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HT ----------

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