N TP HA HC Cu 1.

Cho cc phn ng sau: (1) H2O2 + KNO2 H2O + KNO3 (2) H2O2 + Ag2O 2Ag + H2O + O2 (3) H2O2 + 2KI I2 + 2KOH (4) 5H2O2 + 2KMnO4 + 3H2SO4 5O2 + 8H2O + 2MnSO4 + K2SO4 S phn ng trong H2O2 ng vai tr cht oxi ho l A. 2. B. 3. C. 4 D. 1. Cu 2. Sc kh clo d vo dung dch H2S thu c dung dch X. Nh dung dch BaCl2 vo X, hin tng quan st c l A. xut hin kt ta BaSO3 mu trng. B. xut hin kt ta BaSO4 mu trng. C. khng c kt ta xut hin. D. xut hin kt ta S mu vng. Cu 3. Ch dng mt thuc th no sau y phn bit etanal, propanon v phenol? A. H2 (t0, Ni) B. Dung dch Na2CO3 C. Nc brom D. Dung dch HCl Cu 4. Khi un nng ancol X vi H2SO4 c lm xc tc iu kin nhit thch hp thu c anken Y. d Y/X = 0,7. Bit hiu sut ca phn ng l 100%. CTPT ca ancol X l: A. C4H9OH B. C3H5OH C. C3H7OH D. C2H5OH Cu 5. Nung hn hp kh X gm H2, C2H2 v C2H4 (xt Ni) n khi phn n xong, thu c 5,6 lt hn hp kh Y, dY/H2 = 12,2. t chy hon ton X ri hp th ton b sn phm chy vo dung dch Ca(OH)2 d, thu c m gam kt ta. Gi tr ca m l A. 40 B. 25 C. 50 D. 20 Cu 6. Cho 3 gam Cu tc dng vi 2 lt dung dch c pH = 2 gm HNO 3 aM v H2SO4. Sau khi phn ng xong thu c 0,112 lt NO ( ktc l spkh duy nht) v 1,2 gam mui. Gi tr ca a l A. 7,5. 10-3 B. 5,0.10-3 C. 0,025 D. 2,5. 10-3 Cu 7. Axit sunfuric c thng c dng lm kh cc cht kh m. Dy cc cht kh no di y c th c lm kh bng axit sunfuric c ? A. H2S, HI. B. SO3, CO2. C. NH3 , H2. D. CO2 , O2. Cu 8. Dung dch X gm 0,1 mol H+, z mol Al3+, t mol NO3- v 0,02 mol SO42- . Cho 120 ml dung dch Y gm KOH 1,2M v Ba(OH)2 0,1M vo X, sau khi cc phn ng kt thc, thu c 3,732 gam kt ta. Gi tr ca z, t ln lt l A. 0,02 v 0,012. B. 0,012 v 0,096. C. 0,012 v 0,104. D. 0,02 v 0,12. Cu 9. Cho cc cht: (NH4)2CO3 , NH4HCO3 , NaHSO4 , NaHSO3 , Al2O3 , Al , Al2(SO4)3, NaAlO2 . S cht lng tnh l A. 6 B. 4 C. 5 D. 3 Cu 10. Hp cht hu c A (cha C,H,O) ch c cc nhm chc c hiro linh ng .Khi t chy a mol A th thu c CO 2 v H2O c s mol bng nhau. Mt khc khi cho cng lng cht A tc dng ht vi Na v NaHCO 3 th thu c th tch H 2 bng th tch ca CO2 o cng iu kin . CTCT ca A l A. HOCH2CH2OH B. HOCH2COOH C. HOOC-COOH D. HOCH2CH(OH)COOH Cu 11. in phn dung dch gm Cu(NO3)2 v AgNO3 vi I = 2A ti khi catot bt u c bt kh thot ra th ngng in phn, thy ht 1h420. Khi lng dung dch sau in phn gim 4,72 gam. Tng khi lng mui trong dung dch ban u l A. 7,60 gam B. 8,06 gam C. 9,04 gam D. 8,84 gam Cu 12. Mt hn hp gm mt ankan X v mt anken Y c cng s nguyn t cacbon trong phn t v s mol bng nhau. m gam hn hp ny lm mt mu va 80g dung dch brom 20%. t chy hon ton m gam hn hp trn thu c 0,6 mol CO 2. X v Y c cng thc phn t l: A. C4H10 v C4H8 B. C2H6 v C2H4 C. C3H8 v C3H6 D. C5H12 v C5H10 Cu 13. Hn hp kh X gm O2 ,O3 c t khi so vi H 2 bng 19,2 . Hn hp Y gm CO, H 2 c t khi so vi H 2 bng 7,5 .Cn bao nhiu lit X oxi ha ht 6,0 lit Y ? ( th tch kh o cng iu kin) A. 2,2 B. 3,25 C. 2,5 D. 2,75 Cu 14. Sc t t 2,24 lit CO2 vo 2 lit dung dch Ca(OH)2 0,1M thu c dung dch A. A c dn in so vi dung dch ban u l A. khng i B. gim C. tng D. c th tng hoc gim Cu 15. phn bit axit fomic v axit acrylic, c th dng thuc th l A. qu tm m. B. dung dch Br2 /CCl4. C. dung dch NaHCO3. D. dung dch nc Br2 . Cu 16. t ht V lt ( 0oC; 2 atm) hn hp X gm C2H4 v C3H8 thu c 15,68 lt CO2 (ktc) v 14,4 gam H2O. Gi tr V l A. 6,72 B. 3,36 C. 4,48 D. 1,68 Cu 17. in phn 500 ml dung dch NaCl 0,4M (in cc tr, mng ngn xp) vi cng dng in khng i l 9,65A trong thi gian 16 pht 40 giy. Dung dch sau in phn ho tan c ti a bao nhiu gam bt nhm ? A. 1,35 B. 10,8 C. 5,4 D. 2,7 Cu 18. Mt hn hp X gm axetilen, etilen v mt hirocacbon M. Cho m gam hn hp X li t t qua dung dch brom d thy khi lng bnh brom tng 5,4 gam. Mt khc em t chy hon ton m gam hn hp X thu c 11,2 lt CO 2 ( ktc) v 9 gam H2O. % khi lng ca M c trong hn hp X l A. 22,86% B. 22,88% C. 22,85% D. 22,87% Cu 19. Cho cc cht: NaOH, HF, HBr, CH3COOH, C2H5OH, C12H22O11(saccaroz), HCOONa, NaCl, NH4NO3. Tng s cht thuc cht in li v cht in li mnh l A. 7 v 6 B. 8 v 6 C. 7 v 5 D. 8 v 5 Cu 20. Cho cc cht: Al, Fe3O4, dd NaOH, dd NH4Cl, dd NaNO2, dd H2SO4 20%, dd Na2SO3, KMnO4, HCl. Khi cho cc cht tc dng vi nhau theo tng i mt th thu c bao nhiu kh khc nhau t cc phn ng (c un nng nu cn) ? A. 4 B. 5. C. 6 D. 7

Cu 21. Cho 2,24 lt kh CO 2 ( ktc) li vo 200 ml dung dch NaOH 1,50M, thu c dung dch X. Nh t t 200 ml dung dch HCl 1,25M vo dung dch X thu c V lt kh CO2 ( 0oC; 0,50atm). Gi tr ca V l A. 3,36 B. 1,12 C. 4,48 D. 2,24 Cu 22. Cp cht X v Y no sau y tho mn l X khng phn cc v Y c nhit si cao nht ? A. SO2 v C2H5OH B. CO2 v C2H5OH C. CO2 v H2O D. SO2 v H2O Cu 23. Cho 13,6 hn hp bt X gm Fe v Mg vo 200 ml dung dch CuSO 4 1M. Sau khi phn ng kt thc thu c cht rn gm hai kim loi, cho hai kim loi ny trong dung dch HCl d thu c 2,24 lt H2 ( ktc). % khi lng ca Fe trong hn hp X l A. 41,18% B. 82,35% C. 17,65% D. 58,82% Cu 24. Dung dch axit HF 1M c in li l 2,6%. pH ca dung dch l A. 1,59 B. 112,4 C. 2,58 D. 2,59 Cu 25. Ancol X tc dng vi Na d cho th tch H 2 bng th tch hi ancol X. Mt khc t chy ht mt th tch hi ancol X thu c cha n ba th tch kh CO2 (cc th tch o cng iu kin to, P). Ancol X c tn gi l A. etylenglycol B. propaniol C. ancol etylic D. ancol propylic Cu 26. Hn hp X c m gam gm Al, MgO v CaCO3. Cho X vo nc vi trong d, sau khi phn ng kt thc thu c 18 gam cht rn v 3,36 lt kh H2 ( ktc). Mt khc ho tan X trong dung dch HCl d th thu c 5,6 lt kh Y ( ktc). Phn trm khi lng ca MgO c trong hn hp X l A. 38,64% B. 38,65% C. 13,50% D. 13,05% Cu 27. Mt hp cht X c mt s tnh cht nh: dung dch X lm xanh giy qu tm, t trn ngn la n cn c mu vng, tc dng c vi kh cacbonic, tc dng c vi dung dch AlCl3 thy c bt kh. Hp cht X c khi lng phn t l A. 84u B. 138u. C. 106u D. 40u Cu 28. Ho tan hon ton 2,4 gam FeS2 trong dung dch H2SO4 c, nng (d). Ton b kh thu c cho li vo dung dch brom d. Khi lng brom ( gam) tham gia phn ng l A. 8,8 B. 12 C. 17,60 D. 24 Cu 29. C mt s kh c c thi ra t cc nh my v cc ng c, nh: CO 2, CO, NO2, H2S, SO2. Cho cc kh ny li qua nc vi trong (d) th c bao nhiu kh c loi b ? A. 5 B. 3 C. 2 D. 4 Cu 30. Hp cht hu c X c cng thc phn t C4H14O3N2. Cho X tc dng vi dung dch NaOH th thu c 2 cht kh iu kin thng u c kh nng lm xanh giy qu m. S cng thc cu to ph hp ca X l A. 4 B. 5 C. 3. D. 2 Cu 31. Ancol X no, mch h tc dng c vi Cu(OH) 2 to dung dch mu xanh lam. Oxi ha hon ton X th s mol Oxi cn dng gp 5,5 ln s mol X. S cng thc cu to ph hp ca X l A. 2 B. 4 C. 3 D. 5 Cu 32. t chy hon ton 43,1 gam hn hp X gm axit axetic, glyxin, alalin v glutamic thu c 1,4 mol CO 2 v mol 1,45 mol H2O. Mt khc 43,1 gam X tc dng va vi 0,3 mol HCl. Nu cho 43,1 gam hn hp X tc dng vi 0,7 mol NaOH trong dung dch sau c cn th thu c khi lng cht rn khan l A. 58,5 gam B. 60,3 gam C. 71,1 gam D. 56,3 gam Cu 33. t chy a mol X l trieste ca glixerol vi axit n chc mch h thu c b mol CO 2 v c mol H2O, bit b - c = 4a. Hiro ha m gam X cn 6,72 lt H2 (ktc) thu c 39 gam mt sn phm. Nu un m gam X vi dung dch cha 0,7 mol NaOH n phn ng hon ton, c cn dung dch sau phn ng thu c cht rn khan c khi lng l A. 57,2 gam B. 52,6 gam C. 61,48 gam D. 53,2 gam Cu 34. Cracking ht 1,5 mol hexan thu c sn phm cui cng gm 5% th tch l metan, 50% etilen, 25% propen, cn li l cc ankan khc. Tnh khi lng ca propen trong hn hp X A. 21,5 gam B. 48,84 gam C. 15,75 gam D. 43 gam Cu 35. Cho 0,3 mol hn hp kh gm HCHO v C 2H2 tc dng hon ton vi lng d dung dch AgNO 3/NH3 to ra 91,2 gam kt ta. Nu cho ton b lng X trn vo bnh ng Br2/CCl4 d th khi lng Brom tham gia phn ng ti a l A. 40 gam B. 32 gam C. 64 gam D. 80 gam Cu 36. Dung dch X cha 0,01 mol Fe(NO3)3 v 0,15 mol HCl c th ha tan ti a m gam Cu (sp kh NO). Tm m ? A. 5,12 B. 2,88 C. 3,92 D. 3,2 Cu 37. ha tan mt mu Zn trong dung dch HCl 25 0C cn 243 pht. Cng mu Zn tan ht trong dung dch HCl nh trn 65 0C cn 3 pht. ha tan ht mu Zn trong dung dch HCl c nng nh trn 450C cn thi gian bao lu: A. 9 pht B. 81 pht C. 27 pht D. 18 pht Cu 38. Hn hp X gm 2 este n chc. Cho 0,5 mol X tc dng vi dung dch AgNO 3/NH3 d thu c 43,2g Ag. Cho 14,08g X tc dng vi dung dch KOH va thu c hn hp 2 mui ca 2 axit ng ng lin tip v 8,256g hn hp 2 ancol no n chc ng ng lin tip, mch h. Cng thc ca 2 ancol l: A. C4H9OH v C5H11OH B. CH3OH v C2H5OH C. C2H5OH v C3H7OH D. C3H7OH v C4H9OH Cu 39. X l tetrapeptit c cng thc Gly Ala Val Gly. Y l tripeptit c cng thc Gly Val Ala. un m gam hn hp A gm X, Y c t l mol tng ng l 4:3 vi dung dch KOH va sau khi phn ng xy ra hon ton c cn dung dch thu c 257,36g cht rn khan. Gi tr ca m l: A. 150,88 gam B. 155,44 gam C. 167,38 gam D. 212,12 gam Cu 40. Ha tan 54,44 gam hn hp X gm PCl 3 v PBr3 vo nc c dung dch Y. trung ha hon ton dung dch Y cn 500 ml dung dch KOH 2,6M. % khi lng ca PCl3 trong X l:

A. 26,96%

B. 12,125

C. 8,08%

D. 30,31%