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  • Formación de Monocarboximetilcelulosa

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    Luis Mesen
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    The document describes a method for preparing high regioselectively mono-substituted carboxymethylcelluloses (CMCs) by ring-opening polymerization of glucose orthoester derivatives. Specifically, 6-O-CMC and 3-O-CMC were synthesized by introducing a tert-butyloxycarbonylmethyl protecting group to the orthoester at the O-3 or O-6 position before polymerization. 2-O-CMC was prepared by tert-butyloxy-carbonylmethylation of a cellulose derivative with a free O-2 position.

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    Оригинальное название

    Formación de monocarboximetilcelulosa

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    The document describes a method for preparing high regioselectively mono-substituted carboxymethylcelluloses (CMCs) by ring-opening polymerization of glucose orthoester derivatives. Specifically, 6-O-CMC and 3-O-CMC were synthesized by introducing a tert-butyloxycarbonylmethyl protecting group to the orthoester at the O-3 or O-6 position before polymerization. 2-O-CMC was prepared by tert-butyloxy-carbonylmethylation of a cellulose derivative with a free O-2 position.

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    5 просмотров1 страница

    Formación de Monocarboximetilcelulosa

    Загружено:

    Luis Mesen
    The document describes a method for preparing high regioselectively mono-substituted carboxymethylcelluloses (CMCs) by ring-opening polymerization of glucose orthoester derivatives. Specifically, 6-O-CMC and 3-O-CMC were synthesized by introducing a tert-butyloxycarbonylmethyl protecting group to the orthoester at the O-3 or O-6 position before polymerization. 2-O-CMC was prepared by tert-butyloxy-carbonylmethylation of a cellulose derivative with a free O-2 position.

    Авторское право:

    Attribution Non-Commercial (BY-NC)
    Скачайте в формате PDF, TXT или читайте онлайн в Scribd
    Отметить как неприемлемый контент
    из 1

    CELLULOSE CHEMISTRY AND TECHNOLOGY

    PREPARATION OF HIGH REGIOSELECTIVELY MONO-SUBSTITUTED CARBOXYMETHYLCELLULOSES


    NAOTAKA NISHIO, TOSHIYUKI TAKANO, HIROSHU KAMITAKAHARA and FUMIAKI NAKATSUBO Division of Forest and Biomaterial Science, Graduate School of Agriculture, Kyoto University, Sakyo-ku, Kyoto, 606-8502, Japan

    This paper is dedicated to Prof. Cr. I. Simionescu on the occasion of his 85th birth anniversary.

    Received March 14, 2005

    High

    regioselectively

    mono-substituted

    carboxymethylcelluloses

    (that

    is,

    6-O-Carboxy-methylcellulose (6-O-CMC), 3-O-Carboxymethylcellulose (3-O-CMC), 2-O-Carboxy-methylcellulose (2-O-CMC)) were prepared by ring-opening

    polymerization of glucose orthoester derivatives. In the synthesis of 6-O-CMC or 3-O-CMC, tert-butyloxycarbonylmethyl (t-BCM) group, which can be converted to carboxymethyl group, was introduced to the orthoester at O-3 or O-6 position, respectively, before polymerization. On the other hand, 2-O-CMC was prepared by tert-butyloxy-carbonylmethylation of the cellulose derivative, which had a free

    Cellulose Chem. Technol., 39, 56, 377387 (2005)

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