X1

A1

B1

C1

X2

A2

90
90
90
90
90
90
90

0.47
0.47
0.47
0.47
0.47
0.47
0.47

13.7819
13.7819
13.7819
13.7819
13.7819
13.7819
13.7819

2726.81
2726.81
2726.81
2726.81
2726.81
2726.81
2726.81

217.572
217.572
217.572
217.572
217.572
217.572
217.572

0.18
0.18
0.18
0.18
0.18
0.18
0.18

13.932
13.932
13.932
13.932
13.932
13.932
13.932

90

0.47

13.7819

2726.81

217.572

0.18

13.932

90

0.47

13.7819

2726.81

217.572

0.18

13.932

90

0.47

13.7819

2726.81

217.572

0.18

13.932

A1

B1

C1

Y1

Y2

A2

90
90
90
90
90
90
90

1
1
1
1
1
1
1

13.7965
13.7965
13.7965
13.7965
13.7965
13.7965
13.7965

2723.73
2723.73
2723.73
2723.73
2723.73
2723.73
2723.73

218.265
218.265
218.265
218.265
218.265
218.265
218.265

0
0
0
0
0
0
0

13.8635
13.8635
13.8635
13.8635
13.8635
13.8635
13.8635

90

13.7965

2723.73

218.265

13.8635

90

13.7965

2723.73

218.265

13.8635

90

13.7965

2723.73

218.265

13.8635

Mercedes Cruz Gonzalez

Termodinmica
Exmen

Para el sistema benceno (1)/ tolueno(2)/ etilbence

2788,51

in P1 sat = 13.8858 :220.79 ;

donde T esta en c y la presion vapor en Kpa consi

a) Py yk, dado que t= 110C x1= 0.22 x2= 0.37
b)Py xk, dado que t= 105C y1= 0.45 y2= 0.32
c) ty yk, dado que p= 90kpa x1= 0.47 x2= 0.18
d)ty xk, dado que p= 95kpa y1= 0.52 y2= 0.28

a)
temperatura
X1
X2
x3

3056.96
3056.96
3056.96
3056.96
3056.96
3056.96
3056.96

b)
temperatura
y1
C2
y2
217.625 y3
217.625
217.625 C)
217.625
217.625
217.625
217.625

3056.96

B2

110
0.22 Beceno (1)
0.37 Tolueno (2)
0.41 etilbenceno(3)

A
13.7819
13.932
13.9726

B
2726.81
3056.96
3259.93

105
0.45 Beceno (1)
0.32 Tolueno (2)
0.23 etilbenceno(3)

A
13.7819
13.932
13.9726

B
2726.81
3056.96
3259.93

X 1=

P=
Benceno
0.47

217.625

A1=

13.7819

A2=

3056.96

217.625

2726.81

3056.96

217.625

B1=
C1=

217.572

B2=
C2=

76.1991

T2

T1

sat

Tsup
101.121504

B2

C2

Iteracin #
1
2
3
4
5
6
7

P1sat
185.9886121

90 Kpa
X 2=

P2sat

sat

P3sat

0.89144141 35.5697274

3174.78
3174.78
3174.78
3174.78
3174.78
3174.78
3174.78

211.7
211.7
211.7
211.7
211.7
211.7
211.7

8
9
10

3174.78

211.7

A1=

13.7965

A2=

3174.78

211.7

2723.73

3174.78

211.7

B1=
C1=

218.265

B2=
C2=

74.7135

T2sat

P=
1 CLOROBUTANO
Y 1=
1

T1

sat

Tsup

P1sat

90 Kpa
CLOROBENCENO
Y 2=

P2sat

a12

74.7134583

90 16.1012222 5.58963779

Iteracin #
1
2
3
4
5
6
7
8
9

74.7134583
74.7134583
74.7134583
74.7134583
74.7134583
74.7134583
74.7134583
74.7134583
74.7134583

90
90
90
90
90
90
90
90
90

10

X 1=
0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
1

140

120

T burbuja
127.3522207
117.2473722
109.0774093
102.3242493
96.63078265
91.74809007
87.49924894
83.75579854
80.4223993
77.42683091
74.71345829

16.1012222
16.1012222
16.1012222
16.1012222
16.1012222
16.1012222
16.1012222
16.1012222
16.1012222

5.58963779
5.58963779
5.58963779
5.58963779
5.58963779
5.58963779
5.58963779
5.58963779
5.58963779

Y 1=

T rocio

0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
1

127.352221
124.511675
121.450658
118.125445
114.477002
110.42261
105.840614
100.54018
94.1929546
86.1466389
74.7134583

120

100

80

60

40

20

0
0

X 1=
0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
1

0.2

0.4

Psat burbuja

Y 1=
0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
1

0.6

Psat rocio

nceno (1)/ tolueno(2)/ etilbenceno(3), la presion de vapor de los componentes puros esta dada por:
51
;
79

3096.52

3279.47

in P2 sat = 13.9987 :219.48 ;

in P3 sat = 14.0045 :213.20

y la presion vapor en Kpa considerando que la ley de raoult describe los estados de quilibrio para el sistema, determine:
t= 110C x1= 0.22 x2= 0.37 x3= 0.41
presion de burbuja
t= 105C y1= 0.45 y2= 0.32 y3= 0.23
presion de rocio
p= 90kpa x1= 0.47 x2= 0.18 x3= 0.35
temperatura de burbuja
p= 95kpa y1= 0.52 y2= 0.28 y3= 0.20
temperatura de rocio

presion de burbuja
p1 sat
p2 sat
p3 sat
presion
y1
y2
C
217.572 234.532148
99.61694851 47.3713357
107.8775912 0.478292777
0.341667538
217.625
212.300
presion de rocio
p1 sat
p2 sat
p3 sat
presion
x1
x2
C
217.572 206.141423
86.2048853 40.3920162
86.28687133 0.188361425
0.320304339
217.625
212.300

k=2

Introducir datos
Seleccionar datos manual

Tolueno
0.18

x=

Etilbenceno
0.35

13.932

A=

13.9726

Tburbuja=

3056.96

B=
C=

3259.93

212.300

Y 1=
Y 2=

131.8362

e=

217.625

T3

106.4736
a13

sat

a23

5.22884558 0.0250618

a33
1

Pksat
E x aik
2.08463579

43.17300907

1
0.0001
Tn1
83.05610551

Tn2
128.9437407

k=2
CLOROBENCENO
0

Introducir datos
Seleccionar datos manual
Trocio = 74.7134583 C

13.8635
211.7

X 1=
X 2=

127.3522

e=

3174.78

a22

Pksat

1
0
0.0001
Tn

|Tn-Tsup|<= e PROPUESTA

E yi /aik

16.10122218

74.7134583

0 CORRECTO

1
1
1
1
1
1
1
1
1

0.17890247
0.17890247
0.17890247
0.17890247
0.17890247
0.17890247
0.17890247
0.17890247
0.17890247
0.17890247

16.10122218
16.10122218
16.10122218
16.10122218
16.10122218
16.10122218
16.10122218
16.10122218
16.10122218

74.7134583
74.7134583
74.7134583
74.7134583
74.7134583
74.7134583
74.7134583
74.7134583
74.7134583

0
0
0
0
0
0
0
0
0

CORRECTO
CORRECTO
CORRECTO
CORRECTO
CORRECTO
CORRECTO
CORRECTO
CORRECTO
CORRECTO

T DE BURBUJA
T ROCIO

0.8

1.2

y3
0.18003969

x3
0.49133424

Tnueva

|Tn-Tsup|<= e PROPUESTA