Sample Calculations

Calibration:

Plotted values:
samples
Water
Acetone
Ethyl acetate

(y)

(x)
-4

9.425959091 x 10-3
0.01876524676
0.01575602668

7.776569855 x 10
5.175140337 x 10-4
5.64027746 x 10-4

m= -0.02872984401 (-B)
b=1.041056976 x 10-3 (A) cm2/s2
r2=0.9784544817
Effect of concentration
concentration
Mpyc+sample, g
0.95
24.6816
0.80
25.0666
0.60
25.5302
0.40
25.9559
0.20
26.8518
0.10
26.5390
*plotted values are concentration vs.

solution
0.8010724854
0.8385112321
0.88235933176
0.9249898746
0.9634885753
0.98169925581

Flow time, s
25.1333333
28.2
30.0333333
26.66666667
18.83333333
14.3333333

m= -7.2405526 x 10-3
mpyc= 16.4438 g; mpyc+water= 26.6825 g
o

density of the solution

At 0.95M
(

Viscosity

0.02187595117
0.02547111653
0.02847203607
0.0266756799
0.02036049015
0.01679366945

)(

Effect of temperature
T, oC
30
35
40
45
50
o

T, K
303.15
308.15
313.15
318.15
323.15

G (J/mol)
15320.81015
15185.19007
15316.04781
15381.49324
15265.40355

)(

)(

)(

Gibbs free energy

(

, g/cm-s
0.02305618504
0.01971642944
0.01876772985
0.01744998327
0.01519805128

Viscosity at 30C

, g/mL
0.7958
0.7919
0.7808
0.7840
0.7801

Flow time, s
26.8
22.7
21.6
20
17.1

)(

(
(

Plot G vs T in K: slope= -S; y-int=H

Slope= 1.7098 = -S

)(
)(

)(

S = -1.7098 J/mol-K

y-int = 14758 = H = 14758 J/mol

o

Polymer (NaCMC) solutions

Polymer (NaCMC) solutions.

to = flow time of solvent = 0.673333333 seconds
t at 0.1g/dL = 0.716666667 seconds
Concentration, c (g/dL) = 0.1
sp =

= 0.064356436

]
)

red =

= 0.643564356 dL/g

( ) =

inh =

=
(

) = 0.623703307 dL/g

Plot of sp/c versus c.

Slope = 5.609818017
y-intercept =-0.276181277= []

Plot of inh versus c.

Slope = 1.435772813
y-intercept = 0.586921755 =[]
Calculation of . Using 0.001M NaCl solution.
[] = K a
a =
( a)1/a = ( )1/a
= ( )1/a
[] using red
= ( )1/a
=(

)1/0.91

= 4816.541414 g/mol

Size of molecule (S)

S=

4.520508138x10-21

Radius (r)

1/3

<r2>1/2 = (

)
=(

)
(

) 1/3

= 7.766113452x10-7