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Trochimczuk A.W.
Krawczyk J.
Rieger F.
Ho-Suk Choi
Wroclaw University of Technology

Politechnika Krakowska
Czech Technical University in Prague
Chungnam National University, South Korea
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546.2+546.9+547.1+666.3
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8-100 ( ,
CVD-).
- : Al, Cu, Fe, Ni, Zr, Ti,
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XIII -
-2010
14
529.12
POLYMER IMMOBILIZED ANALOGUES OF IONIC LIQUIDS

Trochimczuk A.W.
Wrocaw University of Technology, Faculty of Chemistry, 50-370 Wroclaw, Poland,
e-mail: Andrzej.Trochimczuk@pwr.wroc.pl
Ionic liquids (IL) can be defined as salts having low melting points, usually
below 100oC. In recent years this new type of material, attracted a lot of attention of
chemists due to some unique properties such as negligible vapour pressure, good
thermal stability and, what is especially important, high polarity. These features
allowed the use of ILs as environmentaly friendly (no vapour pressure) and safe
alternative to organic solvents. Task-specific Ionic Liquids (TSILs) can be defined
as ionic-liquids in which cation, anion or both of them have a functional group
attached covalently as a part of their structure. The group gives desired properties
(catalytic activity, ion-exchange).
Developments in catalysis using IL were widely studied and reviewed. By a
careful choice of the cation and anion it is possible to tune the properties of IL, for
example its miscibility with water and ability to dissolve substrates and products of
the reaction carried in such medium. However, sometimes it is not possible to achieve
easy separation of the reaction products from the IL. In such case the obvious choice
is the heterogenization of the ionic liquid by, for example, its immobilization in or on
the solid support. One of the first examples of such work was immobilization of the
imidazolium salts on the Merrifield type polymeric resin. In such a way it was
possible to prepare an efficient catalytic system for the nucleophilic substitution
reactions, which could be used many times with no loss of activity and it was easily
removable from the after reaction mixture. The supported ionic liquid phases were
also reviewed.
In this work we would like to present some results of research on solid
polymeric analogues of ionic liquids (IL-analogues), in which polarity of the material
is due to the presence of cations and anions known from the chemistry of ionic
liquids: imidazolium and anions like trifluoromethylsulfonate, trifluoroacetate, ptoluenosulfonate. Such materials are obtained by modification of lightly crosslinked
vinylbenzyl chloride-divinylbenzene copolymers with alkyl substituted imidazol,
followed by subsequent ion-exchange of suitable anions. By an introduction of an
additional function, such as for example sulfonic group, it was also possible to obtain
a catalytically active polymer immobilized IL. Additionally, this material, as
crosslinked ones, is totally insoluble in any solvent. The last feature makes possible a
range of applications such as reactive chromatography, column-continous processes.
15

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-2010
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2.1.2/6880).
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-2010
541.133 +544.6.018.47-036.5

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XIII -
-2010
22
542.952.6.691.175.5/8

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( 09-08-00890).
[1] Kiss Q. // Chem. Rev. 2001. V.101. 11. P. 3435-3456.

[2] .., .., .., ..
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23
621.315.592:548.25

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24
XIII -
-2010
MATHEMATICAL MODELING OF THE RAPID EXPANTION OF

SUPERCRITICAL FLUIDS
Anikeev V.I., Stepanov D.A., Yermakova A.
Boreskov Institute of Catalysis SB RAS, Novosibirsk 630090, Russian Federation,
e-mail: anik@catalysis.nsk.su
Mathematical modeling of the rapid expansion of supercritical fluid leading to the
formation and growth of nanoparticles of a solid substance predissolved in the fluid was
performed. According to the scheme of fluid motion, the mathematical model describes
three characteristic segments of the flow motion and a shock wave at the Mach disk: (1)
flow in a capillary; (2) supersonic expansion of a stream; (3) flow motion in subsonic
expansion region. To simulate normal shock wave, the equations of conservation of
mass, momentum and enthalpy were derived. Thermophysical and thermodynamic
parameters and phase state of the mixture were calculated for each isolated segment of
the flow motion using the RedlichKwongSoave equation of real gas state.
Algorithms and a program were developed for solving the model equations.
Choice of the solving methods was determined by specificity of the flow motion and
expansion in each of isolated regions. Thus, as the condition of critical outflow at the
capillary outlet should be satisfied, hydrodynamics of the flow motion in a capillary was
calculated by an iterative method.
Supersonic region of stream expansion is limited by the Mach disk, where all
parameters of the flow undergo an abrupt change, and transition from supersonic
expansion region to subsonic one occurs. In subsonic region of stream expansion the
motion is isobaric, thus the geometry of supersonic region forms so that at the normal
shock wave the post-shock pressure is equal to ambient pressure.
In subsonic isobaric segment of stream expansion the flow rate virtually vanishes;
temperature of the flow tends to ambient temperature. A model of this segment is
supplemented with the equations of nucleus formation and growth of the solid phase
particles along the expansion axis.
A parametric analysis of the mathematical model showed that critical radius and
size of the particles that form during rapid expansion of supercritical fluid depend both
on the parameters of reactor mixture and on the capillary geometry. Size of the nascent
particles can be varied in a wide range by changing the temperature and pressure of
reactor and/or environment at a fixed capillary geometry. Calculation was made for the
composition: 2 solvent 90 mol %, ethanol co-solvent 7.5 mol %, phenanthrene as
dissolved substance 2.5 mol %. Effect of the mixture composition on the outflow
hydrodynamics and particles growth was studied. Components of the mixture and their
percentage were varied. It is worthy of note that for some compositions solution of the
system does not exist. For instance, in some cases, a solid substance dissolved in
supercritical 2 becomes completely soluble in co-solvent under precritical conditions.
We tested several co-solvents: methanol, ethanol and isopropyl alcohol, in combination
with dissolved solid substances: naphthalene, biphenyl, phenanthrene and anthracene.
25
541.182:536.461

..
( ),
. , e-mail: anisimovmp@mail.ru

() , ,
.
[M.P. Anisimov.
J.Aerosol Sci., V.21, suppl.1, P. 23-25 (1990); ... , 352(6), 816818 (1997)].
[M. P. Anisimov, Hopke P.K., Rasmussen D.H. et al. J. Chem. Phys. V.
109(4) P.1435-1444 (1998)].

.
, [.. . . .,
, 1975],
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[L. Anisimova, M. Anisimov, P. Turner, and P.K. Hopke. Journal of Colloid and
Interface Science V. 290, 107-116 (2005)].
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.

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.
10-08-00124-.
XIII -
-2010
26
544.47:544.344
:

.., .., ..
. .. ( ),
. , e-mail: afanasev@catalysis.ru

. ,
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( SiO2 Al2O3),
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; ,

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-Al2O3.

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27
547.979
A NEW APPROACH IN APPLICATION OF LUMINOL REACTION FOR
TRACE BLOOD ANALYSIS
Balantseva E.V.*, Priante S., Vincenti M., Coluccia S. Martra G.,
University of Turin, Department of Inorganic, Physical and Materials Chemistry,
Turin, Italy, e-mail: Bal_lena@hotbox.ru
*
Ivanovo State University of Chemistry and Technology (ISUCT), Ivanovo, Russia
The emission of light observed when a solution containing luminol and hydrogen
peroxide is sprayed on dried bloodstains has been utilised by forensic scientists in
investigations involving violent crime for more than 40 years. During our investigation
of different nanopowders (NPs) (e.g., SiO2, TiO2, Al2O3, hydroxyapatite) we observed
an interesting phenomenon when the NPs were being added to system containing
luminol and H2O2 and blood, resulting in a significant increase of both intensity and
duration of CL [Patent. No. PCT/IB2009/055454].
To explain this phenomenon we started an investigation of the interaction
between hemoglobin (Hb) and inorganic powders mentioned above based on an
integrated approach resulting from the use of IR-/Vis-/EPR-spectroscopies and TGAanalysis. It is known that binding of Hb to a surface is a spontaneous molecular event
where entropic effects and enthalpic ones play a major role in stabilizing the NPsHb
complexes. But these weak interaction can greatly change a conformation of protein
adsorbed and consequently the structure of heme groups. But in which manner is Hb
structure being changed? On the base of IR-measurements of NPs/Hb pellets the extent
of protein folder was researched. At the same time, from the UV/VIS absorption and
reflectance spectra obtained for all NPs/Hb systems in solid and slurry states the affect
from addition of NaOH and H2O2 to NP/Hb have been observed. The data obtained by
this method can provide information about specific changes in heme group, iron state
and close its surroundings. The Al2O3/Hb and TiO2/Hb shown quite different behavior
and particular profile of its spectra in comparison with other NPs/Hb. Though UV/VISspectra allowed us to determine that Hb is adsorbed on NP surface predominantly as
MetHbFeIII(H2O) and MetHbFeIII(OH) the details about iron state can be taken from
EPR measurements. Moreover this method can provides additional data respond to free
radicals which could be formed during redox reaction involving a protein and/or heme.
We also involved the TGA analysis to estimate the amount of Hb irreversible adsorbed
on NP surface and determined that independence on nature of NPs, specific surface
area and size of nanoparticles we have mono layer of Hb for all studied systems. An
integrated analysis of the various type of data collected, giving information on both
quantitative and structural data, allowed to conclude that a relevant role is played by
the capability of NPs to act as efficient adsorbers (resulting in a spatial concentration of
the proteins containing the metal centers responsible for the activation of the Luminol
oxidation), combined with the level of unfolding of the protein structure, with opening
of the hydrophobic pockets where the heme groups are hosted, with a consequent
higher accessibility of the metallic catalytic centers.
XIII -
-2010
28
519.673:620.9.97
CHEMCAD

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, . , e-mail: fsovetin@inbox.lv

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544.431.8

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[6]. EPt pH
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( 05-0333151 09-03-01072).
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[3] A. V. Malashkevich, L. G. Bruk, O. N. Temkin, J. Phys. Chem. A, 1997, v.101,
51, p. 9825.
[4] . . , . . , . ., . . , . . ,
, 2001 ., . 42, 2, . 285-293.
[5] . . , . . , . . , . . , ,
. ., 2003 ., 7, . 1452-1461.
[6] L. G. Bruk, I. V. Oshanina, A. S. Zakieva, A. P. Kozlova, O. N. Temkin,
Kinetics and Catalysis, 1998, 39, 2, 183 186.
XIII -
-2010
30
66.048:548

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XIII -
-2010
32
628.34

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33
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e-mail: piligrim.tula.ru@gmail.com

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(Ph2P(O)H)2PdCl2 Ph2P(O)H, (Ph2P(O)H)2PdCl2 (C6F5)2P(O)H, (Ph2P(O)H)2PdCl2
PPh3, PdCl2 PPh3, PdCl2 (C6F5)2P(O)H, PdCl2 C4H6(CH2PPh2)2, (6Mes)Pd(cinnamyl)Cl, (7-Mes)Pd(cinnamyl)Cl, (SiPr)Pd(cinn)Cl, (7-Dipp)Pd(cinn)Cl,
(IPr)Pd(3,5-).
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C4H6(CH2PPh2)2 ,
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2009-2013 , 02.740.11.0266,
, 09-08-00890.
XIII -
-2010
34
: 532.785

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XIII -
-2010
36
546.92:66.094.37:543.42

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[2] .., .., ... . . . 2008 (81) 234240.
[3] A.Toikka, M.Toikka. Pure and Appl. Chem, 2009 (81) 1591-1602.
38
XIII -
-2010
544.032.73

- 186
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[Gly186].
[1] . . . // . 71 (2001) 1452.

[2] .. , .. , .. .
( ). .:.1989. 256 .

(2009-2010) 2.1.1/5593,
- 2009-2013
( 02.740.11.0253)
39
541.128.3:542.952

.., ..

. .. , e-mail: vitaly-flid@yandex.ru

. Ni(I)
,
, (),
.
Niall2 (all 35, 1-CH3C3H4, 2-CH3C3H4, 1-C6H5C3H4)
Ni (),
77 K g. ()
, . ,
.
Ni ()
Niall2. Niall2
Ni () , 298
10-3 - 10-6 .
() .
Niall2
Ni() .
Ni().
Niall2
Ni()2.
.
Ni () .
. ,

Ni-H. ,-
Ni().
DFT/PBE
. ,
.

. , Ni ()

.
( 08-0300743).
XIII -
-2010
40
541.182:536.461

.., ..*
( ),
*
(), . ,
e-mail: elenafominykh@rambler.ru

.
,
, , .
,
,
,
. ,
,

.
.

[. .
. , . 72, 7, . 664-705 (2003)]
.

, -
-
. [L. Anisimova, M. Anisimov, P. Turner, and P.K.
Hopke. Journal of Colloid and Interface Science V. 290, 107-116 (2005)],
,
() .

.
, ..

.

.
10-08-00124-.
41
665.658.4

9-14

.., ..
, .
, e-mail: evf@tpu.ru

(,
, / . .)

[1].

9-14 ,
: ,
, ,
, Pt-,

, .

.
(Gr, r, Sr)
753 0,2 -
[3].

.
( k0 Ea)

, Delphi 7.

.

4 %,
.

.

. , ,
2 3,5 / 2,9 % .
5 %.
XIII -
-2010
42
541.182:541.128

-
.., . .
... , ,
e-mail: kelizabeth@ya.ru
, , , ,
.
,
,

.
,

.

, 4-3--4-()
(2.45 )
, ,
().
A, . .
1.0
0.9
3
0.8
0.7
0.6
0.5
0.4
0.3
0
. 4--3-4-()

( 30 ,
170 ,
18 ) (1).

33 (2) 23
(3).
10

,
.

.
43
: 66.065.5:621.577

.., ..
.
.. (), . , e-mail: khaibulina@mail.ru

.
.
.

.

,
, [1].

2-.
, ,

.

,

,
.

, , .

,

.
[1] .., .., .., .. //

, 2, 6, 2007, . 75-82
44
XIII -
-2010
541.123

.., .., ..

.. , ., e-mail: dlinn@ya.ru

,
.
,
,
.
()
- .

,
. ( ,

) ,
.

-, - -

( ,
, , , ). ,

() ,
.
( ,
)
.
,

( ).
,
, -, ,
. ,

,
.

( 08-03-00976-).
45
66.023.2+532.5

:

.., ..
-
( ) (()), . -,
e-mail: abiev_r@mail.ru
, 10-15 ,
,
, , , ,
( ),
(lab on a chip)
.
, .
[1] ,
- .
-
. :
;
;
; (
, Ca < 3); .
[2, 3].
,
355
0.92 .
, 230
. - ,
.
,
. ,

, : 0.17 0.73 /,
0.09 0.56 /.
.
[1] Abiev, R.Sh. //Theor. Found. Chem. Eng., 2008, vol. 42, no. 2, p. 105.
[2] Kreutzer, M.T., Kapteijn, F., Moulijn, J.A., et al. //AIChE J., 2005, vol. 51, p.
2428.
[3] Liu, H., Vandu, C.O., and Krishna, R.// Ind. Eng. Chem. Res., 2005, vol. 44, p.
4884.
46
XIII -
-2010
HYDROTHRMAL SYNTHESIS METAL OXIDE NANOPARTICLES

Anikeev V.I.
Boreskov Institute of Catalysis SB RAS, Novosibirsk 630090, Russian Federation,
e-mail: anik@catalysis.nsk.su
Metal and metal oxide nanoparticles, differing from their bulk analogs in
chemical, thermal, optical, magnetic and other properties, are widely used in
catalysis, medicine, electronics and other fields. Continuous hydrothermal synthesis
has the best advantages and possibilities among the methods suggested for synthesis
of metal and metal oxide nanoparticles. This method is simple to implement and scale
up, it allows controlling the particles size and properties. However, an essential
drawback of the method consists in low control of nanoparticles aggregation.
Hydrothermal syntheses of the following metal oxide nanoparticles: LiMeOn
(LiCoO2, LiNiO2, LiZnO2, LiCuO2), MeOn (CdOn, GaOn, CeOn, ZrOn), were
performed in supercritical water in a continuous flow reactor.
The HRTEM and SAXS methods were used for morphological and
compositional characterization of the samples. The syntheses of LiCoO 2, LiNiO2,
LiZnO2, LiCuO2 , GaOn, CeOn, ZrOn were the most efficient.
Example of CeyOx synthesis
A 0.2 M water solution of Ce(NO3)3 salt was prepared for the synthesis. The
reaction temperature was 373-391C, pressure 260 atm. Water flow rate: flow 1 10
ml/min, reactant flow rate: flow 2 3 ml/min. The reaction products of whitish
yellow color, with further precipitation of the solid phase.
Figure a, b. TEM images of CeyOx compound
Solid products of the synthesis were represented by a homogeneous mixture of

well-cut isometric crystals ~ 100 nm in size, Figure a, b. Dendrite aggregates of these
crystals prevail. The crystals are of dislocation block structure. According to XRD
data, CeO2 is the main synthesized phase.
47
541.182:536.461

-
.., ..
( ),

-
[Michael P. Anisimov,
Elena G. Fominykh, Sergey V. Akimov, Philip K. Hopke. Vapor-Gas/Liquid
Nucleation Experiments: A Review of the Challenges. J. Aerosol Sci. 40, 733-746,
2009; .. , .. . :
. , 29(1), 75-85
(2010)]
,
.
1980-.

(FDC) [1]. FDC
, [2], , [3], ,
.
, [4], -
. ,
,
,
. [5] -

.
,
.
10-08-00124-.
[1] M. P. Anisimov, and A.G. Cherevko, J.Aerosol Sci. 1985, 16(2), 97-107.
[2] M. P. Anisimov, K. Hameri, M. Kulmala, T.E. Ovchinnikova, Report Series in
Aerosol Sci. 1993, 23, 19-24.
[3] L. Anisimova, P. K Hopke, J. Terry, J. Chem. Phys. 2001, 114(20):9852.
[4] M.P. Anisimov, J. A. Koropchak, L. V. Timoshina, J. Chem. Phys. 1998,
112(22):9917-9928.
[5] M.P. Anisimov, P. K Hopke, S.D. Shandakov, I. Shvets, J. Chem. Phys. 2000,
113(5):1971.
XIII -
-2010
48
TRANSFORMATIONS OF MONOTERPENE EPOXIDES IN

SUPERCRITICAL SOLVENTS
Volcho K.1, Ilìna I.1, Salakhutdinov N.1 Anikeev V. 2
1
Vorozhtsov Novosibirsk Institute of Organic Chemistry, Novosibirsk 630090,

Russian Federation
2
Boreskov Institute of Catalysis, Novosibirsk 630090, Russian Federation
e-mail: anik@catalysis.ru
Introduction
Monoterpenes and their epoxides are valuable renewable starting materials for
pharmaceutical and cosmetic industries, production of flavorings, pesticides, etc [1].
However, the transformations of these compounds, especially epoxides, in acid media
may give due to isomerization and polymerization reactions not only the target
products, but also a number of undesirable compounds [2]. Moreover, serious
environmental problems are caused by large amount of toxic acid-containing waste.
Reactions based on the transformations of monoterpene epoxides in supercritical
solvents can be considered as an alternative to the conventional methods.
Experimental
In the present work, we have studied the transformations of some monoterpene
epoxides (-pinene, verbenone and verbenol epoxides (Fig. 1)) in various
supercritical solvents for the first time.
Figure 1 : The epoxides structures
O
-pinene
epoxide
O
verbenone
epoxide
OH
verbenol
epoxide
The transformations of epoxides in composite supercritical solvents that

contain 2, lower alcohols (ethanol, isopropanol) with or without water were
studied in the temperature range of 387-575 at pressure 13.5-21.5 MPa. The
addition of water to supercritical solvent will impart acidic properties to the system
and thus make expectable the formation of products of acid-catalyzed transformations
of the epoxide.
Results
Campholenic aldehyde and carveol were shown to be the main products of pinene epoxide reactions in supercritical solvents containing water (Fig. 2). Both
these compounds are valuable feedstock for fragrance industry.
Figure 2 : The -pinene epoxide transformations
49
OH
+
-pinene
epoxide
O
+
...
CHO
campholenic aldehyde
pinocamphone
carveol
In the absence of water, thermolysis of -pinene epoxide in supercritical

solvent yields campholenic aldehyde and pinocamphone, with their total amount in
the reaction mixture attaining 80%. In this case, judging from the composition of
products being formed, the occurrence of two parallel processes can be assumed:
thermal isomerization of -pinene epoxide and its acid-catalyzed isomerization.
The transformations of verbenone and verbenol epoxides led to another types
of the products. For example, the main identified products of verbenone epoxide
isomerization in composite supercritical solvent containing 2, isopropanol with or
without water were -ketoalcohols 1 and 2 with camphane and p-menthane skeletons
accordingly (Fig. 3).
Figure 3 : The verbenone epoxide transformations
O
OH
O
+
O
verbenone
epoxide
O +
...
HO 1
2
The epoxide conversion and products distribution were dependent on the

reactions conditions to a great extent.
Conclusion
The transformations of monoterpene epoxides in supercritical solvents of
different compositions can be considered as new methods of obtaining the target
isomerization products at short (up to 4 min) residence time in a continuous mode in
ecologically friendly conditions.
References
[1] Monteiro, J.L.F.; Veloso, C.O. Topics in Catal., 27, 2004, 169-180.
[2] Ilina, I.V.; Volcho, K.P.; Salakhutdinov, N.F. Russ. J. Org. Chem., 44, 2008, 123.
XIII -
-2010
50
544.3:547.962.9-022.532(043.2)
PHYSICAL-CHEMICAL TOOLS FOR THE ASSESSMENT OF INDOOR
ENVIRONMENTAL EFFECTS ON ARCHIVAL PARCHMENT HERITAGE
IN A CHANGING CLIMATE
Badea E.1, Della Gatta G.1, Odlyha M.2, Larsen R.3, Usacheva T.4
1
University of Turin, Italy, e-mail: giuseppe.dellagatta@unito.it

2
Birkbeck College, University of London, United Kingdom
3
Royal Danish Academy of Fine Arts, Copenhagen, Denmark
4
Ivanovo State Chemistry & Technology University, Ivanovo, Russia
Environmental pollution, climate change, limited energy consumption and lack
of standardisation of best practices, principles, protocols in conservation science are
the challenges that nowadays the science for conservation has to face for securing the
protection of collections in public and private libraries, archives and museums. The
almost entire heritage of the European and Mediterranean civilisations, from classical
times to 15th century, has been delivered to us on parchment in form of scrolls,
manuscripts, codices, book covers, etc.
In this paper, the applications of optical and thermal microscopy, scanning
electron microscopy and atomic force microscopy to surface characterisation of
historical parchments are presented. As parchment is a biomaterial with hierarchical
structure characterised by the intimate relationship and connectivity between
individual molecules and their organisation in micro-fibrils, fibrils and fibres, a micro
to nano-scale investigation protocol was developed for an in-depth assessment of its
deterioration enabling diagnostics, ranking and monitoring of damage of archival
parchments. To answer the sampling ethical requirement and to meet the demand set
by the high variability of historical samples non-invasive and micro-destructive
techniques were used. This innovative tool will significantly improve strategies for
the sustainable preservation of parchment heritage.
The results reported have been obtained within the framework of the EU
Commission Project Improved Damage Assessment of Parchment (IDAP, EVK4-CT2001-00061, 2002-2005) and Italian Project Old Parchment Evaluation: Restoration
and Analysis (OPERA, CIPE-2004-D39, 2006-2009).
References
[1] Della Gatta G., Badea E., Mai A., Ceccarelli R., in Improved Damage
Assessment of Parchment (IDAP) Collection and Sharing of Knowledge, R.
Larsen (Ed.), Luxembourg, L, 2007, ISBN 987-92-79-05378-8, p. 89-98.
[2] Badea E., Miu L., Budrugeac P., Mai A., Della Gatta G., J. Therm. Anal.
Calorim., 2008, 91, 17-27.
[3] Budrugeac P., Badea, E., Della Gatta G., L. Miu, Thermochim. Acta, 2010,
500, 51-62.
[4] Badea E., Della Gatta G., Usacheva T. Polym. Degrad. Stab., in preparation
51
547.979.733

.., .., .., ..,
- (),
. , e-mail: sef@isuct.ru
, .

.
, ,
.

(Pzc(COOH)8M),
-2,3-(5,6-) [1].

[2].

(Pyc(COOH)8M) .
. Pyc(COOH)8M
, Pzc(COOH)8M
N

NC
CN
H NOC
NC
CN
CONH
NC
CN
CONH
NC
H NOC
CN
N
N
N
, NC CN
H NOC CONH
N
N
N
. N
N
N
N
N
N
N
N
N
NC
H NOC
CONH
CN
N M N
N M N
NC
H NOC
CONH
N
N
N CN
N
N
, -
N
N
N
N
.
N
N
N
,
NC CN
H NOC CONH
HOOC COOH
Y
X
N
N
N
X
Y
HOOC
COOH
N M N
HOOC
COOH
Y
X
N
N
N
,
,
X
Y
X=N, Y=C - Pyc(COOO)8M ,
X=N, Y=N - Pzc(COOO)8M
COOH
HOOC

.
[1] Kudrevich S.V., Galpern M.G., van Lier J.E. Synthesis 1994, 779-781.
[2] Kudrevich S.V., Galpern M.G., van Lier J.E. Chem. Abstr. 1996, 125, 58203.
2
XIII -
-2010
52
529.12

.., .., .., ..
-
, 111123, , , 38,
e-mail: ivanovizyamanaki@yandex.ru
PhSi(O)3
, ,
(),
- . - , PhSi(O)3

-.
1- 29Si-
,
PhSi(OR)3 (), PhSi(OR)2(O-) (),
PhSi(OR)(O-)2 (), PhSi(O-)3 (D).

B C
,
PhSi(O)3 -
- . Mw/Mn = 2,0
1,5 - .
Mw = 2800 600 ,
1950 - . ,
- , - - .
53
66.015.4:541.121.001

.., .., ..
.
.. ( . .. ), .
e-mail: nazanski@yandex.ru

, .
, ,
.
. ,

,
, (
).

.
,
.
( )

. ,
.
,
.

,

. , ,
, .

.
,
,
.
,
100%-
.
54
XIII -
-2010
547.53:541.121:544.424.2:544.183.25

.., .., .., ..

() , . ,
e-mail: enk2005@rambler.ru

, , ,
.

. ,
(),
[1],
,
, ,
[2].
.
,

H2SO4
,
DFT/B3LYP 6-311G**
FireFly v.7.1.G [3].
,
, ,

,
, (,
).
1-4 .
( )
( ). ,
N ,
.
-,
,
, .
( 0.01 %)
.
55
( Ac2O)
-.
AcOH
- .
H2SO4
, B3LYP/6-311+G**/PCM

,
H2SO4
.
[4]
-, .
[1] Chemical Reactivity Theory. A Density Functional View. / Chattaraj P.K., Ed.
N.-Y.: CRC Press. 2009. Ch. 18. P. 255 267.
[2] Xiao H., Chen L., Ju X., Ji G. // Science in China. B. 2003. Vol. 46. No. 5. P.
453-464.
[3] A.A.
Granovsky,
FireFly
ver.
7.1.G.
http://classic.chem.msu.su/gran/firefly/index.html
[4] Methods and reagents for green chemistry. / Tundo P., Ed. Hoboken: Wiley J.
2007. 314 p.
56
XIII -
-2010
547.979.733

5,15-

.., .., ..
- (),
. , e-mail: kuvshinova@mail.ru
5,15- (I), 5,15--10- (II),
5,15-10,20- (III), 5,15(4) (IV), 5,15-(4-)-10,20 (V)
(7:3) . ,

(I-V) ,

,
. (III V),
, -
. (V) ,
(III). ,
N-H, - .

(I-V)
(7:3).
(III).
,
,
.
(V) (III), -, ,
I-
.
2009 - 2013
02.740.11.0106 -1105
( 09-03-00927, 10-03-00967)
57
532.783

..1, . 1,2 , .. 1,2
1
2
, , ()
. .. ,
, 117571, . , , 86,
-mail: zoy1940018@mail.ru

(),
.
), .

, ,
(2
2).
,
.
,

. , -, -
.
, ,
.
, (l)
, .
- - ,

. ,
.
,
.

.
Colh 42 243
.
,

,
.
XIII -
-2010
58
541. 572. 128 (043.2)
()

.., .., ..
- ,
. , e-mail: poa@isuct.ru

,

, -
.
,
,
.
, NH-
(-) (2(64F3)8)
( (Py), 2- (MePy), (Mor),
(BzNH2), - (BuNH2), - (t-BuNH2),
(Et2NH), (Et3N), (Pipy)).
, 2(64F3)8 Mor, BzNH2, BuNH2, tBuNH2 Pipy NH-
1:2.
, NH- 2(64F3)8 Mor,
BzNH2, BuNH2, t-BuNH2 Pipy
,
(k298=10-6 /).
,
Mor BzNH2 BuNH2 Pipy
2(64F3)8Mor, 2(64F3)8BzNH2, 2(64F3)8BuNH2
2(64F3)8Pipy .
,
-
NH-
2(64F3)8 t-BuNH2.
, Py, MePy, Et2NH Et3N
2(64F3)8.
,
2(64F3)8Mor,
2(64F3)8BzNH2, 2(64F3)8BuNH2, 2(64F3)8t-BuNH2
2(64F3)8Pipy .
- ,
.

( 10-03-00305-).
59
544.34:549.73:543.554.4
- ,
Cu -
. ., . .
- (),
. , e-mail: vyk_@mail.ru
-

.

.
,
30
- T=450 C.

.
,
.
- 0,1M HCl
0,1M NaOH.
,
. (
- , n/m, ),
- ,
+ . ,
n/m = f (pH) :
n(OH-)/m=f(pH) n(H+)/m=f(pH).
nb(pH) . -
,
. ,
(/)
. ,

-; 4 . ,
.
XIII -
-2010
60
542.973.6

.., .., ..
(), .,
e-mail: htpng-samgtu@mail.ru
, 2008 ,
2013
10 ppm.
,
.
12- ( SnMo12-), 12 (VMo12-), 11--1-
(PVMo11-).
Shimadzu EDX-800
. , 12 (SiMo12-) (..) 12- (PMo12) (..) 110 .
.
Al2O3.
.

0.125
400.
.

. 4.0
(0.1 ), 320, 340, 360, 380 (1),
2 -1 (0.01 -1), / 600 / (25 /).

( 1.14% ., :
3.17 % ., 1.37 % .).

( ): Co-SiMo12(S)/Al2O3 < CoSnMo12(S)/Al2O3 < Co-VMo12(S)/Al2O3 < Co-PVMo11(S)/Al2O3 < Co-PMo12(S)/Al2O3,
(
): Co-PVMo11(S)/Al2O3 < Co-SnMo12(S)/Al2O3 < CoVMo12(S)/Al2O3 < Co-SiMo12(S)/Al2O3 < Co-PMo12(S)/Al2O3.

, .
61
544.032.73
THERMODYNAMICS OF COMPLEX FORMATION BETWEEN
CROWN ETHER 18C6 AND D,L-ALANINE
IN WATER-ACETONE MIXTURES AT 298.15 K
Matteoli E.a, Usacheva T.R.b, Chernov I.V.b, Kuzmina I.A.b, Sharnin V.A.b
a
Institute of Physical-Chemical Processes of National Research Council

(IPCF), Pisa, e-mail: matteoli@ipcf.cnr.it
b
Ivanovo State University of Chemistry and Technology (ISUCT),
Ivanovo, e-mail: oxt@isuct.ru
This study is necessary to create a scientific basis for using the solvent as a
universal driver for processes in the liquid phases.
The determination of thermodynamic reaction parameters and thermodynamic
solvation parameters of reagents and products (G, H, TS), the setting up of the
predictive models for complex formation, the estimation of the influence of mixed
solvent composition on the reactions allow to use solvents to drive the processes of
complex formation in solutions.
As a continuation of our studies here we present the results of investigations of
complex formation reaction between crown ether 18-crown-6 (18C6) and D,L-Alanine
(Ala) in water-acetone mixed solvents and examine the applicability of previously
established patterns for reactions of ions [1] and molecular [2] complex formation in
solution.
The standard thermodynamic parameters of the complex [Ala18C6] were
calculated from thermochemical data at 298.15 K obtained by titration calorimetry at
0.0, 0.08, 0.17, 0.22 and 0.30 mole fraction of acetone. Titration of one reagent by the
other and dilution of the reagents were carried out using the TAM calorimeter MOD
2277 by Thermometric. The calorimetric data were treated using a least-square method
to obtain K and H. The range of used concentrations of acetone was limited by a low
solubility of D,L-Alanine in mixed solvents.
The complex stability and exothermicity of complex formation reaction increase
steeply with increasing the fraction of the non-aqueous components in mixed solutions.
A similar but less marked influence of mixed solvents on the thermodynamic parameters
for complex formation reaction between 18C6 and glycine was found previously [2].
The thermodynamic data were discussed on the basis of the solvation
thermodynamic approach [1] and the enthalpic contributions of the reagents and of the
complex to the enthalpy of complex formation reaction were analyzed.
References
[1] V.A.Sharnin // J. General Chemistry. 71 (2001) 1452.
[2] E. Matteoli, L.Lepori, T.R.Usacheva, V. A. Sharnin // J.Therm.Anal.Cal. 97
(2009) 811.
This work was supported by the program "Development of Scientific Potential of
Higher School (2009-2010)" project 2.1.1/5593, and the Federal Program "Researchers
and Scientific-Pedagogical Staff of Innovations of Russia" for 2009-2013 (State number
02.740.11.0253).
XIII -
-2010
62
66.015.4:541.121.001

.., .., ..
.
.. ( . .. ), .
e-mail: milyaeva.tv@mail.ru

,
.
( ) ,

. ,

,
,
100%-
.
,

.

100%- .

.
,

,
100%- .
63
691:546

.., ..
.,
e-mail: tpp_vlgu@mail.ru

.
,
(, .)
. ,
, ,
.

,
150 .

.
, ,
.
-

.

.

:
, /3
120-150
,
1,5
,
0,05
/()
24
,
4
%

1200600l00
.
XIII -
-2010
64
66.965.5: 621.577

.., .., ..
. .., . , e-mail: nosovga@mail.ru

.
, , ,
.
.

,
.
.

, , ,
.

,

.

.
:

,
,
.
:

,
.

(
, ,
, ,
.) -
. ,

65
541. 572. 128 (043.2)

(3--5--)
.., .., ..
- ,
. , e-mail: poa@isuct.ru

,
.

,
.
.
,
(3-5--)
(H2Pc(NO2)4(t-Bu)4)
() ().
(Py), 2- (2-MePy), (Mor), (BuNH2), (Et2NH) (Pipy).
, H2Pc(NO)4(t-Bu)4
NH-
- H2Pc(NO2)4(t-Bu)42.
,
(Py, 2-MePy, Mor),
H2Pc(NO2)4(t-Bu)42 .
, (BuNH2, Pipy)
H2Pc(NO2)4(t-Bu)42,
- .
H2Pc(NO2)4(t-Bu)42.
.
, Pipy BuNH2
H2Pc(NO2)4(t-Bu)42 ~ 2
,

.
,
BuNH2 Et2NH. BuNH2
Et2NH H2Pc(NO2)4(tBu)42.

( 10-03-00305-).
XIII -
-2010
66
541.64:547.979.733
--
.., .., .., .., ..
- (),
. , e-mail: peclin@mail.ru
,

.
, ,

.
-- 1
-- 3
2 4,
.
N2
OH
Me
Me
Me
Me
Me
NH
N
O H2 H CH2
Br CH2 H CH2
Me
NH
HN
Me
Me
Am
Me
Me
Am
O
NH H CH2
O
CH2 CH Cl
HN
Me
Am
1
Me
Am
3
2 4
.
, 1 , , -, .

, ,
-.
2009 - 2013
02.740.11.0106 -1105
( 09-03-00927, 10-03-00967)
67
661.183.122
-

.., .., ..
- (),

, ,
/
.

,

. ,

.
,

. , ,

.

.

514.

. ,
- 10.5-11.5.
514
- 3-4.
,
4, 10,
514
.
,
, .

,
.
XIII -
-2010
68
661.183.2
.., .., ..
- (),
., e-mail: smirnov@isuct.ru

,
.

-

.
514
7535-86
15-60
-1
- V-4 c 930
5,4 /.
,
,
.

.
.
- AVATAR 360.

1-2/
5-6/ . ,
- .

=2.3-2.7, -
=11-12.

pK=11-12.5.
, ,
, , ,
.
69
541.128:542.97:547-326:547-305.2

-

.., .., ..
. ..
( . .. ), . , e-mail: piligrim.tula.ru@gmail.com

Pd(PPh3)2Cl2 PPh3 - (TsOH).
, ,
.
,
.

, [1].
.
363-383 TsOH
, .
TsOH S-
. ,
,
-.
TsOH
[2] ,
TsOH
:
r
kC M PCO C 6 H10 T sOHC 6 H11OH
PCO
C H OH hPPh 2 iC
2
2
g 6 11
1 a T sOH dC 6 H11OH ePCO f
3
M
PPh3
PPh3
k'T sOH

.

, 09-08-00890.
[1] .. . . . .
: . 2005.
[2] .., .., .., .. //
, 2006, . 46, 6, . 435-445.
XIII -
-2010
70
660:51.001.57+66

..

. .. (),. , e-mail: skvorivan@mail.ru
, ,
n- .
-

n-
.
.
n-
.

,
.
.

.
, .
n.

[1,2].

( 08-08-00318-).
[1] .., ..
// . .
. 2001. . 35. 6. . 603.
[2] .., .., ..
//
. 2001. 6. . 36.
71
660:51.001.57+66

..

. .. (),
. , e-mail: skvorivan@mail.ru
,
,
n-
.

n- A1,,Am, Am+1,,An (1m<n)
Am,Am+1 : )
; )
.
)
,
. ,
) , )
. ) . ).
.

.
,
m n, ,
, .
, ),
.), m
n.
[1,2].

( 08-08-00318-).
[1] .., .., ..

//. 2007. . 41.
6. . 649.
[2] .., .., ..
//. 2005. . 39. 1. . 19.
XIII -
-2010
72
66.093.48

-
.., .., .., ..
() . ,
e-mail: isoldatov@mail.ru
26
. :

( 30% 20%
.
( -
).
- ,
-
s- I- d- VI-, V VII 4
.

(
. . ..
).
-
( . .
.. -
).

(
220 300) .
, ,
( 2189 2195 -1,
33 36 /),

.
220.
, (
0,5 1,0 ),
,
.
601 (328).

.
73
542.973.6

Co-XMo12(S)-
.., .., ..
(), .,
e-mail: htpng-samgtu@mail.ru

, , ,
.

.
12-
.
: 12 (BMo12-), 12- (TiMo12), 12- (VMo12-), 12-
(GeMo12-),
12-
(ZrMo12-),
12 (SnMo12-), 12- (PMo12), 12- (SiMo12-), 12-
(ZnMo12-), 12- (CeMo12-).
- -.
-Al2O3.

.
60, 80, 110 2 ,
1 / 400 2 .
MoO3 CoO
Shimadzu EDX-800.

0,125 400.
.

(0,025
) 320. 340,
360, 380.
: < ZnMo12-< SnMo12-< SiMo12-< TiMo12< VMo12-< GeMo12-< ZrMo12-< PMo12-< CeMo12-<
BMo12-.
, P, Ce.
XIII -
-2010
74
541.128; 541.49:546.74/121
-

3-
.., ..

() ...
e-mail: out@pochta.ru
3
.

,
.
(DFT) PBE [1]
SBK [2] ( .. . ..
[3]) 3
[3C3H5NiX2] (X = F, Cl, Br, I).
H
C2
H
C1
C3
Ni
X
, X = F, Cl, Br, I
X
,
- .
I-Br-Cl-F,
Ni-C Ni-X (
).
Ni-X, -Ni: Ni
1 2.

.
[1] Perdew J.P., Burke K., Ernzerhof M. Phys. Rev. Lett. 1996. V.77. P.3865.
[2] Stevens W.J., Basch H., Krauss M. J.Chem. Phys. 1984.V.81 P.6026.
[3] Laikov D.N. Chem. Phys. Lett. 1997. V.281. P.151.
75
549.752/.753
Li2OZnONb2O5
.., .., ..

. .. (), . , e-mail: valeryfom@rambler.ru

.

- .
Li2OZnONb2O5.
ZnNb2O6LiNb3O8 : LiZnNb4O11.5
LiZnNb6O16.5, ~2.%.
ZnNb2O6 LiNb3O8.
(),
-
.
.
() LiZnNb4O11.5 :
(3D) ((3+1)D) .
,
.

P 21/b. ,
-PbO2 q=0.3a*+1.1b*.
LiZnNb4O11.5
()
,
.
- - .
.
LiZnNb6O16.5,
LiZnNb4O11.5,
.
().
LiZnNb4O11.5,
:
-
-PbO2 q=2/7a*6/7b*.
-
() LiZnNb4O11.5 LiZnNb6O16.5,
, 251100
.
XIII -
-2010
76
541.182:536.461
-
..1, ..1,2, ..1
1
( ),
. , e-mail:anisimovmp@mail.ru.
2
(),
. , e-mail: elenafominykh@rambler.ru
- .
-
.
, [1] :
, ..
, Tc
; c0 c7 ,
; Z(, )
; Z c - [1].
-
CO2,
: 60 oC, 1 ,
110 oC.
,
,
0,08 %, , ,
0.1%.
.
100
600% 4 % .
,
20
.
10-08-00124-.
[1] . ., . . . 392, 1,
2003 . 48 53
77
547.979.7

-
.., .., ..

. .. , . , e-mail: n.bragina@mail.ru

,
[1].
,
,
, ,
- [2].
- ,
,
,
, .., .
,
.

,
-
,
.
, ,

[3].
.

.

2.1.1./2889
[2] S.C. Doan, S.Shanmugham, D.E. Aston, J.L. McHale. // JACS. 2005, V.127,
P.5885-5892.
[3] F. Langa, M.J. Gomez-Escalonilla, P.de la Cruz. // J. Porph. Phthal. 2007.
V.11. P.348-358.
[4] Fedulova I.N., Bragina N.A.et al. // Mendeleev. Commun. 2008. V.18, P.324326.
XIII -
-2010
78
66.048.3-932.2

.., ..

. .. (), . , e-mail: frolkova@mitht.ru

.
.
,
, ,
.

3.1.0-2.
.
( R,
, ) R
3.1.0-2
.

.

( )
.
R ,
.
(
)
R .
,

.

.

.
79
546.819.86.74.73.72

,
.., ..
(), .
e-mail: cabilov@yahoo.com
-
3d-
, .
,
. , (Fe1,2 Sb)1-x
(Pb0,825Sb0,175)x (NiSb)1-xPbx
, (CoSb2)1-x.Pbx
. , ,
, ,
.
( Hs )
( GT0 ) .
(Fe1,2 Sb)0,98 (Pb0,825Sb0,175)0,02 Hs =56,6 / GT0 =-144
/, (NiSb)0,99Pb0,01 Hs =54,8 / GT0 =-69,3
/, (CoSb2)0,98.Pb0,02 Hs =13,6 / GT0 =214,5
/. ,
,
.

(Fe1,2 Sb)0,98 (Pb0,825Sb0,175)0,02 (NiSb)0,99Pb0,01.
GT0
(CoSb2)0,98.Pb0,02
, ,
.

.

,
,
(CoSb2)0,98.Pb0,02.
, ,
,

.
80
XIII -
-2010
542.943-92:544.431.22:542.2232

.., .., ..
(), .,
e-mail: ageeva-ev@yandex.ru

. , (~10-4
/) ,

.
: ,
.

. ,
,
, .
MemOm+1.
(MnO2, Mn3O4, Mn3O4, Fe2O3 (, , ), Fe3O4, PbO2, Pb3O4, ..) .
,
MemOm+1 + HSO3 Mem(OH)Om + SO3
(1)
Mem(OH)Om + HSO3 Mem(OH)2Om1 + SO3

(2)
2
SO3 + SO3 S2O6 ,
(3)
.

.

MemOm+1
;

, ,
;
( 1 )

; ,

(1) (2) ;
MemOm+1
, , .
81

.., .., ..
(), . ,
e-mail: ad.l@rambler.ru

-
, , .

, .
.

, ,
, ,

, ,

.
,
, ,
.

.

20
20 /2 - ( ),
( ).
-
-
(+20 +95 0)
.
,
,
.
,
+20 0
, -5 0
.

,

, ,

.
XIII -
-2010
82
546.831:66.097.5

..*, ..**, ..**, ..**
*
.
.. , . , e-mail:antonyuk2006@yandex.ru
**
-, . ,
e-mail: evgolosman@yandex.ru

, .
, .
, ,
() , .
,
NOx ,
.

,
, .

,
, , , -Al2O3.

Zr-Al-Ca-O , , ,
,
. ,

( 100%) . ,

,
. ,
, ,
,
.
,

.
83
533.9.07

..-., .., ..
- (),
. -, e-mail: fizika@esstu.ru

.
,

, ,

.

.
, ,
: -
, , .

,
. ,
( - I* ,
- I,
- I)
.
U,
d
. , U(d) U(d)
d=1,7 .(U ,
, U -
).

, I, I*,
,
I(U) ,
.

.
XIII -
-2010
84
541.8
-

-
.., ..
. .. ()
, . , e-mail: n_bondarev@rambler.ru
: ,
-
(, , -, ).

(,
, , , )
, , (I) -
-, -, --2-, , -, -, -.

- .

-
, .

. ,
"" -
,
.
-

- - . ,

(- )
, ,
(- ).

.
85
541.8

-
.., ..
. .. ()
, . , e-mail: n_bondarev@rambler.ru
Kex
Kex
LM A
M w A w Lo
o

LM A
o
= KD1,L K (w)+ K (w) K
,
Kex
LM
ass,LM A
D,LMA
M A L
o
K D,L - (L) (w)

() ; K (w)+ LM
; K (w)
ass,LMA
LM+A- ; K
D,LM A
LM+A- .
-

_
[LM + A ]o
_
[LM + A ]o
Kex C o + CLo
M
1 1/ K D,L
1 K 1
D ,L
1
=
o
o
_
[M + ]w [LM + ]w [LM + A ]w Kex CM+ CL

_
M+
[LM + A ]o
-
_
D +
[LM + A ]o
M
100% .

=
100%
o
D
1
+
+
M ,w

-.
86
XIII -
-2010
677.11

.., ..
- (),
. , e-mail: leshcheva@rambler.ru
, ,

,
.

.

,
.
,
.

.

--.
.

.

1,2-1,5 , ,
,
(20-30%) .

.
,
65-70 .
.

35-45% -
,
.
87
546.271

--(12)
.., ..

. .. (), . , e-mail: mp2sdtq@gmail.com
(12)
.

-. ,
1,2-, 1,7-, 1,12-21012 a
22 27 [1].

(12)
, : 1.
, 2.
(),
, 3.
,
, 4.
.
Gaussian 98 [2] (B3LYP/6-31G**, B3LYP/6-311++G**)

. -C2B10H12 > -C2B10H12 > C2B10H12 > -C2H2B10Cl10 > -C2H2B10Cl10
- ,
.
pKa E, H,
G (B3LYP/6-311++G**) (12)
: HC-B10R10-CH HC-B10R10-C + H+ (R = H, Cl). ,

- 5.0 /, ,
.
(3;1)
(bCb),
.
[1] L.I. Zakharkin, N.A. Ogorodnikova // J.Organometal.Chem. 1968. v.12. p. 13.

[2] M. J. Frisch et. al., Gaussian 98, Revision A.7, Gaussian, Inc., Pittsburgh (PA),
1998.
XIII -
-2010
88
547.466+54.052

.., .., ..
(),
. , e-mail: elengrigor@yandex.ru

.

,
,
.

-35
. : ,
,
-35 +- - .

.

-35. ,

,
, ,
.

( 2 /),
.
,
,
,

.
, ,
,
.
89
543.544.5.068.7

5(6)--2-(4-)
..1, ..1, ..1, ..2, ..3,
..1
1
. ..
( . .. ), .
2
(), . ;
3
, . , e-mail: nadina86@rambler.ru
5(6)--2-(4-) ()
,
, .

.
-
-- (LCMS)
-,
() -
(Na).
, (=224 ...)

252 .. :
, 1, 2; Na
: 2, 1, .
,
252 5(6)--2-(4)-1-1,3- 4-(5--2[d]--2-)-2,5-
ON
ON
NO
N
H
N OH
N

.
, 1 2
, (~30% .).
1 2.
XIII -
-2010
90
669.15-194:678.675126.002.68

.., .., ..

., e-mail:organic@vstu.ru
()
. n=60-80
( - 3,
- 50102 ).

(0,0085 / 0,01 /)
25-80 0 ,
Solver PRO
.

.
. 150 ,
40-60 .
77,15 ,
( Ra , ISO 4287/1) 8,26 208,96
.

, : 25 0 (92 ) 80 0 (20 )

, 50-150 , 80 0 , 20
50-450 .
25 0 (92 )
Ra 25,02 287,13
; 80 0 (20 ) Ra
20-45 89-99 .
,
- ,

:
H2C
H
C
O
H2C
N
H2
C
CH2
H
H2C
C
O
- : I 1641 1 , II 1542
III 1250 1 NH- 3108 1 .
1 ,
91
547.128

.., .., .., ..

. .. (), . , e-mail: knyazev.s.p@mail.ru

.

N Si Ge .
,
,
[1].
, ( 1)

( 2). ,
( 3) ,
.
R(CH2CH2)3N + 3H2O = . () + N(CH2CH2OH)3
(1),
R(OR)3 + 3H2O = . () + 3 ROH
(2),
R(OR)3 + N(CH2CH2OH)3 = R(CH2CH2)3N + 3 ROH
(3),
= Si Ge.
() ()
, , ,
: () = ().
(2) (1), ,
3 .
,

, .
2 1 3: G(2) G(1) = G(3).
(3) (
4- 2- ),
G(3),
[1].

.
[1] .. , .. , .. , .. , .. ,
// , 2004, . 74, 1, c.
65-73.
XIII -
-2010
92
66.066.3

.., .., ..
-
(), . -, e-mail: yablokova_m@mail.ru

,
, , .

,
-
.

,
. ..,

.

,
,
.

.
-3D ,

( Flow Vision)
.

.
(Re 500),
. ,
, (500<Re<3000)
,
.

.
,
.

.
93
(III) (III)
-
.., .., .., ..
-
.. ( )
e-mail: denis.lutskii@gmail.com

.
- 50,05 0,5 .
-
. (III) (III)

0,070,2 /. (III) ,
(III), .
94
XIII -
-2010
541.49:(546.74.2+548.736)
[ReOL4Cl]Cl2 2H2O, L-1-2-
.., .., ..
, . ,
e-mail: azimjon51@mail.ru

[ReOL4Cl]Cl22H2O, L-1-2- ().
5%-
1 3,0 % .
.
.
2 mV.

[ReOL4Cl]Cl22H2O .
.
[ReOL4Cl]Cl2 2H2O.
1-; 2-0,05%; 3-0,5%;4-1,5%; 5-2,0%; 6-3,0%.
, [ReOL4Cl]Cl22H2O
.

. 2%
47,7 11,2 . . 4,3 .
,
. 10.
47,7 31,4 . .
3% 5,5. .
95
541.64:539.(199+3)
1,3 -1
..1, ..3, ..1
1
, , e-mail: hruk@list.ru
2
,

: ,
() :
, (B3LYP);
, - 2-
(2);
() 2.
6-31+G**/6-311+G** aug-cc-PVDZ.
Gamess US, Pcgamess, Gaussian06,

Moltran.

-1
,
, .
. ,
:
, -1,

. ,

. . 1:
1.
(k1/k2)
(k = nk1+nk2, .-1.-1).
Gaussian06, pcgamess:
-
k1/k2
k103
1,2-
ub3lyp/aug-cc-pvdz
0,036
4640
H2C=CH-
ub3lyp/aug-cc-pvdz
15,63
6,33
H2C=CH-
ub3lyp/aug-cc-pvdz
4,6
28,4
CH3-CH2-CH=CH2
ub3lyp/aug-cc-pvdz
7,9
232
XIII -
-2010
96
66.022:621.929
-

.., .., .., ..

., e-mail: nikevan@rambler.ru
-

. , -
[1],
: , ,
,
, ..

.
1 - , .

, .
4 .
.
[1]
1 - -
.., .., .. - .: , 2009. 186 .
97
541. 64+548. 33

.., .., ..
. .. ,
. , 05010, . ., 106,
-mail: jumadilov@mail.ru

.

.
, ,
-
() NaB(C6H5)4.

-
(- NaB(C6H5)4), -
60:40,40:60 . %, ( =15000).
, (- NaB(C6H5)4
(60:40
%)
1, 2 11:1 (=330 ), 7:1 (=436 ) 5:1 3

=450 ) 4:1 (=455 ).
15:1 (=326 ).
40% 60%
13:1 1 (=332 ),
3:1 (=461 ).
15:1 (=325 )
.

,
. ,
,
, .
XIII -
-2010
98
669.712

.., .., ..
( ),
. , e-mail: pasechnik@ihim.uran.ru

.

.
, , , ,
, . (Sc2O3 100/).

, .
.
-
,
, .

, 17% 2 15%
.
Ti, Zr, Na Al, V, Fe, Si
.
.

,
. , .
,
,
(>10)
(<8,5)

.
10-03-96039-__.
99
512.54: 579.11:541.62:548:12
D2D- (NH)4C10H24Ni:

.., .., ..
,
170002, , 35, e-mail: smolyakov@inbox.ru
Ni2+
C
,
C
N
C
.
N
C
C-H N-H C
Ni
C
N
(NH)4C10H24Ni (. ) . .
N
C
C
Ni2+ 106
C
C

[Ni(NH2)4(CH2)4]. D2d (E, 3C2,
.
2S4, 2d)
(NH)4C10H24Ni
(NH)4C10H24Ni ,
f l , f m ,... , , ,...
l, m,... . f l , , Z
: ZD2d= 1/8(f128+3f214+2f47+2f12f213).
ZD2d f l (h l x l y l ...) ,
D2d = 1/8{(h+x+)28 +3(h2+x2+)14 +2(h4+x4+)7+2(h+x+)2(h2+x2)13}. (1)
hkxlym (1) ( )
-NHqC24HkXlYm . 3718 :
14 , XY 65, XYZ 169 .. , X-
: D2 = h28+ 4x+ 56x2+ 416x3 +2618x4+12324x5
+47320x6+148148x7+389144x8+863720x9+1641640x10+2684916x11+3804605x12+468
1128x13+5016720x14+ 4681128x15 + 3804605x16+ +416x25 +56x26 + 4x27 + x28.

: ZD2 = 1/4(f128 + 3f214), Z. = 1/4(2f47+2f12f213).
, N.: Z. (D2) 0,
Z(D2d) 38111043076464201013 , Z(D2)
76222086152928401013
. h2x2y2z2u2v2w2f2q2r2t2s2k2l2,
, Z. (D2) 6227020800 .
X-,XY-,

[1] .
[1] Smolyakov V.M., Sokolov D.V., Nilov D.Yu, Grebeshkov V.V., Fedin D.M. //
Journal Rare materials and technology. . China, Dzyasin, 2009. P. 626-636.
C
100
XIII -
-2010
66.017:542.61:546.63/64:548.75:537.533.35

.., .., ..
( ),
. , e-mail: pasechnik@ihim.uran.ru
,
, ,
.

[1]. ,
[2-4].
-. XXI

[5]. , ,
, , .
,
. ()
.
,
. ,
, 12 40% (.)
.
0,7% .

.
, ,
[6].
10-03-96039-__.
[1] .., .., .. . // , 1977.

. 97. . 43-47.
[2] Small H.J. // Jnorg. Chem. 1961. 18. P. 232-238.
[3] Barenova H., Nova-K M. // Coll. Czech. Chem. Comm. 1965. 30. P. 1073-1081.
[4] .., .. // .
1960. . 39-40.
[5] Yoshizawa H., Uemura Y., Kowano Y., Hatate Y. // J. Chem. Eng. Japan.
1993. 26. P.693-697.
[6] Shirokova A.G., Yatsenko S.P. // Abstracts Intern. conf. Functional Materials
ICFM-2009, Ukrain, Crimea, Partenit. 2009. P. 436.
101
620.19

.., .., .., .., ..
- (), .,
e-mail: sharlayev@rambler.ru

.
( ),
,
- .
,
,
, , .

(7421, 2, 20, 5, 71,
84) 4 .
.

.
21,6 2.
,

1,4104 2.
.
-50-1
( 0,5 ) -8.
.
.
,
5,
.
:
84>71>20>7421>2>5. ,
.

, .

, .
,
, ,
.
XIII -
-2010
102
546.05

..1, ..2
1
. .. ( ),
2
, , e-mail: shig_2002@mail.ru

Zn2-xCoxSiO2, 1,5,10,20 %.
-

1 2 (1 )
(2 ).
.
Zn2+ .

.
9200 1 2
() () .

R3
(JCPDS 37-1485).
. ,
.

1,5 ( ).

1-10% .
1000-1850 500-700
424T1 (4F) 424T1 (4P) (II). 20
% , (III),
(2,5/0,1) .

( , 0,4 , -
1%) ,
1 . 2
,
, ,
.

, .
103
546. 264.,553. 682.

.., ..
-
e-mail: iradax@yandex.ru
- .
,

- ,
.

.
.

- .
7500, 1 .
, -
, Mg, 3.
-

CaO.

, ,

Ca(OH2)
.
C(OH2)
.
.. Ca(OH2)
(Mg,Al)
Si2O5
. -
Mg3[Si4O11]nH20,
4CaOAl2O313H2O C2SH.
XIII -
-2010
106
66.023.2+665.6

.., .., ..
-
( ) (()), . -,
e-mail: abiev_r@mail.ru

,
.
, (, , ,
), (, .).
()
""
, ,
, .
-
,
, , ,
.
(),
(), () (),

().

,
5 , ,
.
,
,
( ),
.
,
() (. 2184593, 2184594, 2184595).
,
2-2.5 , 2.5-3.0
, .
()

, ,
.
107
541.64:547.39

2-

.., .., ..
. ..
, . .,
e-mail: abrlidz@yandex.ru
2- ()
() 2- ()
(),
() ()
28.
,
,
().

. ,
, ,
,
.
:
.
, 1:3
120 0, 80 %.

80, 100, 120 150 0,
, ,
.

, ,
93 % 90 %.
,
, ,

.
.
.

(),

,
.
108
XIII -
-2010
AN INVESTIGATION INTO THE REMOVAL OF SO2 FROM EFFLUENT

STREAMS: NOVEL APPROACH TO MINIMIZE SO2 EMISSION FROM
POTENTIAL JORDANIAN OIL SHALE PROCESSING PLANT
Marwan M. Batiha
Chemical Engineering Department, Faculty of Engineering,
Al-Hussein Bin Talal University, Ma'an P.O.Box 20, Jordan.
e-mail: mmbatiha@ahu.edu.jo
SO2 gas is one of the major air pollutants in the world and the main sources of
this gas are the combustion of sulphur-containing fossil fuels. Therefore, the
environmental issues concerning oil shale exploitation in Jordan has been given
considerable attention due to high sulphur content in oil shale. By achieving the goals
of this work, it is expected to make a contribution toward solving the potential
problem of SO2 emission from oil shale processing plants in Jordan using the
available resources. These resources are available in abundant quantities which
include: kaoilinite, zeolitic tuff, Dead Sea water and oil shale ash produced from oil
shale combustion and retorting.
One of the primary environmental concerns of utilization of Jordanian oil shale
is the high S content which have to be removed from the off gas stream upon oil shale
combustion or during shale oil refining. A number of effluent gas desulphurization
techniques are available. These can be broadly classified into four categories:
absorption of SO2 in liquids, absorption by moist particles, gas phase conversion of
SO2, and sorption by solids. The later is considered on of the promising ways for SO2
removal. The current work has been focused on examining the Dead Sea water
capacity for SO2 removal and the utilization of Jordanian kaolin, available in huge
quantities in Jordan, as well as oil shale ash to remove SO2 from off gas streams.
Surface modification of kaolin will be carried out to increase its adsorption capacity
of SO2.
This work presents a kinetic study on the dissolution and solubility of SO2 in
pure and Dead Sea water and a mathematical model which describes these processes
taking into account all the possible reactions involved.
Secondly, an investigation into the adsorption capacity of various natural,
modified and waste materials for SO2 removal from effluent streams has been carried
out. These materials include: alumino-silicate minerals like Jordanian kaolinite, oil
shale ash produced after complete combustion, oil shale ash produced after
microwave and conventional retorting and natural and modified Jordanian zeolite.
109
628.3:658.512:66.011

.., .., ..

( )
., e-mail: yu_beznosyk@rambler.ru

.

.
,
.
,

.

.
-
13X, LiLSX
.
- ,
, , , . ,
,

.
-

.
,
, - ;
;
, .
-
,
.
,

( NO 99,9%).
,

.
XIII -
-2010
110
547.426.1
.., ..
- - .
.,, ., , 10.
. e-mail: jorik17@mail.ru

.
.
.
.

().
,
.
,
.
()
()
.

.

, ,
.

()
(). ,

() ().

, , .
, .
:
W1=6,29105EXP(-(585003000)/RT).C.C.HCl
W1=3,34105EXP(-(585003000)/RT).C.2.CHCl (2)
1 = 1,9
W2=1,6104EXP(-(533003000)/RT).CC. HCl
W2=1.6104EXP(-(533003000)/RT).C.2.CHCl (4)
2 = 1.0
(1)
(3)
111
:661.77+661.743.3

.., .., ..

. , e-mail: kinterm@samgtu.ru

, 90%
.
.
, ,

.

.

60-98 , 30%
;
/H2O2=1/(413) (.).
.
,
, ,
( ),
- -
.

- ;

.
4-6,
- .
30%
. ,
90%: 90-98;
22/=5/1.
(4-6) 73-75 %, - 43-45%.
,
,
-
.
XIII -
-2010
112
529.12

.., .., .., ..
, . , e-mail: epixina@bk.ru.

, .

, .
[1]
,
"SAPO-34".
"SAPO-34"
400 500,
1,6 6,4 .
: 425, 6,4.,
~80%
~80%.
.
"SAPO-34"
. ,

425 6,4 . ~13% 2
. , "SAPO-34"
550 90 .
2 .

-Al2O3 .
, -Al2O3
. 10% 30%.

.
[1] .. , .. , . . .
. XII
2008 09-11 2008 ., . , .73.
113
: 547.546

.., .., .., ..
. .. , . , e-mail: Margyn@yandex.ru

. ,
2,5 ./
. ,
.
,
, , ,
, .
,

.
, ,
:
,
, .
,
.
,
. ,
,
.
,
.

- .

,
.
,
,

.

,
.
.
,
.
XIII -
-2010
114
544.47:544.344
PT/C .

.., .., ..
. .. ( ),
. , e-mail: ignateva@catalysis.ru

( ).

Pt/C ,
.
Pt
. , Pt/C
,
.
Pt/C

.

: , ,
.
,
( , - , , ).
,
Pt/C
1-2 . ,

.
,

(30-40%).
Pt

,
(>98%, 2-,
, 30, 1 . 2, 0.5-1 , /Pt 2000 /).
115
66.097.3.001

..*, .., .., ..**
, . , e-mail: kachalov_dmitrii@mail.ru
*

. .. () , .
**
(),
.

-
.

: ,
, (-16, -16,
-24, -28, -603);
();

(-2207);
.
.
,

,
,
.
,

: ,
,
.
,

,
.
XIII -
-2010
116
541.128-39

..1, . .2, ..1, ..3,
..4, .4.
1
, ,
- . ..,
. ,
3
, .,
4
- , ..
e-mail: Petukhova_liubov@mail.ru

(),
, ,

-, -
,
, 6 - 32
(5,6+) - (5,8+).

,

92-96% . 78-80% ,
,
,
,
.
117
66.095.62:661.727.3

..1, ..1, ..1, ..2, ..2
1
2
- ., e-mail: KorneevaGA@yrd.ru,
, ., e-mail: MFlid@yandex.ru

, , 2, .

140-180 ~30 .

,
[1].
, -
[2],

c 23 /.
,

.

.
.
: 1,8-2,0 ,
89-91, 0,10-0,25 /.
[2],

- 90%
90-95%.
[1] . 5367106. 20.09.1993. Jerry D. Unruh, Wendell L. Pieper, Milo

C. Pass. .
[2] .., .., .., .. // ,
2009, .50, 4, .1-10.
XIII -
-2010
118
665.633

.., , ..
(), . ,
e-mail: julep@sibmail.com

( ,
, ) (, ,
). -

.
, , .
,
.
,
, :
PbO2, Fe2O3, MnO2, , ,
, :
,

(=250) (=750).

. 1 , ,

, -4 Hitec-3000.
1
-4
Hitec-3000
H, /
298
1023
36,09
42,18
54,28
58,24
-105,79
-99,20
S, /()
298
1023
233,40
243,82
258,50
266,35
247,60
257,81
G, /
1023
-207,25
-214,13
-362,94
K
1023
1,0246
1,0254
1,0435
, ,
.

.[1] , ,
,
.
[1] .. . .: , 2005. 288.
119
665.531:547.912:541.128:546.723

..1, ..2, ..1,2
1
(),
( ),
. , e-mail: TSozonova@sfu-kras.ru

,

.

-
- .

, , ,
, , .

() .

.

, , ,
.
: , .
,
, .
,
,
(83-94 % .) .

( )
.
CARL ZEISS.
XIII -
-2010
120
665.3.095.134.3:183.3

.., .., .., ..
,
. , e-mail: serg-solovyev@yandex.ru
,
,
.
.
,
,

.
,
.
,
.
:

,
.

, :
1)
- ();
2)
( );
3)
( -, ) (
);
4)
( ).
.

. , ()

- ,
.
121
662.757

.., .., .., ..*,

..*

. . (), . , e-mail: tretjakov@ips.ac.ru
*
... , .

-

. .

,
,
.
,

(, ) . 100%
300-450.
2-4 (3040%).
49
64%. 5
12, ,
1% .,
-4, -5. ,
,

,
, .

,
, ,
, - ,
.
,
, .
,

. ,

.
XIII -
-2010
122
529.12

.., .., ..
- , . ,
e-mail: mflid@yandex.ru
,

.
0,1-0,2%
,
,
, .
:
, .. /1/

.
,
.

,
. ,
500 15

,
.

, ;
.
460 500
(,

)
.
, .
,
,
, .
[1] Borsa A.G., Herring A.M., McKinnon J.T. et. al. // Ind. Eng. Chem. Res. 1999.
Vol. 38. P. 4259
123
: 661.725.68

.., .., ..
. .. , . ,
e-mail: fedosov_alex@rambler.ru

(), , ,
.
,
:
; ;
;
..
- ,
, , ,
, ,
, - .

.

, ,
, - (
,
,
), .

- 10-13

(TS-1).

10 13
(TS-1) .

-1.

.
.

, -

,
.
XIII -
-2010
124
661.723.612

..
- , .
-
() ,
1,5-2 ,
.

, ,
, ,
, .
, ,
, ,
, , .

10-15%. 10
~0,1/ ,
10% 0,3/ . ,

(
).

(1100-1400 /( .))
.
(
-
3-5 ).
245-255.
1,5-2 .
98-98,5% ,
,
, .

,
.

23-24%.
125
665.64

.., .C., .., ..

(),
., e-mail: sharova@sibmail.com

.
.

. ,
,

.
,

,
.

.
. 1
R-98

. 2
R-98
,
,
(. 1), 20 %
.
18,25 % (.
2). , -
-
, .
126
XIII -
-2010
547.472.3
,

.., ..
- ... (),
., e-mail: shvets@mail.ru

, .
Dow Chemical Co .
,

, - (51%).

.
,

,
.

:
, , , ,
, .

.

,

450 .
,
,

,
, .

,
.
127
547.245.07
.., .., ..
-
()
e-mail: vdsh2004@yandex.ru
(H2=CH)2SiCl2 (I)

, ,
(Cl, CH=CH2). I
(II) : )
b)
a) + SiCl4 / Kat
(CH2=CH)2SiCl2
(CH2=CH)4Si
b) + HCl / Kat
Kat (AlCl3, ZnCl2, SnCl2, SnCl4, SbCl3).

- II
.
I 85 % .
AlCl3/ClCH2CN ( 10 .;
80-90 ). (
) (III).
Na Mg
[(CH2=CH)2Si]n3
(IV),
H3BSMe2
HN(SiMe3)2 Me3SiN=C=NSiMe3
SiNCB
.
, I ,
, , .
, ..
,
, (
),
(, , ..).
N-
-
, .
R
Si
R
OCH2CH2
OCH2CH2
R
N X
X
Si
= , ()NMe2, NMe2, CN.
OCH2CH2
OCH2CH2
R
Si
R
OCH2CH2
OCH2CH2
N X
XIII -
-2010
128
: 661.66

.., .., ..
.
.. (), , e-mail: oilgas@mitht.ru

, (),
.

( ) . .. . ..

() .
,

.
:
( ), ,
(),

() -
(). , ,
, ,
.
.
,
130
~ 14 %
.

,
.

513, 323
803. ,
, .
,
803,
.
129

-
.., .., ..
(), . ,
e-mail: ad.l@rambler.ru

- ,

.
,
,
.
, ,

(- ). 25-75 %
. .

.

.

.

. :
20 , 20 30 , 10
/2, .
,

, .
60 % . ,

.
,
. ,
30 % .

,
.
HYSYS
Hyprotech.
XIII -
-2010
130
660:51.001.57+66

-

.., .., .., ..

.. (), ., e-mail: anokhina.ea @mail.ru
()
() .
.
[1] ()
- (). ,
, ,
, ,
, .
.
[2,3], ,
.

.

, ,
, .

.

,
[1]. :
;
, ;
, .
,
9,7 %
.
[1] R. Monoz, J. B. Monton, M. C. Burguet, J. de la Torre. Separation and

Purification Technology 50 (2006). p. 175 183.
[2] .., .., .. . 2207896 . .
10.07.2003, . 19. 4 .
[3] .., .., ..
, 2009, 3, . 4449.

( 08-08-00318-).
131
660:51.001.57+66

-
.., .., .., ..

.. (), ., e-mail: anokhina.ea @mail.ru
-
86,3 % . [1]
()
() . , ,
, ,
. [24],

(),
.
4 32 %.

. ,
.
[4]
- .
,
. 9,8
16 % .

- . ,
11,2 19,6 % .
, -

.
[1] .. . . . . .: , 1987.
[2] .., .., .. . . . -

. , 2006, . 41-42.
[3] .., .., .. . , 2008, 8,
. 402-407.
[4] .., .., .. . . , 2009,
3, . 4449.

( 08-08-00318-).
XIII -
-2010
132
547.245
. ,

.., .., ..

.. (), ., e-mail: lya17@mail.ru
,
,
.

.
,
.

-
.
, 3,5- (Ia) 3(5)- (I, ')
N- ,
-.
, N / ()
(),
- (II-).
, HN(SiMe3)2 / CO2
O
O
N
N N C OSiMe3
, Me3SiOCNEt2
N
II,
- Et2NH
H I,
Me
N
N
Me
Me
N
Me
N
N
N
'
,
N- () 15-20
, 70-75 0, 92-95%
, ()
9-10 , 87-89%.
,
.
133
547.261 : 547.262 : 544.473 039.63

.., ..
.
.. ( . ..), .
e-mail: egorova1412@mail.ru, bokarev_d@mail.ru

,
. ,

- .
, ,
.

.

,
, ,
.
. , , ,
,
.

.
, (ACF).

,
( ).

ACF, 4000, 60% 74% .
,
18 ,
.
-
36% 48%, 4250.
XIII -
-2010
134
678.049.4

.., .., .., ..
(),
., e-mail: butakovana@mail.ru

,
,
.
14-19,

.

, 50%
.

, .

,

. ,
[1],
2-3 .

,
,
. -

,
, , ,
.

,
,
.
[1] . 2312098 , 07 53/19, 07 51/215, 07 51/225.

/ .. ,
.. .: ; . 20.09.06; . 10.12.07.
135
665.765-404.038.1

.., ., ..
"", . , e-mail: sekr@svniinp.ru
,

-
. ,

. ,

, .
,
.

-
-11
, ,

.
(-300, -312, -313, , -150, -7120, -300, -140)

(Infineum C-9330Ca) .

. ,
,
,
. ,

-11 -11
-7120.
-11
-150 -300, -11
.
-11
, -
.
XIII -
-2010
136
: 547.245

.., .., .., ..

. . (), . ,
e-mail: aleksandra.gavrilova@rambler.ru

,
, ,
[1].
N,N`()
,
.
N,N`() [2].
,
,
.
- ,

.
R
R2SiCl2
Me3SiN=C=NSiMe3
cat.
Me3SiCl
Cl
Si-N=C=N
Me3Si
R
R
R2Si(OR`)2
[1]
[2]
Me3SiN=C=NSiMe3
cat .
Me3SiOR`
Me3Si
SiMe3
Si-N=C=N
R
, . . . /
.. // , . - 1975. 38.
Organosilicon chemistry IV. From molecules to materials. Novel silylcarbodiimide gels for the preparation of Si/C/(N) ceramics / E. Kroke [et al].2000.- P. 812-817.
137
544.473. 547.313.

.., .., .., ..

, ., e-mail: ink@anrb.ru
- , 8-14
.

.

-,
.

8-12
(Y, Beta, ZSM-5, ZSM12) - Y.
, -
Y, Beta, ZSM-12 , ,
, (5-30%
, 110-200) 70-99%.
ZSM-5,
20% , ,
.
, .
( 1%)
.
-

- ,
Y, .
-
8-12. -
, 2-5.
,
-
Na+ + .
138
XIII -
-2010
665.6

..
(), .,
e-mail: grushova.e@mail.ru

,

.
,
,
.

N- (N-).
,

, .
, , N-

.
, ,
, ,
.
, N- ,
,
( 10-15 % .) . ,

.
. ,
VD3 60
: 2:1
10 % ., 1,5 , -
20 % . ,
, ,
.
.

N- , N-
,
.
, .
139
53.092:665.63

-1
.., .., .., ..

() . .. , . ,
e-mail: ivanovmitht@gmail.com

(). (C18 )
,
.
.
.
-1,
[1], ,

.
5%-
- (20-38) 63,9.
-1 ,
0,5 5,5%. . i
, -1 (30)
7,1% - 7-19
20-38.
, (30-40)
-360
~4%.
,
(35)

-360
~3%.
.
, -1

.
, 350,
50-62%. -.
[1] , .,
/ . , .. , ..
, .. // - 2008. - .. - 3. - . 79-86.
XIII -
-2010
140
541.12:66.094.1

.., .., .., .., ..,
..
- (
), . , e-mail: lmkart@mail.ru

( )
(1,2).

,
.
CH4 + HCI + O2 CH3CI + H2O (1)
CH3CI C2H4 + HCI (2)

,
(90%) (
()).

.
.

.

.
230-300
, ,
.
.

.

. ,
.
,
.
0,5%.
Ni-Mo
( 20%).

.
141
665.7.038.2

..1, ..1, ..1, ..1, ..2
1
, . , e-mail: sekr@svniinp.ru
2
, . , e-mail: orgchem@samgtu.ru

.
(),
,

.
() ().
( 1) ( 2)
::, 2:1:2, ,
.
()
::, 2:1:2 ( 3). 4
::, 1:1:1,
, .

.
-200,
.
-92 (800/)
( 2101).

,
.
,
2:1:2. 1

.
3 5
,

.
XIII -
-2010
142
665.652.4:547.562/.563

..3, ..3, ..1, ..3,
..1, ..2
1
2
, . , e-mail: orgchem@samgtu.ru
3
, . , e-mail: sekr@top@nkzmip.ru
()
.

() 16 18.
,
(2,2 - -), -.

,
,
.
-
. ,
- -
,
.
95%, - - 2,753,13.
1250 1350 - -
1,27 1,47.
.
.
,
,
. ,
-,
. 135
,
. ,
: 1:6 135

9698%.
.
143
665.7.038

()
.., .., ..
D,
(),
,
.
.
.

.
9490-75 200 .
:
(), ,
(), ().
5000 1.
1
0,9
0,8
0,7
0,6
0,5
0,4
0,3
0,2
0
10
12
14
16
18
20
22
24
,
1.
5000

1%
1%

1%
1% -11
. 1 % .,
.

.
144
XIII -
-2010
661.715.7 + 661.719.2 + 542.973

.., ..
(), .,
e-mail: kinterm@samgtu.ru

.
,
, ,
, ,
.
,
2% (70%
).

0,5-2 ppm.
:
, , ..
: - ,
,
..

.

: -100, -202 -232.
(-100) (202, -232),
.
25
, 340-380
0,24-0,7 -1.
,
-100, ,
, 99,87%.
2% 1,9 ppm.
145
66.092.088

.., .., .., ..
. ..
(), . , e-mail: tetrationat@rambler.ru

, ,
, , , ,
. ,

.

, ,
.

.

2-4. ,

, .
,

.

.
, Ni/
,
.
Ni/ 2-4.
,
.
150-2500
Ni/
, ,
. Ni/

,
.
XIII -
-2010
146
665.765-404.035.033
.., .., ..

,

.
, ,
, ,
- , ,
,
.
, , ,
(),
() .
)
2 100 .

,%
)
0,5
0,4
0,3
0
-2
-4
-6
-8
-10
-12
0,2
-14
-16
-18
0,1
0
0
5
10
15
20
25
, % .
-20
-22
0
4
6
8 10 12 14 16 18 20 22 24
, % .
.
() ().
, ,
18-22%
0,30,4% 14 18 2 100 .

> 0,5%, ..
.
147
66.011:547.491.8

..*, ..**, ..*
*
-, . ,
e-mail: pravdin@niap-kt.ru
**
-
. .. ( ), . ,
e-mail: Kurilov@newmsk.tula.net
- . ..

, , .
:
1. -
,
,
.
2. ,
- .
3.

800 ,
,
,
.
4.
,
- ,
- Al2O3.
5.

80% 96-98%.
6.

,

.
7. ,
,
, .
XIII -
-2010
148
665.127.6; 661.725.82

.., ..
(),

.
,
, (
). ,
.

( (), ()). ,
: 3 ,
( 130-140) ,
, .

. ,
.
, ,
( ).
- .
, .
,
. :
14-22 -
, .

, -
.
,

-
.
149
: 529.12.

1,2-
.., .., .., ..
- , .

,
. ,
,
.
-l
335 / () 297 /
,
, .

,
,
.
, 460 - 500, 10
- 15 0,1-2,0% .,

13-20%,
0,1-0,7% .
0,5-1,0%
.
,
0,5-0,6%.
,

.
,
, ,
.

-
.
XIII -
-2010
150
66.094.3-92:541.459

N-
.., .., .., .., ..
, , e-mail: smirnovaev@ystu.ru

.

(-).
( )
( ) .
110130
.

, , ,
810 %. ,

.

.

(90 % )
N- (N-)
.
, N- 23 % .
1516 %, 4550 %
120130 23
90 %. , N-
1,52
. N
.
.

N- .
k 2 / k 6
N-.
N-.
151
662.758.2

.., .., .., ..

. ,
,
,
.

. ,
,

90%. 250300,
90%. 20%. 1100. ,
3600 4000.

(31205590), (2530
3480), (28404840).
-
-
4950 250 ppm.
,

- 13 21.

20. -
19 37.
20.
- 14 35.
230.
-

(% .) : 35-55;
10-25; 100.
4950 250 ppm
27 0.
, - -
.
XIII -
-2010
152
665.6

.., .., .., ..
(), . ,
e-mail: kmary@rambler.ru
,

( , )
.

.

.

, , , ,
, , , ,

.
,
,
-
,
.
, ,
,

, ,
,
. , ,
, ,
,
.
,

.
,

, .
153
665.637.8

.., .., .., ..,
..

60/90 , 2224590 .

80 0 20 40 .
.
-
5 /-,
.

.
400 /, 3 /-.
250 0

" " () 11506.
48-49 0,
60/90 22245-90.
1 .
.
7 ,
- 0,14 % .,
3-5 % . . ,
400 /.
.

. 60/90,
.
, 40 ,
75 %, 100 , ,
.
80 0 20 , 22245-90,
.
154
XIII -
-2010
SYNTHESIS OF CARBON NANOTUBES (CNTS) BY PYROLYSIS

CATALYTIC FROM CRUDE OIL
Hamada B., Taheri Taghavi M.T.
Laboratoire de Synthse Ptrochimique- Universit Mhamed BOUGARA de
Boumerds. N1 Avenue de lindpendance Boumerds 35 000, Algeria,
e-mail: bou.hamada@gmail.com
The present study is to provide a process for the preparation of carbon
nanotubes (CNTs), introduced in a gaseous phase which is a colloidal solution of
metal nanoparticles optionally containing a solvent together with an optional carbon
source into a heated reactor to produce the CNTs. According to the present study,
the CNTs can be produced in large scale, the apparatus and the process for the
preparation of nanotubes having various shapes, structures and properties can be
easily and cheaply prepared. Further, the process of the present study is highly
producible and attractive to the industry.
155
544.342

.., ..

.. , . , e-mail: dlinn@ya.ru.

.
, , 1-5
.
.
,
HCl
CH3Cl. -.

(3,0-4,0 ),
.
, SRK PR
.
UNIWAALS,
.
HCl
CH3Cl c UNIWAALS
.
-
.

:
, ,
UNIWAALS.
HCl
, HCl
SRK, .
, ..
.
, 02.740.11.0478.
XIII -
-2010
156
66.048.3.001.57

1,2-
., ..
- , . ,

1,2-
480-500 ~25 . 1,2-
50-55%. ,
; ,
,
,
.
, 1,2-,
,
.
1,2-
,
:
1,2;
1,2-.
;
;
1,2-
;
;
;
(
- );
- .
1,2, ,
,
.
2009- .

.
157
542.934.8: 66.011.24/.34

..1, ..2, .. 2, ..2
1
, .
- , . .
e-mail: radik.nk@inbox.ru; Petukhova_liubov@mail.ru

.

().
,
. -,
,
. -,

, .

.
,
,

, .
, 190
, , ,
, -,
0,01% . 0,2% ., 98,599,9%,
8994% ., 14%
. 25% .

96-98% .
35 , 2-3 .
,
:
, , ;
,

;
XIII -
-2010
158
665.73:621.187.152
-
Cu-
.. .. .. ..1, ..,
. .2
1
- . , e-mail:vesat@yandex.ru
2
- . , e-mail:sapr@sapr-n.ru

-, , .
, -
3 5 % .,
.
.
3 ,

, , .
Cu-Zn-Cr-Al ,
( 17 54 % )
.
(-4).

200-3000. ,
.
-
. ,

,
.
.
50 %, -
.
3
,
. -,
, , ,
.

u- .
159
66.097.3:547.261

( 60-90C)
..1, .., .., .., ..,
., ..2
1
-, . , e-mail: vesat@yandex.ru
2
, . , e-mail: info@rusgazen.ru

,
.
- ,
,
.

, -

60-90 .
,
.
, ,
, .
-2000 - ,
SE -54.
Zlab.
(60-90)
0,7013 / Cu- ,
, .

, .

.

.
,
27 .

. , ( )
, ,
2%. ,
.
XIII -
-2010
160
547.32
-1,2-
.., ., .
(),
. , e-mail: shetnevaa@ystu.ru
-1,2-

.
-1,2-
().
- (1, 2, 3)
3- 4--3--1,2
:
O
Ph
OH
OH
Ph
Ph
OH
OH
1
OH
OH

(56% HNO3 / CH3COOH; 100% HNO3 / CH3COOH; 100%
HNO3 / H2SO4)
100% HNO3 / CHCl3 / RT,
2 3, .
O
O
OH
O
AcCl
O
Ph
Ph
OH
O +
N
O
O CHCl3
O
OH
O
AcCl
O
OH
O
+
OH
7-8%
O O
O
O
HNO3
OH
O +
N
O
CHCl3
7
O
+
O N
OH
88-92%
4
O O
HNO3
OH
O
40..45%
1, 2 3

4 7. -
(HNO3, CH3NO2 / o : : / 12 : 8 : 80). 87..89
%- - 6 7-8 %.
-.
, 4 7 100 %-
.
161
541.128:542.952:541.124:547.257.4.-368:547.952.3

[2+2+2]

.., .., .., ..

. ..
, 119571 , , 86;
e-mail: ilya-efros@yandex.ru
[2+2+2]-
( , , ) (S)
(), Ni(0).
- - [2+2+2]-
(1, 2) (D1-D4) [1, 2, 3].
, P1/P2 D1/D2/D3/D4
,
(P1+P2 D1+D2+D3+D4).
+ D1 + D2 + D3 + D4
S
+ S P1 + P2
DynaFit 3.28.061 (free
academic license www.biokin.com) [4].
,
.
,
S.

.
[2+2+2] ,
.
-
2009-2013. 2451 19.11.2009
[1] Lautens M., Edwards L., Tam W., Lough A., J. Am. Chem. Soc. 1995, 117,
10276-10291.
[2] D.V. Dmitriev, O.S. Manulik, and V.R. Flid, Kinet. Katal.(rus.), 2004, vol. 45,
No. 2, pp. 181-187.
[3] .. , .. , .. , , 2010,
51, 3, . 1-5.
[4] P. Kuzmi. //Analit. Biochem. 1996, 237, 260.
XIII -
-2010
162
541.128:542.952:541.124:547.257.4.-368:547.952.3

--
.., .., .., ..

. ..
, 119571 , , 86;
e-mail: ilya-efros@yandex.ru

.

, [1].
, [2+2+2]-
() (I) ,
Ni(0). [2+2+2]- - - (IIa,
IIb), (III VI) [2, 3].
(PPh3)
(
Ni:PPh3=1:1)
-

Ni:PPh3.

.
() ,
Ni(CO)3L ( L
).
- - , .

.
, , -/- 98 / 2.

- . , , -,
.
-
2009-2013. 2451 19.11.2009
[1] C. A. Tolman, Chem. Rev., 1977, vol. 77, 3, . 313 - 348

[2] D.V. Dmitriev, O.S. Manulik, and V.R. Flid, Kinet. Katal.(rus.), 2004, vol. 45,
No. 2, pp. 181-187.
[3] .. , .. , .. , , 2010, 51,
3, . 1-5.
X
Ni(C3H5)2
IIa
IIb
PPh3
III
IV
VI
163
547.538

.., .., ..,
.., ..
(),
. , e-mail: limarsel@mail.ru

.
, ,
, ..

() -
.
()
.
-24.

. 2000/
4000. 4000, , 2 ,
. 6000 1
, .
6000,
: 1:3, - 1 -1.
,
640.
Gaoyue 42 .
,
. -
-4000.
,
( , ,
), ,
.
,

15-20%
, .
XIII -
-2010
164
547.546 + 547.822.7 + 547.655.1 + 548.539.26

5,7--8-
.., ..
. .. ,
300026, . , . 125, e-mail: reaktiv@tspu.tula.ru

.
,
.
11-
1,9--6,112,7
[7.3.1.0 ]-2,4,6--8-
(III)
,
5,7--8- (I)
-
--.
(I) - (II)
20-250 15-20 NaBH4.
NO2
NO2
NO2
+
NaBH4
2-
-B2H6
NO2
NO2
OH 2Na
II
NO2
OH
I
R= Alkyl, Aryl, Heteryl
2CH2O, H
RNH2
-H2O
III
(II) ,
,
II, 30%
. 30
20-30 4 (
). III
,
.
1,9--6,11-[7.3.1.02,7]2,4,6--8- (III) 1 -.
165
665.656.2

.., ..
. .. , ,
119991, -1, , 47, e-mail: SECRETARY@ioc.ac.ru
N-
,
5%
5 . .
, , , N
. N-
.

N-
.
Al2O3
Fe2O3, CuO (660 .%) Cr, Mn (01 .%),

.
N-,
,
.
:
1)
10 -1
,
, ,
100300
2)

- N,N-, 10 -1
250300
3)
,
a)
;
b)
CO 2 2
2 2; c) CO2 - CO2.
- 500700.
1 /N-
(): 1,32/1,15, 0,34/0,60
1
/, 15 /
XIII -
-2010
166
665.656.2
..
. .. , ,
119991, -1, , 47, e-mail: SECRETARY@ioc.ac.ru

,

, O-, S-, N-
.

.

.

SAPO, PdLaCa(Mg)X(Y)
Faujasite Al2O3.
:
1)
()
SAPO - Al2O3 210-1
300400. 100%-

2)
SAPO
24-1 400450 -/ : 15 .%,
14 .%, 0,5 .%, --1 -2 0,5 .%, 1030 .%, -
5 .%, , , , ,

3)
- - 24
PdLaCa(Mg)X(Y) Faujasite 24-1
50100 ,
,
: 99%,
95%,
8 8085 .%, 9+ 8 .%, 57
9 .%, 6570 .%,
/ 55,5
167
547.785.51

.., ..
... (),
., e-mail: galia712@yandex.ru

. , ,
,

.
, ,
,
,
.
[1,2-a]
[3,2:4,5][1,2a].
.
N-(2-NO2-()) ().

.
R
R
X
N
R1
R2
R1
NO2
a)Na2S
Cl X
+
N
R2
R1
O2N
1,2
R2
ON
CF3
CF3
H2N
O
H
HOHN
)SnCl2
>10 % HCl
N
N
HN
HN
R2
) TiCl3
)SnCl2
2-3 % HCl
t= 0 C
t=50 C
Cl X
+
N
R1
Cl X
+
N
R1
R2
R1
Cl X
+
N
R2
H2N
n
8
3,4
5,6
1, 3, 5 =, R=R1=H, R2= NO2, F3, CN, COOH; R=3, R1=H, R2=CN;

R=Cl, R1=H, R2=CN;
2, 4, 6 =N, R=R1=; R=R1=3; R=, R1=3
,
(II)
2-3 % HCl, , -,
20 0.

-
XIII -
-2010
168
543.429.23

5(6)--2-(4-)
..1, ..1, ..1, ..2, ..3,
..1, ..1, ..1, ..1
1
. ..
( . .. ), .;
2
(), . ; 3
, . , e-mail: benosi@mail.ru
()
,
5(6)--2-(4) ()
252.
5(6)--2-(4-)-1-1,3- (1)
4-(5--2-[d]--2-)-2,5 (2):
ON
ON
NO
N
H
N OH
N
1
2

( -
()). .
1 13.
1 1 2 8
,
, .
1 10,57 ..,
CF3COOH,
,
.
13 1 2
11 , .
13 2
162,76 101,4 ..,
CF3COOH (COOH CF3), .
, 1 13
1 2.
169
547.26122.05

, .., ..
(),
., e-mail: organic@vstu.ru

[1]

.
,
H(CF2CF2)nCH2OS(O)Cl (n = 1,
2, 3) c N,N-
() .
[2, 3], ( )

.
()
.
CH2 (CF2CF2)nH
O
O
HC(O)N(CH3)2
H(CF2CF2)nCH2OS(O)Cl
ROH
ROCH2(CF2CF2)nH + HCl + SO2
H
O
H C
S
Cl
N(CH3)2
n = 1, 2, 4; R = CH2CH=CH.
,
. .
10 5

( (1- 1.1) : 1: 0.05 )
.
,
.
30 3-5 . 28
51%.
[1] . ., .., .. //
.-2007.-.2.-.345.; [2] . ., . . //
.-2007.-.77, .10.-.1750.; [3] . ., .
., . . // .-2008.-.78, .11.-.1842-1848.
XIII -
-2010
170
547.915:621.892

..*, ..*, ..**, ..**
*
**
() ,
" ", . , .
e-mail: ivankin63@mail.ru

()

(), 2 (Na 2-) N,N- ()
().
:
- ;
- Na 2- .
,
99%. Na
2- . ,

: ; Na 2-;
: . ,

.

.
,
(91-92%):
25,0-35,0%; Na 2- 12,0 15,0%; :
1: 0,1-0,3.

, 35%
Na 2- 15%
- .
: 10,5
.

30,0-35,0%.
171
547-304.1

,

.., .., ..
. .. (),
., e-mail: begunov@bio.uniyar.ac.ru

.
, ,
, .
,
.
.
-, ,
2,4-,
: , N (. 1, 1).
X
Na 2S, EtOH
SnCl 2, HCl
X
NH 2
H 2N
Cl
NO2
O2N
FeCl 2, EtOH + HCl
O2N
MeCln, EtOH + HCl

X
NH 2
N
NH 2
NO2
H 2N
MeCln, EtOH + HCl
O
X
NH 2
N
N
H 2N
H 2N
= , 2, N-CH3
,
:
. , (. 2-4)
( 5,6).

.
.
2009-2013 ( 2057)
XIII -
-2010
172
541.28

1 %
,
.., .., ..
() , .,
e-mail: butov@volpi.ru, galina1@mail.ru

,
().

,
, .
20 5
101325 . ,
.
,
. 1%Pt (Pd)
, .
,
Al2O3.
, -, n-
, ,
. , ,

.
-. ,
,
, ,
.
, .
, ,
:
1%Pd/:
-;
1% Pt/: n- .
, , Al2O3

,
173
66.095.132

.., - .., .., ..
" (),
(), .
e-mail: st_melnyk@yahoo.com

[1].

, ,
[2].
( )
45,
, (), (), , () .
,
,
, -,

. ,

.
.

.
[1] WO 049556 C07C 303/32, C07C 67/03, C07C 67/08, C07C

309/01. rocess for the production of metal salts of trifluoromethane sulphonic
acid and their use as esterification catalysts / Finmans P., Hoell D., Vossler H.J., Rozek M., Green M. (); SASOL Germany GMBH International
Application PCT/EP2004/013107. . 18.11.2004; . 02.06.2005;
http://www.wipo.int/pctdb/en/wo.jsp?wo=2005049556.
[2] .., .., ..
. .: , 1982. 200 .
XIII -
-2010
174
665.656
-1

.., .., .., ..
, .
e-mail: rybinagv@ystu.ru

4 5 ,
- .
(,
).
-1
SiO2 4 %.
- --2.
,
-1
. -1,
93 96 %, 5- .
200
600 , 1 4 1.
200 300
-1, 5 12 %,
-1 48 87 %. 400
,
, 500
,
, . , -
.
: 400 , 2 1,
-1 95 %, 71 %,
.

-1.
-1 10 ,
93 %. 6 71 %,
, , 63 %.
, , -
550 ,
1000 2000 1 1 . ,

.
175
665.63

.. .., ..
,
. , e-mail: Irina3980@mail.ru

,
.

,
, ,
,
, .
:
- .

, , .
,
.

, N-.
N.
, , ,

. N ,
.
, N-

.
N-
. , ,

N-.

N- , -, .
N-
, -
.
XIII -
-2010
176
547-311

.., .., .., .., ..
()
, . ,
e-mail: avsulimova@mail.ru
( , , .)

,
.

.

,

.

,

.
, , -1, -1, -2, -2,
, , , .
,
. , , -2,
, , -1, , -1, -2,
, .
.
,
, ,
. , ,
. -,

. -,
,
, ,
. ,
, ,

,
.
177
665.521:621.89

.., ..1, ..
, . -
,
. , e-mail: petroleum9@bk.ru
EN 590
0,2 0,035% ,
45 51 .,
2,7-6,5 2/ 20 .
( 0,05
) 1990 [1].
,

:
-

- ,
.

,
, ,
, , ,
.
, -

0,3% () ,
, :

-43
-49
,
:

680
60 , *
* - 460 .
398
[1]
.., .., .., .., ..,

.., ..
// , 2002, 1, .2831.
178
XIII -
-2010
665.652.4

..
,
. , e-mail: petroleum9@bk.ru

, Y
- [1], ,
,
-
.

, .
,
(10-40%) , ,
. , -

7,5-10%.

.
2009 2013 .
[1] Shiriyazdanov R. R., Rysaev U. Sh., Turanov A. P., Morozov Yu. V.,
Akhmetov S. A., Nikolaev E. A. // Petroleum Chemistry. 2009. Vol. 49, No. 1.
P. 8689.
179
546.28
-1

.., ..
, . ,
e-mail: yurkova@ipac.ac.ru, lermon@ipac.ac.ru

-1.
, 0.3 3 ,
10%- , .
, ,
,
.
-2 -3
12:
[H+]
60 0C
+ C12
0.3
, 400 ,
91% 9% 12.
, 600 , ,
6 : 12=1 : 99.
400 600
. 600 0.3
. ,

6-8 .
182
XIII -
-2010

.., .., ..,
.., ..
. .. . , e-mail: baryshnikov_anat@mail.ru

.
, , ,
,
,
.

.
,
,
.
,
().
,

, ,
. , ,
10 ,
.

.
,
.

, .. ,
,
.
.

-
(, ), (),
().
,
- in vitro.
183
547.458.2

.., ..

. .. (), . , e-mail: c-221@yandex.ru

-
-, ,
.
,
,
.

.

-

,
.
OH
OH
OH
O
HO
OH
OH
OH
O
HO
O
HO
OH
O
HO
O
OH
OH
O
OH
ONHCCH 2O(CH2 CH 2O)75CH2 C NHC 18 H37

(1)
CH2 COOC14 H29
CH2
O
O
ONHCCH 2O(CH2 CH 2O)75CH2 C HN CHCOOC 14 H29
(2)

,
,
, ,
.

( 08-04-01150)
2.1.1/2889.
184
XIII -
-2010

.., .., .., ..
.. ( ),
. , e-mail: chertenok84@list.ru

.

,
,
,
-
.

-3-()
(3-[[(4--1)]]).
,
.
.

1 . %,
.

,

.
,
,
, ,
, .
,

,
.
.
185
547.8:544.773.33

. ., . ., . .
-
. . . (), . ,
e-mail: e_ilyushenko@mail.ru

.

.

N- () ().

.
,
,
.
.

.
( +
)//
.
( - ) 30
40 .
, (-).
( )
80 150 () 140 190 () ().

in vitro 0,1 HCl. , 7
70% .

- .
(
) .
g
.
XIII -
-2010
186
577.113.3

..
. ..
(), . , e-mail: dryulets@mail.ru

(. 1) , , ,
,
, .
- () (.
1).

() (. 1, ).
O
HN
2
4
5O
-
4 N
7HN
8
10
O
O
P
O
12
11
O
O
O
HN
O
O
13
R
B
11
10 N
HN
B
N
HN
12
13
7O
HN
HN
N
R
O
HN
HN
R= CH3,
R= CH2CH2COOH
. 1. (), ()
(, ) (B = Ade, Gua, Thy, Cyt).
, ,
,

-
.
: ;
;
;
;
, .
187
577.152.1

-

.., .., ..
-
, 121552 , , e-mail: alexmak@cardio.ru
()
() - (--)
.

-- ,

. ,
--
, , , TRAP,
22 ,
. --

,
. --
(
,

)
. ,

.

09-08-00023 .
XIII -
-2010
188
547.915.5

.., .., ..

.., . , e-mail: mamaslov@mail.ru

,

.
. ,
, ,

.
,
,
, ,
.
,
.

,
.
: ,
. ,
,

,
.

, (
, ),

,
.
-
( 715) (09-0300874).
189
615.014

..
. ..
. , e-mail:oborotova@mail.ru
( )
, (
) . ,

- ,
, , -
, - .
-

.
,

(Enhanced permeability and retention effect, EPR). , .. ,
,
in vivo.
in vitro.
,
,

.
.

,
42.
: ,
,
, . ,
,
; ,
; ,
.
.
.
XIII -
-2010
190
547.922: 547.415.5

.., .., .., ..,
..

. .. , . , e-mail: mamaslov@mail.ru

.
,
.
,
-.
.
,
,
.

, .

.
,
- ,
, .

.

, . ,

.
-
( 715).
191
378.22; 615.012.6

.., .., .., ..

(), ., e-mail: a_pshenichnikova@mail.ru

.
, ,
.

.
,
, .
,

.
( )
. .. -
, 2007 .
-
, .. .
-
, ,
- .

.
, , ,
.

,
,
,
GMP.
-

.
XIII -
-2010
192
547.979.733:615.849.19:616-073

Yb(AcAc)-
2,4- IX
..*, ..*, ..**, ..**,
..**, ..***
*
. .. , , e-mail: vdrum@mail.ru
**
. .., . ,
e-mail: laserlab@ms.ire.rssi.ru
***
. .. , , e-mail: ivavi@yandex.ru
,
- ,
.
30%
.

,
,
.
.
. ,

, , .
Yb- ,
.
Yb(acac)- 2,4-
IX. ,
.
1,2,4-.
-2.
- 975 , 10 .

Yb(acac)-2,4- IX . .
BALD/C : LD100 200 / ; LD50
150 /; 125 /.
,

2,4- I
0,1-0,5 / .
, 3065
193
563.16; 31

.., .., .., .

( ),
. , e-mail: v@di.r.

.
.

.
- , 2-(3,4-),
-
.
20% 2-(3,4-).
2-(3,4)
.

, ,
.

. L-
,
,
N--L ,
().
, N--L-
D,L- .
,
, ,

N-(5-R1,R2 --1-R3-)-4-R4-.
(N(5- -1-)-4-).
194
XIII -
-2010
66.047
-
.., .., ..
- (),
. , e-mail: piaxt@isuct.ru

.

( 50C)
.

.
-

.
.
30 ,
250 50 %.
30
50 C, 30 80 C,
1 20 . .
22-29 C , 35 80 C.

.
,
-
, ,
,
.

250 % 5
9,3 %,
, 3 45 . 7
. ,
-

.
195
547.426.253
-

.., .., ..*

. .. , .
*
. ..
.. , .
e-mail: anna@lipids.ibch.ru

.
. ,
, :
, ,
, .

, .

,
.
N-[4--5--3-)]
, ,
.
,
, ,
. ,
, .
,
--715
XIII -
-2010
196
547.541

.., ..
,
. .. (), . ,
(), . -,
e-mail: svetlana.artamonova@gmail.com

.

- () -- ()

, .

.
,
--,
.
,
.
,
1-2
, 3 ,
[1].
[2] . ,
(0.064 /) ,
Paxillus atrotomentosus ( ).
3-4 .
,
,
.

.
.
[1] .. -
: ...-, 2000 254.
[2] .., .., .., .. //
. 2009. . 49. 3. . 1-6.
197
547.853.7 + 547.854.83
-4--2--5
.., .., ..
. ..
. , e-mail: reaktiv@tspu.tula.ru
1,3-
.
,
-4--2--5- (5).
1,3- :
O
O
+
N C CH2 C
OC2H5
1
S
+ H2N C NH2
HS
N C CC
OC2H5
3 CH
OC2H5
CH(OC2H5)3
2
O
O
OC2H5
RI
NH2
R = Alkyl, Aryl
RS
OC2H5
N
NH2
1
2 4 .
( ) .
-2
( 60%).
3 .
80
8 . ,
.
-2 ( 70%).
, 3
. -4--2-5- (5) 60%. 5
-.
XIII -
-2010
198
547.853.7 + 547.854.83

2-(3--2-)
.., .., ..
. ..
1,4-
, ,
, , ,
.
.
2,3-
O-, S-
.
H
Cl
N
1
Cl
O R1
R1
N
Cl
3
H
S
R1
R1
N
R 2b
O
O
R 2a
6
R2b
R2a
R1 = Alkyl, aryl; R2 = alkyl, aryl, hetaryl, ..
(1)
(2) -
.
4 . ,
, ,
3 -2 ( 90-95 %).

2- (4), ,

.
,
, -.
6 . 5 50-60%.
6.
40-80 %. 120
1 .
199
547.593.261

.., ..
.
.. (), . , e-mail: liuleka@ya.ru.

-. ,
() -
gp120 Arg59
CD4,
[1].
,
,
.

,
,
gp120 CD4.

CD4
AutoDock4, .

,
.
1. .
[1]
M. Cushman, S. Insaf, G. Paul et.al. Extension of the polyanionic cosalane
pharmacophore as a strategy for increasing anti-HIV potency.// J. Med. Chem.,
1999, Vol. 42, pp. 1767-1777.
XIII -
-2010
200
547.73
..1, ..1, ..1, ..1, ..2,

..3, ..4, ..1, ..1
1

. .. , . ;
2
. .. , . ;
3
, . ;
4
. .. , . .
e-mail: nbelikov@yandex.ru.

(V),
all-E-

1,2-().
-
5- (I).
(II)
-80.
(III, IV)
(V) 12%. = - 1-- (J 16.3 ).
,
- .
O
(EtO)2P
R
(I)
CN
CN
R
NaH, THF
O
(EtO)2P
NaH, THF
DIBAH
R
(II), 90%
(III), 40 %
CN
CN
R
(IV), 80 %
CHO
DIBAH
CHO
R
(V), 40 %
-
[1].
[1] N. Belikov et al. // J. Photochem. Photobiol. A: Chemistry 2008. V. 196. P. 262267
201
547.454
1,3-

.., .., ..

(), ., e-mail: c-221@yandex.ru
1,3-

, ,

.
,
, .

1,3-
- ,
, .
u(I)
,
1,4-.
N N N R'
R' ' C CH
CuI
N
N
R'
R' '
1,4-
1,2,3- ,
, ,
,
.
1,3-

.

.

( 08-04-01150)
2.1.1/2889.
XIII -
-2010
202
:547.979.057

1
.., .., .., ..

. .. (), . , e-mail: brittal-d@mail.ru
()
,
(,
(), , ,
.
,
.
,
600-700 ,
[1]. ,
, .

,
.

lick chemistry.

- . Click-
,
.
1,3

[2].
.

.
-,
.

-, -
.
[1] .. . 1996. 8. . 32-40.

[2] Grin M. A. et al . J. Porphyrins Phthalocyanines. 2009. 13. P. 336-345.
1
( 09-03-00701)
203
577.181.5; 579.841

.., .., ..
. , . , e-mail: a_pshenichnikova@mail.ru
.

,
.

-

Methylophilus quaylei (M. quaylei MT M.
quaylei SM+) ,
, Stenotrophomonas maltophilia.
, 50%,
510-3, 0,9 4,4 / M. quaylei MT, S. maltophilia M. quaylei SM+
.
M. quaylei SM+, S. maltophilia
( 180 , M. quaylei MT).

-,
. =7 0,001 KCl -
-27,38; -27,23; +0,14 M. quaylei MT, M. quaylei SM+ S.
maltophilia . -
.
S. maltophilia ,
( )
, .

,
. S. maltophilia
7,0 9,0 ( ),
, M. quaylei MT M.
quaylei SM+ 3-4,
.

.
204
XIII -
-2010
544.165:[678.742.2+546.3-128](043.2)

. .1, . .2, ..1
1
- (),
. , e-mail: gornoukhina@isuct.ru
2
,

.
, ,
, ,
.
,

()
.

. -,
,
; -, ,
, , .
,
20-% 37-%
(1240 1400 1
),
(1600 1680 -1, ).
- ( )
,
~
300 - .
, .

(I) (II).
, .
2009-2013 .
205
577.113.3

.., .., .., ..
. ..
(), . , e-mail: esipova_ov@mail.ru
,

. (),
,
N-2-,
(.. aeg-).

().
aeg-,

.

.

, 4 .
B
B
O
R2
BocHN
COOH
CF3COO
+
H3N
R1
(1) R1 - CH2CH2COOCH2Ph R2 -H
(2) R1- H R2 - CH2CH2COOCH2Ph
B=Thy, CbzCyt, CbzAde, Cbz(Bzl)Gua
B
O
R2
N
R1
B
O
R2
N
H
N
R1
R2
N
H
n
NH2
R1
(3) R1 - CH2CH2COOH; R2 -H; n=1; TAC

(4) R1- H; R2 - CH2CH2COOH; n=1; TCT
(5) R1 - CH2CH2COOH; R2 -H; n=4; TAGTAC
B=Thy, Cyt, Ade, Gua

, 4 ;
(3, 4, 5),
,
MALDI-TOF-MS.
[1]
[2]
Christensen L., Fitzpatrick R., Gildea B., Peterson K.H., Henrik F. Solid phase
synthesis of peptide nucleic acids // J. Peptide Science. 1995. Vol. 3. P. 175
183.
.., .., .., ..

GlyL-Glu // . 2007. . 2, 5. . 3336.
XIII -
-2010
206
543.054:577.16
12
STREPTOMYCES GRISEUS
..1, ..2, ..1, ..2
1
, ,
e-mail: korenman@vgta.vrn.ru
2
, ,
e-mail: moksnad@mail.ru

. 12
()
Streptomyces griseus.

.
, ,

.
,
.
,

.

,

.

(),
.
12
( , , )
5 ., ,
.
.

l =1
( =360 ).
12 1400

1:20.

12
Streptomyces griseus .
207
547.9

..
(), .,
e-mail: Lena-studia@yandex.ru

,
;
;

.
(Phytolaca Americana)
,
.
,

.
, .

.

.

.

35.
: 1:5.
. ,
,
. 25% 3
, 40% 40 ;
13% .

, ( 45)
(20-25),
;
.
XIII -
-2010
208
547.298.1-547.554
..*, ..*, ..*,

..**, ..*, ..*,
..**
*
.
.. (), . , e-mail: NB714485@yandex.ru
**
- , .
N
,
;
(, , , , , ).
, ..

- .
,
,
.

, -
N- (I)
,

(n = 1 3)
.
,

.
N .

, ,
( )
, .
.
209
: 547.455.627:547.922

.., .., .., ..

. ..
(), ., e-mail: e.a-ivanova@mail.ru

- .

. ,
,
,
. ,
, ,
,

.

.
() .
,
,
, .

.

.

.
-
,
,
.
-
( 715).
XIII -
-2010
210
547.057-7/.8
3--[1,5-],
,
5-6
..1, ..2, ..2, ..2,
..2, ..2, ..1
1
ChemDiv, Inc., 6605 Nancy Ridge Drive, San Diego, CA 92121, USA,
, 114401 ,
., e-mail: kadieva@iihr.ru
[1,5a] - 5-HT6
3-[1,5-a] (),
,

.
Ph
MeX
S
O
(2-PyCO)2CH2
S
O
2-Py
2-Py
O
+
Ph
S
Ph
S
Ph
O
S
N
Ar
H2 N
5
S
O
N
NH
Ph
MeNH
3-Py
3-Py
7
1 - 5: X = S, NH. 5: Ar = Ph, thiophen-2-yl
, 5-HT6
,
I50 = 2,3

.
3-Py
Cl
OMe
N
N
Ph
MeNH
3-Py
4
O
O
MeNH
3-PyCOCH2CO2Et
O
MeX
3-Py
MeNH
ArCOCH2CN
NH2
O
N
N
N
H
Ph
MeX
3-PyCOCH2COR
Ph
MeX
Ph
MeX
O
N
N
Me2 N
N
9
3-Py

,
I50 = 12790 ,

211
547.057-7/.8

3--[2,3-E][1,2,3][1,5]
..1, ..2, .., ..2,
..2, ..2
1
ChemDiv, Inc., 6605 Nancy Ridge Drive, San Diego, CA 92121, USA,
, 114401 ,
. e-mail: kadieva@iihr.ru
510
3-[2,3-e][1,2,3][1,5-]
2-9 () - 5-6

.
SEt
S
O
S
N
N N
HN
NH2
N N
O
S
Alkyl
O
S
N
R
Cl
N
O
S
N
N N
N N
Ar
S
N
N
N N
7
R1
R
N
N N
N N
O
S
N
1
HN
O
S
NH
1(1-9)
Azaheterocyclyl
O
S
5
R
N N
N N
= 4-Me, 4-Et, 4-i-Pr, 3-Cl, 4-Cl, 4-Br, 2,5-di-Me, 3,4-di-Me;
O
S
9
R2 =
amino groups (see Chart 10.
. 510
[2,3-e][1,2,3][1,5-] 2-9.
3-

5-6 ,

.
XIII -
-2010
212
547. 46 052. 1. 057
, ,
,
-
.., .., ..
(),
. , e-mail: viktori_2008@bk.ru

,
.

3-
,
3-,
3, 3- 3-
3-,
3-(3),
3-(3-)-2-,
3-(3), 3-(3-)- 2-2-(3-).
,
, -
, , , .
(1),
N- (2) (3), 3-
.X-C NH . HCl
=
X-CN
+ C2H5OH
NH . HCl
X-C
C
OC2H5
O
.
N C
X-C
O
Cl
+ 2(C2H5)3N
OC2H5
+ 2(C2H5)3N . Cl
(2)
O
N .C
NH2
X-C
OC2H5
(1)
OC2H5
+ HCl
X-C
N
=
. .C
NH
Br
+ C2H5OH
(3)
Br
X= ;
CH3
-CH=CH- ; -C=CH- ; -C-O-CCH3

CH3
,
, ,
,
. N-
, .
213
547.52:547.59.12.047
- -

.., .., ..
(), . ,
e-mail: kamkinanv@ystu.ru

- - -
, .
- .
, -
,
, 4-(1--1-) , 4-(1,2--1-)
7:2:1 ,
.
-
- ,
.
, 1 -
-.
R1
R2
O
OH
Br2 / CCl 4
h / 75 oC / 5
R1
Br
R2
Br
OH
57-70 %
R1 R2 , Alk; R1R2

,
.
-
- .

O, N-, ,

.
XIII -
-2010
214
547.454
.., .., ..
.
.. , . , e-mail: C221@yandex.ru

, .

ArgGlu, LysGlu, OrnGlu, LysGln OrnGln.
-
(8, 14, 16, 18:1)
.
(, -, , ,
)
.

().

.

.
,

- : -
, .

in vivo.

( 08-04-01150)
2.1.1/2889.
215
547.979.733

.., ..

. .. (), ., e-mail: nadejda_73@mail.ru

,
,
.

,
.

,
.

5-(-)10,15,20-, .

,
.
,

.

() ()
. Spirulina
platensis, ,
.

.
172
5-(-)-10,15,20-
.
,
.

( 2.1.1/2889).
XIII -
-2010
216
547.979.7
.., .., .., ..*, ..*,

..*
.
.. , . , e-mail: n.bragina@mail.ru
*
, .
,

, ,
, .[1].
-
- ,
,
.
5,15--
5,10,15,20-

[2].

,
,
Zn, Co, Ni Cu.

.
, ,
[3].

,
, -.
, , .

.

2.1.1./2889
[1] .., .., .. . // :

/ . .. . : ,
2004, 546 .
[2] Fedulova I.N. et al. // Mendeleev. Commun. 2008. V.18, P.324-326.
[3] .., .., .., .. . //
/ Macroheterocycles 2009. V. 2(3-4), P. 228-236.
217
547.057-7/.8
2,5,7- 3-[1,5-],
5-6
.., .., .., ..,
..
(), . .,
ChemDiv Inc., San Diego, USA, e-mail: ivk@iihr.ru

()
5-HT6 (5-HT6R).
[1,5-a]
5-HT6
. 5--4-()-1- 1,
[1,5-a],
2-, 5- 7- ,
5,6,9--3-()-6,7,8,9-[1,5-].

.
5-HT6 ,
. .
Ph
O S
O
Ph
H2 N
O S
O
MeCOCHYCO2Et
Y=H, Cl
XMe
H
N
Me
Me
XMe
POCl3
N N
XMe
Y=H
Me
COCH3
NH2
Me
Me
Ph
O S
O
CO(CH2)nCO2 Et
NHMe
EtO2 C
N
Me
N
Me
N
Me
XMe
Me
5
Ph
O S
O
Me
O S
O
N
Me
Ph
O S
O
XMe
H2 N
10
NH2
N
XMe
Ph
O S
O
Me
1-11: X = S, NH; 7-12: n = 1,2; 4: R1, R2 = H, alkyl
Me
Ph
O S
O
Me
N
n
XMe
N
Me
11
R
4
XMe
NH2
Ph
XMe
N
Me
NHMe
Y= Cl
Me
O S
O
CO2 Et
XMe +
Ph
Ph
O S
O
XMe
1
CN
Ph
O S
O
Me
R1R2NH
Cl
Ph
O S
O
12
XMe
N
XIII -
-2010
218
547.057-7/.8
, 5-6

5,7--3--[1,5]
.., .., .., ..,
. ., .., . .
(), . ,
ChemDiv, San Diego, USA, e-mail: ivk@iihr.ru

5-HT6 (5-HT6R)
().

5-HT6R - 5,7--3()[1,5-].
5-HT6R

.
5,7--2--3()[1,5-] 2(6).
.
Ph
O S
O
Ph
H2 N
O S
O
HN
R
N
AcOH,
H3 C
65-95%
HCl / EtOH H3 C
2(3) 2(4)
NH
95%
CH3
CH3
1(1-11)
2(11)
R
N
Ph
O S
O
2(1-11)
H3 C
Ph
O S
O
N
CH3
N CH3
1) SOCl2
H2O2
2) NH(CH3)2
AcOH,
60%
87%
N
4
Ph
O S
O
H3 C
H3 C
O
N
CH3
S
N
5
1, 2: R = H (1), CH3 (2), OCH2CH2OH (3), SCH3 (4), SC2H5 (5), NHCH3 (6),NHCH2CH2N(CH3)2 (7),
NHCH2CH2CH2N(CH3)2 (8), N(CH3)2 (9), CH3NCH2CH2N(CH3)2 (10), 1-Boc-piperazin-4-yl (11)
CH3
219
616- 006.446.- 091.818: 577.115

.., .., .., ..
.. ,
.
.. ( . .. ), . ,
e-mail: alenmark25@gmail.com

. -
,
, .
-

. ,
.

( 562) .

, : racN-{4-[(2--3-)-1-]}-N,
rac-N-{4-[(2--3-)-1]}-N--4-, rac-N-{4-[(2-3-)-1-]}-N,
rac-N-{4-[(2--3-)-1]}
rac-N-{4-[(2--3)-1-]}-N'-.
(IC50 , -)
562 43 , 38 , 50 , 17 18 .

- G1
. 562
.
I,
.
XIII -
-2010
220
547.792.6

1,2,4--3-
.., .., ..

. .. (), ., e-mail: motyamail@mail.ru
, ()
.

.
1,2,4--3-.

[1].
1,2,4--3 5--1,2,4--3-
, , [2],
. 5--1,2,4--3
5- 1,2,4--3- .
O
O
+
1. NaNO2, H
H2N
OH
N
H
R = NO2; Cl; Br.
2. CuX
OH
N
H
5--1,2,4--3-
[2], 1,2,4--3-

1,2,4--3- ,
[2,3].
O
1. NaNO2, HCl
H2N
OH
N
H
SOCl2
2. MeOH
OH
N
H
Cl
N
H
13 , -.
[1] J.Witkowski et al. // US Patent 3798209, 1974.

[2] .. , .. , 1,2,4-3-, . . , . ., 1965, 624.
[3] . , .. , .. ,
1,2,4-,
, .1, 1967, 180.
221
615.012.1:661.715.5

5-
.., .., .., ..
" ",
. , e-mail: rybinagv@ystu.ru

.
,

.
,
,
: , , , ,
J, , , , .
,
,
SH- NH2-
. ,
-
.

1,2-,
.
O
O
(II)
O
(I)
(III)
5-
,
.
,
110-120
N-
93-95 % .
2--,
.
1,2- MgBr2
90 %. 2--
99 %, .
XIII -
-2010
222
541.49:54-145.4
-

.., ..
- ,
. , e-mail: oxt705@isuct.ru
2-(3,4-)
,
.
, , .
. ,
,
. ,
,

.

Cu(II) - EtOH
00,8 . . pKH
9,050,15, 10,380,10,
11,730,05, .
pH ,
, : -,
-.
EtOH pK1 pK3 0,5
. . pK=f(XEtOH)
0,1 . EtOH. pK
NH3+ -OH
-
.
, Cu(II)
[MxHyDopz], (xyz=101;102;111;112;122), (
DopHCl).
: lg101=15,570,05; lg102=22,20,1;
lg111=22,90,2; lg112=32,80,2; lg122=43,20,2.
[CuxHyDopz] 1-2 lgxyz.
, ,
, L-
. , -,
, .
223
547.298.1 - 547.554
.
-
..*, ..*, ..**, ..*,
..*, .., ..**
*
.
.. (), , 119571, , - .86,
e-mail: NB714485@yandex.ru
**
- ,
, , 121552, , 3- ., .15-

. ,
, - ,
,
.

.

, -
:
R1
X = O, NR 3
n = 1,2
NR 2 = NMe 2, NEt 2, N
RO
R2
R 3 = H, PhCO
nNR2
,N
O, N
R1 = R 2 = H ; R1 =Ph, R 2 = H
R1 + R 2 =
R4 = H, PhCO, PhCH2 CO, PhOCH 2CO, 2,4-C 6 H3 Cl2 OCH 2 CO

.

.

,
.

, ,
.

.
XIII -
-2010
224
547.246

.., .., .., ..,
.., .., ..

. .. (), , e-mail: ya5galina@gmail.com
, , (, , ),
, . , 1-
(LD50 = 0,33 /),
1- 100 .[1]
Si,
Ge.

().

.
, 500-600 oC
GeCl4
:GeCl2. :GeCl2 :SiCl2 CCl PhGeCl3 PhSiCl3 [2,3].

, ,
.

30%
, -, , 1,2() 1--2-.

.
[1] .. , .. , .. .XIV. 1-. // . .1968. N 2. . 227-229.

[2] .. , .. , .. // . . 1994, .
336, N 1. . 69-70.
[3] .. , .. , .. , ..
. // ,
2008. . 3, N 1, .19-26.
225
[546.56121:547.466]:54.057

(II)
.., .., ..
" ",
. , e-mail: general_chemistry@astu.org
- -
, ,
(II).

. H2NCHRCOOH: (R = H),
(R = CH3), [R = (CH3)2CH], (R = HOCH2), (R =
H2NOCCH2), [R = H2N(CH2)4], --- [H2N
CH(C6H5)CH2COOH] (10 ) (5 ) 10
(, , )

. ,
, ( --) - .
.
( 50 0)
, , 3
105
0 . 2382 %.
3992 %

2030 .
98 % 20 3 %-
(8,8 ), 7 .

(, , N, ) , , - .
226
XIII -
-2010
547.963.4:547.964:577.156

..1, ..1, ..1,

..1, ..2
1
.
.. , . , e-mail: laboratory211@yandex.ru
2
, . , . , 86

().

,
,
.
.

3- 13- RGD [5Ala].
RGD,
,
.
,
RGD, [5Ala]-
S.
RGD
, , RGD
.

RGD
BSA. , ,
,
.
S
RGD.
,
RGD.

.
227
457.95:547.426.2

,

.., ..
.
.. (), ., e-mail: nplyavnik@mail.ru

,
,
.
,
(), , ,
.

:
.

- , .
rac-1--3-(), 74%
rac-1- 1,1. -
2,5 . .
(9Z,12Z) (2)
()
N,N- .
11Z,14Z- (2)
1,05.
1,5-
.
0,2 --
, 11Z,14Z 9Z,12Z- , 29% 69%,
.
1-- -.
10-03-00995-.
XIII -
-2010
228
547.466.63+547.268.1+577.1
RGD

.., ..

.. (), . , e-mail: C-221@yandex.ru

,
- .
,
,

.

.
,
RGD-.
,
RGD- ,

O
COOH
NH2CNH(CH2)3CHCNHCH2CNHCHCH2CNH(CH2)3NHCCH2(OCH2CH2)73OCH2CNHC18H37
NH
NH2

(3400), ,
.

( 08-04-01150)
2,1,1/2889
229
[639.371.2.041: 579.252.55]: 661.185

.., .., ..
, . ,
e-mail: general_chemistry@astu.org

,
, , ,
(),

,

.

.

( , , . ).

" " "",
() ""
"-", "" " ".
()
: ,
"Sarma", .
, " "
"" ,
.
""
"Sarma"

.

""

.
XIII -
-2010
230
615.014

.., .., .., .., ..

..
( . .. ), . , e-mail: ltazina@yandex.ru

4043 C. ,

.

.
1,2-sn--3- (DPPC), 1,2--sn--3-
(DSPC), 1,2--sn--3-
(DSPE-PEG-2000) .
50 C -.
.

.

4 % .

. -

,
.
,
()
, .

18 C. ,

.
231
004.822

..
.
.. (), ., e-mail: ugolek84@gmail.com
.
,

, 600 . .

.

.
.

2358 , .
,
PubMed.

Gvedit.
,

.
,
,
,
,
.
,
,

.
,
,
.
XIII -
-2010
232
547.486.5
.., ..
(),
., e-mail: frolovaee@ystu.ru

. ,
,

. - . -
. 4 (1) ,
80 %.
O
CH3
O2, AcOH, 95oC

,
OH
1-
R=
2-
,
1-2
COOH
1-2
1-2
COOH
1-2
,
1-2
4-(4) (1), 4-(4-)- (1), 4(4-)-4-
(1),
2-(4) (1)
.
70-90%.
-
. 1
.
233
544.773.32+665.584.22
-

.., .., ..
- . ..
125047, , , , 9. ( ),
e-mail: n.chudinova@gmail.com
,
,
.

,
.
,
, , ,
-.

,
-
. ,
,
(-
-).
. ,
,
90%, - .

.
-, -=21.16 /.
,
.

-
,
.
( 1.),
, ,
1.2610-7,
3.1010-8.
XIII -
-2010
234
, .
5:1

- ( 2.). 1.429
/3
( = -4.73), ,
,
.

,
.
1.
.

-
g,
s0 ,
,
2
H2/ /2
0,154
0,02
7,010-5
4
3,1
10
-
s0 ,
,
,
2
/2
4,410-6
0,38
7,210-4
0,023 3,2
10-8
11
0-9
/3
4,2
-8
0,625
2,810-4
0,00
6
1,3
10
1,1
-7
__
__
__
__
1,810-6
0,6
21
0-9
0,12
2.

-.
, /
17
15
9.5
7.5
C10 , /
0.537
0.963
3.270
5.778
C20 , /
0.279
0.353
0.921
2.127
C12 , /
0.294
0.397
0.921
1.429
X1
0.6165
0.565
0.53
0.546
-2.04
-2.63
-3.69
-4.73
235
547.728.2+547.239.2+547.854.83

-2-()
.., .., ..
(), . ,
e-mail: chirkovazhv@ystu.ru

-2-(), ,
-2-(),
.
.
-2-(),
, 4 5
,
. -
50-75%. , ,
( 16- ),
. ,

.
R
R
+
CH3
N
O
N
1 (a - c)
CH3
H2 N
X
NH2
NH
O
R1
3 (a, b)
N
H
4 (a - c)
R1
1,3 R=Me, OMe, R1 =H, OMe, X=O,S; 4: a- R=Me, R1=H, X=O; b- R=Me, R1=H, X=S; cR=OMe, R1=OMe, X=S; d- R=Me, R1 =OMe X= O
,
-. 1 ,
,
,
4J NH1-NH3.
XIII -
-2010
236
547.785.51
2-[2-(1-R-1--[d]-2)]
.., ..
. .. ,
300026, . , . 125, e-mail: reaktiv@tspu.tula.ru
,
.
2-[2-(1-R-1--[d]-2)] ,
.
-
2-[2-(1-R-1--[d]-2)] :
R
R
NH2
NH
+
NH2
HO
H2N
SO2R1
2
R
R
HN
N
NH
HN
5
COR1
NH
H2N
NH
HN
CONHR1
R = , CH3, OCH3, Cl; R1 = alkyl, aryl, hetaryl.
1 3-(2-) 2 (
) 4-5 ( 7080%). ,
,
, 4, 5 6.
, 3
500 , .
leadlike,
.
237
547.785.51
2-(1-[d]-2-)

.., .., ..
. ..,
, ,
, ,
. ,
2(1-[d]-2-), .
R1
NH2 O
C
+
NH2 H
O2N
R1
NO2
R1
NH
4
2
3
R1
NH2
H2/Pd/C
O2N
R1
R2COOH
NH
HN
NH
5
C O
H2N
R2
R1 = , CH3; R2 = alkyl, aryl, hetaryl.
- 1 (0.1 )
-2 (70 ) 0-2
- 2.
1 0-2 1 20-25 .
3 50-60
210
.
( 60-70%).

60-70 10-15 % : -2 ( 85-90%).
5
1,1 ().
1-.
XIII -
-2010
238
547.057-7/.8
.., .., ..
, . .2,
.1, ., ., 141401, ,
e-mail: yamanushkin@gmail.com
[1]

1, 2, 4, 5 6.

- 1a,b
3a,b BBr3. 5- 4a,b
3- ,
4-(-3-)- (6-(-3-)-1--3-)
5,b. 5- 6
2--
8. 4 9,
-2,4()- 10.
[1] A.V. Ivachtchenko, P.M. Yamanushkin, O.D. Mitkin, Mend. Comm, 2010,
.
239
573.6086.83: 579.66115; 577.16; 547.94

.., .., .., ..
,
., e-mail:irinamaster@gmail.com
()
, , ,
, - .
:
.
,
: , , ,
, , ,
, , , .

(Buchi Extractor ),
, .
- ,
, , .
( %
).
, .
( )
6 ; 20%- 4 ; 40%- - 6
. 8,4%,
2,3%.

:-
,
, (
)
; -
(,
); - ,
":.
,
: ,
.
XIII -
-2010
240
637.146.33:

..
-
(), . -,e-mail: feodocia@rambler.ru

Propionibaterium shermanii
.
:
1) ;
2)
;
3)

Propionibaterium shermanii;
4) -

;
5) ;
6) :
-
Propionibaterium shermanii;
-
Propionibaterium
shermanii;
:
-
2:1;
- 300 120 .
,
;
-

1,73% 0,95%, ;
-
, ,
.

, .
241
61: 577.1

HLA I

.., .., .., ..,
.., ..
. .. (),
., e-mail: ngolubcova@mail.ru
. .. (),
.

HLA I
.
55 ,
( 6 27 )
1 .
.
HLA I

,
.
(U/ml). 32 ,

HLA I 1012 36 U/ml,
800 1200 U/ml.
.

20%.
, 3 : 1
, 2 3
.
1 (10 )
70 250%. 2 (13 )

HLA I , 3 (32
), 5
, .

HLA I
.
XIII -
-2010
242
658.562
GMP
.., .., ..

. .. , . , e-mail: innagrabovskaya_@mail.ru

GMP
.
.

.

, ,

. .
,
(FMEA) ,
,

. 37
9 ,
.

,

5% .

pk.
- MR-.

,
, .
,

.

,
GMP.
243
: 547.427

2,3--3-

.., .., ..

. . . (), ., e-mail: mila1387@mail.ru
, (2`,3`-3`- (d4T), 3`--3`- (AZT)
) .

.
: ,
, , ,
-
.

-.

(,
),
,

,
-- .

d4T 1 2

,
.
O

O
OR
C15H31
O
1 ,
O
OR
O

C15H31
O
O

1
O
(pH 7.3),
O
(pH 9.5). ,
C15H31
O

O
OR
C15H31
O
OR
1
O
,
2
6.0 .
R = succd4T
XIII -
-2010
244
547.057
,

.., ..
- ,
. , ,
. , e-mail: myk@chemdiv.com
1 - ,
[1, 2].
N
O
N
H
CF3
O
N
R1
N
H
R2
N
H
R1
+
OH
R2
CF3

, , 1 70 16-20
- ) HCl, b) 10% , -
(>50%) 2
3, .
O
O
N
H
a
O
H
N
O
H
N
R2
CF3
O
N
R1
1
R2
N
H
b
N
CF3
O
NH2
2
R1
N
H
R2
N
H
N
R1
3
,
1
, 2.
, , -
, 1,4-
2.
[1] Krasavin et al. Synthesis.- 2010.- .- DOI: 10.1055/s-0029-1219274.

25.01.2010
[2] .. . . . . . 2009. 52.
. 10. . 11-15.
245
547.057
-2,5-

.., ..
- ,
. , ,
. , e-mail: myk@chemdiv.com

Boc-
-.
(~1:1) 1, ,
[1, 2].
.
-2,5- 2
(40-55%) (!) .
R1
R2
R3NH2
R4NC
R1
OH
N
R2
HN
N
R3
R4
O
R1
2) AcOH, MW
R2
N
N
O
1) TFA
R4
R4
R1
R2
R4
R4
2a
2b

2 (,
2a 2b 1
). ,
2,
, :
3.
R1
R2
N
N
O
2a
OH
O
R4
R1
R4
R2
N
N
O
R4
R1
R4
R2
N
N
R4
R4
O
2b

NOESY
,
2.
[1] Krasavin et al. SYNLETT 2009, 260-262.

[2] Krasavin et al. Tetrahedron Lett. 2009, 50, 5529-5531.
XIII -
-2010
246
606:61

,

.., ..
-
, . -, e-mail: lamazhap@mail.ru

.

.
,
.
,
.
,
, .

,
.

,
,
(),
.

- , .
,
,
,

. -,

,
.
,

, -,
, , ,
.
247
541.147; 616-006

:
..
..
( ), ., e-mail: avlobanov@mail.ru

.. (), .
() (,
Al, Zn) (0.1-2 )
,
(670-700 )

, ,
.
.
,
.

, ,
,
(, , )
- ,
.
.
, ,
.

12, 22.
, . -
- -, , 3
, .

.
-15
, -1468.2008.3.
XIII -
-2010
248
: 541.244; 574. 963. 4; 541.49; 542.422

5-(-)-10,15,20-
..1, ..1, ..2, ..2,
..2, ..1
1
.
.. , . 86.
2
. .. , . ,
e-mail: olshevsk@ineos.ac.ru

, 5-(-)-10,15,20- (1),
,
,
.
1 R=H
3 R=
N
O
S
COOH
7 R=
N
H
O
5 R=
HN
O
N
H
CH2
COOH
NH R 4 R=
N
6 R=
O
NH
COOH
COOH
2 R=
1
3
(2, 3) . DCC 2 3 3-- (4, 5)
.
3, , 1,3
1---
9---
(6) (7)
.
6 7
.
- : , -,
1
11 , -.

, 2,1.1/2889 08-03-99084 _
249
658.5.012.7

.., .., .., ..
.
.. (),
. .. ..
( ), ., e-mail: RNatalia07@mail.ru

-
.
,

.
:
1.
:
, , , .
2.

.
.
3.

.

.
, 15,5 %,
(1-10 ).
.
,

.
.
3,5 5 .
4.

.
2,2 %,
4,5 %,
.
XIII -
-2010
250
547.426.2.057

..1, ..2, ..3, ..2
1
University of Nebraska Medical Center (UNMC),

Omaha (USA), e-mail: romfill@mail.ru
2
(),
3
- . ..

.
,
, .

.
,
() , ,
,
. , ,
3 ,

,
N,N-
562/4.
rac-1-2-(/)-3-(5-)
N,N-
.
rac-N-{3-[(2--3)-]}-N,N--N-(2-)
2
( ) -
562 562/4 ,
Pgp.
(IR) IC50
562/4 IC50 562.
,
(IC50 3.6-4.2 , IR 5.0-5.5)
(IC50 2.3 , IR 13.5).
251
547.979.731
-
A 60
.., .., ..

.. (), ., e-mail: r_urs@yahoo.com
, ,
,
.

- ,
,
.
,
.
- ,
. -

.
-
C60 13,15-N-
p6,
. p6 C60
.
N-
3-
. 3- N-
C60 , C60
. 61%.
1H ,
- .

, ,

.
XIII -
-2010
252

2--5--1,3--4(5)-
.1., .1, . 2
1
-
( ). - ., 26, 19801. 2
, , , SE-106 91,
e-mail: a_smirnova80@mail.ru
5-2--4--1,5--4--4- 5-2--4--1,5--4--4- ( ,
),
2--5--1,3--4(5)-.
()
0,125 mM 0,125 nM. ,
(Human
Monoamone Oxidase -A -).

2--5--1,3--4(5)-. (. .
, . . ., , No. 1, 111114 (2008), 2-5--1,3--4(5)- (1)
2- (2a) 2- (2b)
, N[(-4-)]-2--4--3- (3)
N-[-(-4-)]-2--4--3 (3b),
: 5--2--4--1,5--4-4-
(4a)
5--2--4--1,5--4-4- (4b), ,
. ,
(4a) (4b)

(3a) (3b), . ,
, (4)

.

, 2--5--1,3--4(5)- Br, NO2, N(CH3)2, F ,
5-2--4--1,5--4--4-.
253
: 615.322/616-006

..1, ..2
1
, . ,
, . , e-mail: tepkeeva-inna@yandex.ru

(Hypericum perforatum L.),
(Chelidonium majus), (Equisetum arvense L.),
(Inula helenium L.), (Inonotus obliquus),
(, , ) .
,

, , , , .
.
100 0 ,
. - (5:2)
,
.

in vivo in vitro.
,

-
ASF-LL.

: , ,
,
A549, H1299 HeLa.
1299.

.
, , ,
,
.

, 6

. ,

.
XIII -
-2010
256
66.084.2:549.51

..1, ..2, .3
1
()

3
,
., e-mail: abramovma.yar@mail.ru

.
, .
.

.

.
, .

,
.
- 94. (, /)
17,1 102,6 /.
( =102,6 /)
63 2%,
. .
,
-
.

,
63 .
,
10 .

.

: ,
, .
257
620.2

.., .., ..
, . , , e-mail: info@technologiya.ru

, ,
, ..

.

: , , .

,
.
, 5-10 ,

, , ,
.
, ,
4-7 ,
,
,
.

- .
, ,
.

,
.
.

.

.
-
.
XIII -
-2010
258
548.5; 543.2
.., .., ..
. .. , .
e-mail: LudaB2005@mail.ru
[10(4)6()2] ,
,
(, ,
, .),
.
,

, , .

,
(
) ,
.

, , ,

, ,
(
).
.

( - ,
,
.); -

.

( , ,
.) .

,
.
259
666.293.522.53
-

.., ..
, .
e-mail: olchik4@yandex.ru

. ,
, Si3N4-ZrO2
; Si3N4-TiN

.

, .
,
.
().

, .
-
Si3N4
, .

:
3 Si +2 N2 Si3N4 + Q
(1)
(750 /)

, .

, ,
.
( ,
, )
.
Si3N4 ZrO2 Si2N2O Fe, Si3N4 TiN Si2N2O Fe.

0,5 .
%.
,
.
( 09-0300604-)
XIII -
-2010
260
546.9+546.73; 548.7
,

.., .., ..

. .. ( . ..), . ,
e-mail: volchkovaev@bk.ru
()

.
: 1) ,
,
, ; 2)

; 3)
-.
.

, Co(III)
Pt(II) Pt(IV).
: [(N3)5l][t4], Cl-, Br-,
[(N3)5NO2][t(NO2)4] [1].
( 2)
[Co(NH3)6]Cl3 K2[PtCln] ( n=4 6), Co:Pt = 1: 11,5. 30
, 3 HCl
H2O. [Co(NH3)6]2[PtCl4]3 [Co(NH3)6]2[PtCl6]3*H2O
,
, . ,
[Co(NH3)6]2[PtCl4]3 ,
1, : a=7.710(2) , b=7.776(2) ,
c=12.599(3) , =89.13(3), =83.51(3), =88.51(3), V=750.2(3), Z=2.
[Co(NH3)6]3+
[PtCl4]2-. H2
Co:Pt=2:3.
, ,
.
[1] .. -
:
. .../ ..
, 2009. 27 . .: . 2527.
261
546.56

.., .., .., ..
(), .,
e-mail: ger7709@yandex.ru

, d
(, Ni, Fe, Co).
, , ,
- ,
,
,
, ,
,
.

d- : (
), ( ),
( ), (
), EXAFS-. ,
, ,
,
d .

-4
(u -K ).
PCPDFWIN, v. 2.02, 1999,
(JCPDS). EXAFS VEPP3 (, )
:
1. d-
.
2. SE, d-
.
3. EXAFS , d-
, Ti.
d-.

-
( 2.1.2./1587).
262
XIII -
-2010
667.629.825:032.667:661.882

.., ..
.
.. (), . ,
e-mail:gerasimova@chemy.kolasc.net.ru

,
,
. (
CaSiTiO5, - 38%),
- ,

,

( )
.
,
.
:
-
-
,
, .
, ,
, ,
, .

(NH4)2TiO(SO4)2.H2O.
.

(TiOSO4.H2O)

-
,
, .
.
,
- ,
.
263
66.049.6; 661.682
SiO2
.., ..
() ,
., e-mail: larisa-demyanova@ascnet.ru
,
, :
, ,

. ,
, ,

- .

.

.
, ,
95.8 %, .

(NH4F2) ... (.),
.

- ,
, ().
, ,

: 98 2/; ,
20 ; 3 ;
110-4 % .
.

: , , ( ) .

, , ,
, ,
,
, , .
1 10 ./,
4000 ./,
5000 ./ 200 . ./,
.
XIII -
-2010
264
541.11:547.9

.., .., ..
, . ,
e-mail: efimovaos@mail.ru

() ()
(
120) . ,
,
.

( , , ),
, , .% ( 61,9, 5,4, 31,5,
1,2).
- -2
-
10 30 .%.
(): - 200 , 10
; 30 ; , , - 100 /;
- 60 g.
10 30.
( )
(10 30). (10,
10 ..) 900
.
S,
S,
,
2
/
2/

5
10
10
(S)
(.).
16

5
30
30
10
.%,
42

9

262
183
S, 30
10
138
10
421
.%, .
30
195
30
281
,
S
,
,

.
.
265
538.9:620.3:548.55:538.911

:
..
. .. , .
e-mail: rusl-mix@mail.ru

(KI, AgI, AgBr, CuI, CuBr,
SnF2), ().

1-1.2 , .
: , , , .

:

( );
-
;

,
;

(
SimulaTEM);
.

.
1D
, ;
;
.
1D
.
[0001] 1D
AgI, AgBr, CuI, CuBr (.. P63mc .), [001] KI (.. Fm3m)
[283] -SnF2 (.. C2/c).
, 08-02-00774-.
XIII -
-2010
266
544.46:544.227:666.9

..
- (),
., e-mail: nfkosenko@gmail.com
,
,
NaCl, .

, .

,
-
-
.

,
.

""
.

,
.
.
, MgO, CaO, CdO,
, ,
..
,
.
. ,
,
, .
.

. ,
,
-
,
,
.
267
546.98 + 66.081
Pd(II)

..*, ..*, ..*, ..*, ..**
*

. .. (), . , e-mail: len-krylova@yandex.ru
**
.. (), .

CO - ,
Pd(II) Cu(II),

/.

().
Pd(II) 0.1 HCl
( 120),
(SiO2 NH2): 1.63 / (1) 0.5 / (2).
Pd(II) 0.1 HCl ,
, > 0.015 /
, ,
, Pd(II) .
() ,
CPd dd
440 , ,
Pd(II) [1]. ,
237, 272 430
, , 0.1 HCl [PdCl4]2 [Pd(2)Cl3]- ,
: (SiO2NH3)2[PdCl4] (SiO2NH3)[Pd(H2O)Cl3].
Pd : ,
.
CPd = 0.01 / (1) 0.005 / (2).
,
:
2(SiO2NH2)HCl + [PdCl4]2- = (SiO2NH3)2[PdCl4] + 2Cl(SiO2NH2)HCl + [Pd(H2O)Cl3]- = (SiO2NH3)[Pd(H2O)Cl3] + Cl-.
1553 -1
(NH2) , Pd(II) ,
.
[1] .., ..
. , , ,
// . 1999. . 25, 3. . 165 176.
XIII -
-2010
268
546.59: 542.2

.., .., .., .., ..
-
, . , e-mail: ket712@isuct.ru

( ).

, ,
.
, ,
,
. ,

. ,
,
,
.
1.

.
2.
.
, ,
,
90.
3.

.
4.
.
5.
.
6.
:
.
7.
.

.

, ,
, , .
269
66.099.2:631.812.12

.., ..
- (),
. , e-mail: piaxt@isuct.ru

, ,
,
, ,
, . ,
,
.

.
,
, ;
, .
.
(0,8-1,1):1.

.

.
,
.

20

.

10 .
2,4
3,1 .
,
1,5 2,0 .
2-3 800 1600-2500 .
,
,
XIII -
-2010
270
546.05

(Pb-Ge)-Ag
.., ..
C (), .,
e-mail: tat-osipovich@yandex.ru

.
,
.

.
Pb-Ge
60 70 .% (
) ,
PbGeO3.
,
Pb-Ge .
(Pb-Ge)-Ag
Ag 20, 40 60 .% 1273
. (Pb-Ge)
: (60Pb-40Ge), (70Pb-30Ge), (80Pb-20Ge), (85Pb-15Ge).
(Pb-Ge)-Ag ,
,
, ..
.
,
(Pb-Ge)-20Ag (Pb-Ge)-60Ag ,
. (80Pb-20Ge)-20Ag,
(85Pb-15Ge)-20Ag, (60Pb-40Ge)-40Ag, (70Pb-30Ge)-40Ag, (80Pb-20Ge)-40Ag
Pb3GeO5,
Pb5GeO7, Pb6GeO8, Pb19Ge13O45.
Pb3GeO5 Pb4GeO6
, (PbGe)-40Ag .
(Pb-Ge)-Ag
,
,
, .
,
(Pb-Ge)-Ag .
271
533.15:546.291

..1, ..2, ..1,2
1
, .
2
, .
e-mail: pankovamv@mail.ru

-
,
.

.

.

,
, ,
-
.

,
.

,
, .
,
,

-
.

.

, () ,
-
.
ARL ZEISS.
272
XIII -
-2010
661.872
-
(II)
.., ..

( ), .
e-mail: nestor_@mail.ru

(<1)
( -8)
(. ).
- ()

, : 1-15 / (II) 2-50 / ,
0,25 2
.

. ,

(1,78 - 2,61 /)
, (II)
.
,
,
90 %, .
(~ 15 /) (II) (~ 1 /)
,
(II) 10 - 25 %
(0,25 1 ).

.
273
541.124

..
- (),
., e-mail: pv@isuct.ru
, ,
..
50
85 .% (). (
)
.

.
( ),
, .
,
. ,
, : 1) , ,
(
); 2) ,

().
,
.
: , , ,
, .

. , ,
,
, ,
.

- .
[1].
[1] .., .. -
. : , 2004. 316 .
XIII -
-2010
274
546.7
-

.., .., ..

. .. (), .

.

,
,
.
,

.
, ,
.
.

, .

.
, Re4O4(OEt)12, Re4O2(OBun)88BunOH, Re4O6(OiPr)10,
Re4O6(OMe)12 .[1].

, - ,
d-
ROH (R = Me, Et, i-Pr ..),
( ,
), in situ ()
.
1012.
, ,
Re0 ReVI.

.
[1] .. , .. , .. .
n- i- // , 2009, . 4, 5, .
97-102.
275
549.752/.753
Li2OZnONb2O5
.. , .. , ..

. .. (), . , e-mail: valeryfom@rambler.ru

.

- .
Li2OZnONb2O5.
ZnNb2O6LiNb3O8 : LiZnNb4O11.5
LiZnNb6O16.5, ~2.%.
ZnNb2O6 LiNb3O8.
(),
-
.
.
() LiZnNb4O11.5 :
(3D) ((3+1)D) .
,
.

P 21/b. ,
-PbO2 q=0.3a*+1.1b*.
LiZnNb4O11.5
()
,
.
- - .
.
LiZnNb6O16.5,
LiZnNb4O11.5,
.
().
LiZnNb4O11.5,
:
-
-PbO2 q=2/7a*6/7b*.
-
() LiZnNb4O11.5 LiZnNb6O16.5,
, 251100
.
XIII -
-2010
276
546.61:546.881.5

.. , .. , .. , .. .

. . . (), 117571, . , 86,
e-mail: tender-mitht@mail.ru
,
.

, .
,
, , ,
.
,
.
,
.
.

: N-(2--5)--
(-0)
N-(2--5)-- (-2).
(V) -0
-2 . (V)
pH 3-5. ,
: (V)
-0 -2 1:1,
2,5:1, .
(V).
(V) ,

VO3 H2V10O284.
- . , 0,1 -0
-2 25% . 22,74 / V2O5.
-0 -2
. ,
-0 -2 98%.
, H2V10O284
,
VO3.
,
.
277
547.26.118

..
-
(), . , e-mail: vyakshin@bk.ru
()
-
()
.

:
O
O
O
O
+ H2O
O
O
O
+ H2O
II
O
O
O
n
H2O + MA
+ HA
O
A + H3O X
O
O
O
O
O
O
O
O
+ HA
O
H
O
O
O
H
H2O + MA
p
O
H
O
O
H
O
MAp+1
, , n .
,

,
. ,
, . , ,
.

(I) (II) .

Sr(II), Cs(I), Pb(II), Tl(I), Hg(II), Ag(I), Pu(IV), Np(IV) HNO3 U(VI), Pt(IV),
Ir(IV), Pd(IV), Au(III), Ga(III), Sb(III), Fe(II), Fe(III) HCl.
(D=101000)
XIII -
-2010
278
541.128-022.532

.., .., .., .., ..

. .. , , e-mail YASHTULOVNA@rambler.ru

.

, ,
.
-
, .
Si (100) (111)
p- n-
200 2/
10 80 %. 5 60 .
-
.

().
Pd 1
. n- p-
40% 78%
, 2.
,
,
. ,
,
n- p-
.
09-08-00547.
[1] .. ., .. , .. .,.. , . .
-, 2010, 55, 210. [Russ. J. Inorg. Chem., 2010, 55, 180 (Engl. Transl.)].
[2] .. , .. , .. , .. .
, 2008, 124, 8. [Chip News, 2008, 1, 8 (Engl. Transl.)]
279
691.175.2

.., .., ..

.,e-mail: abramovma.yar@mail.ru

.
,
.

.

, .

,
.
- 94.

. ,
,

.

.
3:1

. ,
.

.
,
.

, , , ..
.
XIII -
-2010
280
: 621.382:621.315.592:658.5

..*, .., ..*, .., ..,
..*, .., ..
*
;
. .. , . , e-mail: chegevara-88@mail.ru

.
- ,
, ,
,
.

, , , ,
.
,
( ) ( )
~ 1200. ,
-SiO2 ,

(90-100 ) -SiO1,5:Cn ( n=1,0-4,5),
-SiO2
.
[a-SiO2/a-SiO1,5:C2]
(Cd1-Zn)Te1-
100 ( 1.), ( 2.)
( 3.) :
1.
2.
3.
,
.
281
537.533:543.42

-
..
. .. (),
, . , e-mail: n_alov@mail.ru

-
.
- .

.

.
-
, ,
().
-
,

in situ (210-7 )
LHS-10 Leybold ().

(99,9 %), - .
1015-1018 -2,
1 5 .
, -
.
, (MoO2,
WO2), (MoOx, WOx, 2<x<3) (MoO3,
WO3).
. -
.
, (NbO, TaO),
(NbO2, TaO2) (Nb2O5, Ta2O5) .

,
, Nb2O5 Ta2O5.
XIII -
-2010
282
548

,

.., ..
(), .
, e-mail: ak.cspu@gmail.ru

.
0001 1120.
, ,
.

+
Cu CuCl .
.
,
: Cu+ , Cu0 Cu2+, Cu+
(3d10p6s2) .
Cu e Cu 0 , u e Cu 2 .
, Cu+ ,
.
Cu0 000h
(-0) ,

. 11 2 h
u e Cu 2 (Si-0)+.
( d 10 - d9 s),
( d 10 - d9 ).

Cu O Si ,

.
d 10- d 9 s d10 - d 9 ,

.

Cu O Si .
, 0 0 0 h
1 1 2 h ,
.
283
004.9: 544.55: 661.11

CALS-

.., .., .., ..
, . , e-mail: bessarabov@irea.org.ru

.
,

.
.
CALS-
(Continuous Acquisition and Life cycle Support
).

,

, ( )
.
(CALS-) ,
,
(, , .).
,
:
;
(Z). ,
(10 )
Z = 1.
Z = 12. (d0 = 10 )
(10 )
Z = 50. CALS-
(Z) .
(d0= 10 ). (Z)
20 50.
60 10 .
CALS-

: ,
( -4).
,
.
XIII -
-2010
284
544.773.422:546.776
3,
.., .., .., ..

- . .. (
. .. ), . , e-mail: gavrilovann@yahoo.com

. 3
- ,
().

,
.

3. 3
,

. ,
3
.
, ..
50-100 , ,
.

- . ,
3
.

.
.
1,5
1% .

-
2009-2013 . (.. 1001).
285
547.1128 543.42

VD
.., .., .., .., ..
, . , e-mail: eos2004@inbox.ru

VD
, .

VD. () (I)
() (II), -
.
(N) (III), (N-) (IV). ,

, . 1 29Si
III 2.71:1
, :
III
IV 29Si
.
1:2:3:4
1:2.34:2.55:1.95 :
1
IV

. ,
III IV ,
. 200 0 2-
: III
;
, III, IV.
,
.
XIII -
-2010
286
66.097.3:661.961.6

.., ..
-, .,
e-mail: avdulnev@yandex.ru

- ( )
, ,
-
.
()
.
.

( ).

w2 (
, w ),
, ,

, . ,
.
,

.
- 2009

(-03-01) 30 3, 2009
-76
.
, ( 7
) ,
/ -03-01
(0,13 ,
0,26 ),
. , -03-01
.
125
100 .
287
66.097.3

.., .., ..
-, .,
e-mail: avdulnev@yandex.ru

(2, 2, )
( ),
.

35-60 %.
,
.

. , ,
,
, .
,
.
,
-Al2O3 ,
.
400 .

.
,

(~ 80-100 ),
.

3,0 -

. , ,
0,001 % 4000 -1
0,6-0,7 %
(35 %) 151 159 .
,
20 %. ,

.
XIII -
-2010
288
544.46

., . ., . .
- (),
., e-mail: Ilyin@isuct.ru
ZnO
. ,
,

.
ZnO
. ,
()

ZnO (.1). -
90 58%.
120
.
, , 63%, 45
. ,
,
(. 2).
Zn

8
6
5
4
3
2
1
30
35
40
45
50
2, .
55
60
Zn, %
90
80
70
60
50
40
30
20
10
0
0
20
40
60
80
100
120
, .
1 0 .; 2 5 ; 3 15 ; 4 : 1-
30 ; 5 45 ; 6 60 ; 7 90 .; ; 2 ;
8 120 .
3
. 1
. 2
,
.
289
54.055

C
.., . ., . .
- (),
., e-mail: Ilyin@isuct.ru

.
.
: ,
CunZnm -
- .

Al2O3, CuAlO2 CuAl2O4,
(.1).
,
-
CuO, CuO2, Cu4O3 ( . 1).
, .

. ,

.

(. 2).

-
Cu2O Cu
Al2u
CuO
Cu4O3
Cu
ZnO Cu5Zn8
Cu4O3
Cu2O CuO ZnO Zn
Fe2O3
Al2O3
CuAl2O4
CuAl2O4
2
1
1
20
30
35
40
45
50
2, .
55
1 15 . ; 2 45 . ; 3 90 ., 4 180
.
. 1
30
40
50
60
2, .
1 - 45 . ; 2 60 . ; 3 120 .
. 2
,

.
.
XIII -
-2010
290
66.097.3:661.183.6

.., .., ..
- (),
., e-mail: gordina@isuct.ru

() ,
. ,
, 100
,
,
, .
, ()
, (
), .

, ,
, -
, , .
,
NaA,
-
:
Na2OAl2O32SiO2nH2O.
,
,
,
. , ,
, . ,
: Na2SiO39H2O, Al2O3, Al2O32SiO2
2H2O () 10% NaA
, ,
Na6Al6SiO10O32, H1/2Al11O17. ,
,

.
, ,
, .
,
, ..
,
.
291
66.097.3: 661.183.6: 628.31

.., .., ..
- (),
., e-mail: gordina@isuct.ru

, ,
, .
,

.
,
, .
,
.
(3-10 ) .

,
.

(),
, .
,
Na2SiO39H2O, Al2O3, Al2O32SiO2 2H2O 10%
NaA ,
Na6Al6SiO10O32.
NaO, Al2O3,
Al2O32SiO2 2H2O 10% NaA ,
SiO2.

, ( )
NaA.
, ,
,
.
.
, ,
.
XIII -
-2010
292
543.553 + 66.061

.., .., .., ..
.
.. ( . .. ), . ,
e-mail: knyazkina_ov@mail.ru

.
, ,

,
.
(VI)
,
,
(2-)
(2),
(2,4,4) (Cyanex-272)
().
,

= 1,52,5. -, -
(VI) 2 Cyanex
272 : HCl HNO3 H2SO4;
: H2SO4 HCl HNO3.
,
2
Cyanex 272.

-, -
,
.
,
( 8 ),
.

,
.
293
546.824.31

.., .., .., .., ..
( ),
., e-mail: alex-kolm@mail.ru
, p- 3d-

.

( TiO2)
,
.
()
(IV).
,
-
. -
80C,
.
()
150, 200 240C ( 3 24 )
.

,

.
: )
, , ; )

,
( 15 150C 25 240C).
- .
,
.
,
-
. ,

, ,
,
,
, .
294
XIII -
-2010
544.463:544.478:546.562-31

.., ..
- (),
., e-mail: jek@isuct.ru

.
.
--
.

(100 ) (250 )

, .

.
.

.
3,5 /(.) 220
3,6 /(.) 220
,
-- .
, 400
97 % 98 % .
,
, 75 2/.
,
,

- . ,

.
295
542.65+548.5

NS NK

.., ..
.
.. (), . , e-mail: tascha8@mail.ru

.
,

.

.
,
:
- ,
,
;
- -
(ts ) (ts )
. ,
, ,
.

:
-
NH4NO3
, ,
.
( ) -
20 600. ,
, (
).
:

,
.
296
XIII -
-2010
66.094.373:661.865.5:661.856
-
CeO2-ZrO2 CuO
.., .., .., .., ..,
..
. .. , . , e-mail: tijbfpbb@gmail.com

CeO2-ZrO2
.
-
,
CeO2-ZrO2, 10 .
, -
CeO2-ZrO2 CuO
.
.
-Al2O3 ( 2-3 , S=1,0 2/). CeO2-ZrO2 CuO
. CeO2-ZrO2
CuO 1 200.
, ,
6000 2 .

.
CeO2-ZrO2

.
, (. %): CO 4,1;
O2 9,6; N2 86,3. ,
CeO2-ZrO2/Al2O3
150-4000. 100 % 4000
, 0,8 . % CeO2-ZrO2.

. 1%
. ,
, ,
(II). 0,25
. %.
, uO CeO2ZrO2. , ,
uO-CeO2-ZrO2(9/1)/Al2O3 1500, uOCeO2-ZrO2(4/1)/Al2O3 - 2000.
297
542.61:546.791

-
.., .., ..
-
(), . , e-mail: vyakshin@bk.ru

1-10 /3 ---18--6 (186) --18--6 (186)
(, 1,2-, , 1-).
O
(CH3)3C
O
O
(CH3)3C
C(CH3)3
O
O
O
186
C(CH3)3
O
186
, HCl
(D)
9 /3 HCl 186 67 /3 HCl 186.
D,
, . D
0,01 /3 186 830,
.

, D
186*
186**
()
19
830
1,2- ()
0,5
370
50%+50%
10
620
()
0,02
0,3
- ()
0,6
0,1
3
: * 0,02 / 186, 9 /3 HCl, 10
/3 U; ** 0,01 /3 186, 7 /3 HCl, 100 /3 U.
,
2:1. ,
,
,
.
XIII -
-2010
298
543.06, 504.064.3

.., ., .., .., ..,
..

. .. (), . , e-mail: kuzinad@rambler.ru

.
, ,
, .
,
,
- .

.

, Bi2O3,
MoO3, B2O3, GeO2, ,
. ,

.
, GeO2
20% . c

0 90%.

. 0,03.
,

6 .
, ,
, ,
,
,
,
, , , ,
, .
299
544.46, 504.064.3

-
.., .., .., ..

(
)
.
- , ,

,
.

Bi2O3 - B2O3 - MenOm, - IV-V
.
343-373 0,5 40 .

. ,
.

.

100 /.
,
5 . ,

ln(V/V0)() .

10/
=20 .
,
. , ,
.
,
5 10 .
XIII -
-2010
300
542.65 + 548.5

.., .., ..

. .. (), ., e-mail: v.kuchinsky@mail.ru

,
().

, ,
.

.
,
: ,
-2060,
..
,

.
,
. ,

( IIIIV),
.

.

,

().

,
().
301
661.152.3'12'2:544.7(043.2)

.., .., ..
- (),
. , e-mail: tis@isuct.ru
, ,
, ,
, 90.

.
.
.
.
. - VM-4
- , 930 -1,
5,4 /. .

.
,
.
, ,
(
), , . .
.
,
140-250 <140 0,37 /.
0,32 /. .
<140 .
65 3 .,
0,32 /. 0,22 /.,
82,8 84,4. ,
.
. ,
.
5 . -136-14
(),
( -120), .
, ,
0,03 /.
, 90, : 95,5
%. ; 0,5 %. -136; 2,0 %. -120.
XIII -
-2010
302
66.097.1

.., ..
-
(), . , e-mail: pv@isuct.ru

, , ..

.
.

( -00)
(), -
.
, 1-

Na(AlO2)(H2O)1.25.
50 %. , Al2O3,
, 270 190
, ,
(36)1011
2.
,
Al2O3 ( ).
:
d/d = k(1+)2/3[(1+)1/31]1.

600 .
303
667.629.825:032.667:661.882

.., ..
.
.. (), ,
e-mail: gerasimova@chemy.kolasc.net.ru

,
,
. (
CaSiTiO5, - 38%),
- ,

,

( )
.
,
.
:
-
-
,
, .
, ,
, ,
, .

(NH4)2TiO(SO4)2.H2O.
.

(TiOSO4.H2O)

-
,
, .
.
,
- ,
.
XIII -
-2010
304
541.183.5:547-145

.., .., ..
- . ..
(), . , e-mail: karinavl@mail.ru
- ()
,
, ,
1.
,
( 100 /),
.
( e
)
2. C

3
().

( 69 /, 95/ - 160 /)
;

. , 160 /
( ) 70% ( 23 -/).

3.
,
. , L-,
: - max = 17,2
/, = 0,44, - max = 23,4 /, = 0,20, - max =
31,6 /, = 0,27 . ,
. ,
2 9
.
,
,
(310-9 2/).
1
S.Vangrattanasopon et al. Sep. Sci. Technol., 31, 1523 (1996)

A.S. zcan et al. J. Colloid Interface Sci., 280, 44 (2004)
3
.. . , 22, 60 (2008)
2
305
541.183.5:547-145

.., .., ..
- . ..
(), ., e-mail: karinavl@mail.ru

4. , ,
5.
6,7
.

: ( 2, ), ( ),
( ), -
,
()8.

(-69, -95 -160 /
) 2
(=6). , L-,
: - 18 / 20 /, 50 / 80
/ .
( 100
/ 200 600 /).

300 /.
, , 15%
, 2, - 50%. ,
2 8 10% ,
.
,

( 2 - 2,510-9 2/, -2,210-9 2/,
- 1,010-9 2/, - 2,010-9 2/, 4,210-9 2/).
A.G. Espantaleon at al. Appl. Clay Sci., 24, 105 (2003)

6
.. . . , 9, 1550 (1994)
7
Q. Li et al. J. Hazard. Mater., 147, 370 (2007)
8
.. . , 22, 60 (2008)
5
XIII -
-2010
306
66.095:661.721

-
.., .., .., ..
-
(), ., e-mail: morozov@isuct.ru

.
-
,
.

.
-
,
, .

,
.
,

- .

. ,
,
. , . ,
,
:
-.

-,
.

. ,

,
,
.
307
529.12
Y2O3 YBa2Cu3O7

..*, ..**, ..*
*
**
. .., , . ,
. .., , . , ,
email: moyzykh@gmail.com
II

YBa2Cu3O7 (YBCO).
, YBCO - ,
(-),
(-)
.
.
YBa2Cu3O7 MOCVD
830-890 p(O2) = 0.5 .
Y2O3
- 123 .
(-2, -, , 0.3). ,
Y2O3
- YBCO, , Y2O3
.
, Y2O3 YBCO
20 , .
, -,
YBCO,
- -
.

YBCO , -
,
(87-88 ), Y2O3
.
, ,
YBCO Y2O3
-.
09-08-00774
308
XIII -
-2010
541.128

.., .., ..
- (),
., e-mail: ilyin@isuct.ru
,
, 3
F2(4)3. : 3

,
,
,
;
.

Mo/Fe 1,5 2,5
,
250 400.

3 -Fe2O3, Mo/Fe 1,5
2,5, 400 0.
,
F2(4)3. ,
3 .
,
2.1,
400 0,40
/. Mo/Fe
, ,

.
.

96%
Mo/Fe=2.1.
309
546.621

3.
.., .., .., ..
- (),
. , e-mail: ilyin@isuct.ru
, , ,

.
,
.

, , ,

3 .
-
VM-4 15, 30, 45 90 .
, 3
120 . ()
15 . 10 .
.
,

22 , 0,57 %.

, ,
. -

.
Fe 3
0,38 %.
250
400 ,
, 45 .
.

.
,

.
XIII -
-2010
310
546.824.31

NiTiO3
.., .., .., ..
( ),
., e-mail: 7243201@mail.ru

, , .

,
.

.
TiO2 NiTiO3.
: 1)
() 600 2-
(TiO2-); 2) TiCl4 (
)- (TiO2-); 3) 6-09-3811-79
TiO2- Ni(NO3)2
.
700, 800,
850C () 700 1100C 50C ( )

-. - Netzch Jupiter.
- .
.
- -
JEOL 2000.
,
TiO2- , TiO2-.
,
.
700C
850C TiO2. TiO2-
,
NiO.
.
311
661.635.13:622.822.223(043.2)

.., .., ..
- (),
., e-mail: tis@isuct.ru

.
(),
.
,
(),
-120.

- 1 .%
30 .
NH4+, CO32- -, =. CO32 ,
,
. -
NH4+ , Si-O-Si -,

-. ,

.
, 50 ,

-120.
-120,
. ,

,
( ,
, 0 .,
50 ). ,

, -120.
312
XIII -
-2010
666.192
,

.., .., ..
() , 644040
., 54, .: 8(3812) 56-02-87,
e-mail: suruv@ihpp.oscsbras.ru

, , , ,
,
.
SiO2
,
, .
,
.

,
.
.

.

,

().
().
. ,
,
. ,
500
1000 ,
. ,
Si-C
,
SiO2. ,
: (, );
, -
, . ,

.
313
66.097.3

, ,
..1, ..2, ..1, ..1
1
-
( ), . , ,
e-mail: vniios@mail.ru
2
(), . , .,
-
(Al2O3) .
Al2O3
,
,
, , .
,
,
.

,
.

,
.

(. , .);
, (. -).

,
, ,

.

,

, , .
XIII -
-2010
314
[546.712:547.587.11] 386
(II)
..1, ..2, ..1
1
, ,
e-mail: general_chemistry@astu.org
2
,
. --
, ,

80300 , (II)
(I, R = Alk, Ar) .

, s---, s--- ( ):
O
C
H
O
H
N
C
2H2O
Mn /2
IB
C
H
Mn /2
IA
O
H
IC
II
(C, H, N, Mn) ,
nL 22 ( H2L
I).
33003000 -1, 2060 -1
1730
1660 -1 C=O -
II.
34003300 -1 ,
- ,

.
, ,
dd- ,
III:
H
H
O
H
H
III
R
O
O
O
C
,
Mn
N
C
O
C

N
Mn
C
O
O
O
R

H
H
O
, H
H
.
III
O
315
544.3.032.2:544.353.21:544.43:546.46-31
-

.., ..
- .
, e-mail: fogn@isuct.ru

,
.

. ,
-.
2 (
2,45 , 6 ), /
. -
.
:
.
,
.
,
, .
,
,
, .
3
, ,
.

,

.
,
(, )
()
.

(5-10 % ).
316
XIII -
-2010
541.18

.., ..
- (),
. , e-mail: AFirsov@phosagro.ru

.
,
, ,
.
,

.

:
1. ;
2.
;
3. ,
;
4.
.
:
1.
( 48,56 /)
.
2.
:
- 90-95 ;
- 3 ;
- - 400 800/;
- 1,5-2;
- 40%.
3.
.

, ,
.
317
542.2

.., .., ..
-
, . , e-mail: ket712@isuct.ru

: ,
,
.
.

.
,
.
,
( , 3 ).
, ,
.
, ( ,
),
,
.
,
.
, -, ,

. , ,
.
:
,
.
:
( )
(
).

,
.
XIII -
-2010
318
546.815-121

Bi2O3-PbO Bi-Pb
.., ..
(),
. , e-mail: evg9042@yandex.ru

.

,
.
,
, ,

.
, , .

,
.

Bi-Pb , ,
, ,

.

Bi-Pb
, .
;
Shimadzu XRD 6000.

,

, , 100 %
Pb0.5Bi0.5O1.33,
.

.
319
546.05
C
YBa2Cu3O7-

.., .., .., ..
. .. ,
. , e-mail:boytsova@gmail.com
(- II- ),
YBa2Cu3O7-x,
,

,
,
.
-

(jc), ,
H. jc,
YBa2Cu3O7-x, ,
,
,
. , ,
.
,
.

YBa2Cu3O7-
, .
MOCVD- YBa2Cu3O7-
,
.
,
, BaCeO3.
,
.
XIII -
-2010
320
542.61:546.633
N-(2--5-)-
.., .., ..
.
.. (), ., e-mail: neorganik@inbox.ru
N-(2-5-)-- (-2),

.
,
.
N-(2--5-)- (-2).
,
, ,
-.
,

( ,
).
MgCl2
MgCl2 , .

: ,
, ,
- (=4.5, t=45., MgCl =1-1.5.).

.
Y, Al, Fe(III), Mn, V, Cr 0,25.
-2 1.5. MgCl2.

.
2
321
517.958:536.24:621.315.592

Cd1-ZnTe
Hg1-CdTe
..

. .. (), , e-mail: lgvelesiani@yandex.ru
26
,
.
Cd(1-)ZnTe ( 0.1) ()
().
,
.
,

.
,
,
[1,2].
,
,
, ( Zn),
.
:
-, - ,
[3] .
, ,

:
, , .

()[4].

Matlab Comsol Multiphysics.
[1] .., .., .., .., .. //

.20063.28-32.
[2] .., .., .. //
.20084.11-16.
[3] Houghton D.C., Davies M., Dion M. // Appl. Phys. Lett.1994.V.64P.505
[4] .., .. // .
20003.28-34.
XIII -
-2010
322
669.296

.., .., .., .., ..
- . .. (),
. , e-mail: chizh@rctu.ru
d- III-V
,
, .
,
,
.

()
() .

(),
(
).
, , .
NH3
. (1925 .) ,
(60-70- .) NH3H2O

.. p- d- (Al, Sc,
La, Th, Zr, Hf, Nb, Ta). , ,
, ,
( ),
.
,
,
,
.

(, ) ()

NH3H2O ,
, . ,
. ,

. ,
.
323
669.296:620.18

.., .., .., .., ..,
..
- . .. (),
. , e-mail: chizh@rctu.ru

, , ()
:
, ,

.
, ,
-
.

.
ZrOCl28H2OYCl36H2ONH3H2O
,
,
80- . . .. .. .
-,
, ,
.
(3 . % Y2O3), (500)
(5 )
Pulverisette-5, Fritsch ( ),
: ( 1 )
(50-100 ).

(m-ZrO2 1%) () ~
14 . (
, = 200 ) (1450)
(99% )
( = 95030 ).
324
XIII -
-2010
66.096.5:621.928.23(043.2)

.., .., ..
-
. , e-mail: ale3069@yandex.ru

(), ,
,
: ,
.

.
, ,
, .
5 30%.

.
,
.
,
- (
).

,

, , ,
.
,
, ,
(
0,51,0), ,
.

,
.
, ,
, ,

, .. .
325
665.777.5

.., .., .., .., ..,
..
()
OOO , ., e-mail: leb-ira@mail.ru

-
,
(),
, .
.
,
. ,
- 0,08 26-34%.
.., ,
- ,
, .
,
.

0,08
, % 2,
, %
, % ,
, ,
/2.
/
. .
- 26,0%
1
33,0
26
1,09
30,7
35,3
77,6
42,4
2
35,6
28
1,08
28,2
37,0
71,5
54,2
3
38,3
30
1,16
29,3
34,9
72,1
52,2
4
40,9
32
1,13
28,8
38,0
70,4
46,8
5
43,6
34
1,19
30,0
32,4
72,0
45,1
- 26,5%
6
33,0
26
1,10
29,1
31,8
69,9
42,2
7
35,6
28
1,45
30,1
36,0
66,7
47,8
8
38,3
30
1,43
29,6
38,5
66,3
41,6
9
40,9
32
1,28
27,6
38,2
66,5
38,8
10
43,6
34
1,38
29,6
38,8
72,5
58,3
..,
:
- 40,9%, - 0,08 - 32 %,
( ) - 26,0 %.
XIII -
-2010
326
541.183.12+549.67+546.28
,

..

, . , e-mail: ilahe88@mail.ru
,
,
, ,
,
,
, .
,
, .
(20-10000)
() () ()
( . %): :: = 80:10:10; 70:20:10;
60:30:10; 70:10:20; 60:20:20; 50:30:20; 50:20:30.
--
.

0
1000 C 30 .
,
-.
,
,
.
0
~100 C.
..
-
--
I
II
III
IV
V
VI
VII
, ,
/
0,29
1343
0,35
1393
0,49
1473
0,21
1403
0,52
1653
0,81
1773
0,94
1833
0,78
0,14
0,80
0,17
0,82
0,21
0,85
0,26
0,89
0,29
0,92
0,31
0,98
0,35
,
/3
305
360
430
310
380
480
340
327
546

,

.., .., .., ..
(),
, , e-mail: artemej@mail.ru
-
,
CrO42-, [Fe(CN)6]3-,[Fe(CN)6] 4-, [Hg I4] 2-.
.
8,6 , 9,5, () -9,5-10,5.

.

.
, 100,
200, 300, 400, 500, 6000,
.
,
, - .
,
, . ,

. , ,

.
, ,
.

1200.

, .

, , . .
XIII -
-2010
328
544.4634; 544.552.11

.., . ., ..
(),
. , e-mail: mayrus@mail.ru

, , .
.
,
- .
,
(, ) (
), ( ,
).
, ,
() .

, ( )
Mn + MnnOn+1 + (2n+1)HA (n+1)MnA2 + (n+1) H2O,
Mn + 2HA MnA2 + H2 ,

. , ,
.
, .

.
(II), (II) (I).
(II)
, (II)
.
.

2Fe + O2 + 4HA 2FeA2 + 2H2O
( )
4Fe + 3O2 + 12HA 4FeA3 + 6H2O (
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2269509,
2269508, 2261882, 2268874, 2291855, 2291856, 2292330, 2292331, 2296744,
2296745, 2304575, 2314285, 2326107, 2326861, 2357950, 2318731,
2008104575/04, 2007139162/04, 2004108260/15, 2294921, 2316536, 2331629,
2003104761, 2007147495/04, 2007144399/04, 2008127010/04.

- 2009-2013
:
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2074).
XIII -
-2010
330
521+541.182
-

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XIII -
-2010
332
541.182:549.321:543.42
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-2010
334
544.478

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-2010
336
529.12

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546.48.221231:538.975
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XIII -
-2010
338
666.32.323.94
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-2010
340
546.65:541.8

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-3020.2008.3.
341
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-2010
344
691.175.2

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., e-mail: abramovma.yar@mail.ru

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[1] Drent E., Budzelaar H.P.M. Chem.Rev. 1996, V.96, 2, . 663

[2] .., , ., 2001, .43, .1651
[3] .. .. , 2004, .73. 3, .292
XIII -
-2010
346
541.64

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XIII -
-2010
348
678.067.5

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. . . , . , , e-mail: surikov@mitht.rssi.ru
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349
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XIII -
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350
542.943-92
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-2010
352
678.01:53

-

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( 08-03-00386).
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-2010
354
547.622:542.943

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XIII -
-2010
356
547.21-126

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357
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XIII -
-2010
358
677.494: 677.46.021.5

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359
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,

.
360
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., ..

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.
XIII -
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362
678.686
-

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363
678.044.6

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320-330
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, Co(III)
.
XIII -
-2010
364
541.64:539.3

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366
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XIII -
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368
678.5
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-2010
370
541.64:547.979.733

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- 2009 2013 02.740.11.0106 -1105

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XIII -
-2010
667.6
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547.466:543.42

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-2010
374
547.1127:544.16
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376
677.027
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391
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XIII -
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392
678.01:539

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678.742.2:678.048:532.783

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2009 - 2013 02.740.11.0106 -1105
XIII -
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396
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XIII -
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398
541.64:547.979.733

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XIII -
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400
541.64:547.39

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XIII -
-2010
402
678.027
-

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15813, 2678-94 ( 3.9)
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406
678.84

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.
408
XIII -
-2010
529.12

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., e-mail: sas@isuct.ru

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XIII -
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410
678.762.2
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411
541.64:537.6:539.3

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412
XIII -
-2010
544.032.4:54-145.1:547.992.2(043.2)

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. 2310633, . 20.11.2007, . 32.
-
2009 - 2013 02.740.11.0106
-1105

413
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414
XIII -
-2010
678.675:547.466.1-145(043.2)

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415
544.057

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3-[(2,2,3,3,4,4,5,5-) ]--1(I)
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.
XIII -
-2010
416
661.728; 678.65
,

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541.64:532.77
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418
XIII -
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677.017

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( 02.740.11.0143).

421
532.783+541.66

. ., ..
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OR

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OH
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N
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N
N
Br
Br
N
RO

4
Br
N
N Brh
=
Cs2CO3,
O
RO
,
OR
4
XIII -
-2010
422
678.067.5

.., .., - ..
. . , . , , e-mail: surikov@mitht.rssi.ru
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DR-332, DR-330, 20, -16 -8 .
().

( )
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-
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, 1- .
, ( 120 4 )
364 722 / 1- 60
99 % 4,9 5,3%. ,
~ 0,64-0,68

.
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423
678.6/.7

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. .. ,
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- (.
1-8), 2--5-
.
H2 N
II
1-8
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*
R
R1
N
n
Ar
10-30
Ar
, I X=O, R=COOH, COOCH3, COOC2H5, R1=H;

O
O
II X=
, R=R1=NH2

,
- ,
, .
2009-2013
2433
XIII -
-2010
424
541.6+ 546.3+620.22
,

.. , .. , ..

.. , 11957, , . , 86,
e-mail: regina.bulatova@mail.ru

,
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, , ,
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6
(=1.310 ).
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,
.
:

, (in situ).
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.
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(
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.

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425
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XIII -
-2010
426
541. 66
.., ..
c (), .
e-mail: nigar_guseynova@list.ru

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(5/).
1
2
3
4
5
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-15%
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-40%
..

Tp Tk .. ..
250
240
230
220
215
240
180
200
230
200
,

10%
360
320
310
300
280
260

10%
440
415
385
385
415
410

10%
490
460
420
430
450
425
,
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427
678.632

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()
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130-150 0,5-4
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301
702
603
803
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102-115
103-118
105-122
,
35-45
25-40
20-35
110-195
150,

.
XIII -
-2010
428
678

.., .., ..
(), .
, e-mail: igymti8@rambler.ru
,
,
.

.
(),
,
153-10. 60 - 70 ( 7 %
)

.
0,010,1 . . .

50-80%

.

( ).
,

,
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, ..

, .

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,
.
- -
,
.

.
( 0,01 . .)

15-20 % .

429
: 678.5.03

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. .. ( ),
. 1872
.
1965 , ,
: () .

.
-
,
Cl -
(~CH=CHCHClCH2CHCl~),
(- ).

-
.
~C()CH=CHCH2CHCl~
.
-
,
Cl ,
~C()CH=CHCH2CHCl~,

( ).

.
- .

.
50
.
..
.

.

.
430
XIII -
-2010
541.64:548.736.64 + 677.494.675'126.044.12:661.856

+
N -
. ., . .
(),
. , e-mail: organic@vstu.ru
+
Na - ()

- () H(CF2CF2)nCH2OH
n=2-5. ,

-
.
- .

.
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,
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-
-.

--- (),
-
. -
.

,

.

431
678.684.82.04+541.64:548.736.64 + 677.494.675'126.044.12:661.856

+
N -

. ., . ., . ., . ., ..
(),
. , e-mail: organic@vstu.ru
,
..
-
, , - .
. ,
, , ..
,
.
,
, ,
..
-1,

.
(20 . %).
,

H(CF2CF2)nCH2OH
n=2.
(n=2).
1 100 -1.
. ,
.

.
- ,
.
,
- .
,

.
, ,
.

.
XIII -
-2010
432
667.613
..1, ..2
1
- (), .,
e-mail: lkz@stako.ru
2
(), .,
e-mail: dmitrykuis@mail.ru

,
.
.
,
,
- .

.

(2, 4 ,
, 4,4` - )
,
.

(20, 30 60 )
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20-30 ,
.
-
.

.
(1 1), (50 ) (0,26-0,65
..)
3 ,
.

433
678.747

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(),
, . , -mail: yurakurtash@polynet.lviv.ua.

, , ,
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,
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,

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,
,
.
,
.
,
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,
,
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().
,

.
,
.
,
- .
XIII -
-2010
434
678.742.2.28:628.027.98.

.., ..

.. (), . , e-mail: vasily@markov.biz
10803-020
. () 50000.
(-1002) ().
- . 1.
Hot set
.
.
40%, .
50% , .
(. 1).
. -
. =50%
,
-.
.
1. -
-, %
0 15 29
44
55 63
67

130 63 55
40
(200,0,1 ),%
200
0.085 0.13 0.175 0.21
(),
N/N,
0 1.2 1.6
1.9 2.2 2.5 2.8
(.1)
N/N,

1.1 1.4 1.7 2.0
(. 2)
, %

59
64
68
71
71
30
0.24
3.1
2.2
71

( ),
: N N M 2 , .
, . ,
(N/N>1) 0,7% .
, .
.
N C 2C1 / kT . . 1

435
,
.
, - (
=50%)
( )
. -
, .
XIII -
-2010
436
541.64:542(943+952)

-2- Fe3O4
.., ..

. . . ( ), . ,
e-mail: ozkan@ips.ac.ru

-2- ( ).
,

. . - ,
- -
.

-2- ( )
Fe3O4. .
Fe3O4, ,
(II) (III) 1 2
, .
FeCI2 + 2FeCI3 + 8NH3 H2O Fe3O4 + 8NH4CI + 4 H2O

0. , Fe3O4
.
H
N
NH
COO
Fe3 O4
OOC
(N H 4 ) 2 S 2 O 8
Fe3 O4
COO
H
N
COOH
CO OH
H
N
H
N
]n

. Fe3O4 4<d<14 .
12 .

437
541.64:543.943

Cu
.., .., .., ..

. . . ( ), . ,
e-mail: ozkan@ips.ac.ru

() ,
,
. ()
(9 11) 103 5% [1, 2].

Cu(OOCCH3)2H2O 150-250 .
[Cu]=10 .% .
- ,
Cu(OOCCH3)2H2O
.
812 1650 1,
H 4,4/-
=N .
,
, ,
, Cu2+ Cuo.
-2 H
]n
2Cu(OOCCH3)2H2O t , C Cu2O + CH3COOH

o
Cu2O + H2 t , C Cu + H2O

Cu,
.
2<d<12 .
[1] . ., . ., . ., . . //
. . . 2006. . 48. 1. . 126.
[2] .., .., .. // . . . 2006. .
48. 1. . 134.
XIII -
-2010
438
66.081.6
-

.., ..
()
. , e-mail: larisa_potehina@mail.ru

. ,
.

, , ,
.

.

(
).

-
,
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,

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,
.

439
678.762.2
,

.., .., ..
, .
e-mail: eco-inna@yandex.ru
,
.
,
,

.
, ,

.

( 1,0 % . ).

.

.
.
, .

.

,
.
3-15 % .
.
,

,
.
, , ,

,
,
.
440
XIII -
-2010
541.49:(546.74.2+548.736)
12,35
(V)

.., .., ..
(), . ,
e-mail: azimjon51@ mail.ru

12,35
(V)
() .(.).
(, %)
; +1% 12,35; +1%
[ReOL2Cl3]3H2O
, %
+1%L
+1%[ReOL2Cl3]3H2O
.
15 25 45 15 25 45
15
25 45
0,5
9,1 8,8
5,3
6,2
5,6
4,9
5,0
4,1
3,6
1
10,8 10,5
8
8,1
6,0
5,6
6,8
5,2
4,8
1,5
15,7 12,1 8,8 10,9 8,1
6,4
7,4
6,7
5,4
2
17,4 12,0 9,2 14,3 10,3 8,3
10,8
8,0
6,5
2,5
17,8 12,8 9,9 15,6 11,8 9,8
12,1
9,5
8,3
3
18,1 13 10,2 17,2 12,2 10,6
13,5
10,0
9,1
5
18,8 13,5 12,4 17,9 12,8 11,5
14,2
10,7
9,8
15
19,2 14, 12,6 18,8 13,3 12,0
16,1
11,2
10,3
25
19,8 14,2 13,1 19,4 13,8 13,1
16,8
12,5
11,0
35
20,4 14,8 13,7 19,7 14,0 13,8
17,2
13,1
12,2
, 12,3
5 (V)
.

[ReOL2Cl3]3H2O.
(D)
, D
, ,
(V).

441
541.49:(546.74.2+548.736)
[ReOL2Cl3]3H2O, L 12,3
5

1 .., 1 .., ..1, ..2
1
(), . ,
e-mail: azimjon51@ mail.ru
2
(), . ,
e-mail: kubgu-gk@mail.kuban.ru

5
(1--2,3)
( v, s, E0, max) (0,5 )

() .
.
.
[ReOL2Cl3]3H2O, L- 1--2,3-

, %
0
0,01
0,05
0,1
0,5
1,0
2,0
3,0
0,5,
0, /
max, /
v,
s ,
207
120,3
90,2
73,8
35,8
20,1
17,0
17,3
491
228,4
150,3
139,4
70,3
35,9
30,5
31,1
101013
2,91013
2,31013
2,01013
1,91013
1,71013
1,01013
1,81013
39,21013
9,81013
9,11013
8,91013
8,01013
7,91013
1,51013
2,61013
min
126,4
76,6
64,9
17,4
4,9
1,6
2,7
2,8
,

.
(E0, max v, s,) .

(0,01%) 1,65 . ,
.
442
XIII -
-2010
675.6.06

..
(), .,
e-mail: Gulnaz-f@yandex.ru

( ).

(
()-, ),
.
.
,
,
.
938.0.

, , ; ;
; .
:
(n)1016-10193, (j) 102-1,8*106/-2,
() (1-50)*102*-1,
(c) 108-1010 -1.

(30-200).
, .
190-650 3
, .
190-520,
.
.
170-550
2 ,
170-500.
,

, ,
.

443
675.6.06

-

..
(), .,
e-mail: Gulnaz-f@yandex.ru

-
(
()).
-
.

.

Bruker D8 Advance,
Vario Vantec. CuK
,
.
- ( ) .
=1,54178
(1 = 10-10 = 0.1 ). : 40kV 30 mA.
- V20xV20.
0.02, 1.2 , 3-652.

, , ; ; ;
.

6-102, 12-302 35-502,
.
(Fe2O3)
2,69 2,51 1,84 1,69 .

, .

.
c d~10.65 ,
.
,
-
.
XIII -
-2010
444
678

.. , .., ..
(),
. , e-mail: fishkina@bk.ru
, ,
,
(,
, )
(, , .)

(, , , ) ,
[
15803-020,
.
: 1. , , ,
; 2. , , ; 3. , , ,
. .

150300 .Battaggion SpR ().
130-150 110-125 ,
0,75-0,95.

, ,
. ()
-, ,

.
,
.

.
, ,
,
.

.

445
547.729: 678.04
-
-
.., ..

. .. , . , e-mail: sokolova_mchti@mail.ru
-
-, .
,

()

.
-1.4- -
-1.4- , ,
. ,

() -.
, -,
-,
.

-. ,
, ,
.
,
, , , ,
40%. ,

, .
- .

, , .
, -,
, .
,

.
XIII -
-2010
446
678.5
..

. .. (), . , e-mail: ushob@yandex.ru
,
,
.
PE 4FE69,

20 80 .%
.
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()
.
,
,

.
.
,
(,
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)
. ,

,
.

,
(Irganox 1010/ ADKStab 1178 (1/2))

447
678.5.0: 661.63

.., .., ..*

( ), . , e-mail: ovp2808@rambler.ru
*
- (),
.
POCl3
( ),

, =POCl POCl2,
. [1]
, 6% 15% .
(18%).
,
, . ,
35% ,
210255 . ( 30-35%, . 1)

( 15-20 ).
, ().
1
() ,
15-20
50-55
70-75 95-100 120-125 145-150

**
**
[1]
**
**
**
**
[1]
10% 1400-1440 600-620 290-310 110-120 85-95 30-35 420
20%
610-630 105-120 1100 70-80
35-40
25-30 23-25 45
30%
85-100
50-60 60-90 12-15
10-15
8-10
6-8 5-10
35%
75-90
20-25 20-25 10-15
5-8
4-6
3-5 3-5
10%,.
1400-1440
25-27
18-20
15-17
10-12
8-10
**
**

. (2-3 )
(+20% ) 0,1-0,8%.
.
[1] .., .., ..

//
. 1983. 2. . 370-375.
XIII -
-2010
448
541.64:542.938
NEW GRADES OF SUPERABSORBENT POLYMERS

Shapovalov S.V.,1 Sackmann G.2, Korte S.,2 Meyer R.-V.2
1
Joint-stock company Saratov-Polymer, Saratov, Russia,

e-mail: svs.polymer@mail.ru
2
Bayer AG, Leverkusen, Germany
Superabsorbent Polymers (SAPs) are cross-linked polyelectrolytes. Due to their

ionic nature and interconnected structure, they absorb large quantities of water and other
aqueous solutions without dissolving. This makes them ideally suited as absorbents of
body fluids in many personal care products sold today. These applications count for
more than 90 % of the SAP consumption worldwide.
Commercially available SAPs consist normally of partially neutralized, crosslinked poly(acrylic acid), which is produced by copolymerization of acrylic acid,
acrylates and crosslinking agents.
The novel manufacturing process presented starts from low-priced
Poly(acrylonitrile) (PAN). Advantages of the new process are cost-efficiency as well as
performance improvement of the SAP grades with new properties. Starting materials for
the production of SAP according to the new BAYER process are aqueous emulsions of
ultra high molecular weight PAN (> 2 millions). Polymerization of acrylonitrile under
specific conditions utilizing another BAYER Technology leads to the desired PAN
emulsions with solid contents of 35 to 37 wt.-% and average particle sizes between 100
and 150 nm.
The novel process was developed for the continuous production of SAP by
polymer-analogous transformation of the nitrile groups of PAN through alkaline
hydrolysis using available high viscosity equipment. Process control allows the selective
variation of the hydrolysis reaction parameters to produce SAPs with well-adjusted
properties. In addition, variation of the molar ratio of PAN to sodium hydroxide opens
the way to new copolymers with acrylic acid, sodium acrylate, acrylamide and
acrylonitrile moieties.
A cross-linking reaction is required for achieving superabsorbing properties. The
new production process offers two alternatives for cross-linking: a) starting from slightly
crosslinked PAN emulsions, prepared by copolymerizing acrylonitrile with bifunctional
monomers or b) cross-linking by controlled intermolecular reactions between the
polymer chains during hydrolysis that lead to product improvements.
A further enhancement of the already excellent properties of the novel SAP
grades is possible by chemical surface treatment. Such optimized SAPs are showing
excellent anti gel-blocking, very high absorbency under load (AUL), good Rewetproperties as well as retention values up to 30 g/g. The AUL-values at 0,3 psi reach 26
g/g and at 0,7 psi up to 25 g/g, respectively. A special feature of these products is their
extremely fast initial uptake of the aqueous liquids and the very dry feeling of the
swollen particles. This feature can be attributed to the unique morphology of the SAP
powder. Independent test results demonstrate the improved performance of the new
grades in comparison to commercially available SAPs.

449
541.64:542.938
MODIFIED SUPERABSORBENT POLYMERS BASED ON
POLYACRYLONITRILE EMULSIONS
Shapovalov S.V.,1 Sackmann G.2
1
Joint-stock company Saratov-Polymer, Saratov, Russia,

e-mail: svs.polymer@mail.ru
2
Bayer AG, Leverkusen, Germany
The superabsorbing polymers (SAPs) produced by partial alkaline hydrolysis of

high-molecular, finely dispersed uncrosslinked or crosslinked aqueous emulsions of
Polyacrylonitrile (PAN) also exhibit some disadvantageous characteristics, among which
a certain tendency towards gel blocking may be mentioned particularly. When using
these products for example in personal hygiene articles gel blocking is observed
which results in low initial transport rate of the liquid to be absorbed, and which
subsequently leads to overall relatively poor liquid transport properties and low
absorbency under load (AUL) values. Such a process ultimately gives low rewet
values.
This gel blocking behavior is also known in superabsorbents based on
polyacrylic acid. In order to eliminate this disadvantageous characteristic, which has a
negative impact on product performance two methods may be used: 1) treatment of the
SAPs with antiblocking agents, which have a greater surface area than the SAPs (silica
gel, cellulose fluff or other synthetic or natural hydrophilic fibers etc.) or 2) surface
crosslinking of the SAP particles with various crosslinking agents containing at least two
functional groups.
The novel process for modifying SAPs was developed with the aim to avoid gel
blocking and thus, to achieve an increase in the initial transport rate, an improvement in
AUL-values and the transport rate under load.
According to this process the SAP containing hydrolyzed PAN is treated by a
water/alcohol reaction mixture containing a crosslinking agent and silica. The
concentration of water in the reaction mixture is dependent upon the liquid/solid ratio.
Most preferably the silica is applied in form of a colloidal solution with particle
diameters in the range of 5 to 10 nm. The drying temperature for the SAPs treated with
the above-mentioned reaction mixture is 80 to 100C.
During this modification surface crosslinking and simultaneous immobilization of
silica in the surface structure of the SAP particles through crosslinking reactions take
place.
By means of scanning tunnel electron microscopy (SEM) and x-ray
spectromicroscopy it is demonstrated that the depth of the modification encompasses a
range from 500 nm to several microns and depends on the concentration of water in the
reaction mixture and on the initial structure of the SAP surface.
It has been found, that simultaneous crosslinking and immobilization of silica
generates a synergetic effect. This is manifested by disappearance of gel blocking
accompanied by a simultaneous increase in initial transport rate and significant
improvement in AUL values.
452
XIII -
-2010
001.895: 303.722.2: 661.632

.., .., .., ..
, , . , e-mail: bessarabov@irea.org.ru

.
.

,
.

15 .
,
.

1995-2008 .,
4-.

.
,

( ).

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. ,

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( 0,96).

(0,91)
(0,88).

,
.
.
453
504.45.058
,

..
(), . ,
e-mail:borusiv@mail.ru

.

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22 ()

. 22
52.18.24.83-89,
.
,
, ,

, 22 .

,
,

< 1000 ... =
40 000 . . .,
46.58%
58.05%
.
, ,

,
.
XIII -
-2010
454
543.05:543.423

,

..
- , .
, e-mail: vilkovaom@bk.ru

,
,

. ,
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.
-
( , ,
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().

: , ,
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(,
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.
ETHOS TC Milestone,
TFM-,
100 230-2400.
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, 73
167 785 . ,
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001.18: 502.33: 378

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456
XIII -
-2010
504.03

..
.
(), . , e-mail: bondgirl007@yandex.ru
-
, .
, .

: 1)
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; --
.
457
543.06, 504.064.3

.., ., .., .., ..,
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.
, ,
, .
,
,
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.

, Bi2O3,
MoO3, B2O3, GeO2, ,
. ,

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470
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-2010
474
004.65: 66.011: 502.37
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XIII -
-2010
476
537.523:543.97
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2
3
4
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6
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.
,

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, %
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53,1
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2007-2015 .
2008
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.
XIII -
-2010
478
661.865.5:66.097.5
2
CuO/CeO2

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479
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-2010
480
541.183.5:547-145

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A.G. Espantaleon at al. Appl. Clay Sci., 24, 105 (2003)

14
.. . . , 9, 1550 (1994)
15
Q. Li et al. J. Hazard. Mater., 147, 370 (2007)
16
.. . , 22, 60 (2008)
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481

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485
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330.15; 349.6

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,
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().
488
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-2010
547.495

..
(), .,
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490
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-2010
678.049.91

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492
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493
677.027.423.124.2

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: Cr (III) .
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.

Cr (VI), .

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. ,
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Cr (VI) 2-3
.

.
30-40%
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-2010
494
66.097.3

N2O
..*, ..**, ..**, ..*,
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.
495
504.054; 661.183

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:
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-2010
496
665.772

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542.547.89
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500
338.24
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-2010
502
620.193
DICSIS
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DICSIS ().
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.
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30 .
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,
1350-1400 ,
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,

.
XIII -
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506
628.316.12:537.523.9
, ,

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628.355.2:628.316.7

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508
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518
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-2010
522
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in situ
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. .
(), . , e-mail: tretjakov@ips.ac.ru *
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XIII -
-2010
526
Polymer immobilized analogues of ionic liquids
Trochimczuk A.W.
Wrocaw University of Technology, Faculty of Chemistry, 50-370 Wroclaw, Poland, e-mail:
Andrzej.Trochimczuk@pwr.wroc.pl ............................................................................................. 14

..
. .., , .
, 86, e-mail: frolkova@mitht.ru ............................................................................... 15
110 .. :
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, 86, e-mail: frolkova@mitht.ru ............................................................................... 17

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fat@hepti.kiae.ru ........................................................................................................................... 19

.., .., .., ..

. .. ,
, e-mail: yaroslav@igic.ras.ru .......................................................................................... 20

Pd(PPh3)2Cl2 PPh3
.., .., ..
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InAs/GaAs
-
.., ..
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(), . , e-mail: rakchur@mail.ru .................................................... 23
Mathematical modeling of the rapid expantion of supercritical fluids
Anikeev V.I., Stepanov D.A., Yermakova A.

Boreskov Institute of Catalysis SB RAS, Novosibirsk 630090, Russian Federation, e-mail:
anik@catalysis.nsk.su.................................................................................................................... 24

..
( ), . ,
e-mail: anisimovmp@mail.ru ........................................................................................................ 25
527
.., .., ..
. .. ( ), . , e-mail:
afanasev@catalysis.ru ................................................................................................................... 26
A new approach in application of Luminol reaction for trace blood analysis
Balantseva E.V.*, Priante S., Vincenti M., Coluccia S. Martra G.,

University of Turin, Department of Inorganic, Physical and Materials Chemistry, Turin, Italy,
e-mail: Bal_lena@hotbox.ru *Ivanovo State University of Chemistry and Technology (ISUCT),
Ivanovo, Russia ............................................................................................................................. 27
CHEMCAD

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528
XIII -
-2010
.., ..
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1
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9-14

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529
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:

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) (()), . -, e-mail: abiev_r@mail.ru ........................ 45
Hydrothrmal synthesis metal oxide nanoparticles
Anikeev V.I.
Boreskov Institute of Catalysis SB RAS, Novosibirsk 630090, Russian Federation, e-mail:
anik@catalysis.nsk.su.................................................................................................................... 46
-
.., ..
( ), . ,
e-mail: anisimovmp@mail.ru ........................................................................................................ 47
Transformations of monoterpene epoxides in supercritical solvents
Volcho K.1, Ilìna I.1, Salakhutdinov N.1 Anikeev V. 2

1
Vorozhtsov Novosibirsk Institute of Organic Chemistry, Novosibirsk 630090, Russian

Federation 2 Boreskov Institute of Catalysis, Novosibirsk 630090, Russian Federation e-mail:
anik@catalysis.ru .......................................................................................................................... 48
Physical-chemical tools for the assessment of indoor environmental effects on archival
parchment heritage in a changing climate
Badea E.1, Della Gatta G.1, Odlyha M.2, Larsen R.3, Usacheva T.4
1
University of Turin, Italy, e-mail: giuseppe.dellagatta@unito.it 2 Birkbeck College, University

of London, United Kingdom 3 Royal Danish Academy of Fine Arts, Copenhagen, Denmark 4
Ivanovo State Chemistry & Technology University, Ivanovo, Russia ......................................... 50

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530
XIII -
-2010
.., .., .., ..

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enk2005@rambler.ru ..................................................................................................................... 54
5,15
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e-mail: vyk_@mail.ru.................................................................................................................... 59

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(), ., e-mail: htpngsamgtu@mail.ru ............................................................................................................................ 60
Thermodynamics of complex formation between crown ether 18C6 and D,L-Alanine in
water-acetone mixtures at 298.15 K
Matteoli E.a, Usacheva T.R.b, Chernov I.V.b, Kuzmina I.A.b, Sharnin V.A.b
a
Institute of Physical-Chemical Processes of National Research Council (IPCF), Pisa, e-mail:

matteoli@ipcf.cnr.it bIvanovo State University of Chemistry and Technology (ISUCT), Ivanovo,
e-mail: oxt@isuct.ru ...................................................................................................................... 61

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531
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isoldatov@mail.ru ......................................................................................................................... 72
532
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-2010
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.., .., ..
(), ., e-mail: htpngsamgtu@mail.ru ............................................................................................................................ 73
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Li2OZnONb2O5
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534
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-2010
.., .., ..
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(III) (III) -

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[ReOL4Cl]Cl2 2H2O, L-1--2-

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, 170002, , 35, e-mail:
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An investigation into the removal of SO2 from effluent streams: Novel approach to
minimize SO2 emission from potential Jordanian oil shale processing plant
Marwan M. Batiha
Chemical Engineering Department, Faculty of Engineering, Al-Hussein Bin Talal University,
Ma'an P.O.Box 20, Jordan. e-mail: mmbatiha@ahu.edu.jo ........................................................ 108

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kinterm@samgtu.ru ..................................................................................................................... 111

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536
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-2010
.., .., .., ..

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Pt/C .
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293, 310
454
54
259
376
405
358
135
237
485
260, 267
210
139
290
89, 168
136
203
284, 296
278
417
327, 508
106
256
403
106
28
416
321
261
206
262, 303
409
367
310
111
377
584
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..
..
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..
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..
..
..
..
..
..
..
..
..
..
..
..
..
..
..
..
..
..
XIII -
-2010
516
134
292
396
162
298, 299, 457
258
210, 211, 218
345
82, 147, 165,
313, 494
241
204
402
87, 91
290, 291
204
29, 139
242
150
516
346
88
285, 386
143, 146
137
202
473, 506
8
379
138, 152, 496
81
424
384
183, 201
378
425, 426
425, 426
379
481
..
..-.
..
..
..
..
..
..
..
..
..
..
..
..
..
..
..
..
..

..
..
..
..
..
..
..
..
..
..
..
..
..
..
..
..
..
..
..
504
83
107, 113, 123,
176, 400
427
200
253
263
60, 73
270
380, 381
380
367
455
137
97
433
110
161, 162
67, 68
169
279, 344
494
280
382
8
36
85
268, 317
287
325
325
274
111
73
334
291
159
276
456
585
..
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286, 287
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213
347
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236
112
205
193
159
205
113
264
51
158, 494
113
341
246
288
289
376
193
226
293
475
502
383
290, 291
322, 323
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384
473
370
394
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420
265
474, 479
359
110
..
..
..
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..
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..

..
..
..
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..
..
..
..
..
..
..
..
..
..
..
348
463
359
223
408
116, 157
278
142
153
349, 385
172
134, 349, 350,
385
54
224
206, 475
118
207
92
170
192
52
80, 328
42
387, 397
130, 155
283
139
96
208
52
209
54
184
118, 125
210, 211, 217,
218, 238
230
428
481
586
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..
..
..
..
..
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..
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..
..
..
..
..
..
..
- ..
..
..
..
XIII -
-2010
30
288, 308, 309
9, 197, 288,
289, 308, 309,
316
185
184, 384
194
506
53
351
402
361
210, 211, 217,
218
215
338, 484, 505
34
476
248
249
140
212
213
362
151
477
114
125
72
330
436, 437
140, 464
319
103
115
173
452
506
8
..
..
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..
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..
..
..
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..
..
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..
..
..
..
..
..
..
..
..
..
..
..
..
..
.
..
..
..
..
..
..
185, 233
331
399
119
132, 136
90
186, 205
357
210, 218
309
433
428
388, 389
478
293
322, 323
125
87, 91
292
407
417
324
487
437
86, 390
126
51, 370, 377,
395, 398, 401,
523, 524
352
113
293, 310
413
160
214
224
260
324
59, 294
75, 275
587
..
..
..
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215
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295
364
391
478
52, 397, 407,
415
206, 475
51
405
117
88
429
353
452
420
182
212
210, 211, 217,
218
171
266, 315
184
261
352, 392
312
115
141, 151, 153
141, 142
32
283
463
403
150, 354
354
296
297
393, 411
244, 245
..
..
..
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..
..
..
..
..
213
148
409
200
387
95
82, 494
216
54
267
170
72
56
355, 394
476, 507
430, 431
57
516
298, 299, 457
58
356, 363
395, 398
292
211, 217, 218
26
177
177
334
432
405
427
143
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301, 311
248
484
150
8
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433
588
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XIII -
-2010
172
147
298, 457
299, 509
137
149
300
441
45
325
244
246
200
301, 311
372
498
224
251
325
473
354
325
111, 144
280
222
410
135
278
179
302
92
163, 366
296, 478
357
269, 347, 357
490
26, 114
93
136
247, 396
..
..
..
..
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..
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..
..
..
..
..
340
127
507
175, 522
248
200
322, 323
123
261
93
93
276
20
330
365
66, 370
479
490
306
94
145
95
248
121
401
187
60
7
326
474, 479
208
397
384
387, 434
434
405
219
397, 407
350
327, 508
589
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..
..
..
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..
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..
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327, 508
298, 457, 509
188, 190, 195,
209
262, 303
220
510
11, 36
38
13
306
328
221
164
512
174, 221
173
173
280
304, 305, 458,
480
388, 389
174
8
428
413
62
192, 202, 248,
251
169
395, 398
210, 211, 217,
218, 238
31
296, 478
159
241
481
361
77
81, 129
..
..
..
..
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..
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..
..
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..
141, 142
483
483
307
206, 373, 475
222
75, 275
306
188, 190, 209
223
395
8
380, 381
112
416, 417
416, 417
399
163
338, 484, 505
330
43, 64
107, 400
35, 53, 62
284, 296
403
371, 406
32
32
461
146
226
459, 485
268, 317
272
33
486, 513
261
161
418
331
590
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..
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..
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..
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..
..
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..
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..
..
.
..
..
..
..
..
..
..
XIII -
-2010
487
128, 145
96
401
63
44
439
245
99
431
33
346, 361, 431
241
216
20
399
174
57
117
34, 64
97
367
182, 189, 230
331
232
286, 287
176
224
114
225
269
8
8
436, 437
226
358, 402
248
432
230
514
..
..
..
..
..
..
..
..
..
..
..
..
..
..
..
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..
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..
..
..
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..
..
..
.
..
..
..
..
..
..
..
..
..
..
270
368, 369, 396,
429
521
239
388, 389
226
403
488
271
63, 351
98, 100
264
444
444
359
332
404
58, 65
360
226
415
361
116, 157
190
116, 157
66
128, 145
272
160
132
219, 227, 250
153
80, 328
144
285, 386, 391
230
145
371
283
591
..
..
..
..
..
..
..
..
..
..
..
..
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..
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..
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..
..
..
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..
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..
..
.
.
..
..
..
..
..
..
325
460
84
95
212
168
323
447
354
366
438
305, 480
147, 159
239
241
109
65
152
273, 302
274
396
439
409
406
67, 68
378
191, 203
98
371, 375
228
78
249
252
252
440, 441
90, 169
90, 430, 431
366
442, 443
320
..
..
..
..
..
..
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..
..
..
..
..
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..
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.
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..
..
..
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.
405
173
460
109
263
74
141
304, 305, 458,
480
112
117
250
333
158
101
101
361
515
130
170
390
251
289, 308, 309
192, 509
150
423
406
117
174, 221
408, 523, 524
444
285, 386, 391
167
192
176
101, 336
225, 314
338, 484, 505
313
406
592
..
..
..
..
..
..
..
..
..
..
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..
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..
..
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..
..
..
..
..
..
..
..
..
..
..
..
..
..
..
..
..
..
..
..
XIII -
-2010
380, 381
445
116
362
515
319
489
190
496
102
116
94
148, 461
20
490
523, 524
382
356, 363
183, 201, 214,
228
22, 33, 69
438
439
369
56, 66
371
320
363
411
306
30
391
188, 190, 209,
219, 227, 250
158
364, 367, 420
293, 310
491
363
334
..
..
..
..
..
..
..
..
-
..
..
..
..
..
..
..
..
..
..
..
..
..
..
..
..
..
..
..
..
..
..
..
..
..
..
..
..
..
..
..
346
149
502
375, 383
134, 350
229
131
407
348, 404, 422
193
280
70, 71
284
194
9, 68, 492
301, 311, 408
89, 168
252
492
150
493
99
118
120
28
119
99
182
445
492
335
52
72
60, 73
336
365
120
409, 410
258
593
..
..
..
..
..
..
..
..
..
..
..
..
..
..
..
..
.
..
..
..
..
..
..
..
..
..
..
..
..
..
..
..
..
..
..
..
..
..
..
35, 53, 62
175
298, 457, 467
221
516
225
358
393, 411
115, 256
10, 285, 371,
375, 386
337
151
101
346
433
517
8
392
257
176
176
11, 36
11, 36
348, 362
356, 363
312
518
143, 146
462, 519
412
56, 58, 65, 66
313
230
12
295, 300, 463
300, 463
142, 410
253
314
..
..
..
..
..
..
..
..
..
..
..
..
..
..
..
..
..
..
..
..
..
..
..
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..
..
..
..
..
..
..
..
..
..
..
..
..
..
156
17
141, 142
312
130, 131
152
487
431
229
187
140, 464
242, 249, 498
74
416
37
198
139
415
292
112, 140, 149,
464, 466
13, 121
13, 121
465
348
494
122
121
153
153
64
231
418
202
338
38, 50, 61
338, 505
216, 421
33
314
594
..
..
..
..
..
..
..
..
..
..
..
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..
..
..
..
..
..
..
..
..
..
..
..
..
..
..
..
..
..
..
..
XIII -
-2010
446
429
158
282, 339
19
284
520
340
123
358
404
184, 384
315
235
120
316
39, 161, 162
117, 122, 124,
140, 149
271
142
200
40, 47, 76
75, 275
223
77
41
121
30
15, 17, 31, 44,
78
129
232
465, 500
42
43
257
415
72, 116
44, 155
..
..
..
..
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..
..
..
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..
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..
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..
..
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..
..
..
..
..
..
..
416, 417
239
264
200
168
242, 504, 521
422
414
182
507
297
352
495
156
57
418
465, 500
276
366
268, 317
466
194
322, 323
31
319
341
335
208, 223
447
333
91, 224
368
274
393
368
67
419
419
322, 323
235
595
..
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93, 340, 341

341
356
220
233
259
327
229
83
157
136
39
168
158, 159
101
376
196
38, 61, 459
125
199, 243
373
236, 237
191, 200, 203,
220, 243
126
331
127
102
160
192
193
103
177, 178
100
205
494
280
..
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365
496
219, 250
122
192
158, 159
427
375, 383
382
338
267
161, 162
364, 420
163
354
179
410
152, 496
92
279, 344
452
224
175, 522
171
239
164, 237
497
277, 297
238
296
20
498
82
163
151
98, 100
278

Tesis

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-

001. 8:278 (043.2)

Wroclaw University of Technology

[1] .., .. . 1968. . 42. . 1210.

..1, ..1, ..1, ..2,

POLYMER IMMOBILIZED ANALOGUES OF IONIC LIQUIDS

[1] Kiss Q. // Chem. Rev. 2001. V.101. 11. P. 3435-3456.

MATHEMATICAL MODELING OF THE RAPID EXPANTION OF

PdBr2 PPh3 HBr -1

[1] .., .., .., ... .

[1] . . . // . 71 (2001) 1452.

[1] .., .., .., .. //

HYDROTHRMAL SYNTHESIS METAL OXIDE NANOPARTICLES

Figure a, b. TEM images of CeyOx compound

Solid products of the synthesis were represented by a homogeneous mixture of

TRANSFORMATIONS OF MONOTERPENE EPOXIDES IN

Vorozhtsov Novosibirsk Institute of Organic Chemistry, Novosibirsk 630090,

The transformations of epoxides in composite supercritical solvents that

In the absence of water, thermolysis of -pinene epoxide in supercritical

The epoxide conversion and products distribution were dependent on the

University of Turin, Italy, e-mail: giuseppe.dellagatta@unito.it

.., .., .., ..

Institute of Physical-Chemical Processes of National Research Council

541. 572. 128 (043.2)

kC M PCO C 6 H10 T sOHC 6 H11OH

[1] .., .., ..

Mem(OH)Om + HSO3 Mem(OH)2Om1 + SO3

K D,L - (L) (w)

[M + ]w [LM + ]w [LM + A ]w Kex CM+ CL

[1] L.I. Zakharkin, N.A. Ogorodnikova // J.Organometal.Chem. 1968. v.12. p. 13.

.., .., .. - .: , 2009. 186 .

1, 2 11:1 (=330 ), 7:1 (=436 ) 5:1 3

[1] .., .., .. . // , 1977.

546. 264.,553. 682.

AN INVESTIGATION INTO THE REMOVAL OF SO2 FROM EFFLUENT

2008 09-11 2008 ., . , .73.

[1] . 5367106. 20.09.1993. Jerry D. Unruh, Wendell L. Pieper, Milo

[1] .. . .: , 2005. 288.

.., .., .., ..*,

.., .C., .., ..

Kat (AlCl3, ZnCl2, SnCl2, SnCl4, SbCl3).

= , ()NMe2, NMe2, CN.

[1] R. Monoz, J. B. Monton, M. C. Burguet, J. de la Torre. Separation and

547.261 : 547.262 : 544.473 039.63

[1] . 2312098 , 07 53/19, 07 51/215, 07 51/225.

(-300, -312, -313, , -150, -7120, -300, -140)

.., .., .., ..

661.715.7 + 661.719.2 + 542.973

SYNTHESIS OF CARBON NANOTUBES (CNTS) BY PYROLYSIS

[1] C. A. Tolman, Chem. Rev., 1977, vol. 77, 3, . 313 - 348

547.546 + 547.822.7 + 547.655.1 + 548.539.26

1, 3, 5 =, R=R1=H, R2= NO2, F3, CN, COOH; R=3, R1=H, R2=CN;

ROCH2(CF2CF2)nH + HCl + SO2

FeCl 2, EtOH + HCl

MeCln, EtOH + HCl

MeCln, EtOH + HCl

[1] WO 049556 C07C 303/32, C07C 67/03, C07C 67/08, C07C

.., .., .., .., ..,

ONHCCH 2O(CH2 CH 2O)75CH2 C NHC 18 H37

.., .., ..*,

.., .., .., .., ..,

.., .., .., ..*, ..***

.., .., ..**