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[7],

,
s-
, (III),
FeLCl (R 1=H; R2= C H 3).

|--
(F eL )20,
(III):

*2*

. , /(-
[8] .
2, .
S-
( I X II). 0,1 S-
100 0,1
.' 120200 .
0,1 Na2C 03 50 ,
,
-
. 7590%.
. 1.
-- ( ), (FeL )20 (X IIIX X V III).
FeCl3-6H20 (0,54 , 2 ) 20
-, 3 (18 ) .
,
2 s- 2
20 , -
. -
3,5 (27 ) .
,
-. 4080% .
. 2.
(FeL )20 FeLCl (H2L: R= H , R3=C H 3).
100 [--N1, -() ] ( ), FeLCl (R= H , R2= C H 3) [7] 10
5 20%-
10 .
. , 2
120 3. ~ 5 .
,
.
50 (54% ) .
, %: 51,46; 3,82; N 11,22.
C32H26Fe2Ne5S2
, %: 51,22; 3,49; N 11,20.
, -1: v (FeFe) 845; v (C = N ) 1580, [1600.
1745

S
)
NH,
CH =N N =C
"S R

, 1

R1

R2

2 5

'-

1 5 3 -1 5 4

II

- 3 7

150

III

- C 4H 9

12 2

IV

C0H 5

173

-7

1 4 4 -1 4 5

VI

W-C4H 9

1 3 6 -1 3 7

V II

Ci

2 5

1 5 1 -1 5 2

V III

K-C3H 7

1 4 3 -1 4 4

IX

-4 9

1 2 8 -1 2 9

2 5

1 5 3 -1 5 5

XI

W-C3 H 7

1 2 3 -1 2 4

X II

W-C4H 9

1 3 0 -1 3 2

v(C =N )

53,76
53,79
55,42
55,67
57,62
57,34
55,60
55,60
57,13
57,34
59,34
58,84
46,37
46,59
48,85
48,61
50,67
50,43
39.44
39,75
41,56
41,79
44.07
43,64

5,79
5,86

18,94
18,82
17,71
17,71
16,47
16,71
17,48
17,71
16.78
16,72
15.84
15,83
16.79
16.30
15.92
15.46
14.57
14,70
13.27
13.90
12,78
13,29
12,59
12,79

6 ,2 1

6,37
6,95
6,82
6,37
6,37
6,56
6,82
7.20
7.21
4.77
4.69
5.21
5.19
5,81
5,64
3.78
4.00
4.17
4.46
5.01
4,88

v(OH)

V(NH)

1640

3080

3200, 3430

1630

3070

3280, 3430

1640

3055

3200, 3420

1645

3070

3300, 3430

1650

3070

3305, 3400

1640

3040

3295, 3430

1630

3050

3280, 3460

1630

3070

3270, 3470

1620

3080

3270, 3470

1610

3100

3260, 3460

1640

3070

3300, 3410

1625

3070

3270, 3470

200 X III 20
10 2N 1 2,5 .
, ,
-.
30 (28% ) - .
; %: 47,10; 3,42; N 9,80; 1 9,47.
C16H13FeN30 2SCl
, %: . 47,73; 3,25; N 10,44; 1 8,80.

1600 -1.

v (F e Fe) ;

v (C = N )

1570,

--{[8--,14-()-0, , ]( I I I )} [(F eL )20]-2H 0


(R*=H,
R 2= C H 3). 1 Fe(C 1 0 4) 2 -1 0 H 2 0 20
, 2,5 .
1 s-
, 1 0,5 20 13,5 .
1746

R1

R2

X III

-49

XIV

II

2 5

25

XV

li-37

XVI

-49

-49

X V II*

X VIII

2 5

25

XIX

- 3 7

XX

-49

XXI

CI

XXII

25

2 5

X X III **

- 7

XXIV

CL

-49

XXV

W-C4H9OH,

XXVI

2 5

-49

XXVII

-3 7

2 5,

XXVIII **

' -49

-4 9,

1747

2 5

, -?-

51,22
52,15
52,45
53,65
53,62
54,00
54,69
54,32
54,55
54,62
54,69
55,26
55,69
56,76
56,64
43.53
43.27
44,93
44,56
46,96
46,35
46,51
46,90
36,49
36,06
37.27
37,33
38,45
38.54
40,18
40,60

3,89
3,49
3,84
3,88
4,52
4,25
4,41
4,59
4,77
5,04
4,74
4,59
4,95
4,91
5,28
5,21
2,69
2,50
3,25
2,86
4,21
4,08
3,52
3,52
2,38
2,08
2,69
2,40
2,97
2,69
3,59
0,7

, - 1
^. - .

11,12
11,20
10,79
10,76
10,04
10,42
10,44
10,07
9,96
9,54
9,58
10,07
9,07
9,74
8,66
9,43
9,18
9,46
8,52
9,17
8,22
8,11
8,21
8,60
7,73
7,88
7,39
7,68
7,18
7,49
7,14
6,77

' 2-.

Fe

14,79
14,88
13,90
14,30
13,94
13,85

13,05
12,95
12,18
12,58
10,33
10,77
10,23
10,48
10,09
10,21
9,04
8,99

850

1580, 1600

1,87 (299)

850

1580, 1600

1,78 (294)

830

1570, 1600

1,83 (298)

830

1575, 1600

1,89 (301)

830

1,69 (294)

820

1590, 1630
v(OH) 3370
1580, 1615

855

1575, 1610

1,80 (295)

850

1570, 1615

1,75 (295)

870

1580, 1600

1,93 (296)

840

1570, 1600

1,45 (292)

850

1,95 (296)

830

1580, 1600
v(OH) 3450
1580, 1610

1,79 (296)

820

1580, 1600

2,11 (289)

840

1570, 1590

2,13 (291)

850

1570, 1590
1570. 1590
v(OH) 3450

1,75 (298)

845

1,94 (295)

1,81 (295)

-
.
, %: 48,92; 3,36; N 10,61.
^ 2N(3 .>
, %: 48,87; 3,84; N 10,68.

,
, .
-
=16,449 (4), 6=17,785 (5), =14,275 (3) , ^=120,49, =1,498, , =
=1,451 /3 2 = 4 ^;
2{/.

(1)
(2)

8 (1)

8 (1) *

(2)
8 (2) *

0 ( 1)
0 ( 2)

16---------- 17

0 (3 )
0 (4 )
0 (5 )
N( 1 )

N(2)
N(3)
N(4)
N(5)

N(6)
(1)
(2)
(3)

(4)

-31

(5)
(6)
(7)
(8)
(9)
(10)

3279(1
939(1
3131(3
3337(1
783(3
1573(1
3976(4
3788(4
788(4
-5 4 (4
2054(3
3485(4
3420(5
3324(6
1187(5

1200(6
481(4
3618(6
3562(6
3309(7
1412(6
840(7
-3 6 (6
1472(5
1835(6
1930(6
1654 ((;

27-------- 28

. 1. [ () 20]-2 20

\
' ( )- 0/20-
412/. 3603
/ ^ 2 .
( 1 ) = 0,061,
-.

20 .

, 3 :1 .
. 1.
. 3. , -
.
! 75 I

.
= 2 ,8 2 8 ( ') 1,! .. (1 ..= 9,274-10-24 2)
[9].
1748

--


;




,
(

, ]
,
--

^;


(. 1




]
(\]

(104)

F e (l)
Fe(2)
S (l)
S (l) *
S(2)
5 (2) *
0 (1)
0 (2 )
0(3)
0 (4 )
0 (5 )
N (l)
N(2)
N(3)
N(4)
N(5)
N(6)
C (l)
C(2)
C(3)

(4)
C(5)
C(6)
C(7)
C(8)
C(9)
(10)

x/a

v/b

z/c

3279(1)
939(1)
3131(3)
3337(11)
783(3)
1573(14)
3976(4)
3788(4)
788(4)
-54(4)
2054(3)
3485(4)
3420(5)
3324(6)
1187(5)
1200(6)
481(4)
3618(6)
3562(6)
3309(7)
1412(6)
840(7)
-36(6)
1472(5)
1835(6)
1930(6)
1654(6)

1325(1)
154(1)
3495(3)
3931(9)
2658(2)
2743(14)
1296(4)
824(6)
-672(4)
-713(4)
601(4)
2489(4)
2164(4)
3037(5)
1021(4)
1797(5)
1009(4)
2690(5)
2042(5)
2862(6)
950(6)
1778(6)
889(5)
227(5)
298(6)
-357(6)
-1101 (6)

7513(1)
6820(1)
9134(3)
7569(13)
7127(3)
5381(20)
6448(4)
8335(4)
5872(5)
7566(4)
7371(4)
6914(5)
8622(5)
7484(6)
5714(5)
5935(6)
7254(3)
6029(7)
9490(7)
8380(8)
4846(7)
6738(8)
7989(7)
4494(6)
3592(7)
3229(7)
3743(7)

A tom

C(11)
C(12)
C(13)
(14)
(15)
C(16)
(17)
(18)
C(19)
(20)
(21)
(22)
(23)
(24)
(25)
(26)
(27)
(28)
(29)
(30)
(31)
(31) *
(32)
(32) *
0(1)
20 (2)

v/

1272(7)
1170(6)
-460(6)
-461(7)
-914(5)
-1328(6)
-1348(6)
-935(7)
3706(6)
3809(5)
3967(7)
4000(6)
3902(6)
3759(7)
3799(5)
3981(6)
4219(6)
4266(7)
4091(6)
3864(6)
2884(26)
2920(53)
1350(25)
1639(55)
1132(17)
4181(8)

-1212(5)
-546(6)
137(6)
-640(6)
-1359(6)
-1287(6)
-545(6)
144(6)
1377(5)
783(5)
159(6)
117(6)
702(6)
1306(6)
2228(5)
1555(5)
1177(6)
1440(6)
2098(6)
2488(6)
4171(20)
4223(40)
3484(21)
3427(41)
2694(9)
3889(12)

4611(7)
5033(6)
8558(7)
8326(6)
8933(7)
'9761(7)
9984(7)
9376(7)
9849(6)
9249(6)
9681(7)
10637(7)
11213(7)
10819(7)
5338(6)
5581(6)
4850(7)
3952(7)
3707(7)
4399(7)
8379(12)
8785(29)
6236(11)
6147(30)
3655(12)
1975(14)

* ,

(i-- (III) (F eL )20 (X IIIX X V III, . 2)



(III), S-
( I X II, . 1),
.
.
FeLCl(H 2L : R*=H, R2= C H 3),
2- S- Fem
[7], X I I I X X V III (. 2)

( 10,87).

, .
, [10],
-- .
X III
^: F e L C l^ (F eL )20 . -- FeLCl
- .

(. ).
X I I I X X V III -
. , ,
, , .
.

v(N H ) v(OH) (30003600 -1), v (C = N )
2060 ~
1749

( I X II,

, oi
N4 S-a,
:
N1


[10].
,

. 2. ]

(. 2
.
(
:
^ , 2= 3)

, ]
, , !
^


0 (5 )
0 ( 5 ) ( 2 )

1,'-( 1
,
^
;
-<

( I X II, [11]) .
33703450 -1 XVII, X X III X X V III
v(OH) ,
.
,
N4 S-,

N1 N4. X IIIX X V III
~850 ~\
'F e Fe
[10]. ,
, (1 -

. 2.

(. 2),
.
X I I I X X V III
X III, (F eL )20-2H 20 (H2L:
R4= H , R2= C H 3). ,
. ,
, ,
, , , [12].
(F eL )20
20 .
3,481
0 ( 5 ) . Fe Fe: F e ( l)
0 ( 5 ) F e (2) (5) =1,769 , F e ( l) 0 ( 5 ) F e ( 2 ) =156,4.
Fe Fe
, [13],
,/-()(81) [14, 15] , [10, 16].

(139174) Fe0.
- Fe 0,15 .

5,

.
.

0 ( 1 ) , 0 ( 2 ) , N (1),N (2)

II

0 ( 3 ) , 0 ( 4 ) , N (4),N (6)

III

(7 ), (8 ), (9 ) ,
(1 0 ), (1 1 ), (12)

IV

(1 3 ), (1 4 ), (15),
(16), (17), (18)

(19), (20), (21),


(22), (23), (24)

VI

(25), (26), (27),


(28), (29), (30)

V II

F e ( l),N (l),N ( 2 )

V III

Fe(2), N (4), N (6)

F e (l) (-0,6136), N(1) (-0,0459), N(2)


(0,0450), 0 (1 ) (0,0411), 0 (2 ) (-0,0402),
(1) (0,0382), (2) (0,3175), (19) (0,3122),
(20) (0,1235), (25) (-0,0243),
(26) (-0,0054)
Fe (2) (0,6102), N (4) (-0,0207), N (6) (0,0206),
(3) (0,0185), (4) (-0,0184), (4) (-0,2593),
(6) (-0,1746), (7) (-0,2020), (12) (-0,0411),
G(13) (-0,1698), (14) (-0,0999)
(7) (0,0089), (8) (-0,0104), (9) (0,0016),
(10) (0,0090), ( ) (-0,0100), (12) (0,0011),
(4) (0,0319), (3) (-0,0340), N (4) (0,2019),
Fe(2) (0,5948)
(13) (0,0172), (14) (0,0025), (15) (-0,0188),
( 16) (0,0159), (17) (0,0045), (18) (-0,0213).
(6) (0,0205), 0(4) (0,0065),N(6) (0,1503),
Fe(2) (0,6070)
(19) (-0,0012), (20) (-0,0032), (21) (0,0072),
(22) (-0,0066), (23) (0,0019), (24) (0,020),
(2) (0,0142), (2) (0,0239), N (2) (-0,0912),
Fe ( 1) (-0,4489)
(25) (-0,0028), (26) (-0,0009), (27) (0,0034),
(28) (-0,0022), (29) (-0,0017), (30) (0,0042),
(1) (0,0849), 0 (1 ) (0,0517), N(1) (0,0109),
F e (l) (-0,5741)
Fe (2) (-3,2640), (3) (-0,3578), N (3) (-0,3874),
S (1) (-0,7928), (31) (-1,3564)
F e (1) (3,4070), (5) (0,3996), N(5) (0,3942)
S (2) (0,8381), (32) (1,2973)

I
II
III
IV
V
VI
VII

II

III

IV

VI

VII

V III

29,41

22,63
6,80

29,31
3,87
7,33

9,09
34,55
28,13
35,36

1,04
29,59
22,79
29,34
9,95

21,33
27,05
23,12
29,72
17,59
22,32

14,68
21,14
15,30
19,24
23,49
14,11
29,12

-
[ 14].
-
, 1 [7], ,
1~ 2-.
2~,
( 0= 1 ,9 1 2 ) ( N =2,102 ).
. 4.
, 120 2, ^
-0,046
. , 20 2
(1) 0,614 , (2) 0,610
0 ( 5 ). , 1 ]20 2 .
'
.

(1) (2).
1752

1 N (1) N (3) =1,303


(1,407),
N (3) (3) =1,314 (1,281), N (2 ) (3) = 1,386 (1,394) ,
.
72,7 (72,4);
. 4. (3) S (1) =1,687 (1,709) S ( l) (31) =
=1,809 (1,805) ,
[7] 1,737 1,781 , S 103,7 (105,7).
L2- ,
180 , 0 (1 )0 (2 )N (3 )C (3 )
N (5 ) (5).
.
. 3 .
: *(3)S*(l) =
=1,585 (1,669); S * (l)1*(31) =2,030 (1,598) .
0 = 1 ,3 1 5 , N =1,304 , =1,416
, Salen [15, 16],
FeLCl [7].
(. 5).
, F e(2 ), , FeLCl
[7], . . N ^0,150
0,200 . F e (l)0 (2 )C (2 0 )C (1 9 )
(2 )N(2) N . VI
.
FeLCl
710 (. 5).

29.
.

. 2. -- . 20 ,
.
, ,
. , 20 ,
, 212
Salen [15, 16]. -,

, ,
, . 2.
, [7]
Fe111
S-.

(III).
. .
.

1.
2.
3.
4.
5.
6.

. . . : , 1980, . 51.
. . , ., 1982, 1, . 3.
. ., . . . . , 1982, . 27, 3, . 547.
. . . , 1970, . 39, 3, . 361.
. ., . . . , 1975, . 44, 2, . 260.
Synthetic m ultidentate macrocyclic compounds. Ed. Isatt R. ., Christensen J. J.
N. Y.: Academic Press, 1978.
7. . ., . ., J i . ., . ., . .
. . , 1982, . 27, 10, . 2551.
8. / . . .: , 1966,
. 607.

1
.

9. . ., . . .
. .: , 1980, . 276.
10. Murray . S. Coord. Chem Rev., 1974, v. 12, 1, p. 1.
11. . ., . ., . ., . .,
. . . , 1982, . 8, 2, . 141.
12. . ., Lalancette R. A., Potenza J. A., Schugar . J. J. Amer. Chem. Soc., 1978,
v. 100, 7, p. 2053.
13. Hoffman A. B., Collins D. ., Day V. W., Fleischer E. B., Srivastava T. S., Hoard J.L.
J. Amer. Chem. Soc., 1972, v. 94, 10, p. 3620.
14. Gerloch ., McKenzie E. D Towl A. D. C. J. Chem. Soc., A, 1969, 18, p. 2850.
15. JI. ., . ., . . . . 1970 N 3
. 557.
16. Gdzen S., Peters R., Owston P. G., Tasker P. A. J. Chem. Soc. Chem. Comm.. 1980,
24, p. 1199.



1754


2. VI.1982

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