2.

Hordes
HP
Location: Route 19 Encounter Rate: common Level: 24 EVs: 2 Atk per each Location: Route 5 Encounter Rate: common Level: 5 EVs: 1 HP per each or: In case its raining on Route 14 or 19, you cant use Sweet Scent and Honey to encounter hordes. Alternatively use:

Location: Connecting Cave Encounter Rate: common Level: 7 EVs: 1 HP per each

Location: Frost Cavern Encounter Rate: common Level: 20 EVs: 1 Atk per each

Defence

Attack
Location: Route 10 Encounter Rate: common Level: 11 EVs: 1 Def per each or:

Location: Route 14 Encounter Rate: common Level: 16 EVs: 1 Atk per each or:

/ Location: Route 18, Terminus Cave Encounter Rate: common/uncommon Level: 23/23 EVs: 1 Def per each/2 Def per each

Speed

Special Attack

Location: Frost Cavern Encounter Rate: Common Level: 20 EVs: 1 SpAtk per each Smoochum horde can be found in Frost Cavern as well. Its very rare, but the EV yield is the same as Vanillites, so you can just use them if you find them.

Location: Route 8 Encounter Rate: common Level: 9 EVs: 1 Speed per each Taillow horde can be found on Route 8 as well. Its very rare, but the EV yield is the same as Wingulls, so you can just use them if you find them. In case its raining on Route 8, you cant use Sweet Scent and Honey to encounter hordes. Alternatively, use:

Special Defence

Location: Route 7 Encounter Rate: common Level: 6 EVs: 1 SpDef per each

Location: Connecting Cave Encounter Rate: common Level: 8 EVs: 1 Speed per each