Академический Документы
Профессиональный Документы
Культура Документы
1. 2. 3.
cell
= E
cathode
E anode
E = E -
4. 5. 6. 7. 8. 9.
G = -nFEcell R=
0.059 1 log n+ (At 298 K) n [M ] 2.303RT [Anode ion] Ecell = Ecell log nF [Cathode ion] 0.059 Ecell = log K c (At 298 K) n
l 1 l = A A 1 R
Conductance:G =
1 1 l l = = ( ) =G R A A
m =
m
15. Kohlrauschs Law of independent migration of ions: If the limiting molar conductivity of the cations is denoted by o + and that of the anions by o then the limiting molar conductivity of electrolyte is:
0 0 m = + 0 + + v
Where v+ and v- are the number of cations and anions per formula of electrolyte. 16. Faraday constant: It is equal to 96487 C mol-1 or approximately equal to 96500 C mol-1.