Chng 5: HIROCACBON NO

Cu 1: Khi cho ankan X (83,72% khi lng cacbon trong phn t) tc dng vi clo theo t l mol 1:1
(trong iu kin chiu sng) ch thu c 2 dn xut monoclo ng phn ca nhau. Tn ca X l
A. butan
B. 2- metylpropan
C. 2,3-imetylbutan D. 3-metylpentan.
Cu 2: Khi brom ha mt ankan ch thu c mt dn xut monobrom duy nht c t khi hi i vi
hiro l 75,5. Tn ca ankan l
A. 2,2,3-trimetylpentan.
B. 2,2-imetylpropan. C. 3,3-imetylhexan.
D. isopentan.
Cu 3: t chy hon ton mt hirocacbon X thu c 0,11 mol CO 2 v 0,132 mol H2O. Khi X tc
dng vi kh clo (theo t l s mol 1:1) thu c mt sn phm hu c duy nht. Tn gi ca X l
A. 2-Metylbutan.
B. etan
C. 2,2-imetylpropan.
D. 2-Metylpropan.
Cu 4: Hirocacbon mch h X trong phn t ch cha lin kt v c hai nguyn t cacbon bc ba
trong mt phn t. t chy hon ton 1 th tch X sinh ra 6 th tch CO 2 ( cng iu kin nhit , p
sut). Khi cho X tc dng vi Cl2 (theo t l s mol 1 : 1), s dn xut monoclo ti a sinh ra l
A. 3
B. 4
C. 2
D. 5
Cu 5: Hn hp gm hirocacbon X v oxi c t l s mol tng ng l 1:10. t chy hon ton
hn hp trn thu c hn hp kh Y. Cho Y qua dung dch H2SO4 c, thu c hn hp kh Z c t
khi i vi hiro bng 19. Cng thc phn t ca X l
A. C3H8.
B. C3H6.
C. C4H8.
D. C3H4.
Cu 6: t chy hon ton mt th tch kh thin nhin gm metan, etan, propan bng oxi khng kh (trong
khng kh, oxi chim 20% th tch), thu c 7,84 lt kh CO2 ( ktc) v 9,9 gam nc. Th tch khng kh
( ktc) nh nht cn dng t chy hon ton lng kh thin nhin trn l
A. 70,0 lt.
B. 78,4 lt.
C. 84,0 lt.
D. 56,0 lt.
Cu 7: Cho isopentan tc dng vi Cl2 theo t l s mol 1 : 1, s sn phm monoclo ti a thu c l
A. 2.
B. 3.
C. 5.
D. 4.
Cu 8: Khi crackinh hon ton mt th tch ankan X thu c ba th tch hn hp Y (cc th tch
kh o cng iu kin nhit v p sut); t khi ca Y so vi H2 bng 12. CTPT ca X l
A. C6H14.
B. C3H8.
C. C4H10.
D. C5H12.
Cu 9: Cng thc n gin nht ca mt hirocacbon l CnH2n+1. Hirocacbon thuc dy ng
ng ca
A. ankan.
B. ankin.
C. ankaien.
D. anken.
Cu 10: t chy hon ton 20,0 ml hn hp X gm C3H6, CH4, CO (th tch CO gp hai ln th tch
CH4), thu c 24,0 ml CO2 (cc th tch kh o cng iu kin nhit v p sut). T khi ca X
so vi kh hiro l
A. 12,9.
B. 25,8.
C. 22,2.
D. 11,1.
Cu 11: Hirocacbon X khng lm mt mu dung dch brom nhit thng. Tn gi ca X l
A. xiclohexan.
B. xiclopropan.
C. stiren.
D. etilen.
Cu 12: (A 10) Trong s cc cht: C3H8, C3H7Cl, C3H8O v C3H9N; cht c nhiu ng phn cu to
nht l
A. C3H7Cl.
B. C3H8O.
C. C3H8.
D. C3H9N.
Cu 13: (A 10) t chy hon ton mt lng hirocacbon X. Hp th ton b sn phm chy vo
dung dch Ba(OH)2 (d) to ra 29,55 gam kt ta, dung dch sau phn ng c khi lng gim 19,35
gam so vi dung dch Ba(OH)2 ban u. Cng thc phn t ca X l
A. C3H4.
B. C2H6.
C. C3H6.
D. C3H8.
Cu 14: (C 10) t chay hoan toan 6,72 lit (ktc) hn hp gm hai hirocacbon X va Y (M Y > MX), thu
c 11,2 lit CO2 (ktc) va 10,8 gam H2O. Cng thc cua X la
A. C2H6
B. C2H4
C. CH4
D. C2H2
Cu 15: (B 12) Cho phng trnh ha hc : 2X + 2NaOH " 2CH4 + K2CO3 + Na2CO3
Cht X l
A. CH2(COOK)2
B. CH2(COONa)2
C. CH3COOK
D. CH3COONa
Cu 16: (C12) Nung mt lng butan trong bnh kn (c xc tc thch hp) thu c hn hp kh X gm
ankan v anken. T khi ca X so vi kh hiro l 21,75. Phn trm th tch ca butan trong X l
A. 33,33%
B. 50,00%
C. 66,67%
D. 25,00%
Chng 6: HIROCACBON KHNG NO
Cu 1: Hirat ha 2 anken ch to thnh 2 ancol. Hai anken l
1

A. eten v but-2-en. B. 2-metylpropen v but-1-en.

C. propen v but-2-en. D. eten v but-1-en.
Cu 2: Ba hirocacbon X, Y, Z l ng ng k tip, khi lng phn t ca Z bng 2 ln khi lng
phn t ca X. Cc cht X, Y, Z thuc dy ng ng
A. ankan
B. ankaien
C. anken
D. ankin
Cu 3: Dy gm cc cht c dng tng hp cao su Buna-S l:
A. CH2=C(CH3)-CH=CH2, C6H5CH=CH2.
B. CH2=CH-CH=CH2, C6H5CH=CH2.
C. CH2=CH-CH=CH2, CH3-CH=CH2.
D. CH2=CH-CH=CH2, lu hunh.
Cu 4: Cho cc cht sau: CH2=CH-CH2-CH2-CH=CH2, CH2=CH-CH=CH-CH2-CH3,
CH3-C(CH3)=CH-CH3, CH2=CH-CH2-CH=CH2. S cht c ng phn lp th l
A. 4.
B. 1.
C. 2.
D. 3.
Cu 5: Cho cc phn ng:
t0
HBr + C2H5OH
C2H4 + Br2

askt (1:1mol)
C2H4 + HBr
C2H6 + Br2
S phn ng to ra C2H5Br l
A. 4.
B. 3.
C. 2.
D. 1.
Cu 6: Hn hp kh X gm H2 v C2H4 c t khi so vi He l 3,75. Dn X qua Ni nung nng, thu
c hn hp kh Y c t khi so vi He l 5. Hiu sut ca phn ng hiro ho l
A. 20%.
B. 25%.
C. 50%.
D. 40
Cu 7: Cho cc cht: xiclobutan, 2-metylpropen, but-1-en, cis-but-2-en, 2-metylbut-2-en. Dy gm cc
o
cht sau khi phn ng vi H2 (d, xc tc Ni, t ), cho cng mt sn phm l:
A. xiclobutan, cis-but-2-en v but-1-en.
B. but-1-en, 2-metylpropen v cis-but-2-en.
C. xiclobutan, 2-metylbut-2-en v but-1-en.
D. 2-metylpropen, cis-but-2-en v xiclobutan.
Cu 8: Hn hp kh X gm H2 v mt anken c kh nng cng HBr cho sn phm hu c duy nht. T
khi ca X so vi H2 bng 9,1. un nng X c xc tc Ni, sau khi phn ng xy ra hon ton, thu c
hn hp kh Y khng lm mt mu nc brom; t khi ca Y so vi H2 bng 13. Cng thc cu to ca
anken l
C. CH2=CH-CH2-CH3. D. CH3-CH=CH-CH3.
A. CH2=C(CH3)2.
B. CH2=CH2.
Cu 9: Cho hirocacbon X phn ng vi brom (trong dung dch) theo t l mol 1 : 1, thu c cht hu
c Y (cha 74,08% Br v khi lng). Khi X phn ng vi HBr th thu c hai sn phm hu c
khc nhau. Tn gi ca X l
A. but-1-en.
B. xiclopropan.
C. but-2-en.
D. propilen.
Cu 10: Cho hn hp hai anken ng ng k tip nhau tc dng vi nc (c H2SO4 lm xc tc) thu
c hn hp Z gm hai ancol X v Y. t chy hon ton 1,06 gam hn hp Z sau hp th ton
b sn phm chy vo 2 lt dung dch NaOH 0,1M thu c dung dch T trong nng ca NaOH
bng 0,05M. Cng thc cu to thu gn ca X v Y l (Cho th tch dung dch thay i khng ng
k)
A. C4H9OH v C5H11OH. B. C3H7OH v C4H9OH. C. C2H5OH v C3H7OH. D. C2H5OH v C4H9OH.
Cu 11: Mt hirocacbon X cng hp vi axit HCl theo t l mol 1:1 to sn phm c thnh phn khi
lng clo l 45,223%. Cng thc phn t ca X l
A. C4H8.
B. C3H6.
C. C3H4.
D. C2H4.
Cu 12: Cho 4,48 lt hn hp X ( ktc) gm 2 hirocacbon mch h li t t qua bnh cha 1,4 lt dung
dch Br2 0,5M. Sau khi phn ng hon ton, s mol Br2 gim i mt na v khi lng bnh tng thm 6,7
gam. Cng thc phn t ca 2 hirocacbon l
A. C3H4 v C4H8.
B. C2H2 v C3H8.
C. C2H2 v C4H8.
D. C2H2 v C4H6.
Cu 13: un nng hn hp kh gm 0,06 mol C2H2 v 0,04 mol H2 vi xc tc Ni, sau mt thi gian thu
c hn hp kh Y. Dn ton b hn hp Y li t t qua bnh ng dung dch brom (d) th cn li
0,448 lt hn hp kh Z ( ktc) c t khi so vi O2 l 0,5. Khi lng bnh dung dch brom tng l
A. 1,04 gam.
B. 1,32 gam.
C. 1,64 gam.
D. 1,20 gam.
Cu 14: t chy hon ton 1 lt hn hp kh gm C 2H2 v hirocacbon X sinh ra 2 lt kh CO 2 v 2 lt
hi H2O (cc th tch kh v hi o cng iu kin nhit , p sut). Cng thc phn t ca X l
A. C2H6
B. C2H4
C. CH4
D. C3H8
Cu 15: Dn 1,68 lt hn hp kh X gm hai hirocacbon vo bnh ng dung dch brom (d). Sau khi
phn ng xy ra hon ton, c 4 gam brom phn ng v cn li 1,12 lt kh. Nu t chy hon ton
2

1,68 lt X th sinh ra 2,8 lt kh CO2. Cng thc phn t ca hai hirocacbon l (cc th tch kh u o
ktc).
A. CH4 v C2H4
B. CH4 v C3H4
C. CH4 v C3H6
D. C2H6 v C3H6
Cu 16: Ba hirocacbon X, Y, Z k tip nhau trong dy ng ng, trong khi lng phn t Z
gp i khi lng phn t X. t chy 0,1 mol cht Y, sn phm kh hp th hon ton vo dung
dch Ca(OH)2 (d), thu c s gam kt ta l
A. 20.
B. 40.
C. 30.
D. 10.
Cu 17: Dn V lt ( ktc) hn hp X gm axetilen v hiro i qua ng s ng bt niken nung
nng, thu c kh Y. Dn Y vo lng d AgNO3 trong dung dch NH3 thu c 12 gam kt ta.
Kh i ra khi dung dch phn ng va vi 16 gam brom v cn li kh Z. t chy hon ton kh
Z thu c 2,24 lt kh CO2 ( ktc) v 4,5 gam nc. Gi tr ca V bng
A. 11,2.
B. 13,44.
C. 5,60.
D. 8,96
Cu 18: Hn hp X c t khi so vi H2 l 21,2 gm propan, propen v propin. Khi t chy hon ton
0,1 mol X, tng khi lng ca CO2 v H2O thu c l
A. 18,60 gam.
B. 18,96 gam.
C. 20,40 gam.
D. 16,80 gam.
Cu 19: Cho s chuyn ha : CH4 C2H2 C2H3Cl PVC. tng hp 250 kg PVC theo s
3
trn th cn V m kh thin nhin ( ktc). Gi tr ca V l (bit CH4 chim 80% th tch kh thin
nhin v hiu sut ca c qu trnh l 50%)
A. 224,0.
B. 448,0.
C. 286,7.
D. 358,4.
Cu 20: t chy hon ton hn hp M gm mt ankan X v mt ankin Y, thu c s mol CO2
bng s mol H2O. Thnh phn phn trm v s mol ca X v Y trong hn hp M ln lt l
A. 75% v 25%.
B. 20% v 80%.
C. 35% v 65%.
D. 50% v 50%.
Cu 21: Hn hp kh X gm anken M v ankin N c cng s nguyn t cacbon trong phn t. Hn hp
X c khi lng 12,4 gam v th tch 6,72 lt ( ktc). S mol, cng thc phn t ca M v N ln lt l
A. 0,1 mol C2H4 v 0,2 mol C2H2.
B. 0,2 mol C2H4 v 0,1 mol C2H2.
C. 0,1 mol C3H6 v 0,2 mol C3H4.
D. 0,2 mol C3H6 v 0,1 mol C3H4.
Cu 22: Hn hp kh X gm 0,3 mol H2 v 0,1 mol vinylaxetilen. Nung X mt thi gian vi xc tc Ni
thu c hn hp kh Y c t khi so vi khng kh l 1. Nu cho ton b Y sc t t vo dung dch
brom (d) th c m gam brom tham gia phn ng. Gi tr ca m l
A. 16,0.
B. 3,2.
C. 8,0.
D. 32,0.
Cu 23: Cho hn hp X gm CH4, C2H4 v C2H2. Ly 8,6 gam X tc dng ht vi dung dch brom (d)
th khi lng brom phn ng l 48 gam. Mt khc, nu cho 13,44 lt ( ktc) hn hp kh X tc dng
vi lng d dung dch AgNO3 trong NH3, thu c 36 gam kt ta. Phn trm th tch ca CH4 c trong
X l
A. 20%.
B. 50%.
C. 25%.
D. 40%.
Cu 25: kh hon ton 200 ml dung dch KMnO 4 0,2M to thnh cht rn mu nu en cn V lt kh
C2H4 ( ktc). Gi tr ti thiu ca V l
A. 2,240.
B. 2,688.
C. 4,480.
D. 1,344.
Cu 26: (C 10) Cho 3,12 gam ankin X phn ng vi 0,1 mol H 2 (xc tc Pd/PbCO3, t0), thu c hn hp
Y ch c hai hirocacbon. Cng thc phn t ca X l
A. C2H2
B. C5H8
C. C4H6
D. C3H4
Cu 27: (A 10) un nng hn hp kh X gm 0,02 mol C2H2 v 0,03 mol H2 trong mt bnh kn
(xc tc Ni), thu c hn hp kh Y. Cho Y li t t vo bnh nc brom (d), sau khi kt thc cc
phn ng, khi lng bnh tng m gam v c 280 ml hn hp kh Z (ktc) thot ra. T khi ca Z so vi
H2 l 10,08. Gi tr ca m l
A. 0,328.
B. 0,205.
C. 0,585.
D. 0,620.
Cu 28: (B 10) Hn hp kh X gm mt ankan v mt anken. T khi ca X so vi H2 bng 11,25. t
chy hon ton 4,48 lt X, thu c 6,72 lt CO 2 (cc th tch kh o ktc). Cng thc ca ankan v
anken ln lt l
A. CH4 v C2H4.
B. C2H6 v C2H4.
C. CH4 v C3H6.
D. CH4 v C4H8.
0

+ H 2 ,t
xt,t
+Z
X
Y
Cao su buna N
Cu 29: (B 10) Cho s chuyn hoa sau: C 2 H 2
Pd,PbCO3
t 0 ,xt,p

Cac cht X, Y, Z ln lt la :
A. benzen; xiclohexan; amoniac
C. vinylaxetilen; buta-1,3-ien; stiren

B. axetanehit; ancol etylic; buta-1,3-ien

D. vinylaxetilen; buta-1,3-ien; acrilonitrin
3

Cu 30: (C 10) Cht no sau y c ng phn hnh hc?

A. But-2-in
B. But-2-en
C. 1,2-icloetan
D. 2-clopropen
Cu 31: (C 10) S lin tip (xch ma) c trong mi phn t: etilen; axetilen; buta-1,3-ien ln lt l
A. 3; 5; 9
B. 5; 3; 9
C. 4; 2; 6
D. 4; 3; 6
Cu 32: (A 1 1) Cho buta-1,3-ien phn ng cng vi Br2 theo t l mol 1:1. S dn xut ibrom (ng
phn cu to v ng phn hnh hc) thu c l
A. 2.
B. 3.
C. 4.
D. 1.
Cu 33: (A 1 1) Hn hp X gm C2H2 v H2 c cng s mol. Ly mt lng hn hp X cho qua cht
xc tc nung nng, thu c hn hp Y gm C2H4, C2H6, C2H2 v H2. Sc Y vo dung dch brom
(d) th khi lng bnh brom tng 10,8 gam v thot ra 4,48 lt hn hp kh (ktc) c t khi so vi H2
l 8. Th tch O2 (ktc) cn t chy hon ton hn hp Y l
A. 22,4 lt.
B. 26,88 lt.
C. 44,8 lt.
D. 33,6 lt.
Cu 34: (A 1 1) Cho 13,8 gam cht hu c X c cng thc phn t C7H8 tc dng vi mt lng d
dung dch AgNO3 trong NH3, thu c 45,9 gam kt ta. X c bao nhiu ng phn cu to tha mn
tnh cht trn?
A. 2.
B. 5.
C. 4.
D. 6.
Cu 35: (A 1 1) t chy hon ton hn hp X gm C2H2, C3H4 v C4H4 (s mol mi cht bng
nhau) thu c 0,09 mol CO2. Nu ly cng mt lng hn hp X nh trn tc dng vi mt lng
d dung dch AgNO3 trong NH3, th khi lng kt ta thu c ln hn 4 gam. Cng thc cu to ca
C3H4 v C4H4 trong X ln lt l:
A. CHC-CH3, CH2=C=C=CH2.
B. CH2=C=CH2, CH2=CH-CCH.
C. CHC-CH3, CH2=CH-CCH.
D. CH2=C=CH2, CH2=C=C=CH2.
Cu 36: (B 11) S ng phn cu to ca C5H10 phn ng c vi dung dch brom l
A. 8.
B. 7.
C. 9.
D. 5.
Cu 37: (B 11) Trong qu gc chn rt giu hm lng
A. vitamin A.
B. ete ca vitamin A. C. -caroten.
B. este ca vitamin A.
Cu 38: (B 11) Cho butan qua xc tc ( nhit cao) thu c hn hp X gm C4H10, C4H8, C4H6 v
H2. T khi ca X so vi butan l 0,4. Nu cho 0,6 mol X vo dung dch brom (d) th s mol brom ti a
phn ng l
A. 0,24 mol.
B. 0,36 mol.
C. 0,60 mol.
D. 0,48 mol.
Cu 39: (B 11) Hn hp kh X gm etilen, metan, propin v vinylaxetilen c t khi so vi H2 l 17.
t chy hon ton 0,05 mol hn hp X ri hp th ton b sn phm chy vo bnh dung dch Ca(OH)2
(d) th khi lng bnh tng thm m gam. Gi tr ca m l
A. 7,3.
B. 6,6.
C. 3,39.
D. 5,85.
Cu 40: (C 11) Cht no sau y c ng phn hnh hc?
A. CH2=CH-CH=CH2
B. CH3-CH=CH-CH=CH2
C. CH3-CH=C(CH3)2
D. CH2=CH-CH2-CH3
Cu 41: (A 12) Hn hp X gm H2 v C2H4 c t khi so vi H2 l 7,5. Dn X qua Ni nung nng, thu
c hn hp Y c t khi so vi H2 l 12,5. Hiu sut ca phn ng hiro ha l
A. 70%
B. 60%
C. 50%
D. 80%
Cu 42: (A 12) Hiro ha hon ton hirocacbon mch h X thu c isopentan. S cng thc cu to c
th c ca X l
A. 6.
B. 5.
C. 7.
D. 4.
Cu 43: (A 12) t chy hon ton 4,64 gam mt hirocacbon X (cht kh iu kin thng) ri em
ton b sn phm chy hp th ht vo bnh ng dung dch Ba(OH) 2. Sau cc phn ng thu c 39,4
gam kt ta v khi lng phn dung dch gim bt 19,912 gam. Cng thc phn t ca X l
A. C3H4.
B. CH4.
C. C2H4.
D. C4H10.
Cu 44: (B 12) Hirat ha 2-metylbut-2-en (iu kin nhit , xc tc thch hp) thu c sn phm
chnh l
A. 2-metybutan-2-ol
B. 3-metybutan-2-ol
C.3-metylbutan-1-ol D.2-metylbutan-3-ol
Cu 45: (B 12) Hn hp X gm 0,15 mol vinylaxetilen v 0,6 mol H 2. Nung nng hn hp X (xc tc Ni)
mt thi gian, thu c hn hp Y c t khi so vi H 2 bng 10. Dn hn hp Y qua dung dch Brom d,
sau khi phn ng xy ra hon ton, khi lng brom tham gia phn ng l
A. 0 gam
B. 24 gam
C. 8 gam
D. 16 gam
4

H , Pd / PbCO , t
H O , H SO , t
Cu 46: (B 12) Cho dy chuyn ha sau: CaC2 +HO X +

Y +
Z
Tn gi ca X v Z ln lt l:
A. axetilen v ancol etylic.
B. axetilen v etylen glicol.
C. etan v etanal
D. etilen v ancol etylic.
Cu 47: (B 12) t chy hon ton hn hp X gm hai hirocacbon (t l s mol 1 : 1) c cng thc n
gin nht khc nhau, thu c 2,2 gam CO2 v 0,9 gam H2O. Cc cht trong X l
A. mt ankan v mt ankin
B. hai ankaien
C. hai anken.
D. mt anken v mt ankin.
Cu 48: (C12) t chy hon ton hn hp X gm hai hirocacbon k tip nhau trong dy ng ng,
thu c 2,24 lt kh CO2 (ktc) v 3,24 gam H2O. Hai hirocacbon trong X l
A. C2H2 v C3H4.
B. C2H4 v C3H6.
C. CH4 v C2H6
D. C2H6 v C3H8
Chng 7: HIROCACBON THM
Cu 1: S ng phn hirocacbon thm ng vi cng thc phn t C8H10 l
A. 5.
B. 3.
C. 2.
D. 4.
Cu 2: (B 11) Cho cc pht biu sau:
(a) Khi t chy hon ton mt hirocacbon X bt k, nu thu c s mol CO2 bng s mol H2O
th X l anken.
(b) Trong thnh phn hp cht hu c nht thit phi c cacbon.
(c) Lin kt ho hc ch yu trong hp cht hu c l lin kt cng ho tr.
(d) Nhng hp cht hu c khc nhau c cng phn t khi l ng phn ca nhau.
(e) Phn ng hu c thng xy ra nhanh v khng theo mt hng nht nh.
(g) Hp cht C9H14BrCl c vng benzen trong phn t.
S pht biu ng l
A. 2.
B. 5.
C. 4.
D. 3.
Cu 3: (B 11) Cho phn ng: C6H5-CH=CH2+ KMnO4C6H5-COOK +K2CO3 + MnO2 +KOH+H2O.
Tng h s (nguyn, ti gin) tt c cc cht trong phng trnh ho hc ca phn ng trn l
A. 27.
B. 24.
C. 34.
D. 31.
Cu 4: (C 11) Cho cc cht: axetilen, vinylaxetilen, cumen, stiren, xiclohexan, xiclopropan v
xiclopentan. Trong cc cht trn, s cht phn ng uc vi dung dch brom l:
A. 4.
B. 3.
C. 5.
D. 6.
Cu 5: (C 11) Sn phm ch yu trong hn hp thu c khi cho toluen phn ng vi brom theo t l s
mol 1:1 (c mt bt st) l
A. o-bromtoluen v p-bromtoluen
B. benzyl bromua
C. p-bromtoluen v m-bromtoluen
D. o-bromtoluen v m-bromtoluen
Cu 6: (C 11) Cht X tc dng vi benzen (xt, t0) to thnh etylbenzen. Cht X l
2

A. CH4.

B. C2H2.

C. C2H4.

D. C2H6.

Cu 7: (A 12) Cho dy cc cht : cumen, stiren, isopren, xiclohexan, axetilen, benzen. S cht trong dy
lm mt mu dung dch brom l
A. 2
B. 3
C. 4
D. 5
Chng 8: DN XUT HALOGEN ANCOL PHENOL
Cu 1: Hp cht hu c X (phn t c vng benzen) c cng thc phn t l C 7H8O2, tc dng c vi
Na v vi NaOH. Bit rng khi cho X tc dng vi Na d, s mol H 2 thu c bng s mol X tham gia
phn ng v X ch tc dng c vi NaOH theo t l s mol 1:1. Cng thc cu to thu gn ca X l
A. C6H5CH(OH)2.
B. HOC6H4CH2OH. C. CH3C6H3(OH)2.
D. CH3OC6H4OH.
Cu 2: S cht ng vi cng thc phn t C 7H8O (l dn xut ca benzen) u tc dng c vi dung
dch NaOH l
A. 2.
B. 3.
C. 1.
D. 4.
Cu 3: Cho 15,6 gam hn hp hai ancol n chc, k tip nhau trong dy ng ng tc dng ht
vi 9,2 gam Na, thu c 24,5 gam cht rn. Hai ancol l
A. C3H5OH v C4H7OH.
B. C2H5OH v C3H7OH.
C. C3H7OH v C4H9OH.
D. CH3OH v C2H5OH.
Cu 4: Cho m gam tinh bt ln men thnh ancol etylic vi hiu sut 81%. Ton b lng
CO2 sinh ra c hp th hon ton vo dung dch Ca(OH)2, thu c 550 gam kt ta v dung dch
X. un k dung dch X thu thm c 100 gam kt ta. Gi tr ca m l
A. 550.
B. 810.
C. 650.
D. 750.
5

Cu 5: Khi tch nc t mt cht X c cng thc phn t C4H10O to thnh ba anken l ng phn
ca nhau (tnh c ng phn lp th). Cng thc cu to thu gn ca X l
A. (CH3)3COH.
B. CH3OCH2CH2CH3. C. CH3CH(OH)CH2CH3. D. CH3CH(CH3)CH2OH.
Cu 6: Cc ng phn ng vi cng thc phn t C8H10O (u l dn xut ca benzen) c tnh cht:
tch nc thu c sn phm c th trng hp to polime, khng tc dng c vi NaOH. S lng
ng phn ng vi cng thc phn t C8H10O, tho mn tnh cht trn l
A. 2.
B. 4.
C. 3.
D. 1.
Cu 7: X l mt ancol no, mch h. t chy hon ton 0,05 mol X cn 5,6 gam oxi, thu
c hi nc v 6,6 gam CO2. Cng thc ca X l
A. C3H5(OH)3.
B. C3H6(OH)2.
C. C2H4(OH)2.
D. C3H7OH.
Cu 8: Trong mt bnh kn cha hi cht hu c X (c dng CnH2nO2) mch h v O2 (s mol O2
o
gp i s mol cn cho phn ng chy) 139,9 C, p sut trong bnh l 0,8 atm. t chy hon ton
X sau a v nhit ban u, p sut trong bnh lc ny l 0,95 atm. X c cng thc phn t l
A. C4H8O2.
B. C3H6O2.
C. CH2O2.
D. C2H4 O2.
Cu 9: Cho m gam mt ancol no, n chc X qua bnh ng CuO (d), nung nng. Sau khi phn ng
hon ton, khi lng cht rn trong bnh gim 0,32 gam. Hn hp hi thu c c t khi
i vi hiro l 15,5. Gi tr ca m l
A. 0,92.
B. 0,32.
C. 0,64.
D. 0,46.
Cu 10: Dy gm cc cht u phn ng vi phenol l:
A. dung dch NaCl, dung dch NaOH, kim loi Na. B. nc brom, axit axetic, dung dch NaOH.
C. nc brom, anhirit axetic, dung dch NaOH.
D. nc brom, anehit axetic, dung dch NaOH.
Cu 11: Cho cc cht sau: phenol, etanol, axit axetic, natri phenolat, natri hiroxit. S cp cht tc
dng c vi nhau l
A. 4.
B. 3.
C. 2.
D. 1.
Cu 12: t chy hon ton mt ancol X thu c CO2 v H2O c t l s mol tng ng l 3 : 4.
Th tch kh oxi cn dng t chy X bng 1,5 ln th tch kh CO2 thu c ( cng iu kin). Cng
thc phn t ca X l
A. C3H8O3.
B. C3H4O.
C. C3H8O2.
D. C3H8O.
Cu 13: t chy hon ton 0,2 mol mt ancol X no, mch h cn va 17,92 lt kh O 2 ( ktc). Mt
khc, nu cho 0,1 mol X tc dng va vi m gam Cu(OH) 2 th to thnh dung dch c mu xanh lam.
Gi tr ca m v tn gi ca X tng ng l
A. 4,9 v glixerol. B. 4,9 v propan-1,2-iol.
C. 4,9 v propan-1,3-iol. D. 9,8 v propan-1,2-iol
Cu 14: C bao nhiu ancol bc 2, no, n chc, mch h l ng phn cu to ca nhau m phn t
ca chng c phn trm khi lng cacbon bng 68,18%?
A. 2.
B. 3.
C. 4.
D. 5.
Cu 15: Cho cc cht c cng thc cu to nh sau: HOCH2-CH2OH (X); HOCH2-CH2-CH2OH (Y);
HOCH2-CHOH-CH2OH (Z); CH3-CH2-O-CH2-CH3 (R); CH3-CHOH-CH2OH (T). Nhng cht tc dng
c vi Cu(OH)2 to thnh dung dch mu xanh lam l
A. X, Y, R, T.
B. X, Z, T.
C. Z, R, T.
D. X, Y, Z, T.
Cu 16: Khi thc hin phn ng tch nc i vi ancol X, ch thu c mt anken duy nht.
Oxi ho hon ton mt lng cht X thu c 5,6 lt CO2 ( ktc) v 5,4 gam nc. C bao nhiu
cng thc cu to ph hp vi X?
A. 5.
B. 4.
C. 3.
D. 2.
Cu 17: Cho m gam hn hp X gm hai ancol no, n chc, k tip nhau trong dy ng ng
tc dng vi CuO (d) nung nng, thu c mt hn hp rn Z v mt hn hp hi Y (c t khi hi
so vi H2 l 13,75). Cho ton b Y phn ng vi mt lng d AgNO3 trong dung dch NH3 un nng,
sinh ra 64,8 gam Ag. Gi tr ca m l
A. 7,8.
B. 7,4.
C. 9,2.
D. 8,8.
Cu 18: Khi tch nc t ancol 3-metylbutan-2-ol sn phm chnh thu c l
A. 2-metylbut-3-en.
B. 3-metylbut-2-en.
C. 3-metylbut-1-en.
D. 2-metylbut-2-en.
Cu 19: un nng
hn hp gm hai ancol n chc, mch h, k tip nhau trong dy ng ng vi
o
H2SO4 c 140 C. Sau khi cc phn ng kt thc, thu c 6 gam hn hp gm ba ete v 1,8 gam
nc. Cng thc phn t ca hai ancol trn l
A. CH3OH v C2H5OH. B. C2H5OH v C3H7OH. C. C3H5OH v C4H7OH. D. C3H7OH v C4H9OH.
Cu 20: Khi lng ca tinh bt cn dng trong qu trnh ln men to thnh 5 lt ancol
6

etylic 46 l (bit hiu sut ca c qu trnh l 72% v khi lng ring ca ancol etylic nguyn cht l
0,8 g/ml)
A. 5,4 kg.
B. 5,0 kg.
C. 6,0 kg.
D. 4,5 kg.
Cu 21: un nng mt ancol n chc X vi dung dch H2SO4 c trong iu kin nhit
thch hp sinh ra cht hu c Y, t khi hi ca X so vi Y l 1,6428. Cng thc phn t ca X l
A. C3H8O.
B. C2H6O.
C. CH4O.
D. C4H8O.
Cu 22: nh hng ca nhm OH n gc C6H5 trong phenol th hin qua phn ng gia phenol vi
A. dung dch NaOH. B. Na kim loi.
C. nc Br2.
D. H2 (Ni, nung nng).
Cu 23: Cho dy cc cht: CH4, C2H2, C2H4, C2H5OH, CH2=CH-COOH, C6H5OH (phenol), C6H6
(benzen). S cht trong dy phn ng c vi nc brom l
A. 6.
B. 8.
C. 4.
D. 5.
o
Cu 24: Khi un nng hn hp ancol gm CH3OH v C2H5OH (xc tc H2SO4 c, 140 C) th s ete
thu c ti a l
A. 4.
B. 2.
C. 1.
D. 3.
Cu 25: t chy hon ton hn hp M gm hai ancol X v Y l ng ng k tip ca nhau, thu c
0,3 mol CO2 v 0,425 mol H2O. Mt khc, cho 0,25 mol hn hp M tc dng vi Na (d), thu c cha
n 0,15 mol H2. Cng thc phn t ca X, Y l:
A. C2H6O2, C3H8O2. B. C2H6O, CH4O.
C. C3H6O, C4H8O.
D. C2H6O, C3H8O.
Cu 26: t chy hon ton mt ancol a chc, mch h X, thu c H2O v CO2 vi t l s mol tng
ng l 3:2. Cng thc phn t ca X l
A. C2H6O2.
B. C2H6O.
C. C3H8O2.
D. C4H10O2.
Cu 27: Oxi ho ancol n chc X bng CuO (un nng), sinh ra mt sn phm hu c duy nht l
xeton Y (t khi hi ca Y so vi kh hiro bng 29). Cng thc cu to ca X l
C. CH3-CO-CH3.
D. CH3-CH2-CH2-OH.
A. CH3-CHOH-CH3.
B. CH3-CH2-CHOH-CH3.
Cu 28: un nng 6,0 gam CH3COOH vi 6,0 gam C2H5OH (c H2SO4 lm xc tc, hiu sut phn
ng este ho bng 50%). Khi lng este to thnh l
A. 6,0 gam.
B. 4,4 gam.
C. 8,8 gam.
D. 5,2 gam.
Cu 29: Khi phn tch thnh phn mt ancol n chc X th thu c kt qu: tng khi lng ca
cacbon v hiro gp 3,625 ln khi lng oxi. S ng phn ancol ng vi cng thc phn t ca X l
A. 3.
B. 4.
C. 2.
D. 1.
Cu 30: Hp cht hu c X tc dng c vi dung dch NaOH v dung dch brom nhng khng tc
dng vi dung dch NaHCO3. Tn gi ca X l
A. axit acrylic.
B. anilin.
C. metyl axetat.
D. phenol.
Cu 31: Cho hn hp X gm hai ancol a chc, mch h, thuc cng dy ng ng. t chy hon ton
hn hp X, thu c CO2 v H2O c t l mol tng ng l 3 : 4. Hai ancol l
A. C2H5OH v C4H9OH.
B. C2H4(OH)2 v C3H6(OH)2.
C. C3H5(OH)3 v C4H7(OH)3.
D. C2H4(OH)2 v C4H8(OH)2.
Cu 32: un nng hn hp hai ancol n chc, mch h vi H 2SO4 c, thu c hn hp gm cc ete.
Ly 7,2 gam mt trong cc ete em t chy hon ton, thu c 8,96 lt kh CO 2 ( ktc) v 7,2 gam
H2O. Hai ancol l
A. CH3OH v C3H7OH.
B. C2H5OH v CH3OH.
C. C2H5OH v CH2=CH-CH2-OH.
D. CH3OH v CH2=CH-CH2-OH.
Cu 33: Mt hp cht X cha ba nguyn t C, H, O c t l khi lng mC : mH : mO = 21 : 2 : 4. Hp
cht X c cng thc n gin nht trng vi cng thc phn t. S ng phn cu to thuc loi hp cht
thm ng vi cng thc phn t ca X l
A. 4.
B. 3.
C. 6.
D. 5.
Cu 34: t chy hon ton m gam ancol no n chc mch h, sau phn ng thu c 13,2 gam CO2
v 8,1 gam nc. Cng thc ca ancol l
A. C3H7OH.
B. C2H5OH.
C. CH3OH.
D. C4H9OH.
Cu 35: C 3 cht lng ring bit : ancol etylic, glixerol v phenol. Dng ho cht no sau y phn
bit 3 cht lng ?
A. Natri v dung dch Br2.
B. dung dch Br2 v Cu(OH)2.
C. dung dch NaOH v Cu(OH)2.
D. Natri v Cu(OH)2.
7

Cu 36: un nng metanol vi H2SO4 c 1400C thu c sn phm chnh l

A. C2H5OSO3H.
B. C2H4.
C. C2H5OC2H5.
D. CH3OCH3.
Cu 37: S ng phn ancol ca C3H7OH l
A. 1.
B. 2.
C. 3.
D. 4.
Cu 38: Cho 3,00 gam mt ancol X no, n chc, mch h tc dng vi natri d thy c 0,56 lt kh thot
ra ( ktc). Cng thc phn t ca X l
A. C2H6O.
B. C3H8O.
C. C4H10O.
D. C5H12O.
Cu 39: Th tch kh H2 thu c ( ktc) khi cho 0,46 gam Na phn ng ht vi ancol etylic l
A. 0,672 lt.
B. 0,560 lt.
C. 0,112 lt.
D. 0,224 lt.
Cu 40: Mt ancol n chc A c cng thc phn t l C4H10O. Oxi ho A to ra anehit, tch nc to
anken mch khng nhnh. Cng thc cu to ca A l
A. CH3CH2CH2CH2OH.
B. CH3CHOHCH2CH3. C. (CH3)2CHCH2OH.
D. (CH3)3COH.
0
Cu 41: Khi un nng butan-1-ol vi H2SO4 c 180 C th s anken khc loi thu c l
A. 4.
B. 1.
C. 2.
D. 3.
Cu 42: Hai ancol X, Y u c cng thc phn t C3H8O. Khi un hn hp gm X v Y vi H2SO4 c
nhit cao tch nc, thu c
A. 3 anken.
B. 2 anken.
C. 4 anken.
D. 1 anken.
Cu 43: Ch dng Cu(OH)2 ta c th phn bit c 2 cht lng
A. etanol v propan-1-ol.
B. etanol v glixerol. C. etanol v phenol. D. Phenol v 4-metyl phenol.
Cu 44: Thuc th dng phn bit gia axit axetic v ancol etylic l
A. kim loi Na.
B. qu tm.
C. dung dch NaNO3.
D. dung dch NaCl.
Cu 45: Cho 9,2 gam ancol etylic phn ng va vi Na, sau phn ng thu c V lt kh H2 ( ktc).
Gi tr V l
A. 4,48.
B. 1,12.
C. 3,36.
D. 2,24.
Cu 46: Glixerol to c dung dch mu xanh lam khi phn ng vi
A. CuO.
B. CuCl2.
C. C2H5OH.
D. Cu(OH)2.
Cu 47: Ancol etylic phn ng c vi
A. axit bromhiric.
B. benzen.
C. ietyl ete.
D. etyl axetat.
Cu 48: t chy hon ton 6,0 gam hp cht hu c X c 6,72 lt CO2 ( ktc) v 7,2 gam nc.
Cng thc phn t ca X l
A. C3H8O.
B. C3H8.
C. C2H4O2.
D. C3H6.
Cu 49: Tch nc ancol X thu c olefin Y duy nht l cht kh iu kin thng. Y tc dng vi
nc ch thu c X duy nht. Tn ca X l
A. propan-2-ol.
B. etanol.
C. 2-metylpropan-1-ol. D. propan-1-ol.
Cu 50: Glixerol khc vi ancol etylic phn ng
A. vi Na.
B. este ha.
C. vi Cu(OH)2.
D. vi HBr.
Cu 51: Cho 11 gam hn hp 2 ancol n chc vo bnh ng Na d thy thot ra 3,36 lt H2 ( ktc).
Nu cho hn hp ancol vo dung dch H2SO4 c 1400C thu c m gam ete (hiu sut phn ng t
80%). Gi tr ca m l
A. 8,8.
B. 8,3.
C. 6,64.
D. 4,4.
Cu 52: Cht c kh nng phn ng vi dung dch NaOH un nng l
A. anilin.
B. benzyl clorua.
C. Ancol benzylic.
D. ancol etylic.
Cu 53: phn bit glixerol v ancol etylic trong 2 l mt nhn cn dng
A. dung dch NaOH.
B. Na.
C. Cu(OH)2.
D. nc brom.
Cu 54: Cho Na tc dng vi 18,8 gam hn hp 2 ancol no, n chc l ng ng k tip nhau sinh ra
5,6 lt H2 ( ktc). Tn ca 2 ancol l
A. metanol, etanol.
B. etanol, propan-1-ol.
C. etanol, propan-2-ol.
D. butanol, propan-2-ol.
Cu 55: Khi lng benzen cn dng iu ch c 94 gam phenol (hiu sut phn ng 80%) l
A. 62,4 gam.
B. 78 gam.
C. 39 gam.
D. 97,5 gam.
Cu 56: Cho 9,2 gam ancol X tc dng vi Na d thu c 3,36 lt H2 ( ktc). Cng thc ca X l
A. CH3OH.
B. HOCH2CH2OH.
C. C3H6(OH)2.
D. C3H5(OH)3.
Cu 57: Cho Na d vo 100 ml cn 460 (khi lng ring ca ancol etylic l 0,8 g/ml). Th tch H2 bay ra
( ktc) l
A. 40,32 lt.
B. 42,56 lt.
C. 4,48 lt.
D. 22,4 lt.
Cu 58: X, Y, Z l 3 cht hu c cng chc c cng thc phn t l : CH4O, C2H6O v C3H8O3. Phn t
X, Y, Z c cha chc
8

A. ete.
B. ancol.
C. anehit.
D. xeton.
Cu 59: t chy hon ton 0,1 mol hp cht hu c X cn 0,2 mol O2 v thu c 0,2 mol CO2 v 0,2
mol H2O. Cng thc phn t ca X l
A. C2H4.
B. C2H4O.
C. C2H4O2.
D. C2H4O3.
Cu 60: Chn mnh ng.
A. Ancol etylic c nhit si cao hn imetyl ete.
B. imetyl ete c nhit si cao hn ancol etylic.
C. Nhit si ca ancol etylic v ca imetyl ete bng nhau.
D. Ancol etylic v imetyl ete u si O0C.
Cu 61: un hn hp 3 ancol no, n chc vi H2SO4 c 1400C th s ete thu c l
A. 3.
B. 4.
C. 5.
D. 6.
Cu 62: Phenol tan c trong
A. nc lnh.
B. dung dch NaOH.
C. dung dch brom.
D. dung dch HCl.
Cu 63: nhn ra ancol etylic c ln mt t nc, ngi ta thng dng
A. dung dch CuSO4.
B. CuSO4 khan.
C. mt t Na.
D. H2SO4 c.
Cu 64: Cho ancol a chc X c dng R(OH)n. Bit 1 mol X tc dng vi Na d, gii phng 33,6 lt kh
( ktc). Gi tr ca n l
A. 2.
B. 3.
C. 4.
D. 5.
Cu 65: Thuc th duy nht nhn bit 3 cht lng ng trong 3 l mt nhn: phenol, stiren, ancol
benzylic l
A. Na.
B. qu tm.
C. dung dch KMnO4.
D. dung dch Br2.
Cu 66: Dn hn hp gm hi ancol C4H10O v khng kh qua ng ng bt Cu nung nng thu c
anehit tng ng. Cng thc cu to ca ancol l
A. CH3CH2CH2CH2OH.
B. CH3CHOHCH2CH3.
C. (CH3)2CHCH2OH.
D. CH3CH2CH2CH2OH v (CH3)2CHCH2OH.
Cu 67: Hp cht X c cng thc phn t C4H10O. X tc dng vi natri sinh ra cht kh. Khi un X vi
H2SO4 c, sinh ra hn hp 2 anken ng phn cu to ca nhau. Tn ca X l
A. butan-1-ol.
B. 2-metylpropan-1-ol. C. 2-metylpropan-2-ol. D. butan-2-ol.
Cu 68: Cho 5,8 gam mt ancol n chc tc dng vi Na va thu c m gam mui (ancolat) v
1,12 lt H2(ktc). Gi tr ca m l
A. 8,1 gam.
B. 7,9 gam.
C. 8,2 gam.
D. 8,0 gam.
Cu 69: Ancol etylic v phenol lng u phn ng vi
A. Na.
B. nc Br2.
C. dd Na2CO3.
D. dd NaOH.
Cu 70: Cht X c cng thc C7H8O c bao nhiu ng phn tc dng c vi NaOH:
A. 1.
B. 2.
C. 3.
D. 4.
Cu 71: (A 10) Trong s cc pht biu sau v phenol (C6H5OH):
(1) Phenol tan t trong nc nhng tan nhiu trong dung dch HCl.
(2) Phenol c tnh axit, dung dch phenol khng lm i mu qu tm.
(3) Phenol dng sn xut keo dn, cht dit nm mc.
(4) Phenol tham gia phn ng th brom v th nitro d hn benzen. Cc pht biu ng l:
A. (1), (2), (4).
B. (2), (3), (4).
C. (1), (2), (3).
D. (1), (3), (4).
Cu 72: (A 10) t chy hon ton m gam hn hp 3 ancol n chc, thuc cng dy ng ng, thu
c 3,808 lt kh CO2 (ktc) v 5,4 gam H2O. Gi tr ca m l
A. 4,72.
B. 5,42.
C. 7,42.
D. 5,72.
Cu 73: (A 10) Anken X hp nc to thnh 3-etylpentan-3-ol. Tn ca X l
A. 3-etylpent-3-en. B. 2-etylpent-2-en.
C. 3-etylpent-2-en.
D. 3-etylpent-1-en.
Cu 74: (A 10) Tch nc hn hp gm ancol etylic v ancol Y ch to ra 2 anken. t chy cng s
mol mi ancol th lng nc sinh ra t ancol ny bng 5/3 ln lng nc sinh ra t ancol kia. Ancol Y
l
A. CH3-CH2-CH(OH)-CH3.
B. CH3-CH2-CH2-CH2-OH.
C. CH3-CH2-CH2-OH.
D. CH3-CH(OH)-CH3.
Cu 75: (B 10) Cho 13,74 gam 2,4,6-trinitrophenol vo bnh kn ri nung nng nhit cao. Sau khi
phn ng xy ra hon ton, thu c x mol hn hp kh gm: CO2, CO, N2 v H2. Gi tr ca x l
A. 0,60.
B. 0,36.
C. 0,54.
D. 0,45.

Cu 76: (B 10) t chay hoan toan mt lng hn hp X gm 2 ancol (u no, a chc, mach h, co
cung s nhom -OH) cn va u V lit khi O2, thu c 11,2 lit khi CO2 v 12,6 gam H2O (cac th tich khi
o ktc). Gia tri cua V la
A. 14,56
B. 15,68
C. 11,20
D. 4,48
Cu 77: (B 10) Phat biu nao sau y ung?
A. Khi un C2H5Br vi dung dich KOH chi thu c etilen
B. Dung dich phenol lam phenolphtalein khng mau chuyn thanh mau hng
C. Day cac cht : C2H5Cl, C2H5Br, C2H5I co nhit si tng dn t trai sang phai
D. un ancol etylic 1400C (xuc tac H2SO4 c) thu c imetyl ete
Cu 78: (B 10) Co bao nhiu cht hu c mach h dung iu ch 4-metylpentan-2-ol chi bng phan
ng cng H2 (xuc tac Ni, t0)?
A. 3
B. 5
C. 2
D. 4
Cu 79: (B 10) Cho cac cht : (1) axit picric; (2) cumen; (3) xiclohexanol; (4) 1,2-ihiroxi-4metylbenzen; (5) 4-metylphenol; (6) -naphtol. Cac cht thuc loai phenol la:
A. (1), (3), (5), (6)
B. (1), (2), (4), (6)
C. (1), (2), (4), (5)
D. (1), (4), (5), (6)
+ H 2O
+ Br2
+ CuO
X
Y
Z
Cu 80: (B 10) Cho s phn ng: Stiren
H + ,t 0
t0
H+
Trong X, Y, Z u l cc sn phm chnh. Cng thc ca X, Y, Z ln lt l:
A. C6H5CHOHCH3, C6H5COCH3, C6H5COCH2Br.
B. C6H5CH2CH2OH, C6H5CH2CHO, C6H5CH2COOH.
C. C6H5CH2CH2OH, C6H5CH2CHO, m-BrC6H4CH2COOH
D. C6H5CHOHCH3, C6H5COCH3, m-BrC6H4COCH3.
Cu 81: (B 10) t chy han tan m gam hn hp X gm ba ancol (n chc, thuc cng dy ng
ng), thu c 8,96 lt kh CO2 (ktc) v 11,7 gam H2O. Mt khc, nu un nng m gam X vi H2SO4
c th tng khi lng ete ti a thu c l
A. 7,85 gam.
B. 7,40 gam.
C. 6,50 gam.
D. 5,60 gam.
0
Cu 82: (C 10) Cho 10 ml dung dich ancol etylic 46 phan ng ht vi kim lai Na (d), thu c V lit khi
H2 (ktc). Bit khi lng ring cua ancol etylic nguyn cht bng 0,8 g/ml. Gia tri cua V la
A. 4,256
B. 0,896
C. 3,360
D. 2,128
Cu 83: (C 10) Oxi ho khng hon ton ancol isopropylic bng CuO nung nng, thu c cht hu c
X. Tn gi ca X l
A. metyl phenyl xeton B. propanal
C. metyl vinyl xeton D. imetyl xeton
Cu 84: (C 10) Cho 4,6 gam mt ancol no, n chc phn ng vi CuO nung nng, thu c 6,2 gam
hn hp X gm anehit, nc v ancol d. Cho ton b lng hn hp X phn ng hon ton vi lng
d dung dch AgNO3 trong NH3, un nng, thu c m gam Ag. Gi tr ca m l
A. 16,2
B. 43,2
C. 10,8
D. 21,6
Cu 85: (C 10) Kh nng phn ng th nguyn t clo bng nhm OH ca cc cht c xp theo chiu
tng dn t tri sang phi l:
A. anlyl clorua, phenyl clorua, propyl clorua
B. anlyl clorua, propyl clorua, phenyl clorua
C. phenyl clorua, anlyl clorua, propyl clorua
D. phenyl clorua, propyl clorua, anlyl clorua
+ Br2 (1:1mol),Fe,t 0
+ NaOH (d ),t 0 ,p
+ HCl(d )
Cu 86: Cho s chuyn ho sau: Toluen
X
Y
Z
Trong X, Y, Z u l hn hp ca cc cht hu c, Z c thnh phn chnh gm :
A. m-metylphenol v o-metylphenol
B. benzyl bromua v o-bromtoluen
C. o-bromtoluen v p-bromtoluen
D. o-metylphenol v p-metylphenol
Cu 87 : Khi t 0,1 mol mt cht X (dn xut ca benzen), khi lng CO2 thu c nh hn 35,2 gam.
Bit rng, 1 mol X ch tc dng c vi 1 mol NaOH. Cng thc cu to thu gn ca X l (cho C =12, O =
16)
A. HOCH2C6H4COOH.
B. C2H5C6H4OH.
C. HOC6H4CH2OH.
D. C6H4(OH)2.
Cu 88: C 3 cht lng benzen, phenol, stiren, ng ring bit trong 3 l mt nhn. Thuc th phn
bit 3 cht lng trn l
A. giy qu tm.
B. nc brom.
C. dung dch NaOH.
D. phenolphtalein.
Cu 89: Cho s
+ Cl2 (t l mol 1:1)

+ NaOH c (d)

+ axit HCl

C6H6 (benzen) X
Y Z
o
Fe, to

t cao, p cao

Hai cht hu c Y, Z ln lt l :
10

C. C6H5OH, C6H5Cl. D. C6H5ONa, C6H5OH.

A. C6H6(OH)6, C6H6Cl6.
B. C6H4(OH)2, C6H4Cl2.
Cu 90: (A 11 ) Cho0 dy chuyn ho sau:
C 2 H 4 ( xt ,t )
Br2 ( as ,1:1)
KOH , ROH
Benzen +
X +
Y
Z (trong X, Y, Z l cc sn phm chnh)
Tn gi ca Y, Z ln lt l
A. benzylbromua v toluen.
B. 2-brom-1-phenylbenzen v stiren.
C. 1-brom-2-phenyletan v stiren.
D. 1-brom-1-phenyletan v stiren.
Cu 91: (A 1 1) Hp cht hu c X cha vng benzen c cng thc phn t trng vi cng thc n
gin nht. Trong X, t l khi lng cc nguyn t l mC : mH : mO = 21 : 2 : 8. Bit khi X phn ng
hon ton vi Na th thu c s mol kh hiro bng s mol ca X phn ng. X c bao nhiu ng
phn (cha vng benzen) tha mn cc tnh cht trn?
A. 7.
B. 9.
C. 3.
D. 10.
Cu 92: (B 11) Ho tan cht X vo nc thu c dung dch trong sut, ri thm tip dung dch cht Y
th thu c cht Z (lm vn c dung dch). Cc cht X, Y, Z ln lt l:
A. phenol, natri hiroxit, natri phenolat.
B. phenylamoni clorua, axit clohiric, anilin.
C. anilin, axit clohiric, phenylamoni clorua.
D. natri phenolat, axit clohiric, phenol.
Cu 93: (B 11) Chia hn hp gm hai ancol n chc X v Y (phn t khi ca X nh hn ca Y) l
ng ng k tip thnh hai phn bng nhau:
- t chy hon ton phn 1 thu c 5,6 lt CO2 (ktc) v 6,3 gam H2O.
o
- un nng phn 2 vi H2SO4 c 140 C to thnh 1,25 gam hn hp ba ete. Ho hi hon ton hn
hp ba ete trn, thu c th tch hi bng th tch ca 0,42 gam N2 (trong cng iu kin nhit , p
sut). Hiu sut phn ng to ete ca X, Y ln lt l
A. 25% v 35%.
B. 20% v 40%.
C. 40% v 20%.
D. 30% v 30%.
Cu 94: (C 11) un si hn hp propyl bromua, kali hiroxit v etanol thu c sn phm hu c l
A. propin.
B. propan-2-ol.
C. propan.
D. propen.
Cu 95: (C 11) S hp cht ng phn cu to ca nhau c cng thc phn t C8H10O, trong phn t c
vng benzen, tc dng c vi Na, khng tc dng c vi NaOH l
A. 4.
B. 6.
C. 7.
D. 5.
Cu 96: (C 11) Cho m gam hn hp X gm phenol v etanol phn ng hon ton vi natri (d), thu c
2,24 lt kh H2 (ktc). Mt khc, phn ng hon ton vi m gam X cn 100 ml dung dch NaOH 1M.
Gi tr ca m l:
A. 7,0
B. 14,0
C. 10,5
D. 21,0
Cu 97: (C 11) t chy hon ton mt lng hn hp X gm 3 ancol thuc cng dy ng ng thu
c 6,72 lt kh CO2 (ktc) v 9,90 gam H2O. Nu un nng cng lng hn hp X nh trn vi H 2SO4
c nhit thch hp chuyn ht thnh ete th tng khi lng ete thu c l:
A. 6,45 gam
B. 5,46 gam
C. 7,40 gam
D. 4,20 gam
Cu 98: (C 11) S ancol ng phn cu to ca nhau c cng thc phn t C5H12O, tc dng vi CuO un
nng sinh ra xeton l:
A. 4
B. 2
C. 5
D. 3
Cu 99: (A 09) Khi t chy hon ton m gam hn hp hai ancol no, n chc, mch h thu c V lt
kh CO2 ( ktc) v a gam H2O. Biu thc lin h gia m, a v V l
V

A. m = 2a - 22,4
B. m = 2a - 11,2
C. m = a + 5,6
D. m = a - 5,6
Cu 100: (A 12) Trong ancol X, oxi chim 26,667% v khi lng. un nng X vi H 2SO4 c thu c
anken Y. Phn t khi ca Y l
A. 56.
B. 70.
C. 28.
D. 42.
Cu 101: (A 12) t chy hon ton mt lng ancol X to ra 0,4 mol CO2 v 0,5 mol H2O. X tc dng
vi Cu(OH)2 to ra dung dch mu xanh lam. Oxi ha X bng CuO to hp cht hu c a cht Y. Nhn
xt no sau y ng vi X?
A. X lm mt mu nc brom
B. Trong X c hai nhm OH lin kt vi hai nguyn t cacbon bc hai.
C. Trong X c ba nhm CH3.
D. Hirat ha but-2-en thu c X.
Cu 103: (A 12) t chy hon ton 3 lt hn hp X gm 2 anken kt tip nhau trong dy ng ng cn
va 10,5 lt O2 (cc th tch kh o trong cng iu kin nhit , p sut). Hirat ha hon ton X
trong iu kin thch hp thu c hn hp ancol Y, trong khi lng ancol bc hai bng 6/13 ln
11

tng khi lng cc ancol bc mt. Phn trm khi lng ca ancol bc mt (c s nguyn t cacbon ln
hn) trong Y l
A. 46,43%.
B. 31,58%.
C. 10,88%.
D. 7,89%.
Cu 104: (A 12) Cho cc pht biu sau v phenol (C6H5OH):
(a) Phenol tan nhiu trong nc lnh.
(b) Phenol c tnh axt nhng dung dch phenol trong nc khng lm i mu qu tm.
(c) Phenol c dng sn xut phm nhum, cht dit nm mc.
(d) Nguyn t H ca vng benzen trong phenol d b thay th hn nguyn t H trong benzen.
(e) Cho nc brom vo dung dch phenol thy xut hin kt ta.
S pht biu ng l
A. 5.
B. 2.
C. 3.
D. 4.
Cu 105: (B 12) Cho hn hp X gm ancol metylic, etylen glicol v glixerol. t chy hon ton m gam
X thu c 6,72 lt kh CO 2 (ktc). Cng m gam X trn cho tc dng vi Na d thu c ti a V lt kh
H2 (ktc). Gi tr ca V l
A. 3,36
B. 11,20
C. 5,60
D. 6,72
Cu 106: (B 12) t chy hon ton m gam hn hp X gm hai ancol, thu c 13,44 lt kh CO 2 (ktc)
v 15,3 gam H2O. Mt khc, cho m gam X tc dng vi Na (d), thu c 4,48 lt kh H 2 (ktc). Gi tr
ca m l
A. 12,9
B. 15,3
C. 12,3
D. 16,9
Cu 107: (B 12) Cho phenol (C6H5OH) ln lt tc dng vi (CH3CO)2O v cc dung dch: NaOH, HCl,
Br2, HNO3, CH3COOH. S trng hp xy ra phn ng l
A. 3
B. 4
C. 2
D. 1
Cu 108: (B 12) Oxi ha 0,08 mol mt ancol n chc, thu c hn hp X gm mt axit cacboxylic,
mt anehit, ancol d v nc. Ngng t ton b X ri chia lm hai phn bng nhau. Phn mt cho tc
dng ht vi Na d, thu c 0,504 lt kh H 2 (ktc). Phn hai cho phn ng trng bc hon ton thu c
9,72 gam Ag. Phn trm khi lng ancol b oxi ha l
A. 50,00%
B. 62,50%
C. 31,25%
D. 40,00%
Cu 109: (B 12) t chy hon ton 20 ml hi hp cht hu c X (ch gm C, H, O) cn va 110 ml
kh O2 thu c 160 ml hn hp Y gm kh v hi. Dn Y qua dung dch H 2SO4 c (d), cn li 80 ml
kh Z. Bit cc th tch kh v hi o cng iu kin. Cng thc phn t ca X l
A. C4H8O2
B. C4H10O
C. C3H8O
D. C4H8O
Cu 110: (B 12) C bao nhiu cht cha vng benzen c cng cng thc phn t C7H8O?
A. 3
B. 5
C. 6
D. 4
Cu 111: (C12) S ancol bc I l ng phn cu to ca nhau c cng thc phn t C5H12O l
A. 4.
B. 1
C. 8.
D. 3
Cu 112: (C12) Cho m gam hn hp hi X gm hai ancol (n chc, bc I, l ng ng k tip) phn
ng vi CuO d, thu c hn hp hi Y gm nc v anehit. T khi hi ca Y so vi kh hiro bng
14,5. Cho ton b Y phn ng hon ton vi lng d dung dch AgNO 3 trong NH3, thu c 97,2 gam
Ag. Gi tr ca m l
A. 14,0.
B. 14,7.
C. 10,1.
D. 18,9.
Cu 113: (C12) t chy hon ton hn hp X gm hai ancol no, hai chc, mch h cn va V1 lt kh
O2, thu c V2 lt kh CO2 v a mol H2O. Cc kh u o iu kin tiu chun. Biu thc lin h gia
cc gi tr V1, V2, a l
A. V1 = 2V2 - 11,2a B. V1 = V2 +22,4a
C. V1 = V2 - 22,4a
D. V1 = 2V2 + 11,2a
Cu 114: (C12) Cho dung dch cha m gam hn hp gm phenol (C 6H5OH) v axit axetic tc dng va
vi nc brom, thu c dung dch X v 33,1 gam kt ta 2,4,6-tribromphenol. Trung ha hon ton
X cn va 500 ml dung dch NaOH 1M. Gi tr ca m l
A. 21,4
B. 24,8
C. 33,4
D. 39,4

ANEHIT XETON AXIT CACBOXYLIC

Cu 1: Cho 0,1 mol anehit X tc dng vi lng d AgNO 3 trong dung dch NH3, un nng thu c
43,2 gam Ag. Hiro ho X thu c Y, bit 0,1 mol Y phn ng va vi 4,6 gam Na. Cng thc cu
to thu gn ca X l (cho Na = 23, Ag = 108)
A. CH3CHO.
B. OHC-CHO.
C. HCHO.
D. CH3CH(OH)CHO.
Cu 2: un nng V lt hi anehit X vi 3V lt kh H2 (xc tc Ni) n khi phn ng xy ra hon ton ch
thu c mt hn hp kh Y c th tch 2V lt (cc th tch kh o cng iu kin nhit , p sut).
12

Ngng t Y thu c cht Z; cho Z tc dng vi Na sinh ra H 2 c s mol bng s mol Z phn ng.
Cht X l anehit
A. khng no (cha mt ni i C=C), hai chc.
B. no, hai chc.
C. no, n chc.
D. khng no (cha mt ni i C=C), n chc.
Cu 3: Cho 6,6 gam mt anehit X n chc, mch h phn ng vi lng d AgNO3 trong
dung dch NH3, un nng. Lng Ag sinh ra cho phn ng ht vi axit HNO3 long, thot ra 2,24 lt kh NO
(sn phm kh duy nht, o ktc). Cng thc cu to thu gn ca X l (cho H = 1, C = 12, O = 16)
A. CH3CHO.
B. HCHO.
C. CH3CH2CHO.
D. CH2 = CHCHO.
Cu 4: (A 10) Oxi ho ht 2,2 gam hn hp hai ancol n chc thnh anehit cn va 4,8 gam CuO.
Cho ton b lng anehit trn tc dng vi lng d dung dch AgNO3 trong NH3, thu c 23,76
gam Ag. Hai ancol l:
A. C2H5OH, C2H5CH2OH.
B. C2H5OH, C3H7CH2OH.
C. CH3OH, C2H5CH2OH.
D. CH3OH, C2H5OH.
Cu 5: t chy hon ton a mol axit hu c Y c 2a mol CO2. Mt khc, trung ha a mol Y
cn va 2a mol NaOH. Cng thc cu to thu gn ca Y l
A. HOOC-CH2-CH2-COOH. B. C2H5-COOH. C. CH3-COOH. D. HOOC-COOH.
Cu 6: Hiro ho hon ton m gam hn hp X gm hai anehit no, n chc, mch h, k tip nhau
trong dy ng ng thu c (m + 1) gam hn hp hai ancol. Mt khc, khi t chy hon ton cng m
gam X th cn va 17,92 lt kh O2 ( ktc). Gi tr ca m l
A. 10,5.
B. 8,8.
C. 24,8.
D. 17,8.
Cu 7: Dy gm cc cht u tc dng vi AgNO3 trong dung dch NH3, l:
A. anehit axetic, but-1-in, etilen.
B. anehit axetic, axetilen, but-2-in.
C. axit fomic, vinylaxetilen, propin.
D. anehit fomic, axetilen, etilen.
Cu 8: Khi thc hin phn ng este ho 1 mol CH3COOH v 1 mol C2H5OH, lng este ln nht
thu c l 2/3 mol. t hiu sut cc i l 90% (tnh theo axit) khi tin hnh este ho 1 mol
CH3COOH cn s mol C2H5OH l (bit cc phn ng este ho thc hin cng nhit )
A. 0,342.
B. 2,925.
C. 2,412.
D. 0,456.
Cu 9: trung ha 6,72 gam mt axit cacboxylic Y (no, n chc), cn dng 200 gam dung dch
NaOH 2,24%. Cng thc ca Y l (cho H = 1, C = 12, O = 16, Na = 23)
A. C2H5COOH.
B. CH3COOH.
C. C3H7COOH.
D. HCOOH.
Cu 10: t chy hon ton 0,1 mol mt axit cacboxylic n chc, cn va V lt O2 ( ktc), thu
c 0,3 mol CO2 v 0,2 mol H2O. Gi tr ca V l
A. 8,96.
B. 11,2.
C. 6,72.
D. 4,48.
Cu 11: t chy hon ton a mol mt anehit X (mch h) to ra b mol CO2 v c mol H2O (bit b = a + c).
Trong phn ng trng gng, mt phn t X ch cho 2 electron. X thuc dy ng ng anehit
A. no, hai chc.
B. no, n chc.
C. khng no c hai ni i, n chc.
D. khng no c mt ni i, n chc.
Cu 12: Cho tt c cc ng phn n chc, mch h, c cng cng thc phn t C2H4O2 ln lt tc dng
vi: Na, NaOH, NaHCO3. S phn ng xy ra l
A. 4.
B. 5.
C. 3.
D. 2.
Cu 13: Khi oxi ha hon ton 2,2 gam mt anehit n chc thu c 3 gam axit tng ng. Cng thc
ca anehit l
A. C2H3CHO.
B. CH3CHO.
C. HCHO.
D. C2H5CHO.
Cu 14: Oxi ho 4,48 lt C2H4 ( ktc) bng O2 (xc tc PdCl2, CuCl2), thu c cht X n chc.
Ton b lng cht X trn cho tc dng vi HCN (d) th c 7,1 gam CH3CH(CN)OH
(xianohirin). Hiu sut qu trnh to CH3CH(CN)OH t C2H4 l
A. 60%.
B. 50%.
C. 80%.
D. 70%.
Cu 15: Cho s chuyn ho: Glucoz X Y CH3COOH. Hai cht X, Y ln lt l
A. CH3CH2OH v CH2=CH2.
B. CH3CHO v CH3CH2OH.
C. CH3CH2OH v CH3CHO.
D. CH3CH(OH)COOH v CH3CHO.
Cu 16: Cho 5,76 gam axit hu c X n chc, mch h tc dng ht vi CaCO3 thu c 7,28 gam
mui ca axit hu c. Cng thc cu to thu gn ca X l
A. CH2=CH-COOH.
B. CH3COOH.
C. HCC-COOH.
D. CH3-CH2-COOH.
Cu 17: Cho 2,9 gam mt anehit phn ng hon ton vi lng d AgNO3 trong dung dch NH3 thu c
21,6 g Ag. Cng thc cu to thu gn ca anehit l
13

A. HCHO.
B. CH2=CH-CHO.
C. OHC-CHO.
D. CH3CHO.
Cu 18: un 12 gam axit axetic vi 13,8 gam etanol (c H2SO4 c lm xc tc) n khi phn ng t ti
trng thi cn bng, thu c 11 gam este. Hiu sut ca phn ng este ho l
A. 55%.
B. 50%.
C. 62,5%.
D. 75%.
Cu 19: Trung ho 5,48 gam hn hp gm axit axetic, phenol v axit benzoic, cn dng 600 ml dung dch
NaOH 0,1M. C cn dung dch sau phn ng, thu c hn hp cht rn khan c khi lng l
A. 6,84 gam.
B. 4,90 gam.
C. 6,80 gam.
D. 8,64 gam.
Cu 20: Cho 3,6 gam anehit n chc X phn ng hon ton vi mt lng d AgNO3 trong dung
dch NH3 un nng, thu c m gam Ag. Ho tan hon ton m gam Ag bng dung dch HNO3 c,
sinh ra 2,24 lt NO2 (sn phm kh duy nht, ktc). Cng thc ca X l
A. C3H7CHO.
B. HCHO.
C. C2H5CHO.
D. C4H9CHO.
Cu 21: S ng phn axit ng vi cng thc phn t C6H12O2 l
A. 8.
B. 4.
C. 5.
D. 6.
Cu 22: Dy gm cc cht c xp theo chiu nhit si tng dn t tri sang phi l:
A. CH3CHO, C2H5OH, C2H6, CH3COOH.
B. C2H6, C2H5OH, CH3CHO, CH3COOH.
C. C2H6, CH3CHO, C2H5OH, CH3COOH.
D. CH3COOH, C2H6, CH3CHO, C2H5OH.
Cu 23: S ng phn xeton ng vi cng thc phn t C5H10O l
A. 5.
B. 4.
C. 3.
D. 6.
Cu 24: Cho cc cht: ancol etylic, glixerol, glucoz, imetyl ete v axit fomic. S
cht tc dng c vi Cu(OH)2 l
A. 1.
B. 3.
C. 4.
D. 2.
Cu 25: Oxi ho 1,2 gam CH3OH bng CuO nung nng, sau mt thi gian thu c hn hp sn phm
X (gm HCHO, H2O v CH3OH d). Cho ton b X tc dng vi lng d AgNO3
trong dung dch NH3, c 12,96 gam Ag. Hiu sut ca phn ng oxi ho CH3OH l
A. 76,6%.
B. 80,0%.
C. 65,5%.
D. 70,4%.
Cu 26: Axit cacboxylic no, mch h X c cng thc thc nghim (C3H4O3)n, vy cng thc phn t
ca X l
A. C6H8O6.
B. C3H4O3.
C. C12H16O12.
D. C9H12O9.
Cu 27: Cho 3,6 gam axit cacboxylic no, n chc X tc dng hon ton vi 500 ml dung dch gm
KOH 0,12M v NaOH 0,12M. C cn dung dch thu c 8,28 gam hn hp cht rn khan. Cng
thc phn t ca X l
A. C2H5COOH.
B. CH3COOH.
C. HCOOH.
D. C3H7COOH.
Cu 28: Ba cht hu c mch h X, Y, Z c cng cng thc phn t C3H6O v c cc tnh cht: X, Z
u phn ng vi nc brom; X, Y, Z u phn ng vi H2 nhng ch c Z khng b thay i nhm
chc; cht Y ch tc dng vi brom khi c mt CH3COOH. Cc cht X, Y, Z ln lt l:
A. C2H5CHO, CH2=CH-O-CH3, (CH3)2CO.
B. (CH3)2CO, C2H5CHO, CH2=CH-CH2OH.
C. C2H5CHO, (CH3)2CO, CH2=CH-CH2OH.
D. CH2=CH-CH2OH, C2H5CHO, (CH3)2CO.
Cu 29: Cho dy cc cht: HCHO, CH3COOH, CH3COOC2H5, HCOOH, C2H5OH, HCOOCH3. S
cht trong dy tham gia phn ng trng bc l
A. 3.
B. 6.
C. 4.
D. 5.
Cu 30: Cho hn hp gm 0,1 mol HCHO v 0,1 mol HCOOH tc dng vi lng d AgNO3 trong
dung dch NH3, un nng. Sau khi cc phn ng xy ra hon ton, khi lng Ag to thnh l
A. 43,2 gam.
B. 10,8 gam.
C. 64,8 gam.
D. 21,6 gam.
Cu 31: Cho cc cht sau: CH3-CH2-CHO (1), CH2=CH-CHO (2), (CH3)2CH-CHO (3), CH2=CH-CH2o
OH (4). Nhng cht phn ng hon ton vi lng d H2 (Ni, t ) cng to ra mt sn phm l:
A. (2), (3), (4).
B. (1), (2), (4).
C. (1), (2), (3).
D. (1), (3), (4).
Cu 32: t chy hon ton mt anehit X, thu c s mol CO2 bng s mol H2O. Nu cho X tc dng
vi lng d AgNO3 trong dung dch NH3, sinh ra s mol Ag gp bn ln s mol
X phn ng. Cng thc ca X l
A. HCHO.
B. CH3CHO.
C. (CHO)2.
D. C2H5CHO.
Cu 33: Cho cc cht sau: phenol, etanol, axit axetic, natri phenolat, natri hiroxit. S cp cht tc
dng c vi nhau l
A. 4.
B. 3.
C. 2.
D. 1.
14

Cu 34: Trung ho 8,2 gam hn hp gm axit fomic v mt axit n chc X cn 100 ml dung dch
NaOH 1,5M. Nu cho 8,2 gam hn hp trn tc dng vi mt lng d dung dch AgNO 3 trong NH3, un
nng th thu c 21,6 gam Ag. Tn gi ca X l
A. axit acrylic.
B. axit propanoic.
C. axit etanoic.
D. axit metacrylic.
Cu 35: Dy gm cc cht c th iu ch trc tip (bng mt phn ng) to ra axit axetic l:
A. CH3OH, C2H5OH, C2H5COOCH3.
B. CH3CHO, C6H12O6 (glucoz), CH3OH.
C. CH3OH, C2H5OH, CH3CHO.
D. C2H4(OH)2, CH3OH, CH3CHO.
Cu 36: Cho cc cht HCl (X); C2H5OH (Y); CH3COOH (Z); C6H5OH (phenol) (T). Dy gm cc cht
c sp xp theo tnh axit tng dn (t tri sang phi) l:
A. (T), (Y), (X), (Z).
B. (X), (Z), (T), (Y).
C. (Y), (T), (Z), (X).
D. (Y), (T), (X), (Z).
Cu 37: Oxi ho m gam etanol thu c hn hp X gm axetanehit, axit axetic, nc v etanol d. Cho
ton b X tc dng vi dung dch NaHCO 3 (d), thu c 0,56 lt kh CO 2 ( ktc). Khi lng etanol
b oxi ho to ra axit l
A. 1,15 gam.
B. 4,60 gam.
C. 2,30 gam.
D. 5,75 gam.
Cu 38: Dy gm cc cht u tc dng vi ancol etylic l:
A. HBr (to), Na, CuO (to), CH3COOH (xc tc). B. Ca, CuO (to), C6H5OH (phenol), HOCH2CH2OH
C. NaOH, K, MgO, HCOOH (xc tc).
D. Na2CO3, CuO (to), CH3COOH (xc tc), (CH3CO)2O
Cu 39: Hai hp cht hu c X, Y c cng cng thc phn t C 3H6O2. C X v Y u tc dng vi Na; X
tc dng c vi NaHCO3 cn Y c kh nng tham gia phn ng trng bc. Cng thc cu to ca X v
Y ln lt l
A. C2H5COOH v HCOOC2H5.
B. HCOOC2H5 v HOCH2COCH3.
C. HCOOC2H5 v HOCH2CH2CHO.
D. C2H5COOH v CH3CH(OH)CHO.
Cu 40: Hiro ho hon ton hn hp M gm hai anehit X v Y no, n chc, mch h, k tip nhau
trong dy ng ng (MX < MY), thu c hn hp hai ancol c khi lng ln hn khi lng M l 1
gam. t chy hon ton M thu c 30,8 gam CO2. Cng thc v % khi lng ca X ln lt l
A. HCHO v 50,56%.
B. CH3CHO v 67,16%.
C. CH3CHO v 49,44%.
D. HCHO v 32,44%.
Cu 41: Cho cc cht: axit propionic (X), axit axetic (Y), ancol etylic (Z) v imetyl ete (T).
Dy gm cc cht c sp xp theo chiu tng dn nhit si l
A. T, Z, Y, X.
B. Z, T, Y, X.
C. T, X, Y, Z.
D. Y, T, X, Z.
Cu 42: Cho 0,04 mol mt hn hp X gm CH2=CH-COOH, CH3COOH v CH2=CH-CHO phn ng
va vi dung dch cha 6,4 gam brom. Mt khc, trung ho 0,04 mol X cn dng va 40 ml
dung dch NaOH 0,75 M. Khi lng ca CH2=CH-COOH trong X l
A. 0,72 gam.
B. 1,44 gam.
C. 2,88 gam.
D. 0,56 gam.
Cu 43: Cho dung dch X cha hn hp gm CH3COOH 0,1M v CH3COONa 0,1M. Bit 250C, Ka ca
CH3COOH l 1,75.10-5 v b qua s phn li ca nc. Gi tr pH ca dung dch X 250C l
A. 2,88.
B. 4,24.
C. 1,00.
D. 4,76.
Cu 44: Cho 0,25 mol mt anehit mch h X phn ng vi lng d dung dch AgNO3 trong NH3, thu
c 54 gam Ag. Mt khc, khi cho X phn ng vi H2 d (xc tc Ni, to) th 0,125 mol X phn ng ht
vi 0,25 mol H2. Cht X c cng thc ng vi cng thc chung l
A. CnH2n-3CHO (n 2).
B. CnH2n-1CHO (n 2). C. CnH2n+1CHO (n 0). D. CnH2n(CHO)2 (n 0).
Cu 45: Cho hn hp kh X gm HCHO v H2 i qua ng s ng bt Ni nung nng. Sau khi phn ng
xy ra hon ton, thu c hn hp kh Y gm hai cht hu c. t chy ht Y th thu c 11,7 gam
H2O v 7,84 lt kh CO2 ( ktc). Phn trm theo th tch ca H2 trong X l
A. 35,00%.
B. 65,00%.
C. 53,85%.
D. 46,15%.
Cu 46: Cho hn hp X gm hai axit cacboxylic no, mch khng phn nhnh. t chy hon ton 0,3
mol hn hp X, thu c 11,2 lt kh CO 2 ( ktc). Nu trung ha 0,3 mol X th cn dng 500 ml dung
dch NaOH 1M. Hai axit l:
A. HCOOH, CH3COOH.
B. HCOOH, HOOC-COOH.
C. HCOOH, C2H5COOH.
D. HCOOH, HOOC-CH2-COOH.
Cu 47: Hn hp X gm hai ancol no, n chc, mch h, k tip nhau trong dy ng ng. Oxi ho
hon ton 0,2 mol hn hp X c khi lng m gam bng CuO nhit thch hp, thu c hn hp sn
phm hu c Y. Cho Y tc dng vi mt lng d dung dch AgNO 3 trong NH3, thu c 54 gam Ag.
Gi tr ca m l
15

A. 13,5.
B. 8,1.
C. 8,5.
D. 15,3.
Cu 48: Hn hp X gm axit Y n chc v axit Z hai chc (Y, Z c cng s nguyn t cacbon). Chia X
thnh hai phn bng nhau. Cho phn mt tc dng ht vi Na, sinh ra 4,48 lt kh H 2 ( ktc). t chy
hon ton phn hai, sinh ra 26,4 gam CO 2. Cng thc cu to thu gn v phn trm v khi lng ca Z
trong hn hp X ln lt l
A. HOOC-COOH v 42,86%.
B. HOOC-COOH v 60,00%.
C. HOOC-CH2-COOH v 70,87%.
D. HOOC-CH2-COOH v 54,88%.
Cu 49: Khi cho a mol mt hp cht hu c X (cha C, H, O) phn ng hon ton vi Na hoc vi
NaHCO3 th u sinh ra a mol kh. Cht X l
A. ancol o-hiroxibenzylic. B. axit aipic.
C. axit 3-hiroxipropanoic. D. etylen glicol.
Cu 50: Cho cc hp cht hu c:
(1) ankan; (2) ancol no, n chc, mch h;
(3) xicloankan; (4) ete no, n chc, mch h;
(5) anken; (6) ancol khng no (c mt lin kt i C=C), mch h;
(7) ankin; (8) anehit no, n chc, mch h;
(9) axit no, n chc, mch h; (10) axit khng no (c mt lin kt i C=C), n chc.
Dy gm cc cht khi t chy hon ton u cho s mol CO2 bng s mol H2O l:
A. (2), (3), (5), (7), (9). B. (1), (3), (5), (6), (8). C. (3), (4), (6), (7), (10).
D. (3), (5), (6), (8), (9).
Cu 51: t chy hon ton mt hp cht hu c X, thu c 0,351 gam H 2O v 0,4368 lt kh CO 2 (
ktc). Bit X c phn ng vi Cu(OH)2 trong mi trng kim khi un nng. Cht X l
A. C2H5CHO.
B. CH2=CH-CH2-OH.
C. CH3COCH3.
D. O=CH-CH=O.
Cu 52: Cho X l hp cht thm; a mol X phn ng va ht vi a lt dung dch NaOH 1M. Mt khc, nu
cho a mol X phn ng vi Na (d) th sau phn ng thu c 22,4a lt kh H 2 ( ktc). Cng thc cu to
thu gn ca X l
A. HO-CH2-C6H4-OH.
B. HO-C6H4-COOCH3. C. HO-C6H4-COOH.
D. CH3-C6H3(OH)2.
Cu 53: Cho s chuyn ha:
CH3CH2Cl + KCN X
X
+ H3O+ (un nng) Y
Cng thc cu to ca X, Y ln lt l:
A. CH3CH2NH2, CH3CH2COOH.
B. CH3CH2CN, CH3CH2CHO.
C. CH3CH2CN, CH3CH2COOH.
D. CH3CH2CN, CH3CH2COONH4.
Cu 54: X, Y, Z l 3 cht hu c cng chc c cng thc phn t l : CH2O2, C3H4O2 v C3H4O4. Phn t
X, Y, Z c cha chc
A. este.
B. ancol.
C. anehit.
D. axit.
Cu 55: trung ha 300 gam dung dch ca axit hu c no, mch h, n chc X nng 7,4% cn
100 ml dung dch NaOH 3M. X l
A. CH3COOH.
B. C3H7COOH.
C. C2H5COOH.
D. HCOOH.
Cu 56: trung ha dung dch cha m gam axit X (X n chc, no, mch h) cn 100 ml dung dch
NaOH 2M. C cn dung dch sau trung ha c 16,4 gam mui khan. Cng thc ca X l
A. CH3COOH.
B. C3H7COOH.
C. C2H5COOH.
D. HCOOH.
Cu 57: Oxi ha 8 gam ancol metylic bng CuO ri cho anehit tan vo 10 gam nc. Nu hiu sut
phn ng l 80% th nng anehit trong dung dch l
A. 67%.
B. 42,9%.
C. 76,6%.
D. 37,5%.
Cu 58: Khi lng axit axetic trong gim n thu c l bao nhiu khi ln men 0,5 lt ancol etylic 60.
Bit khi lng ring ca ancol etylic l 0,8 gam/ml.
A. 31,3 gam.
B. 34,5 gam.
C. 39,8 gam.
D. 34,9 gam.
Cu 59: Oxi ha V (ml) ancol etylic 920 (khi lng ring ca ancol etylic nguyn cht l 0,8 g/ml) thu
c dung dch axit axetic. trung ha hon ton lng axit axetic cn dng 30 ml dung dch NaOH
3M. Gi tr ca V l (Cho hiu sut phn ng oxi ha t 100%)
A. 5,750.
B. 5,180.
C. 5,625.
D. 4,600.
Cu 60: C 3 cht: ancol etylic, glixerol v axit axetic. nhn bit cc cht trn c th dng
A. qu tm.
B. CaCO3.
C. Cu(OH)2.
D. Na.
Cu 61: t chy hon ton 5,8 gam cht hu c X cho 2,65 gam Na 2CO3, 2,25 gam H2O v 12,1 gam
CO2. Bit X ch cha mt nguyn t oxi. CTPT ca X l
A. C6H5ONa
B. C6H4ONa2
C. C6H5COONa
D. C2H5ONa
16

Cu 62: Oxi ha 4,02 gam cht hu c Y ch thu c 3,18 gam xa v 0,672 lt kh CO 2 ( ktc). Y c
CTGN l
A. CH2ONa
B. Na2CO2
C. NaCO2
D. Na2C2O4
Cu 63: Trung ha 6,0 gam mt axit cacboxylic no, n chc, mch h cn dng 100 ml dung dch
NaOH 1M. Cng thc cu to ca axit l
A. CH3COOH.B. CH2=CH-COOH. C. C2H5COOH.
D. HCOOH.
Cu 64: Cho phn ng sau: CnH2n + 1 - 2aCHO + H2 CnH2n + 1CH2OH. S mol H2 phn ng l:
A. a.
B. 2a.
C. a + 1.
D. a + 2.
Cu 65: Khi oxi ho ancol A bi CuO un nng th thu c 2 metylpropanal. Cht A l:
A. Butan-1-ol.
B. 2-metylpropan-2-ol.
C. 2-metylpropan-1-ol.
D. Butan-2-ol.
Cu 66: Cht hu c C2H4O2 c my ng phn tc dng vi Na:
A. 1.
B. 2.
C. 3.
D. 4.
Cu 67: Mt anehit n no, ly 0,87 gam anehit y tc dng hon ton vi dd AgNO 3/NH3 c d th
thu c 3,24 gam bc. Cng thc anehit l:
A. CH3CHO
B. C2H5CHO
C. C3H7CHO
D. (CHO)2.
Cu 68: Trong 4 cht di y, cht no phn ng c vi c 3 cht : Na, NaOH, NaHCO3 ?
A. C6H5OH.
B. C2H5OH.
C. CH3COOH.
D. HO-CH2-CH2-OH.
Cu 69: Dy gm 2 cht u tc dng vi NaOH l
A. CH3COOH, C6H5OH.
B. CH3COOH, C2H5OH.
C. CH3COOH, C6H5CH2OH.
D. CH3COOH, C6H5NH2.
Cu 70: Cho hn hp X gm 0,2 mol CH2=CH-COOH v 0,1 mol CH3CHO. Th tch H2 ( ktc)
phn ng va vi hn hp X l
A. 4,48 lt.
B. 6,72 lt.
C. 8,96 lt.
D. 2,24 lt.
Cu 71: Cho 2,9 gam mt anehit no, n chc, mch h tc dng hon ton vi dung dch AgNO3 trong
dung dch NH3, un nng thu c 10,8 gam Ag. Anehit c cng thc l
A. CH3CHO.
B. C2H5CHO.
C. CH2=CHCHO.
D. HCHO.
Cu 72: S hp cht anehit c cng thc phn t C4H8O l
A. 1.
B. 2.
C. 3.
D. 4.
Cu 73: Khi cho anehit no, n chc, mch h phn ng vi H2 (xc tc Ni, un nng) thu c
A. ancol no, n chc, mch h, bc 1.
B. ancol no, n chc, mch h, bc 2.
C. ancol no, n chc, mch h, bc 3.
D. axit cacboxykic no, n chc, mch h.
Cu 74: Cht no di y c th tc dng vi nc brom ?
A. Axit acrylic.
B. Axit axetic.
C. Benzen.
D. Axit clohiric.
Cu 75: phn bit dung dch anehit axetic v dung dch ancol c th dng
A. dung dch NaOH.
B. AgNO3 dd NH3.
C. dung dch NH3.
D. phenolphtalein.
Cu 76: trung ha 10 ml dung dch CH3COOH cn dng 20 ml dung dch NaOH 1M. Nng mol
ca CH3COOH l
A. 1M.
B. 2M.
C. 3M.
D. 4M.
Cu 77: Nhn nh no sau y ng ?
A. Anehit khng c tnh : kh v oxi ha.
B. Anehit ch c tnh oxi ha.
C. Anehit ch c tnh kh.
D. Anehit c tnh kh v tnh oxi ha.
Cu 78: Cho 2,2 gam anehit axetic tc dng vi lng d AgNO3 trong dung dch NH3. Khi phn ng
xy ra hon ton, khi lng Ag thu c l
A. 10,8 gam.
B. 21,6 gam.
C. 5,40 gam.
D. 1,08 gam.
Cu 79: Trung ha 3,6 gam axit n chc bng dung dch NaOH thu c 4,7 gam mui, axit l
A. axit fomic.
B. axit axetic.
B. axit acrylic.
D. axit propionic.
Cu 80: trung ha 6,72 gam mt cacboxylic Y (no, n chc) cn dng 200 gam dung dch NaOH
2,24%. Cng thc ca Y l
A. CH3COOH.
B. C3H7COOH.
C. C2H5COOH.
D. HCOOH.
Cu 81: Cho 11,16 gam hn hp 2 axit n chc k tip nhau trong dy ng ng tc dng vi NaHCO3
thu c 4,48 lt CO2 ( ktc). Cng thc cu to ca 2 axit l
A. HCOOH v CH3COOH.
B. CH3COOH v C2H5COOH.
C. C2H3COOH v C3H5COOH.
D. C2H5COOH v C3H5COOH.
Cu 82: Dy gm cc cht c xp theo chiu tng dn tnh axit l
A. phenol, ancol etylic, axit axetic.
B. ancol etylic, axit axetic, phenol.
C. ancol etylic, phenol, axit axetic.
D. axit axetic, ancol etylic, phenol.
17

Cu 83: Hn hp X gm axit HCOOH v axit CH3COOH (t l mol 1:1). Ly 5,3 gam hn hp X tc

dng vi 5,75 gam C2H5OH (c xc tc H2SO4 c) thu c m gam hn hp este (hiu sut ca cc
phn ng este ho u bng 80%). Gi tr ca m l
A. 10,12.
B. 6,48.
C. 8,10.
D. 16,20.
Cu 84: (A 10) Tng s cht hu c mch h, c cng cng thc phn t C2H4O2 l
A. 3.
B. 1.
C. 2.
D. 4.
Cu 85: (A 10) Axeton c iu ch bng cch oxi ho cumen nh oxi, sau thu phn trong dung
dch H2SO4 long. thu c 145 gam axeton th lng cumen cn dng (gi s hiu sut qu trnh
iu ch t 75%) l
A. 300 gam.
B. 500 gam.
C. 400 gam.
D. 600 gam.
Cu 86: (A 10) Cho s chuyn ho:
ddBr2
O2 ; xt
CH 3OH ;t 0C ; xt
NaOH
CuO ;t 0C
C3 H 6
X
Y
Z
T
E (Este a chc)
Tn gi ca Y l
A. propan-1,3-iol. B. propan-1,2-iol.
C. propan-2-ol.
D. glixerol.
Cu 87: (A 10) Cho m gam hn hp etanal v propanal phn ng hon ton vi lng d dung dch
AgNO3 trong NH3, thu c 43,2 gam kt ta v dung dch cha 17,5 gam mui amoni ca hai axit
hu c. Gi tr ca m l
A. 10,9.
B. 14,3.
C. 10,2.
D. 9,5.
Cu 88: (A 10) Hn hp gm 0,1 mol mt axit cacboxylic n chc v 0,1 mol mui ca axit vi
kim loi kim c tng khi lng l 15,8 gam. Tn ca axit trn l
A. axit propanoic.
B. axit metanoic.
C. axit etanoic.
D. axit butanoic.
Cu 89: (A 2010) Hiro ho cht hu c X thu c (CH3)2CHCH(OH)CH3. Cht X c tn thay th l
A. metyl isopropyl xeton.
B. 3-metylbutan-2-on.
C. 3-metylbutan-2-ol. D. 2-metylbutan-3-on.
Cu 90: (B 10) Hn hp Z gm hai axit cacboxylic n chc X v Y (MX > MY) c tng khi lng l 8,2
gam. Cho Z tc dng va vi dung dch NaOH, thu c dung dch cha 11,5 gam mui. Mt khc, nu
cho Z tc dng vi mt lng d dung dch AgNO3 trong NH3, thu c 21,6 gam Ag. Cng thc v phn
trm khi lng ca X trong Z l
A. C3H5COOH v 54,88%.
B. C2H3COOH v 43,90%.
C. C2H5COOH v 56,10%.
D. HCOOH v 45,12%.
Cu 91: (B 10) Dy gm cc cht u tc dng vi H 2 (xc tc Ni, t0) to ra sn phm c kh nng phn
ng vi Na l:
A. C2H3CH2OH, CH3COCH3, C2H3COOH.
B. C2H3CHO, CH3COOC2H3, C6H5COOH.
C. C2H3CH2OH, CH3CHO, CH3COOH.
D. CH3OC2H5, CH3CHO, C2H3COOH.
Cu 92: (B 10) Hn hp X gm 1 ancol v 2 sn phm hp nc ca propen. T khi hi ca X so vi
hiro bng 23. Cho m gam X i qua ng s ng CuO (d) nung nng. Sau khi cc phn ng xy ra hon
ton, thu c hn hp Y gm 3 cht hu c v hi nc, khi lng ng s gim 3,2 gam. Cho Y tc
dng hon ton vi lng d dung dch AgNO3 trong NH3, to ra 48,6 gam Ag. Phn trm khi lng ca
propan-1-ol trong X l
A. 65,2%.
B. 16,3%.
C. 48,9%.
D. 83,7%.
Cu 93: (B 10) Cho phn ng: 2C6H5-CHO + KOH C6H5-COOK + C6H5-CH2-OH
Phn ng ny chng t C6H5-CHO
A. va th hin tnh oxi ha, va th hin tnh kh. B. ch th hin tnh oxi ha.
C. ch th hin tnh kh.
D. khng th hin tnh kh v tnh oxi ha.
Cu 94: (B 10) Hn hp M gm anhit X (no, n chc, mach h) va hircacbon Y, co tng s mol la
0,2 (s mol cua X nho hn cua Y). t chay hoan toan M, thu c 8,96 lit khi CO 2 (ktc) va 7,2g H2O.
Hircacbon Y la
A. CH4
B. C2H2
C. C3H6
D. C2H4
Cu 95: (B 10) Hn hp M gm axit cacboxylic X, ancol Y (u n chc, s mol X gp hai ln s mol
Y) va este Z c tao ra t X va Y. Cho mt lng M tac dung va u vi dung dich cha 0,2 mol NaOH,
tao ra 16,4 gam mui va 8,05 gam ancol. Cng thc cua X va Y la
A. HCOOH va CH3OH
B. CH3COOH va CH3OH
C. HCOOH va C3H7OH
D. CH3COOH va C2H5OH
Cu 96: (C 10) ng vi cng thc phn t C3H6O c bao nhiu hp cht mch h bn khi tc dng vi
kh H2 (xc tc Ni, t0) sinh ra ancol ?
A. 3
B. 4
C. 2
D. 1
18

Cu 97: (C 10) Axit cacboxylic X c cng thc n gin nht l C 3H5O2. Khi cho 100 ml dung dch axit
X nng 0,1M phn ng ht vi dung dch NaHCO 3 (d), thu c V ml kh CO 2 (ktc). Gi tr ca V
l
A. 112
B. 224
C. 448
D. 336
Cu 98: (C 10) iu kin thch hp: cht X phn ng vi cht Y to ra anehit axetic; cht X phn ng
vi cht Z to ra ancol etylic. Cc cht X,Y, Z ln lt l:
A. C2H4, O2, H2O
B. C2H2, H2O, H2
C. C2H4, H2O, CO
D. C2H2, O2, H2O
Cu 99: (C 10) Hai cht X v Y c cng cng thc phn t C 2H4O2. Cht X phn ng c vi kim loi
Na v tham gia phn ng trng bc. Cht Y phn ng c vi kim loi Na v ho tan c CaCO 3. Cng
thc ca X, Y ln lt l
A. HOCH2CHO, CH3COOH
B. HCOOCH3, HOCH2CHO
C. CH3COOH, HOCH2CHO
D. HCOOCH3, CH3COOH
Cu 100: (C 10) Anehit no mch h X c cng thc n gin nht C2H3O. Cng thc phn t ca X l
A. C8H12O4
B. C6H9O3
C. C2H3O
D. C4H6O2
Cu 101: (C 10) Cho 16,4 gam hn hp X gm 2 axit cacboxylic la ng ng k tip nhau phan ng
hoan toan vi 200 ml dung dich NaOH 1M va KOH 1M thu c dung dich Y. C can dung dich Y, thu
c 31,1 gam hn hp cht rn khan. Cng thc cua 2 axit trong X la
A. C2H4O2 va C3H4O2 B. C2H4O2 va C3H6O2 C. C3H4O2 va C4H6O2 D. C3H6O2 va C4H8O2
Cu 102: (A 11 ) t chy hon ton anehit X, thu c th tch kh CO2 bng th tch hi nc (trong
cng iu kin nhit , p sut). Khi cho 0,01 mol X tc dng vi mt lng d dung dch AgNO3 trong
NH3 th thu c 0,04 mol Ag. X l
A. anehit no, mch h, hai chc.
B. anehit khng no, mch h, hai chc.
C. anehit axetic.
D. anehit fomic.
Cu 103: (A 1 1) X, Y, Z l cc hp cht mch h, bn c cng cng thc phn t C3H6O. X tc dng
c vi Na v khng c phn ng trng bc. Y khng tc dng c vi Na nhng c phn ng trng
bc. Z khng tc dng c vi Na v khng c phn ng trng bc. Cc cht X, Y, Z ln lt l:
A. CH3-CH2-CHO, CH3-CO-CH3, CH2=CH-CH2-OH.
B. CH2=CH-CH2-OH, CH3-CO-CH3, CH3-CH2-CHO.
C. CH2=CH-CH2-OH, CH3-CH2-CHO, CH3-CO-CH3.
D. CH3-CO-CH3, CH3-CH2-CHO, CH2=CH-CH2-OH.
Cu 104: (A 11 ) Pht biu no sau y v anehit v xeton l sai?
A. Axetanehit phn ng c vi nc brom.
B. Hiro xianua cng vo nhm cacbonyl to thnh sn phm khng bn.
C. Axeton khng phn ng c vi nc brom.
D. Anehit fomic tc dng vi H2O to thnh sn phm khng bn.
Cu 105: (A 1 1) t chy hon ton x gam hn hp gm hai axit cacboxylic hai chc, mch h v u
c mt lin kt i C=C trong phn t, thu c V lt kh CO2 (ktc) v y mol H2O. Biu thc lin h
gia cc gi tr x, y v V l
A. V =

28
( x + 30 y)
55

B. V =

28
28
28
( x 30 y) C. V =
( x + 62 y) D. V =
( x 62 y )
55
95
95

Cu 106: (A 1 1) t chy hon ton x mol axit cacboxylic E, thu c y mol CO2 v z mol H2O (vi
z = y x ). Cho x mol E tc dng vi NaHCO3 (d) thu c y mol CO2. Tn ca E l
A. axit oxalic.
B. axit acrylic.
C. axit aipic.
D. axit fomic.
Cu 107: (A 1 1) Trung ho 3,88 gam hn hp X gm hai axit cacboxylic no, n chc, mch h bng
dung dch NaOH, c cn ton b dung dch sau phn ng thu c 5,2 gam mui khan. Nu t chy
hon ton 3,88 gam X th th tch oxi (ktc) cn dng l
A. 2,24 lt.
B. 4,48 lt.
C. 1,12 lt.
D. 3,36 lt.
Cu 108: (A 1 1) Hn hp X gm axit axetic, axit fomic v axit oxalic. Khi cho m gam X tc dng
vi NaHCO3 (d) th thu c 15,68 lt kh CO2 (ktc). Mt khc, t chy hon ton m gam X cn
8,96 lt kh O2 (ktc), thu c 35,2 gam CO2 v y mol H2O. Gi tr ca y l
A. 0,2.
B. 0,3.
C. 0,6.
D. 0,8.
Cu 109: (A 11 ) Ho hi 15,52 gam hn hp gm mt axit no n chc X v mt axit no a chc Y
(s mol X ln hn s mol Y), thu c mt th tch hi bng th tch ca 5,6 gam N2 (o trong cng
iu kin nhit , p sut). Nu t chy ton b hn hp hai axit trn th thu c 10,752 lt CO2
(ktc). Cng thc cu to ca X, Y ln lt l
19

A. H-COOH v HOOC-COOH.
B. CH3-COOH v HOOC-CH2-CH2-COOH.
C. CH3-CH2-COOH v HOOC-COOH.
D. CH3 -COOH v HOOC-CH2 -COOH.
Cu 110: (B 11) Hn hp M gm mt anehit v mt ankin (c cng s nguyn t cacbon). t chy
hon ton x mol hn hp M, thu c 3x mol CO2 v 1,8x mol H2O. Phn trm s mol ca anehit trong
hn hp M l
A. 30%.
B. 40%.
C. 50%.
D. 20%.
Cu 111: (B 11) hiro ho hon ton 0,025 mol hn hp X gm hai anehit c khi lng 1,64
gam, cn 1,12 lt H2 (ktc). Mt khc, khi cho cng lng X trn phn ng vi mt lng d dung dch
AgNO3 trong NH3 th thu c 8,64 gam Ag. Cng thc cu to ca hai anehit trong X l
A. CH2=C(CH3)-CHO v OHC-CHO.
B. OHC-CH2-CHO v OHC-CHO.
C. H-CHO v OHC-CH2-CHO.
D. CH2=CH-CHO v OHC-CH2-CHO.
Cu 112: (B 11) Hn hp X gm hai anehit n chc Y v Z (bit phn t khi ca Y nh hn ca Z).
Cho 1,89 gam X tc dng vi mt lng d dung dch AgNO3 trong NH3, sau khi cc phn ng kt thc,
thu c 18,36 gam Ag v dung dch E. Cho ton b E tc dng vi dung dch HCl (d), thu c
0,784 lt CO2 (ktc). Tn ca Z l
A. anehit acrylic.
B. anehit butiric.
C. anehit propionic. D. anehit axetic.
Cu 113: (B 11) X l hn hp gm H2 v hi ca hai anehit (no, n chc, mch h, phn t u c
s nguyn t C nh hn 4), c t khi so vi heli l 4,7. un nng 2 mol X (xc tc Ni), c hn hp Y
c t khi hi so vi heli l 9,4. Thu ly ton b cc ancol trong Y ri cho tc dng vi Na (d), c V
lt H2 (ktc). Gi tr ln nht ca V l
A. 22,4.
B. 13,44.
C. 5,6.
D. 11,2.
Cu 114: (B 11) Cho cc pht biu sau:
(a) Anehit va c tnh oxi ho va c tnh kh.
(b) Phenol tham gia phn ng th brom kh hn benzen.
(c) Anehit tc dng vi H2 (d) c xc tc Ni un nng, thu c ancol bc mt.
(d) Dung dch axit axetic tc dng c vi Cu(OH)2.
(e) Dung dch phenol trong nc lm qu tm ho .
(g) Trong cng nghip, axeton c sn xut t cumen.
S pht biu ng l
A. 4.
B. 2.
C. 5.
D. 3.
Cu 115: (B 11) Cho s phn ng:
+ HCN
+H ,t
(1) CH3CHO
X1 HO

X2
2

+ CO2
+ HCl
Y1
(2) C2H5Br
Y2
Y3.
+ ete
+ Mg

Cc cht hu c X1, X2, Y1, Y2, Y3 l cc sn phm chnh. Hai cht X2, Y3 ln lt l
A. axit 2-hiroxipropanoic v axit propanoic.
B. axit 3-hiroxipropanoic v ancol propylic.
C. axit axetic v axit propanoic.
D. axit axetic v ancol propylic.
Cu 116: (B 11) Hn hp X gm hai axit cacboxylic no, mch h Y v Z (phn t khi ca Y nh hn
ca Z). t chy hon ton a mol X, sau phn ng thu c a mol H2O. Mt khc, nu cho a mol X tc
dng vi lng d dung dch NaHCO3, th thu c 1,6a mol CO2. Thnh phn % theo khi lng
ca Y trong X l
A. 46,67%.
B. 40,00%.
C. 25,41%.
D. 74,59%.
Cu 117: (B 11) Cho s phn ng:
xt, to
(1) X + O2
axit cacboxylic Y1.
xt, to
(2) X + H2
ancol Y2.
xt, to
3) Y1 + Y2
Y3 (thun nghch)
Bit Y3 c cng thc phn t C6H10O2. Tn gi ca X l
A. anehit acrylic.
B. anehit propionic. C. anehit metacrylic. D. anehit axetic.
Cu 118: (C 11) Hn hp G gm hai anehit X v Y, trong Mx < My < 1,6 Mx. t chy hn hp G thu
c CO2 v H2O c s mol bng nhau. Cho 0,10 mol hn hp G vo dung dch AgNO3 trong NH3 thu
c 0,25 mol Ag. Tng s cc nguyn t trong mt phn t Y l
A. 10
B. 7.
C. 6.
D. 9.
H ,t
Cu 119: (C 11) Cho s chuyn ha: CH3CH2Cl KCN
X
Y


+

20

Trong s trn, X v Y ln lt l
A. CH3CH2CN v CH3CH2OH
B. CH3CH2NH2 v CH3CH2COOH
C. CH3CH2CN v CH3CH2COOH
D. CH3CH2CN v CH3COOH
Cu 120: (C 11) Dy gm cc cht xp theo chiu lc axit tng dn t tri sang phi l:
A. HCOOH, CH3COOH, CH3CH2COOH
B. CH3COOH, HCOOH, (CH3)2CHCOOH
C. C6H5OH, CH3COOH, CH3CH2OH
D. CH3COOH, CH2ClCOOH, CHCl2COOH
+ X(xt,t o )
+ Z( xt,t o )
+ M( xt,t o )
Cu 121: (C 11) Cho s phn ng: CH 4
Y
T
CH 3COOH
(X, Z, M l cc cht v c, mi mi tn ng vi mt phng trnh phn ng).
Cht T trong s trn l:
A. C2H5OH
B. CH3COONa
C. CH3CHO
D. CH3OH
Cu 122: (C 11) Hai cht hu c X, Y c thnh phn phn t gm C, H, O (M X < MY < 82). C X v Y
u c kh nng tham gia phn ng trng bc v u phn ng c vi dung dch KHCO 3 sinh ra kh
CO2. T khi hi ca Y so vi X c gi tr l:
A. 1,47
B. 1,61
C. 1,57
D. 1,91
Cu 123: (A 12) Hirat ha 5,2 gam axetilen vi xc tc HgSO 4 trong mi trng axit, un nng. Cho
ton b cc cht hu c sau phn ng vo mt lng d dung dch AgNO 3 trong NH3 thu c 44,16 gam
kt ta. Hiu sut phn ng hirat ha axetilen l
A. 80%.
B. 70%.
C. 92%.
D. 60%.
Cu 124: (A 12) t chy hon ton 7,6 gam hn hp gm mt axit cacboxylic no, n chc, mch h
v mt ancol n chc (c s nguyn t cacbon trong phn t khc nhau) thu c 0,3 mol CO 2 v 0,4
mol H2O. Thc hin phn ng este ha 7,6 gam hn hp trn vi hiu sut 80% thu c m gam este. Gi
tr ca m l
A. 4,08.
B. 6,12.
C. 8,16.
D. 2,04.
Cu 125: (A 12) Hn hp X gm axit fomic, axit acrylic, axit oxalic v axit axetic. Cho m gam X phn
ng ht vi dung dch NaHCO3 thu c 1,344 lt CO2 (ktc). t chy hon ton m gam X cn 2,016 lt
O2 (ktc), thu c 4,84 gam CO2 v a gam H2O. Gi tr ca a l
A. 1,62.
B. 1,80.
C. 3,60.
D. 1,44.
Cu 126: (A 12) Cho dy cc hp cht thm: p-HO-CH2-C6H4-OH, p-HO-C6H4-COOC2H5,
p-HO-C6H4-COOH, p-HCOO-C6H4-OH, p-CH3O-C6H4-OH. C bao nhiu cht trong dy tha mn ng
thi 2 iu kin sau?
(a) Ch tc dng vi NaOH theo t l mol 1 : 1.
(b) Tc dng c vi Na (d) to ra s mol H2 bng s mol cht phn ng.
A. 3.
B. 4.
C. 1.
D. 2.
Cu 127: (A 12) Ha hi 8,64 gam hn hp gm mt axit no, n chc, mch h X v mt axit no, a
chc Y (c mch cacbon h, khng phn nhnh) thu c mt th tch hi bng th tch ca 2,8 gam N 2
(o trong cng iu kin nhit , p sut). t chy hon ton 8,64 gam hn hp hai axit trn thu c
11,44 gam CO2. Phn trm khi lng ca X trong hn hp ban u l
A. 72,22%
B. 65,15%
C. 27,78%
D. 35,25%
Cu 128: (A 12) Cho s chuyn ha sau:
(a) C3H4O2 + NaOH X + Y
(b) X + H2SO4 (long) Z + T
(c) Z + dung dch AgNO3/NH3 (d) E + Ag + NH4NO3
(d) Y + dung dch AgNO3/NH3 (d) F + Ag +NH4NO3
Cht E v cht F theo th t l
A. (NH4)2CO3 v CH3COOH
B. HCOONH4 v CH3COONH4
C. (NH4)2CO3 v CH3COONH4
D. HCOONH4 v CH3CHO
H 3O +
KCN
Y
Cu 129: (A 12) Cho s chuyn ha : CH3Cl
X
t0
Cng thc cu to X, Y ln lt l:
A. CH3NH2, CH3COOH
B. CH3NH2, CH3COONH4
C. CH3CN, CH3COOH
D. CH3CN, CH3CHO
Cu 130: (B 12) Cho 0,125 mol anehit mch h X phn ng vi lng d dung dch AgNO 3 trong NH3
thu c 27 gam Ag. Mt khc, hiro ha hon ton 0,25 mol X cn va 0,5 mol H 2. Dy ng ng
ca X c cng thc chung l
A. CnH2n(CHO)2(n 0) B. CnH2n-3CHO (n 2) C. CnH2n+1CHO (n 0)
D. CnH2n-1CHO (n 2)
21

Cu 131: (B 12) Hn hp X gm hai axit cacboxylic n chc. t chy hon ton 0,1 mol X cn 0,24
mol O2 thu c CO2 v 0,2 mol H2O. Cng thc hai axit l
A. HCOOH v C2H5COOH
B. CH2=CHCOOH v CH2=C(CH3)COOH
C. CH3COOH v C2H5COOH
D. CH3COOH v CH2=CHCOOH
Cu 132: (B 12) Cho axit cacboxylic X phn ng vi cht Y thu c mt mui c cng thc phn t
C3H9O2N (sn phm duy nht). S cp cht X v Y tha mn iu kin trn l
A. 3
B. 2
C. 4
D. 1
Cu 133: (C12) Cho dy cc cht: etan, etanol, etanal, axit etanoic. Cht c nhit si cao nht trong
dy l
A. etanal
B. etan
C. etanol.
D. axit etanoic.
Cu 134: (C12) Cht no sau y va tc dng c vi dung dch NaOH, va tc dng c vi nc
Br2?
A. CH3CH2CH2OH B. CH3COOCH3
C. CH3CH2COOH. D. CH2=CHCOOH.
Cu 135: (C12) Trong phn t axit cacboxylic X c s nguyn t cacbon bng s nhm chc. t chy
hon ton mt lng X thu c s mol CO2 bng s mol H2O. Tn gi ca X l
A. axit axetic.
B. axit oxalic.
C. axit fomic.
D. axit malonic
t
Cu 136: (C12) Cho cc phn ng sau: X + 2NaOH 2Y + H2O (1) Y + HCl (long) " Z + NaCl (2)
Bit X l cht hu c c cng thc phn t C 6H10O5. Khi cho 0,1 mol Z tc dng ht vi Na (d) th s
mol H2 thu c l
A. 0,20
B. 0,15
C. 0,10
D. 0,05
0

22