Планирование эксперимента в химии и химической технологии (С.А Семенов)

. ..
()

. . ..
..
, 2001 .
www.mitht.ru/e-library
66-9.001.4/.5:65.012.2
24:30.606:6
: . ..
..
. - . .: , 2001 ., 93 .
. ,
...... 5
1. 8
1.1. .... 8
.. 4
(STATGRAPHICS
Plus for Windows 2.1;Excel 97; Mathcad 8 PRO).

6-
,
551600
5- , 072200
, ( ) .
1.2. ... 11
1.3. .16
1.4. .. 18
2. - 20
2.1. ........ 20
2.2. ........ 21
2.3. ... 38
2.4. . 42
2.5. .. 45
3. ..... 51
3.1. .. 51
3.2. ... 59
4. .
. .., 2001

...... 70
5.
N .
- .. 79
P .
5.1. .... 79
2
s
- .
5.2. -
82
s 2y
1. . 89
t .
2. ..90
xi .
3. .... 91
Xi .
4. . 92
yj .
..... 93
- .
- .
i .
xi xi.
.
bi .
B .
f .
. -
F .
G .
, ,
i . j .
k .
[1]. -
n .
.. .[2].
..,
..,
..,
()
. -
. 20- . -
STATGRAPHICS Plus for Windows 2.1 [3];
Excel 97 [4]; Mathcad 8 PRO [5, 6]
1951 . -
. ..
, -
. , , .

1.
, -
1.1.
, (.1).
, -

,
.
,
, . , , , , .
1, 2 ..
, .

(1, 2) (
c ). .2 .

, -
- -
.2.
, ,
, .. -
. 1.
y1, y2 ..
.
yj=yj(xi,...,xn)
j=1, 2,..., m.
, y.
(1.1)
y.
10
11
, .2. x1 x2. .
, .2,
.
. y , . .2, , .

. 2. .
, .
,
1.2.

.
, . ,
y=f(x1,x2,x3), x1-const, x2=const x3=const.
, , . .
13
12
. 1. -
1
y ji
k i 1
(j=1,2,...,N)
(1.2)
k - ,
, kj
N k 2 4.

:
s2j
1 k
( y ji y j ) 2
k 1 i1
(1.3)
yj
s 2j
1
2
3
y11 y12 ... y1k y1

y21 y22 ... y2k y 2
y31 y32 ... y3k y 3
...
j
... ... ... ...

yj1 yj2 ... yjk
...
N
... ... ... ... ...

yN1 yN2 ... yNk y N
s12
s 22
s 32
...
s 2j
...
s 2N
...
yj
Gp
max s
N
2
j
=0.95,

(1.4)
. p=1-P -
s2j
j1
G -
. G, -
N -
1, ,
f, , f=k-1.
14
15
Gp G
Samples
. OK. -
(1.5)
,
- . ,
, .

,
.

STATGRAPHICS Plus [3]. ,
StatFolio ,
Compare. , Multiple
Multiple
Samples
Comparison. Tabular Options,

Variance Check , OK,
(Cochrans C test). The StatAdvisor .
1.1. ,
y (%),
x1 (C) x2 (%).
.2.

:
Samples, Multiple
Gp
Samples Comparison.
max s 2j
s 2j
1.28
0.51
0.50 0.72 1.28
, ,
G=0.967 1.
16
17
s 2y
x1, C
x2, %
yj1, %
s 2j
y j ,%
1 N 2
sj
N j1
(1.6)
.
f=N(k-1).
.2
yj2, %
24
45
35.0
36.0
35.5
0.50
1
s 2y (0.50 0.72 1.28) 0.83
3
24
55
39.3
38.1
38.7
0.72
f=N(k-1)=3(2-1)=3
26
45
31.8
33.4
32.6
1.28
: =0.95; N=3; f=k-
2
y
1=2-1=1.
GpG , ,
s 2y
k
(1.7)

f=N(k-1).
1.1
1.3.
s 2y
0.83
0.42
2
y,
18

s 2y .
19
III - 05
, -
VI - 30
, -
s2y.
III, II, IV, VI, V, I ( I, V, VI, IV, II, III)

-
1.4.

, , .
, (.
2).
Excel [4].
, , , .

. . . -
, ,
6 , I, II,,VI.
6 ,
2. , .
, :
I - 60
IV - 15
II - 12
V - 34
, . .
.
. OK.
.
. 1
, ,
.
20
21
100 , .. -
100 .
1 100 , - -
. -
,
, -

, :
, 1. OK. -
- ;
;
- .
2. -
,
, -
-.
2.1.
, -
2.2.
. -
23
22
-
Xi -
(x01, x02, ...,
x0n).

. 3. .
(.3). -
y= 0+ 1X1+ 2X2++ nXn+ 12X1X2++

+ (n-1)nXn-1Xn+ 11X21+ 22X22++ nnX2n+
(2.2)
Xi=(xi-x0i)/xi
(i=1,2,...,n)
(2.1)
xi - Xi.
x0i xi
. -
x imax x imin
x 0i
;
2
,
-
x imax x imin
x i
;
2
0=y(0, ..., 0) -
max
i
min
i
. ,
,
24
25
, , -
x2
.
, ,
, b.
x1
, 0
y=b0+b1X1+b2X2+...+bnXn+
+b12X1X2+...+
+b(n-1)nXn-1Xn
(2.3)
. 4. .
-
.
-
.3 -
, ,
+1 -1.
, .3,
, -
(.4).
26
27
X1
X2
-1
+1
-1
+1
-1
-1
+1
+1
.
:
X ji 0
(2.4)
j1
N
1
2
3
4
X 2ji N
y1
y2
y3
y4
(2.5)
j1
N
X jl X jm
( lm).
(2.6)
j1
N - . 4 -
j - ;
i,l,m - .
. .5
, (2.6),
. ,
. 3,4 5 -
(. , 2.8-2.10).

;
,
N=2n,
(2.7)
28
29
X1
X2
X3
X4
-1
-1
-1
-1
y1
+1
-1
-1
-1
y2
-1
+1
-1
-1
y3
X1
X2
X3
-1
-1
-1
y1
+1
-1
-1
y2
-1
+1
-1
y3
+1
+1
-1
-1
y4
+1
+1
-1
y4
-1
-1
+1
-1
y5
-1
-1
+1
y5
+1
-1
+1
-1
y6
+1
-1
+1
y6
-1
+1
+1
-1
y7
-1
+1
+1
y7
+1
+1
+1
-1
y8
+1
+1
+1
y8
-1
-1
-1
+1
y9
10
+1
-1
-1
+1
y10
11
-1
+1
-1
+1
y11
12
+1
+1
-1
+1
y12
13
-1
-1
+1
+1
y13
14
+1
-1
+1
+1
y14
15
-1
+1
+1
+1
y15
16
+1
+1
+1
+1
y16
n .
, :
1 N
b0 y j
N j1
(2.8)
31
30
1 N
b i X ji y j
N j1
1 N
b lm X jl X jm y j
N j1
(2.9)
,
.
( lm)
(2.10)
,
, .. -
. , -
, - , -
, -
Fp
s 2b
s 2y
N
(2.11)
2
s
max(s 2 , s 2y )
2
2
y
min(s , s )
(2.13)
- .
C -
(2.13) ,
- -
bsbt
(2.12)
1 N
s
( y j y pj ) 2
N B j1
2
t - (.
3). , t
,
s 2y .
(2.14)
-
, ;
32
33
yj, ypj - -
j- ;
Dependent Variable -
N - .
, ,
Independent
Variables ,
. OK.
(2.15)
, - -
f=N-B
FpF,
(2.16)
F - ( 4).
2.1. ,
y (%)
x1 (C) -
x2 (%).
(2.13).
,
-

x01=50C x02=25 %.
. -
STATGRAPHICS Plus [3]. ,
StatFolio
, -
y=b0+b1X1+b2X2
Multiple regression.
35
34
X1
x1 x 01
x x 02
, X2 2
x 1
x 2

, .6.
1
b 0 (35.5 38.7 32.6 36.2) 35.6
4
1
b1 (35.5 38.7 32.6 36.2) 1.95
4
6
7
X2
x1, C
x2, %
-1
-1
45
24
35.5
+1
-1
55
24
38.7
26
-1
+1
45
26
32.6
24
+1
+1
55
26
36.2
x1, C
x2, %
50
25
55
45
. 7.

,
(2.8) (2.9):
y,
X1
1
b 2 (35.3 38.7 32.6 36.2) 1.35
4
,
s 2y
1.3 0.42. ,
3 .
37
36

sb
s 2y
N
y1p 35.6 1.95(1) 1.35(1) 35.0
0.42
0.32
4
y p2 35.6 1.95(1) 1.35(1) 38.9

y 3p 35.6 1.95(1) 1.35(1) 32.3
3, , -
y p4 35.6 1.95(1) 1.35(1) 36.2
=0.95 3 t=3.18.
(2.14) -
Sbt=0.323.18=1.03

2
s
1 N
1
p 2
[(35.5 35.0) 2
(y j y j )
N B j1
43
b 0 35.6 s b t
(38.7 38.9) 2 (32.6 32.3) 2 (36.2 36.2) 2 ]
b1 1.95 s b t
0.38

b 2 1.35 s b t
f=N-B=4-3=1.
,
. ,
Fp
y=35.6+1.95X1-1.35X2

2
max(s
; s 2y )
2
2
y
min(s ; s )
0.42
1.11
0.38
38
39
,
4. ,
2.3.
X1
X2
X3
-1
-1
-1
y1
+1
-1
-1
y2
-1
+1
-1
y3
+1
+1
-1
y4
-1
-1
+1
y5
+1
-1
+1
y6
-1
+1
+1
y7
+1
+1
+1
y8
(2.7).
, .
: 1/2, 1/4 ..
(. .8).
, -
1/4
1/2
1/4
1/4
1/2
1/4
, ,

8 . c .
y=b0+b1X1+b2X2+b3X3
40
41
. 8 X1X2 -
(. 9) -
X3 .
X1X2 X3.
b12 b3 . -
23-1
X1
X2
X1X2
X3
(2.9)
1
4
b12+b3= (y1-y2-y3+y4)
-1
-1
+1
+1
y1
+1
-1
-1
-1
y2
-1
+1
-1
-1
y3
4.
+1
+1
+1
+1
y4
(2.8), :
1
4
b0= (y1+y2+y3+y4)
(2.9) :
, . 2n-p, n - , - ,
. . 8 23-1.
1
4
b1= (-y1+y2-y3+y4)
1
4
b2= (-y1-y2+y3+y4)
42
43
2.4. -

X, . X=X1X2X3.

,

, -
,
X=+1, - X=-1.
, .9, 24-1
X=X1X2X3.
.
, -
, ,
, -
, ,
- . ,
.. -
, ,
- (, , -
, ).
y=b0+b1X1+b2X2+b3X3+b12X1X2+b23X2X3+
, -
+b123X1X2X3
, -
, .
b00;
b22
b11;
b33
45
44
b1212;
1
8
b2323
b1313;
b1= [-(y1+)+(y2+)-(y3+)+(y4+)-(y5-)+
b123123+
1
8
+(y6-) --(y7-)+(y8-)]= (-y1+y2-y3+y4-y5+y6 10
-y7+y8)
X1
X2
X3
X=X1X2X3
1
8
b123= [(y1+)+(y2+)+(y3+)+(y4+)-(y5-)-(y6
1
8
-)-(y7-)-(y8-)]= (y1+y2+y3+y4-y5-y6-y7-y8)+
-1
-1
+1
+1
y1+
+1
-1
-1
+1
y2+
, ,
-1
+1
-1
+1
y3+
b123, , -
+1
+1
+1
+1
y4+
-1
-1
-1
-1
y5-
+1
-1
+1
-1
y6-
2.5.
-1
+1
+1
-1
y7-
, -
+1
+1
-1
-1
y8-
, . -
, , b1 b123:
46
47
, - .
. -
ymin, ,
, -
, -
,
-
. , -
[7]. -
, . ,
. . -
- .
, .
. -
. , -
, - . -
, -
(. 3) "" .
ymax, ,
, -
48
49
, ..
, , ,
, , , -
, -
, -
, -
, . -
: -
, -
, -
. ,
. ,
. -
, -
. ,
, ,
( ).
x1 x2
, .
, x1 x2 -
50
51
, . -
). ,
. -
? ,
). -
. :
: -1 -1. -
..
, . -
3.

.
: ,
( ),
.

.
, x1x2x3,
.
,
3.1.

- .
, .
,
. ,
52
53
. -
( ,
, -
).
. .
, . -
. .
, -
, , -
y, -
- , -
(2.3).
, , -
. ,
, .
b1x1.
, .
, -
. x1*x1.
54
x1*
b1x1
55
2. y.
(3.1)
, - y
xi*=bixi
(3.2)
,

.
(2.3), -
(.5).
, .
xi .
(2.3),
y,
. -
xi .
.

:
1.
.
56
57
3.1. -
4 ,
( 2.1)
x1*
4
0.41
b1x1 195
. 5
y1=35.6+1.95X1. 5. .
x1 ( 2.1).
1.35X2
2.1, y1 - , X1 - , X2
x2*=b2x2=0.41(-1.35).1=-0.55
- .
y 2,
-3. -1
( ). ,
, (3.2), . x2*=0.5o.
y22.5.
, -
, . 11,
30 x1120
y1
- -
10%x270%

.
y1p
y 2
- .

59
58
x1, x2 ,
11.
.11, N 4 -
x1
x2
X1
X2
50
25
35.6
35.1
2.9
-0.5
0.8
-0.5
p
1
. -
N 3. x1 x2
.
3.2.

N 1
54
24.5
0.8
-0.5
36.5
36.9
3.2
N 2
58
24.0
1.6
-1.0
37.4
37.2
3.7
N 3
62
23.5
2.4
-1.5
38.2
38.5
2.8
N 4
66
23.0
3.2
-2.0
39.1
40.7
2.3
, n+1 , n - ,
. , .

.6.
N 5
70
22.5
4.0
-2.5
40.0
38.1
1.9
N 6
74
22.0
4.8
-3.0
40.9
37.2
1.6
(2.1)
60
61
-
. 6. .
, -
5.
(-
1, 2, 3).
, -
"" -
,
,
.
-
1, 2 3,
. ,
, -
, ""
1. ,
. ,
4, -
1 -
, -
, 2
3.
62
63
12
, .
, .. .
, .
.12.
X1
X2
...
Xn-1
Xn
k1
k2
...
kn-1
kn
y1
-R1
k2
...
kn-1
kn
y2
-R2
...
kn-1
kn
y3
...
...
...
...
...
...
...
n-1
...
kn-1
kn
yn-1
...
-Rn-1
kn
yn
n+1
...
-Rn
yn+1
"0" , .. , . 11,
.
, , -
, , ( -
).
1
ki
2i(i 1)
Ri=iki
i - .
(3.3)
,
. 12 (3.3) (3.4), . 13.
(3.4)
64
65
xi
. 12 13
,
2 n1
( x ji x*i ) x*i
n j1
(3.6)
n - ;
j - ;
xi=x0i+xiXi
(3.5)
, (2.1).
-
i - ;
xi* - i-
.
,
13

X1
X2
X3
,
, -
X4
1 n 1
xi
x ji
n 1 j1
0.5
0.289
0.204
0.158
-0.5
0.289
0.204
0.158
-0.578
0.204
0.158
i=1,2,...,n, .. -
-0.612
0.158
-0.632
(3.7)
66
67
14
xn+1=x0(n+1)+xn+1(Rn+1+kn+1)
(3.8)
x0(n+1) - ;
xn+1 -
x1, .-3
1.0
0.1
x2, .-3
1.5
0.2
x3, oC
60.0
5.0
;
Rn+1, kn+1 - , (3.3) (3.4).

. .

.15.
,
x31=1+0.1.0=1
. 1962 .
3.2 -
x32=1.50+0.2(-0.578)=1.38
x33=60+5.0.204=61
(%),
.
-3
x1 x2 ( )
o
x3 ( ).
,
- .

, ,
. 14.
. -
(3.5) .12, -
68
69
15

x1
x2
x3
.
,
1.05
1.56
61
72.3
0.95
1.56
61
70.1
1.00
1.38
61
65.4
1.00
1.50
57
68.2
1.00
1.70
58
73.9
1.00
1.72
63
76.5
, , .
500 /.
x4
x4=100 /.
(.
.15) N 1,2,5 6.
,
N 7 (.16). N 7 (3.7) (3.8):
N 5, -
x71=(1/4)(1.05+0.95+2.1.00)=1.00
(3.6):
x72=(1/4)(2.1.56+1.70+1.72)=1.64
x51=(2/3)(1.05+0.95+1.00)-1.00=1.00
x73=(1/4)(2.61+58+63)=61
x52=(2/3)(2.1.56+1.50)-1.38=1.70
x74=500+100(0.632+0.158)=579580
x53=(2/3)(2 61+57)-61=58
, N 1, 2,
4 5, "" N 4. -
,
.
N 6, , (3.6).
70
71
16.
(). -
x1
x2
x3
x4
1.05
1.56
61
500
72.3
0.95
1.56
61
500
70.1
1.00
1.70
58
500
73.9
1.00
1.72
63
500
76.5
1.00
1.64
61
580
78.1
N=2n+2n+1
(4.1)
2n - , ;
2n - ,
(,0,0,...,0);
(0,,0,...,0),...,
(0,0,...,). , -
4.
- ;
1 - , ..
(0,0,...,0) (
). -
(2.3). -
(2.3),
""
, , .
73
72
-
. -
y=bo+b1X1+b2X2+...+bnXn+b12X1X2+...
+b(n-1)nXn1Xn+ +b11X12+b22X22+...+bnnXn2

n :
n .............2
b11 N 2
b nn N 2
b0 b
X j1 ... X jn
N j1
N j1
*
0
..........1.000 1.215 1.414 1.547

.
, .7
.
y=bo*+b1X1+b2X2+...+bnXn+b12X1X2+...+b(n-1)nXn+b11X1*+...+bnnXn*
1 N
b yj
N j1
*
0
(4.2)
1 N
X X X 2ji
N j1
*
ji
2
ji
(4.5)
.17
1Xn+
(4.4)
(4.6)
X ji y j
(4.3)
j - ; i - ,
, , .

bi
j1
N
( X ji )
j1
( i0)
2
(4.7)
74
75
:
X2
+1
s b*
s2y
2
b0
s s b*
-1
+1
(4.10a)
ns2bii
N
X 2ji
(4.10)
j1
17
X1
X1
X2
X1X2
X1*
X2*
-1
-1
+1
+0.33
+0.33
+1
-1
-1
+0.33
+0.33
-1
+1
-1
+0.33
+0.33
+1
+1
+1
+0.33
+0.33
+1
+0.33
-0.67
-1
+0.33
-0.67
+1
-0.67
+0.33
-1
-0.67
+0.33
-0.67
-0.67
o
-1
.7.
: - ; * - ; - .
N
X*ji y j
b ii
j1
N
(4.9)
( X*ji ) 2
i 1
76
2
bi
77
b. , -
s2y
( i0)
( X ji )
(4.10)
( ): b11, b1, b0, b2, b22, b12.
j1
s2bik
2
y
( ik)
(4.11)
( X ji X jk ) 2
j1
D- . D-
2
b ii
s2y
(4.12)
( X*ji ) 2
bi
.
D- -
j1
bi> sb t . i
, . , . [8] , -
. -
0.8-1.2.
Mathcad 8 PRO [5].
Y. -
b=regress(X,Y,n), n ,
Mathcad 8 PRO [5,6]. -
n=2.
78
79
, .
5.
f(x,y),
. N
,
x, y.
i j xi, yj . i:=0..N j:=0..N.
5.1.
,
,
(q-1)- [9].
q
xi yj
xi
, -
i 1
1,
(5.1)
i j. -
xi0 - ; q -
zij -
, zij=f(xi,yj). Insert
- :
Graph
Surface Plot
. q=3 - -
, z
, ,
. ,
.
, - .
80
81
(y)
- ,
-
y=b1x1+b2x2+b3x3+b12x1x2+b13x1x3+b23x2x3.
18 .
. -
18

,
-
(5.2)
, -
3 (-
10
15
10
14
20
35
15
25
35
70
, , .
21
41
56
126
36
92
120
330
, -
10
55
175
220
715
. .
, .

,
82
83
5.2. -
- , [9]. (q-1) . {q, n}- , q -

; n - . .
(n+1)
xi=0, 1/n, 2/n, , 1

. , {q, 2},
.8. {3, n}-: ; ;

;
.

(n=2),
: 0, 1/2 1, (n=3) 0, 1/3, 2/3 1 .. {3, n}- .8.
.
{3, 3*}, , {3, 2},
; {3, 4} - {3, 2}.
85
84
,
(.18). -
{3, 2} (.19).
bi=yi,
19
bij=4yij-2yi-2yj.
{3, 2}-
N
x1
x2
x3
y1
y2
y3
1/2
1/2
y12
1/2
1/2
y13
. -
1/2
1/2
y23
. -
, 1 x1,
y1, 4
1/2x1 1/2x2, y12.
. -
. -
(5.2)
86
87
n,
s 2y s 2y
,
n
-, -
(5.3)
,
. -
1 i q
a i2
a ij2 .
(5.4)
1 i j q
(5.4) -
y
s 2y s 2y
y n
,
s 2y 1
,
-
y y y ;
n -
. t,
(.9).
, tp/2l(f), p - ; l - ; f - .
,
t<t .

.9. ()
().
y y y ,
t p / k ,f s y ,
89
88
k - -
. (5.3)
t p / k ,f
sy
n
(=0.95)
1 / 2 .
N
f=k-1
0.999
0.975
0.939
0.906
0.877
0.853
(.9),
0.967
0.871
0.798
0.746
0.707
0.677
0.907
0.768
0.684
0.629
0.590
0.560
0.841
0.684
0.598
0.544
0.507
0.478
0.781
0.616
0.532
0.480
0.445
0.418
0.727
0.561
0.480
0.431
0.397
0.373
0.680
0.516
0.438
0.391
0.360
0.336
0.639
0.478
0.403
0.358
0.329
0.307
10
0.602
0.445
0.373
0.331
0.303
0.282
12
0.541
0.392
0.326
0.288
0.262
0.244
15
0.471
0.335
0.276
0.242
0.220
0.203
t p / k ,f
sy
n
1 / 2 .
90
91
66 25 32 38 64 70 26 27 67 77 40 04
(=0.95)
40 52 02 29 82 69 34 50 21 74 00 91
63 88 23 62 51 07 69 59 02 89 49 14
12.71
11
2.20
25 21 15 08 82 34 57 57 35 22 03 33
4.30
12
2.18
61 88 23 13 01 59 47 64 04 99 59 96
3.18
13
2.16
2.78
14
2.14
2.57
15
2.13
2.45
16
2.12
2.36
17
2.11
2.31
18
2.10
2.26
19
2.09
10
2.23
20
2.09
44 08 67 79 41 61 41 15 60 11 88 83
24 40 09 00 65 46 38 61 12 90 62 41
27 84 05 99 85 75 67 80 05 57 05 71
39 30 02 34 99 46 68 45 15 19 74 15
43 96 38 13 83 80 72 34 20 84 56 19
85 77 30 16 69 32 46 46 30 84 20 68
48 84 88 24 55 46 48 60 06 90 08 83
19 05 68 22 58 04 63 21 16 23 38 25
81 87 21 31 40 46 17 62 63 99 71 14
43 75 12 91 20 36 25 57 92 33 65 95
92
93
4
(=0.95)
f1
( )
f2
161.45
199.50
215.71
224.58
18.51
19.00
19.16
19.25
10.13
9.55
9.28
9.12
7.71
6.94
6.59
6.39
6.61
5.79
5.41
5.19
5.99
5.14
4.76
4.53
5.59
4.74
4.35
4.12
5.32
4.46
4.07
3.84
5.12
4.26
3.86
3.63
10
4.97
4.10
3.71
3.48
1. . . 3- . 1: / .., .., .. ./
. .. - .: , 1996. - 376 .
2. C.. . .: , 1975. - 48 .
3. . .
: , 1997. 240 .
4. . Microsoft Excel 97 : 2
. : BHV - -, 1997. . II. - 640 .
5. .., .. Mathcad 8 PRO
, Internet. : , 1999. 512 .
6. .., .. Mathcad: : .
. .: , 1999. - 656 .
7. .., .., ..

. .: , 1976. 279 .
8. .., ..
. .:
, 1980. 280 .
9. .., ..
. .:
. , 1978. - 319 .
6090/16
. . .

... 4.1. 100 . ___
-
..
117571, , . ,86

Язык

Планирование эксперимента в химии и химической технологии (С.А Семенов)

Загружено:

Сведения о документе

Авторское право

Доступные форматы

Поделиться этим документом

Поделиться или встроить документ

Параметры публикации

Этот документ был вам полезен?

Это неприемлемый материал?

Авторское право:

Доступные форматы

Планирование эксперимента в химии и химической технологии (С.А Семенов)

Загружено:

Авторское право:

Доступные форматы

. ..

Plus for Windows 2.1;Excel 97; Mathcad 8 PRO).

STATGRAPHICS Plus for Windows 2.1 [3];

Excel 97 [4]; Mathcad 8 PRO [5, 6]

y=f(x1,x2,x3), x1-const, x2=const x3=const.

y11 y12 ... y1k y1

... ... ... ...

... ... ... ... ...

Comparison. Tabular Options,

: =0.95; N=3; f=k-

III, II, IV, VI, V, I ( I, V, VI, IV, II, III)

(x01, x02, ...,

y= 0+ 1X1+ 2X2++ nXn+ 12X1X2++

STATGRAPHICS Plus [3]. ,

y1p 35.6 1.95(1) 1.35(1) 35.0

y p2 35.6 1.95(1) 1.35(1) 38.9

y p4 35.6 1.95(1) 1.35(1) 36.2

(38.7 38.9) 2 (32.6 32.3) 2 (36.2 36.2) 2 ]

+(y6-) --(y7-)+(y8-)]= (-y1+y2-y3+y4-y5+y6 10

..........1.000 1.215 1.414 1.547

( ): b11, b1, b0, b2, b22, b12.

Mathcad 8 PRO [5].

Mathcad 8 PRO [5,6]. -

- , [9]. (q-1) . {q, n}- , q -

.8. {3, n}-: ; ;

1/2x1 1/2x2, y12.

Вам также может понравиться