Reaksi Pembakaran

CH4 + 3O2 --> CO2 + 2H2O

C2H6 + 5O2 --> 2CO2 + 3H2O
C3H8 + 7O2 --> 3CO2 + 4H2O
2CO + O2 --> 2CO2
2H2 + O2 --> 2H2O

Bahan Bakar Gas

F1 = 100 mol
CH4 = 30%
C2H6 = 22%
C3H8 = 8%
CO = 8%
H2 = 18%
N2 = 14%
T1 = 25oC

Udara
F2 = ...
O2 = 21%
N2 = 79%
T2 = 25oC
Molekul BBG
(senyawa)
CH4
C2H6
C3H8
CO
H2
Jumlah

Jumlah mol Kebutuhan O2

(mol)
(mol)
30
22
8
8
18
100

Kebutuhan Udara Teoritis

F2 Teoritis

90
110
56
4
9
269

Panas Pembakaran Emisi CO2 Emisi H2O

(kJ)
mol
mol
26724
30
60
34335.4
44
66
17753.6
24
32
2264
8
0
5144.4
0
18
86221.4
106
176
172442.8
282

1280.952381 mol
1280.952381 mol

Excess Air
Temperatur(Celcius) O2
2%
4286.635638
5%
4171.746827
10%
3993.439208
13%
3893.629952
15%
3829.83365
20%
3679.183798

Flue Gas(persen)
N2
H2O
0.403427959 78.45035 13.19764
0.9803207 78.46574 12.82799
1.873196936 78.48957 12.25586
2.371689704 78.50287 11.93644
2.689829217 78.51136 11.73259
3.439583524 78.53137 11.25217

T adiabatik vs Excess Air

CO2
7.948581
7.725948
7.381371
7.188994
7.066218
6.776875

T adiabatik vs Excess Air

4400
4300

Temperatur(Celcius)

4200
4100
4000
3900
3800
3700
3600
0%

5%

10%

15%

Persen Udara Berlebih

20%

25%

Flue Gas
F3 = ...
CO2 = ...%
H2O = ...%
N2 = ...%
O2 = ...%
T3 = ...

O2 + 3H2O
CO2 + 4H2O

O2 = 21%
N2 = 79%
C
Excess Air 5%
F2 =
1345
Komposisi F3
mol
CO2
106
H2O
176
O2
13.45
N2
1076.55
F3 =
1372
Cp total
41.58508
T
4146.747
T3
4171.747

Excess Air 2%
F2 =
1306.571
Komposisi F3
mol
CO2
106
H2O
176
O2
5.38
N2
1046.191
F3 =
1333.571
Cp total
40.46399
T
4261.636
T3
4286.636

Data Kalor Pembakaran

CH4
890.8
C2H6
1560.7
C3H8
2219.2
CO
283
H2
285.8

Nilai Cp Gas (bukan fungsi tempera

CH4
35.06014
C2H6
52.95187
C3H8
74.91745
CO
29.1572
H2
28.83295
N2
29.11563
O2
29.38999
CO2
37.13864
H2O
33.57193

mol
persen
7.725948
12.82799
0.980321
78.46574
mol
kJ/K
oC
oC

Excess Air 10%

F2 =
1409.048
Komposisi F3
mol
CO2
106
H2O
176
O2
26.9
N2
1127.148
F3 =
1436.048
Cp total
43.45356
T
3968.439
T3
3993.439

mol
persen
7.381371
12.25586
1.873197
78.48957
mol
kJ/K
oC
oC

mol
persen
7.948581
13.19764
0.403428
78.45035
mol
kJ/K
oC
oC

Excess Air 13%

F2 =
1447.476
Komposisi F3
mol
CO2
106
H2O
176
O2
34.97
N2
1157.506
F3 =
1474.476
Cp total
44.57464
T
3868.63
T3
3893.63

mol
persen
7.188994
11.93644
2.37169
78.50287
mol
kJ/K
oC
oC

Konsentrasi Flue Gas terhadap Excess Air

Konsentrasi Flue Gas terhadap Excess Air

90
80

Persen Flue Gas

70
60
50

O2

40

N2
H2O

30

CO2
20
10
0
0%

5%

10%

15%

% Udara Berlebih

20%

25%

Pembakaran
kJ/mol
kJ/mol
kJ/mol
kJ/mol
kJ/mol

s (bukan fungsi temperatur)

J/mol K
J/mol K
J/mol K
J/mol K
J/mol K
J/mol K
J/mol K
J/mol K
J/mol K

Excess air 15%

F2 =
1473.095
Komposisi F3
mol
CO2
106
H2O
176
O2
40.35
N2
1177.745
F3 =
1500.095
Cp Total
45.32203
T
3804.834
T3
3829.834

mol
persen
7.066218
11.73259
2.689829
78.51136
mol
kJ/K
oC
oC

Excess air 20%

F2 =
1537.143
Komposisi F3
mol
CO2
106
H2O
176
O2
53.8
N2
1228.343
F3 =
1564.143
Cp Total
47.19051
T
3654.184
T3
3679.184

mol
persen
6.776875
11.25217
3.439584
78.53137
mol
kJ/K
oC
oC