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) ( , r n
f
Porosity Porosity: can be defined as a porosity distribution
l g g c c
r V r V r + + = ) ( ) ( ) (
=
=
=
l
g
c
where
capillary porosity
gel porosity
Interlayer porosity
=
=
) (
) (
r
g
r
c
V
V
volume of capillary pores
volume of gel pores
( )
) ( ) (
exp 1
r
i
r
i
B V =
( ) g c i , = 1 0
) (
r
i
V
Yonsei CMME Lab.
Remark Remark
hcp
a cement particle
) (r
l g g c c
r V r V r + + = ) ( ) ( ) (
formation of micro pores
r
hydration
products
Hydration
Yonsei CMME Lab.
Micro observation Micro observation
anhydrous
inner product
outer product
(C-H-S gel)
r
C-S-H gel
free space
average radius
(before contact to adjacent free surface)
(after contact to adjacent free surface)
1.0
28 . 0 =
ch
) 1 ( =
n
n
m ch u
ch
const hcp =
max
ln(1/B)
r ln
Br
e Br
dV
Yonsei CMME Lab.
) (
) ln(
) (
r f e Br
r d
r dV
Br
= =
Remark Remark
r ln
ln d
dV
s
r
1
) ln(r
dV
r=1=(1/B)
B=1
1
0.368
368 . 0 ) (
) ln( , 1
1
0 ) (
=
=
= =
r f
r r
B
r r f
if
) exp( 1 :
0
s
r
Br dV S V
s
= =
P p
Q P k div
t
P
Pore
distribution
Pore radius
Saturation
degree
Relative
humidity
liquid vapour
dry
wet
Virgin curve
Sink
So
0
1
1
Moisture
capacity of
pore str.
Moisture
transfer of
liquid and
vapour
Loss of moisture due to
hydration and pore structure
formation
Yonsei CMME Lab.
Solution of moisture transfer
Solution of moisture transfer
Governing Equation ;
Chemically
combined water
Moisture
diffusivity
Moisture capacity
Pore pressure,
P
Hydration heat
Thermal
conductivity
Thermal capacity
Temperature,
T
Sink term,
Q
Conductivity,
D
Specific capacity,
Variable,
X
0
2
= +
Q X
t
X
D