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1.

Given vapour pressure and temperature data and assuming that heat of vaporization is
independent of temperature, devise a graphical method of predicting the heat of
vaporization from the Clausius-Clapeyron equation. Vapour pressure of 2,2,4-trimethyl
pentane at various temperatures is given below. Use your method to estimate the heat of
vaporization for this compound. Comment on the validity of your assumption. (R=8.314
Joules mol
-1
K
-1
)
P
vap
(kPa) 1.333 2.666 5.333 8.000 13.33 26.66
T (K) 268.85 280.65 293.85 302.25 313.85 331.25