UNIVERSIDAD DE SAN CARLOS DE GUATEMALA

FACULTAD DE CIENCIAS QUIMICAS Y FARMACIA

ESCUELA DE QUIMICA
DEPARTAMENTO DE ANALISIS INORGNICO
ANLISIS INORGNICO I, 2014
CURVA DE NEUTRALIZACIN ENTRE UN CIDO FUERTE Y UNA BASE FUERTE

Base
No. Vol
1
0.0
2 10.0
3 25.0
4 45.0
5 70.0
6 73.0
7 74.0
8 74.5
9 74.9
10 75.0
11 75.5
12 78.0
13 80.0
14 85.0
15 90.0

mmol
0
4.5
11.25
20.25
31.5
32.85
33.3
33.53
33.71
33.75
33.98
35.1
36
38.25
40.5

0.45 M
0.45 M
cido
mmol
33.75
29.25
22.5
13.5
2.25
0.9
0.45
0.225
0.045
0

33.75 mmol
75 mL
Base

0.225
1.35
2.25
4.5
6.75

Concentracin
M
0.4500
0.3441
0.2250
0.1125
0.0155
0.0061
0.0030
0.0015
0.0003
0.0000
0.0015
0.0088
0.0145
0.0281
0.0409

cido
Base

Pto estequimtrico

pH

pOH

0.347
0.463
0.648
0.949
1.809
2.216
2.520
2.822
3.523
7.000
11.175
11.946
12.162
12.449
12.612

Neutralizacin AB-BF
HCl 0.45 M vr NaOH 0.45M
14.000
12.000

Uniades de pH

75 mL
33.75 mmol

10.000
8.000

6.000
4.000
2.000

2.8
2.1
1.8
1.6
1.4

0.000
0.0

10.0

20.0

30.0

40.0

50.0

60.0

70.0

Volumen de Base (Titulante) agregado

80.0

90.0

100.0

UNIVERSIDAD DE SAN CARLOS DE GUATEMALA

FACULTAD DE CIENCIAS QUIMICAS Y FARMACIA
ESCUELA DE QUIMICA
DEPARTAMENTO DE ANALISIS INORGNICO
ANLISIS INORGNICO I, 2014
CURVA DE NEUTRALIZACIN ENTRE UN CIDO FUERTE Y UNA BASE FUERTE

No.
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15

Base
Vol
0.0
10.0
25.0
40.0
50.0
54.0
55.0
55.4
55.5
55.6
56.0
60.0
65.0
85.0
90.0

mmol
0.00
1.80
4.50
7.20
9.00
9.72
9.90
9.97
9.99
10.01
10.08
10.80
11.70
15.30
16.20

0.2 M
0.18 M
cido
mmol
10.00
8.20
5.50
2.80
1.00
0.28
0.10
0.03
0.01
-0.01
-0.08
-0.80

10 mmol
55.56 mL
Base

0.08
0.8
1.7
5.3
6.2

cido
Base

Pto estequimtrico

Concentracin pH
pOH
M
0.2000 0.699
0.1367 0.864
0.0733 1.135
0.0311 1.507
0.0100 2.000
0.0027 2.570
0.0010 3.021
0.0003 3.576
0.0001 4.023
7.000
0.0008 10.878 3.1
0.0073 11.862 2.1
0.0148 12.170 1.8
0.0393 12.594 1.4
0.0443 12.646 1.4

Neutralizacin AB-BF
HNO3 0.2M vr KOH 0.18M
14.000
12.000

Uniades de pH

50 mL
10 mmol

10.000
8.000
6.000

4.000
2.000
0.000

0.0

10.0

20.0

30.0

40.0

50.0

60.0

70.0

Volumen de Base (Titulante) agregado

80.0

90.0

100.0

UNIVERSIDAD DE SAN CARLOS DE GUATEMALA

FACULTAD DE CIENCIAS QUIMICAS Y FARMACIA
ESCUELA DE QUIMICA
DEPARTAMENTO DE ANALISIS INORGNICO
ANLISIS INORGNICO I, 2014
CURVA DE NEUTRALIZACIN ENTRE UN CIDO FUERTE Y UNA BASE FUERTE

No.
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20

0.3 M
0.4 M

Base
cido
Vol
mmol mmol
0.0
0
30
20.0
8
22
40.0
16
14
60.0
24
6
70.0
28
2
72.0 28.8
1.2
73.0 29.2
0.8
74.5 29.8
0.2
74.8 29.92
0.08
75.0
30
0
75.1 30.04 -0.04
75.5 30.2
76.0 30.4
78.0 31.2
79.0 31.6
80.0
32
90.0
36
100.0
40
110.0
44
120.0
48

30 mmol
75 mL
Base

0.04
0.2
0.4
1.2
1.6
2
6
10
14
18

Concentracin
M
0.3000
0.1833
0.1000
0.0375
0.0118
0.0070
0.0046
0.0011
0.0005
0.0000
0.0002
0.0011
0.0023
0.0067
0.0089
0.0111
0.0316
0.0500
0.0667
0.0818

cido
Base Pto estequimtrico
pH
0.52
0.74
1.00
1.43
1.93
2.16
2.33
2.94
3.34
7.00
10.36
11.06
11.36
11.83
11.95
12.05
12.50
12.70
12.82
12.91

pOH

Curva de Titulacin
HClO4 0.30 M vr NaOH 0.40 M
14.00
12.00

Uniades de pH

100 mL
30 mmol

10.00
8.00
6.00

4.00
2.00

3.6
2.9
2.6
2.2
2.0
2.0
1.5
1.3
1.2
1.1

0.00
0.0

20.0

40.0

60.0

80.0

100.0

Volumen de NaOH (Titulante) agregado

120.0

140.0

UNIVERSIDAD DE SAN CARLOS DE GUATEMALA

FACULTAD DE CIENCIAS QUIMICAS Y FARMACIA
ESCUELA DE QUIMICA
DEPARTAMENTO DE ANALISIS INORGNICO
ANLISIS INORGNICO I, 2014
CURVA DE NEUTRALIZACIN ENTRE UN CIDO DBIL Y UNA BASE FUERTE

Ka

No.
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20

50 mL
9 mmol
5.10E-04

Base
Vol
0.0
10.0
20.0
23.6842
30.0
45.0
47.0
47.1
47.2
47.3684
47.4
48.0
50.0
60.0
70.0
79.0
80.0
90.0
100.0
110.0
120.0

Base
mmol
0.000
1.900
3.800
4.500
5.700
8.550
8.930
8.949
8.968
9.000
9.006
9.120
9.500
11.400
13.300
15.010
15.200
17.100
19.000
20.900
22.800

0.18 M
0.19 M

cido
mmol
9
7.1
5.2
4.5
3.3
0.45
0.07
0.051
0.032

9 mmol
47.368421 mL

cido
Base

Pto estequiomtrico

Ecuacion cuadrtica
Base Concentracin
a
b
c
X1
M
0.1800
1 5.10E-04 -9.18E-05 -3.47E-04
0.1183
1
0.0743
1
0.0611
1
0.0413
1
0.0047
1
0.0007
0.0005
1
0.0003
1
0.0000
1
0.006
0.0001
1
0.120
0.0012
1
0.500
0.0050
1
2.400
0.0218
1
4.300
0.0358
1
6.010
0.0466
1
6.200
0.0477
1
8.100
0.0579
1
10.000
0.0667
1
11.900
0.0744
1
13.800
0.0812
1

pH

-1.63E-04
1.91E-03
6.98E-04
5.10E-04
2.95E-04
2.68E-05
4.00E-06
2.91E-06
1.82E-06
0.00E+00

2.03
2.72
3.16
3.29
3.53
4.57
5.40
5.54
5.74
8.13
9.79
11.09
11.70
12.34
12.55
12.67
12.68
12.76
12.82
12.87
12.91

pOH

Curva de Titulacin
HNO2 0,18 M vr KOH 0,19 M
14.00
12.00

4.2
2.9
2.3
1.7
1.4
1.3
1.3
1.2
1.2
1.1
1.1

Uniades de pH

H+

10.00
8.00
6.00
4.00
2.00
0.00
0.0

20.0

40.0

60.0

80.0

Volumen de NaOH (Titulante) agregado

tulacin
r KOH 0,19 M

100.0

OH (Titulante) agregado

120.0

140.0