Unit

operations

Stream

Autothermal
Reactor
(ATR)
(R101)
Water
Separator
1
(D101)
FT
Reactor
(R102)

Inlet

3-phase
Separator
1
(D102)

3-phase
separator
2
(D103)

3-phase
separator
3
(D105)
2-phase
separator
(D106)

Split
fraction
(D104)

Manual
calculation

Outlet
(S104)
Inlet
696000.00
(S105)
Outlet 518149.127
177849.686
Inlet 695998.813
(S108)
Outlet 517585.227
(S109)
Inlet 517585.227
(S1092)
Outlet 185032.048
134138.473
198303.190
Inlet 185032.048
(S1102)
Outlet 143050.267
7789.530
34192.856
Inlet 143050.267
(S113)
Outlet 122201.699
9374.581
11473.667
Inlet 131575.909
(S1201)
Outlet 120041.954
11535.971
Inlet 141926.397
(S114)
Outlet 26512.844
115425.706

Total

696000.00

Mass flow rate (kg/hr)

ASPEN
Total
Value
240000.00 696000.00
312000.00
144000.00
696000.00 696000.00
696000.00

696000.00

Deviation (%)

695998.813 517474.157 696000.00

0.130 0.00017
178525.815
0.379
695998.813 517474.157 517474.157 0.00017 0.00017
517585.227 517474.157 517474.157

0.021

0.021

517585.227 517474.157 517474.157

0.021

0.021

517473.711 185032.048 517474.157

0
0.00009
134138.353
0.00009
198303.310
0.00006
185032.048 185032.048 185032.048
0
0

185032.653 143049.786 185032.048 0.00034 0.00033

7788.044
0.0190
34194.718
0.00545
143050.267 143049.786 143049.786 0.00034 0.00034
143049.947 122201.988 143049.786 0.00024 0.00011
9373.921
0.00704
11474.050
0.00334
131575.909 131575.909 131575.909
0
0

131577.925 120041.174 131575.909 0.00065

11534.734
0.01072
141926.397 141926.397 141926.397
0

0.0015

141938.55

0.0086

26512.546 141926.397 0.0011

115413.851
0.0103

Autothermal
Reactor
(R101)
Overall
Component
CH4
O2
H2O
CO
H2
CO2
Water
Separator 1
(D101)
Overall
Component
CH4
H2O
CO
H2
CO2
FisherTropsh
Reactor
(R102)
Overall
Component
CH4
CO2
CO
H2
H2O
C4H10
C3H8
C8H18
C16H34

Hand Calculation
(kg/hr)

ASPEN Calculation
(kg/hr)

Deviation (%)

Inlet

Outlet

Inlet

Outlet

Inlet

Outlet

Inlet

Outlet

Inlet

Outlet

Inlet

Outlet

S105

Inlet
696000.00
Inlet
6255.046
176976.842
354190.956
73852.099
84725.058

Hand
Calculation
(kg/hr)
Outlet
695866.423
Outlet
6256.436
176976.309
354059.440
73849.168
84725.070

Hand Calculation
(kg/hr)

Inlet
Outlet
517377.027 517585.227
Inlet
Outlet
5996.039
5996.039
78720.335 78720.335
352241.949 17612.520
73756.094 23687.742
6662.612 221942.213
7308.939
1848.628
26934.520
115689.003

ASPEN Calculation
(kg/hr)
Outlet
696000.00
Outlet
6255.046
176976.842
354190.956
73852.099
84725.058
ASPEN Calculation
(kg/hr)

Inlet
517474.157
Inlet
5995.947
78719.985
352246.176
73852.102
6659.948
-

Outlet
517474.157
Outlet
5995.947
78719.985
17612.309
23639.362
221884.394
7309.337
1848.460
26934.686
115687.098

Deviation (%)

Outlet
0.0192
Outlet
0.0220
0.0003
0.0371
0.0039
1.5x10-5
Deviation (%)

Inlet
0.01900
Inlet
0.00153
0.00045
0.00120
0.13000
0.04000
-

Outlet
0.02100
Outlet
0.00153
0.00045
0.00119
0.20000
0.02600
0.00545
0.00909
0.00062
0.00165

C20H42
C21H44
C9H20
3-phase
Separator 1
(D102)
Overall
Component
CH4
CO2
CO
H2
H2O
C4H10
C3H8
C8H18
C16H34
C20H42
C21H44
C9H20
3-phase
separator 2
(D103)
Overall
Component
CH4
CO2
CO
H2
H2O
C4H10
C3H8
C8H18
C16H34
C20H42
C21H44
C9H20

5330.023
3551.842
8963.423

5329.898
3552.058
8960.624

0.00235
0.00608
0.03100

S109-2

Hand Calculation
(kg/hr)

ASPEN Calculation
(kg/hr)

Deviation (%)

Inlet
517474.157
Inlet
5995.947
78719.985
17612.309
23639.362
221884.394
7309.337
1848.460
26934.686
115687.098
5329.898
3552.058
8960.624

Outlet
517473.711
Outlet
5995.954
78720.090
17612.333
23639.362
221884.049
7309.337
1848.460
26934.686
115686.856
5329.886
3552.058
8960.619

Outlet
517474.157
Outlet
5995.947
78719.985
17612.309
23639.362
221884.394
7309.337
1848.460
26934.686
115687.098
5329.898
3552.058
8960.624

Outlet
8.6x10-5
Outlet
0.00012
0.00013
0.00014
0
0.00016
0
0
0
0.00021
0.00023
0
5.6x10-5

S110-2

Hand Calculation
(kg/hr)

ASPEN Calculation
(kg/hr)

Deviation (%)

Inlet
185032.048
Inlet
5685.372
77008.190
17453.216
23639.375
36121.703
3854.865
1184.209
15032.964
1126.864
0.297
0.109
3924.884

Outlet
185032.653
Outlet
5685.359
77008.028
17453.216
23639.375
36122.353
3854.865
1184.209
15033.030
1126.887
0.297
0.109
3924.925

Outlet
185032.048
Outlet
5685.372
77008.190
17453.216
23639.375
36121.703
3854.865
1184.209
15032.964
1126.864
0.297
0.109
3924.884

Outlet
0.00033
Outlet
0.00023
0.00021
0
0
0.00180
0
0
0.00044
0.00204
0
0
0.00104

3-phase
separator 3
(D105)
Overall
Component
CH4
CO2
CO
H2
H2O
C4H10
C3H8
C8H18
C16H34
C20H42
C21H44
C9H20
2-phase
separator
(D106)
Overall
Component
CH4
CO2
CO
H2
H2O
C4H10
C3H8
C8H18
C16H34
C20H42
C21H44
C9H20
Split
fraction
(D104)
Overall

S113

Hand Calculation
(kg/hr)

ASPEN Calculation
(kg/hr)

Deviation (%)

Inlet
143049.786
Inlet
5616.730
75292.956
17426.201
23639.313
4454.020
3221.203
1109.695
10521.191
0.905
Trace
Trace
1767.573

Outlet
143049.947
Outlet
5616.730
75292.982
17426.195
23639.313
4454.063
3221.203
1109.695
10521.288
0.905
Trace
Trace
1767.573

Outlet
143049.786
Outlet
5616.730
75292.956
17426.201
23639.313
4454.020
3221.203
1109.695
10521.191
0.905
Trace
Trace
1767.573

Outlet
0.00011
Outlet
0
0.00003
0.00003
0
0.00097
0
0
0.00092
0
0
0
0

S120-1

Hand Calculation
(kg/hr)

ASPEN Calculation
(kg/hr)

Deviation (%)

Inlet
131575.909
Inlet
5605.182
70661.506
17416.853
23639.305
129.598
2932.066
1083.299
8560.407
0.682
Trace
Trace
1547.010

Outlet
131577.925
Outlet
5605.182
70661.506
17416.853
23639.305
130.973
2933.780
1083.300
8559.334
0.682
trace
Trace
1547.010

Outlet
131575.909
Outlet
5605.182
70661.506
17416.853
23639.305
129.598
2932.066
1083.299
8560.407
0.682
Trace
Trace
1547.010

Outlet
0.00150
Outlet
0
0
0
0
1.06090
0.05850
0.00009
0.01253
0
0
0
0

S114

Hand Calculation
(kg/hr)

ASPEN Calculation
(kg/hr)

Deviation (%)

Inlet
141926.397

Outlet
141938.55

Outlet
141926.397

Outlet
0.0086

Component
CH4
CO2
CO
H2
H2O
C4H10
C3H8
C8H18
C16H34
C20H42
C21H44
C9H20

Inlet
27.464
1210.349
13.789
0.002
663.090
301.016
56.254
16383.922
115683.47
430.812
287.114
6869.112

Outlet
27.464
1210.349
13.789
0.002
663.090
301.016
56.254
16383.922
115690.99
428.929
287.114
6875.631

Outlet
27.464
1210.349
13.789
0.002
663.090
301.016
56.254
16383.922
115683.47
430.812
287.114
6869.112

Outlet
0
0
0
0
0
0
0
0
0.0065
0.4371
0
0.0949