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lv
FINAL
2011
ROUND, PROBLEMS
Solve all problems provides. Fill answer sheets and till 13:00, March 20, 2011 send them to email:
kimijas_olimpiades@inbox.lv You will receive answer that your solutions are received and will be graded in few
days.
This round consists from two parts. Part A 60 multiple choice questions with one correct answer each.
Maximum points for this round is 30 points. Part B 6 short answer problems. Each problem is graded with
maximum5points.Pointsforfinalroundareaddedtopointsgainedinfirstthreerounds.
PartAMultiplechoicetest
Chooseonecorrectanswerforeachquestionandwritecorrespondingletterinanswersheetprovided.
Question1
Question2
Question3
Question4
Question5
Question6
Question7
Question8
Question9
Time,s
Question10
Question11
Question12
Question13
Question14
Question15
Question16
Question17
Question18
Question19
Question20
Question21
Question22
Question23
Question24
Question25
Question26
Question27
Question28
Question29
Question30
Question31
Question32
Question33
Question34
Question35
Question36
Question37
Question38
Question39
Question40
Question41
Question42
Question43
Question44
Question45
Question46
Question47
Question48
Question49
Question50
Question51
Question52
Question53
Question54
Question55
Question56
Question57
Question58
Question59
Question60
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FINAL
2011
ROUND, PROBLEMS
PartBShortanswerquestions
Problem1
Chemicalcrosswordinorganicchemistry(8points)
LettersA,B,Dect.standsforunknowninorganiccompounds,whichreactasshownintable.Formulasforall
organiccompoundsareknown.
CompoundAcontainstransitionmetalandtransitionmetalcontentisapproximately72%(bymass)
SolutionsofcompoundsU,N,arestronglybasic.Therearenoinformationaboutsolutionsofother
compounds.
SolutionsofcompoundsOandNcolorsgasflameyellow,whilecompoundsUuncolorsflamepurple
red.
WatersolutionsofcompoundsV,PandLareblue.
SubstancesE,G,H,M,R,S,containonlyonechemicalelement.
Threetransitionmetalsarementionedinthiscrossword.
Equationsincrosswordarenotbalanced.
Writechemicalformulasforallcompoundsabbreviatedwithletters.
A
+
E
F
+
G
E
+
U
F
+
T
+
+
I
+
H
L
+
N
O
+
P
G
+
J
E
+
K
R
+
Q
+
E
C2H5NO2 +
D
+
H
M
+
Q
+ F
+
V +
+
W
I
D
+
R
B
+
I
+
E
U
+
F
+
+
E
C2H5Cl
+
F
Z
+
F
C2H6 +
Y
+
+
C
H
2 5OH
C2H6
+
+
CH3Cl
I
+
D
+
I
G
+
E
+
Y
C2H4
C2H6
Problem2
Useofmathtodescribechemicalprocessesphysicalchemistry(10points)
Problem3
Someorganicchemistry(6points)
Problem4
Complexformationandredoxproperties(6points)
You have to investigate 1st type electrode using software MS Excel (or analogue). The first type electrode
consistsfrommetal(M(s))anditsionsinsolution(Mx+(aq)).Thistimesolutionalsocontainprotolyticpairfrom
whichconjugatedbaseactsasligandsandformcomplexionswithMx+.
DrawgraphtoshowhowreductionstandardpotentialisdependentonpHiffreeligandconcentrationin
solutionisa)0.1M,b)1.0Mand5.0M.
Givenelectrode:
Cu2+(aq)+2eCu(s)
Eo=+0.345V
+
pKa(NH4+)=9.25
Ligands:
NH3/NH4
Summarycomplexformationconstants:
lg1=3.99
lg1,2=7.33
lg1,2,3=10.06
lg1,2,3,4=12.03
lg1,2,3,4,5=11.43
lg1,2,3,4,5,6=8.9
Hints:
1. Assumethatconcentrationsumforconjugateacidandbaseandacidareconstant(ifbaseareusedfor
complexformationitisaddedtosolutiontomaintainconstantconcentrationorconcentrationofbase
ishugeenoughandstaysalmostconstant).
2. Writemathematicalequationsforcalculationrealreductionstandardpotentialsdependingfrommolar
fractionofmetalionsinsolution.
Example:
3. UsingMSExcelprogramcalculaterealstandardpotentialvalues,ifpHchangesfrom0to14(step0.5).
Madecalculationinthreecases:a)conjugateacidandbaseconcentrationsumisCL=0.1M,b)CL=1
Mandc)CL=5M.Allcalculationresultscollectintable.
www.biosan.lv
FINAL
PartAMultiplechoicetest
Q.number
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.
13.
14.
15.
16.
17.
18.
19.
20.
21.
22.
23.
24.
25.
26.
27.
28.
29.
30.
31.
33.
Answer
B
B
D
Nocorrectanswer,D,allstatementsaretrue
A
32.
B
A
33.
D
B
34.
A
A
35.
A
D
36.
B
C
37.
B
D
38.
C
A
39.
D
B
40.
A
A
41.
D
B
42.
B
D
43.
C
A
44.
B
B
45.
A
B
46.
D
B
47.
A
C
48.
A
C
49.
B
D
50.
B
A
51.
B
B
52.
D
A
53.
D
C
54.
A
B
55.
A
B
56.
C
C
57.
C
A
58.
A
B
59.
C
D
60.
B
2011
ROUND, SOLUTIONS
PartBShortanswerquestions
Problem1
Chemicalcrosswordcorrections(madewithredcolor)
A
+
E
F
+
G
E
+
U
F
+
T
+
+
I
+
H
L
+
N
O
+
P
G
+
J
E
+
K
R
+
Q
+
E
D
+
H
M
+
Q
+ F
+
V
+
+
W
I
C2H5Cl
+
F
C2H5NO2 +
D
+
R
B
+
I
+
E
U
+
F
+
+
E
C2H6
+
S
+
CH3Cl
+
F(notI)
(notG)
Z
+
F
+
Y
+ C2H5OH
C2H6
+
D
+
E
C2H4
C2H6
Answers:
AFe3O4orotheroxidewhichcontains72%metal,Mn3O4,Rh2O5,CaOisnotacceptedwrongchemistry
BCO
DCO2
EH2
FH2O
GFe
HC
IO2
JHCl
KFeCl2
LCuCl2
MCu
NNaOH
ONaCl
PCu(OH)2
QH2SO4
RZnorothermetal
SLiorotheralkalimetal
TLiHorotheralkalimetal
ULiOHorotheralkalimetal
VCuSO4
WSO2
ZNO2
YHNO3
CaH2,Caaccepted
ZnO
Al
H2CO3
Li[Al(OH)4]
Ca(OH)2
CaCO3
CaO
LiClorothermetal
ZnSO4
Problem2
Problem3
Problem4
Cu2++2eCu
0
red
=0,764V
Cu2++NH3
[Cu(NH3)]2+
lg 1 = 3,99
Cu2++2NH3
[Cu(NH3)2]2+
lg 2 = 7,33
Cu2++3NH3
[Cu(NH3)3]2+
lg 3 = 10,06
Cu2++4NH3
[Cu(NH3)4]2+
lg 4 = 12,03
Cu2++5NH3
[Cu(NH3)5]2+
lg 5 = 11,43
Cu2++6NH3
[Cu(NH3)6]2+
lg 6 = 8,9
NH4++H2O
H3O++NH3
pKA=9,25
= red
RT
RT
1
0
= red
+
ln
ln [Cu 2+ ]
2+
2 F [Cu ]
2 F
[ H 3O + ] [ NH 3 ]
K A =
+
[ NH 4 ]
2+
K = [{Cu ( NH 3 )} ]
1 [Cu 2+ ] [ NH ]
3
[{Cu ( NH 3 ) 2 }2+ ]
K 2 = [Cu 2+ ] [ NH ]2
3
[{Cu ( NH 3 ) 3 }2+ ]
K 3 =
[Cu 2+ ] [ NH 3 ]3
[{Cu ( NH 3 ) 4 }2+ ]
K 4 =
[Cu 2+ ] [ NH 3 ]4
2+
K 5 = [{Cu ( NH 3 ) 5 } ]
[Cu 2+ ] [ NH 3 ]5
2+
K = [{Cu ( NH 3 ) 6 } ]
6 [Cu 2+ ] [ NH 3 ]6
2+
2+
2+
2+
2+
CCu = [Cu ] + [{Cu ( NH 3 )1} ] + [{Cu ( NH 3 ) 2 } ] + [{Cu ( NH 3 ) 3 } ] + [{Cu ( NH 3 ) 4 } ] +
2+
2+
+ [{Cu ( NH 3 ) 5 } ] + [{Cu ( NH 3 ) 6 } ]
+
CL = [ NH 4 ] + [ NH 3 ]
[ H 3O + ] [ NH 3 ]
K
=
A
[ NH 4+ ]
10 pH [ NH 3 ]
+
+
CL = [ NH 4 ] + [ NH 3 ] [ NH 4 ] = CL [ NH 3 ] K A =
CL [ NH 3 ]
10 pH [ NH ] = K C [ NH ] K (10 pH + K ) [ NH ] = K C
3
3
3
A
L
A
A
A
L
K A CL
[ NH 3 ] = 10 pH + K
A
[{Cu ( NH 3 ) }2 + ]
[{Cu ( NH 3 ) }2 + ]
K C
=
1 =
1
2+
[Cu ] [ NH 3 ]
+ KA
K C
10
[Cu 2 + ] pHA L
+ KA
10
K A CL
[{Cu ( NH 3 ) 2 }2 + ]
[{Cu ( NH 3 ) 2 }2 + ]
2+
2+
2 =
[{Cu ( NH 3 ) 2 } ] = 2 [Cu ] pH
2 =
2
[Cu 2 + ] [ NH 3 ]2
+ K A
K A CL
10
2+
[Cu ] pH
+ K A
10
3
2+
= [{Cu ( NH 3 )3} ] K [{Cu ( NH ) }2 + ] = [Cu 2 + ] K A CL
3 3
3
10 pH + K
3 [Cu 2 + ] [ NH ]3
3
A
4
2+
K A CL
[{Cu ( NH 3 ) 4 } ]
2+
2+
4 =
K [{Cu ( NH 3 ) 4 } ] = 4 [Cu ] pH
[Cu 2 + ] [ NH 3 ]4
+ K A
10
5
K A CL
[{Cu ( NH 3 )5 }2 + ]
2+
2+
5 = [Cu 2 + ] [ NH ]5 K [{Cu ( NH 3 )5 } ] = 5 [Cu ] 10 pH + K
3
A
2+
A CL
6 = [{Cu2(+NH 3 )6 } 6] K [{Cu ( NH 3 )6 }2 + ] = 6 [Cu 2 + ] K
10 pH + K
[Cu ] [ NH 3 ]
2+
2+
2+
2+
2+
CCu = [Cu ] + [{Cu ( NH 3 )} ] + [{Cu ( NH 3 ) 2 } ] + [{Cu ( NH 3 )3} ] + [{Cu ( NH 3 ) 4 } ] +
2+
2+
+ [{Cu ( NH 3 )5 } ] + [{Cu ( NH 3 )6 } ]
CCu = [Cu 2 + ] + [{Cu ( NH 3 )}2 + ] + [{Cu ( NH 3 ) 2 }2 + ] + [{Cu ( NH 3 )3}2 + ] + [{Cu ( NH 3 ) 4 }2 + ] +
+ [{Cu ( NH 3 )5 }2 + ] + [{Cu ( NH 3 ) 6 }2 + ] =
2
3
4
1 + K a CL + K a CL + K a CL + K a C L +
1
2
3
4
pH
pH
pH
pH
+ Ka
+ Ka
+ Ka
+ Ka
10
10
10
10
= [Cu 2 + ]
5
6
K a CL
K a CL
+ 6 pH
+ 5 pH
+ Ka
+ Ka
10
10
[Cu 2 + ] =
1
2
K a CL
K a CL
K a CL
K a CL
+ 2 pH
+ 3 pH
+ 4 pH
+
1 + 1 pH
+ Ka
+ Ka
+ Ka
+ K a
10
10
10
10
5
K a CL
K a CL
+ 6 pH
+ 5 pH
+ K a
+ Ka
10
10
,
0
= red
red
RT
1
+
ln
2
3
4
2 F
1 + 1 K a CL + 2 K a CL + 3 K a CL + 4 K a CL +
10 pH + K
10 pH + K
10 pH + K
10 pH + K
a
a
a
a
5
6
K a CL
K a CL
+ 6 pH
+ 5 pH
+ Ka
+ Ka
10
10
K a = 10 pK a
K n = 10 lg K n
E(Cu2+),V
0,40
0,35
0,30
0,25
0,20
C=0,1mol/L
0,15
C=0,5mol/L
0,10
C=5mol/L
0,05
0,00
0,05
0,10
0,15
pH
0,0
5,0
10,0
www.biosan.lv
Name
Sigitas Mikutis
Emilis Bruzas
Jurgis Kuliesius
Kristina Smokrovich
Taivo Pungas
Rene Lomp
Jana Volaric
Julia Tseglakova
Mirna Mustapi
Aurimas Narkevicius
Kaur Aare Saar
Mindaugas Siauciulis
Eva-Lotta Kasper
Katrina Sepp
Lona-Liisa Sutt
Jnis Brika
Valdis Dakus
Jaan Toots
Kristers Ozols
Kert Ptsepp
Mantas Vasiliauskas
George Trenin
Ralf Ahi
Mris Serns
Vytaute Maciulsyte
Elza Linia
Kaur Karus
Greta Macileviciute
Ernestas Blazevic
Erik Tamre
Gediminas Aucina
Katrna Krievia
Augustinas Juskauskas
Madis Ollikainen
Tatjana Gerasimova
Pijus Savickas
Simonas Balkaitis
j Svambaryte
y
Silvija
Dovile Meliauskaite
International jury:
State
LT
LT
LT
CR
EE
EE
CR
EE
CR
LT
EE
LT
EE
EE
EE
LV
LV
EE
LV
EE
LT
LV
EE
LV
LT
LV
EE
LT
LT
EE
LT
LV
LT
EE
LV
LT
LT
LT
LT
School
Form TOTAL
12
12
12
11
4th
11
4th
11
10
11
11
12
10
11
11
10
11
12
10
10
11
12
150,00
107,71
105,83
102,56
97,99
95,53
94,19
93,91
91,05
86,75
82,51
80,82
67,49
64,54
59,94
55,46
,
53,45
50,30
48,88
43,02
35,08
33,86
27,61
23,10
19,25
18,75
17,20
,
13,25
11,01
10,81
8,50
7,40
6,08
6,05
5,52
5,29
5,24
4,26
,
4,14
3,00
Prize
1st place
2nd place
3rd place
Honorary mention
Honorary mention
Honorary mention
Honorary mention
Honorary mention
Egle Maksimaviciute LT
Vladislav Ivanitev EE
Kaspars Veldre LV
Filip Topi CRO
Students will be awarded during Chemistry Olympiad of Baltic states, 2011, April 15-17, Vilnius, Lithuania
1.
8
3,28
6,24
4,64
4,04
5,56
4
3,12
1,28
2,84
2,44
0
0
3,72
3,68
3,16
,
0,8
0
1,08
0
0,12
0,2
2.
10
9,25
9,25
7,75
6,25
9
7
6
8
4,5
6
0
4
8,5
7,75
0,75
,
6,25
0
0
8
9,25
5,25
0
0
0
0
,
1,6
0,24
3,64
0
0
0,84
0,12
0
0,6
0
0,12
0
0,52
4,5
0
6,75
0
0
0,75
0
0
0
0
0
0
0
0
0
0
0
Round 1
3.
4.
4
8
4
7,724
4
8
1
7,724
4
6,345
0
8
4
8
4
8
7,72
0
4
6,621
4
6,345
0
7,034
0
7,448
0
7,172
0
8
0
6,621
,
7,72
0
0
5,793
0
8
4
7,172
0
7,034
0
4,966
0
0
4
0
0
0
0
0
0
0
0
0
0
0
0
0
0
7,172
0
8
0
0
5,517
7,172
0
0
5,241
5,931
5,517
4,69
5,241
4,138
,
4,138
2,483
Sum
30
24,25
27,49
21,11
20,63
22,56
23
21,12
17
17,96
18,78
7,034
11,45
19,39
19,43
10,53
,
14,77
5,793
9,08
19,17
16,4
10,42
0
11,67
0
18,75
0
,
1,6
6,507
10,81
0
0
6,081
6,051
5,517
5,29
5,241
4,258
,
4,138
3,003
1.
5
4,1
3,8
4,5
3,65
5
6
4,25
2,8
3,75
4,3
4
4,15
4,38
4,13
4,45
0
3,5
0
0
4,5
2,6
2.
5
2,32
3
4,5
4,16
3,83
3,205
3,85
4
3,33
3,285
3,58
3,75
2,5
0,83
3,375
4
3,65
0
4,15
,
2,5
3,25
0
0
4,23
0
0
0
0
0
0
0
0
Round 2
3.
4.
10
5
7,5
5
7
4,5
8,9
4,5
9,3
4,5
9,2
5
8,9
5
9,4
5
4
5
8,8
5
7,5
5
8,5
5
6,5
3,5
3
0
4,5
3
5,4
5
5.
5
4,6
3,9
4,8
2,5
2
1,5
2,8
3,8
3,7
1,2
1
1,1
1,2
0,7
2
3,17
3,5
0,4
1,875
1
4,3
0
2,5
1
1
0,9
2,125
3
0,4
8,9
4
3
0,9
0,7
2,045
,
0,25
1,25
6
,
3,9
0
3,5
4
0
1,5
1
0
2,17
7,5
0
0
1
1
0
Sum
30
23,52
22,2
27,2
24,11
25,03
24,605
25,3
19,6
24,58
21,285
22,08
19
11,08
13,16
20,225
0
12,57
0
0
14,175
5,5
0
11,425
19,25
0
17,195
,
11,65
4,5
0
8,5
7,4
0
0
0
0
0
0
0
0
1.
5
3,5
3,5
4
3,5
4
Round 3
3.
4.
8
9
8
5,499
7,002
3,2
6,201
8
6,804
0
1,602
8
8
4,302
3,2
2,196
8
4,725
0
1,305
0
0,801
0
0,504
0
0
3,5
4,5
3,5
3,5
3
3,5
2,5
2.
8
4,83
7,17
3,54
7,17
2,33
0,375
4,08
6,5
5,21
3,17
1,5
1,5
0
1
5
0
0,833
0
0
0,594
0,594
1,5
0,999
Sum
30,00
21,83
17,67
16,94
25,47
7,93
8,38
19,88
16,40
21,44
7,98
5,30
5,50
2,50
0,00
0,00
,
0,00
1,59
6,43
0,00
4,50
0,00
0,00
0,00
0,00
0,00
0,00
,
0,00
0,00
0,00
0,00
0,00
0,00
0,00
0,00
0,00
0,00
0,00
,
0,00
0,00
Part A
30,00
23,50
24,50
22,50
23,00
23,50
25,00
24,00
24,00
22,50
19,50
24,50
22,00
21,50
21,50
20,00
,
21,00
21,50
23,00
19,00
0,00
17,00
21,50
0,00
0,00
0,00
0,00
,
0,00
0,00
0,00
0,00
0,00
0,00
0,00
0,00
0,00
0,00
0,00
,
0,00
0,00
Part B1
8,00
2,35
4,47
2,59
1,41
3,53
3,76
0,00
3,29
0,00
5,88
7,29
0,71
6,82
2,59
4,71
,
8,00
7,29
3,29
3,06
0,94
0,00
FINAL ROUND
Part B2 Part B3
10,00
6,00
6,25
6,00
7,50
6,00
7,78
4,44
0,00
3,36
7,22
5,76
4,17
5,28
3,61
0,00
5,00
5,76
0,28
0,00
5,00
4,08
8,33
5,28
4,03
4,80
0,00
3,24
2,78
0,48
0,00
0,00
,
,
5,83
3,84
0,83
0,72
7,08
0,00
0,83
0,96
0,00
0,00
0,00
0,00
6,11
0,00
0,00
0,00
0,00
0,00
0,00
0,00
0,00
0,00
,
,
0,00
0,00
0,00
0,00
0,00
0,00
0,00
0,00
0,00
0,00
0,00
0,00
0,00
0,00
0,00
0,00
0,00
0,00
0,00
0,00
0,00
0,00
,
,
0,00
0,00
0,00
0,00
Part B4
6,00
0,00
-4,00
0,00
0,00
0,00
0,00
0,00
0,00
0,00
1,00
0,00
0,00
0,00
0,00
,
0,00
0,00
0,00
0,00
0,00
0,00
Sum
60,00
38,10
38,47
37,31
27,77
40,01
38,21
27,61
38,05
22,78
34,46
46,41
31,53
31,56
27,35
24,71
,
38,67
30,35
33,38
23,85
0,00
17,94
27,61
0,00
0,00
0,00
0,00
,
0,00
0,00
0,00
0,00
0,00
0,00
0,00
0,00
0,00
0,00
0,00
,
0,00
0,00