CHEMISTRY SOLUTION

31. (C)
Sol.
n
The oxidation potential for Mg is highest .Thus, tendency of Mg to get oxidized is
greatest So Mg is best reducing agent.

32. (B)

33. (B)
Sol.
n
For isothermal process
PV =C
Pdv +Vdp =0
[
dP
dV
=
-P
V

34. (B)

35. (C)
Sol.
n
[Mg
2+
] =10
-3
M
10
-3
[OH
-
]
2
=10
-13
[OH
-
] =10
-5
M
pOH =5 pH =9
36. (C)

37. (B)
Sol.
n
R
2
=K[Cl][CHCl
3
]
From r n 1: : K
cq
=
[CI]
2
[CI
2
]
[Cl] =_K
cq
[Cl
2
]
R overall =K

K
cq
[CHCl
3
][Cl
2
]
1/ 2

=K [CHCl
3
][Cl
2
]
1/ 2

38. (C)

39. (C)
Sol.
n
H=30Kcal
E
a
t
=294 KJ =70 Kcal
We know H=E
a
t
E
a
b

30=70E
a
b
E
a
b
=100 Kcal

40. (B)

41. (C)
Sol.
n
Moles of H
2
SO
4
=
100+x
98

Moles of Ca(OH)
2
taken =2.75 0.5 = 1.375
Moles of H
3
PO
3
used =
15.7
82

Since H
3
PO
3
is dibasic, moles of Ca(OH)
2
left =
15.7
82

Moles of Ca(OH)
2
used with H
2
SO
4
=1.375
15.7
82


100+x
98
=1.375
15.7
82

Solving, x =15.64
SO
3
=
15.64
18
80 =71.1 g

42. (A)

43. (B)
Sol.
n
Half Rn for I: Am
+6
+e
-
Am
+5

AmO
2
2+
+e
-
AmO
2
+

Half Rn for II Am
+6
+2e
-
Am
+4

AmO
2
2+
+4H
+
+2e
-
Am
+4
+2H
2
O
Half Rn for III Am
+4
+2e
-
Am
+2

Form above half r n it is evident that E depends on [H
+
] only for Rn II.

44. (A)

45. (B)
Sol.
n

( )
2 2 4 2
, 1 / (100 ,0.1 ) (0.05 )| , 1
g
g
Pt H atm HA ml M H SO M Pt H atm

Here
E =0.059 log
[H
+
]anodc
[H
+
]cathodc

E =0.059 (pH
anodc
pH
cathodc
)
Initially; pH
anodc
=1 pH
cathodc
=remain constant in both cases =1
E
InItIaI
=0.059(1 1) =0 V
HA+NaOH NaA+H
2
O
m mole
10 5
5

[H
+
] after r n =
5
150
=
1
30
M pH=1.477
E
fInaI
=0.059(1.4771) =0.028
E increase by 0.028 v

46. (B)

47. (B)
Sol.
n
Cu
2+
+2e
-
Cu 0.337 V
Cu
+
+e
-
Cu x V (suppose)
Cu
2+
+e
-
Cu
+
y V (suppose)
Given: Cu+Cu
2+
2Cu
+
E

=0.3678V
y x =0.3678..Eq. 1
Also, R
1
=R
2
+R
3

G
1

=G
2

+G
3

2f(0.337) =1f(x) 1f(y)
x +y =0.674V Eq.2
Eq.2Eq.1 Gives 2x =1.0418
x =0.521V

48. (C)

49. (D)
Sol.
n
No. of faradays passed =
253600
96500
=0.373
No.of equivalents deposited =0.373

22
1
Z
=0.373
Z
=
1770.373
22


Z
=3

50. (A)

51. (A)
Sol.
n
If partial pressures are equal then mole function must be equal
i.e. the mixture must be equimolar

m
C
o
28
=
m
N
2
28

m
C
o
m
N
2
=1
52. (B)

53. (C)
Sol.
n
O.R =
-1
2
N
2
O
S
t
=
1
4
[NO
2
]
t
=
[O
2
]
t


Rate of disappearance of N
2
O
5
=
-N
2
O
S
t
=
1
2
[NO
2
]
t

=
1
2

2010
-3
5

=210
-3


54 (C)

55. (C)
Sol.
n

K
300
K
290
=3 log3=
E
a
2.303R
j
1
290

1
300
[
E
a
=
2.30320.4771290300
10

=19.118Kcal

56 (B)

57. (B)
Sol.
n
=
A
m
A
m

=
7.365
390.7
=0.0188
K
a
=
cu
2
1-u
K
a
=
0.05(0.0188)
2
1
(1 1)
K
a
=1.7610
-5


58. (D)

59. (C)
Sol.
n
Rate =K [4]
x

2.4 =K (2.2)
x

0.6 =K (1.1)
x

4=2
x
x =2
60. (A)