componente Tb

etanol
metanol

A
351.4
337.7

Tb
335
336
337
338
339
340
341
342
343
344
345
346
347
348
349
350
351
352
353
354
355
356
357
358
359
360

volatilidad
1.7649833
1.75783374
1.75078699
1.74384171
1.73699661
1.7302504
1.72360178
1.71704951
1.71059234
1.70422903
1.69795836
1.69177913

0.3481222
0.3461763
0.3442304
0.34228449
0.34033859
0.33839268
0.33644678
0.33450088
0.33255497
0.33060907
0.32866316
0.32671726
0.32477136
0.32282545
0.32087955
0.31893364
0.31698774
0.31504184
0.31309593
0.31115003
0.30920413
0.30725822
0.30531232
0.30336641
0.30142051
0.29947461

B
-8.51838
-8.54796

0.34163
0.76982

-5.73683
-3.1085

tA
PvapB
0.34646898 0.51039886
0.34451814 0.53342867
0.3425673 0.55732622
0.34061647
0.5821169
0.33866563
0.6078266
0.33671479 0.63448168
0.33476395
0.662109
0.33281311 0.69073591
0.33086227 0.72039023
0.32891143
0.7511003
0.32696059 0.78289493
0.32500975 0.81580342
0.32305892 0.84985559
0.32110808 0.88508173
0.31915724 0.92151262
0.3172064 0.95917956
0.31525556 0.99811433
0.31330472
1.0383492
0.31135388 1.07991695
0.30940304 1.12285083
0.3074522 1.16718461
0.30550137 1.21295255
0.30355053 1.26018938
0.30159969 1.30893035
0.29964885 1.35921119
0.29769801 1.41106811

PvapA
0.91211454
0.94928764
0.98771415
1.0274266
1.0684581
1.11084226
1.15461329
1.19980593
1.24645548
1.29459782
1.34426936
1.39550709
1.44834857
1.50283192
1.55899582
1.61687955
1.67652292
1.73796635
1.8012508
1.86641783
1.93350957
2.00256872
2.07363856
2.14676296
2.22198635
2.29935376

promedio volatilidad
1.72109167

Tc
8.32581
1.54481

513.9
512.6

XA
1.21877528
1.12194606
1.028546
0.93841004
0.85138208
0.76731437
0.68606712
0.60750796
0.53151157
0.45795922
0.38673844
0.31774265
0.2508708
0.1860271
0.1231207
0.06206544
0.00277955
-0.05481455
-0.11079051
-0.16521824
-0.21816413
-0.26969122
-0.31985942
-0.36872563
-0.41634392
-0.46276567

1.68569016
1.67969026

Pc

PT
61.4
80.9

diagrama T-XY sistema metanol-etanol

354
352
350

T(K)

348
346
344
342
340
338
336
0

0.2

0.4

0.6

0.8

XA-YA

XA-YA
1
0.8
0.6
YA

YA
1.11166265
1.06504952
1.01590943
0.96414745
0.90966607
0.85236523
0.79214221
0.72889166
0.66250551
0.59287301
0.51988064
0.44341211
0.36334836
0.27956746
0.19194466
0.10035234
0.00465998
-0.09526585
-0.1995615
-0.30836627
-0.42182243
-0.54007521
-0.66327284
-0.79156652
-0.9251105
-1.06406199

0.4

Series1

0.2
0
0

0.2

0.4

0.6
XA

0.8

XA
YA

Series1

componente Tb
etanol
metanol

A
351.4
337.7

Tb
335
336
337
338
339
340
341
342
343
344
345
346
347
348
349
350
351
352
353
354
355
356
357
358
359
360
361
362
363
364
365
366
367
368
369
370
371
372
373
374
375

0.3481222
0.3461763
0.3442304
0.34228449
0.34033859
0.33839268
0.33644678
0.33450088
0.33255497
0.33060907
0.32866316
0.32671726
0.32477136
0.32282545
0.32087955
0.31893364
0.31698774
0.31504184
0.31309593
0.31115003
0.30920413
0.30725822
0.30531232
0.30336641
0.30142051
0.29947461
0.2975287
0.2955828
0.29363689
0.29169099
0.28974509
0.28779918
0.28585328
0.28390737
0.28196147
0.28001557
0.27806966
0.27612376
0.27417786
0.27223195
0.27028605

B
-8.51838
-8.54796

0.34163
0.76982

-5.73683
-3.1085

tA
PvapB
0.34646898 0.51039886
0.34451814 0.53342867
0.3425673 0.55732622
0.34061647
0.5821169
0.33866563
0.6078266
0.33671479 0.63448168
0.33476395
0.662109
0.33281311 0.69073591
0.33086227 0.72039023
0.32891143
0.7511003
0.32696059 0.78289493
0.32500975 0.81580342
0.32305892 0.84985559
0.32110808 0.88508173
0.31915724 0.92151262
0.3172064 0.95917956
0.31525556 0.99811433
0.31330472
1.0383492
0.31135388 1.07991695
0.30940304 1.12285083
0.3074522 1.16718461
0.30550137 1.21295255
0.30355053 1.26018938
0.30159969 1.30893035
0.29964885 1.35921119
0.29769801 1.41106811
0.29574717 1.46453782
0.29379633 1.51965752
0.29184549 1.57646488
0.28989465 1.63499808
0.28794382 1.69529576
0.28599298 1.75739706
0.28404214 1.82134157
0.2820913
1.8871694
0.28014046
1.9549211
0.27818962
2.0246377
0.27623878 2.09636072
0.27428794 2.17013213
0.2723371 2.24599437
0.27038627 2.32399036
0.26843543 2.40416345

PvapA
0.91211454
0.94928764
0.98771415
1.0274266
1.0684581
1.11084226
1.15461329
1.19980593
1.24645548
1.29459782
1.34426936
1.39550709
1.44834857
1.50283192
1.55899582
1.61687955
1.67652292
1.73796635
1.8012508
1.86641783
1.93350957
2.00256872
2.07363856
2.14676296
2.22198635
2.29935376
2.37891079
2.46070362
2.54477901
2.63118432
2.71996748
2.81117699
2.90486196
3.00107207
3.09985758
3.20126934
3.30535879
3.41217795
3.52177942
3.63421639
3.74954263

Tc
8.32581
1.54481

513.9
512.6

XA
11.1760665
10.7405917
10.322487
9.92092255
9.53511297
9.16431472
8.80782375
8.46497317
8.13513104
7.81769845
7.51210754
7.21781979
6.93432434
6.6611364
6.39779584
6.14386578
5.8989313
5.66259822
5.43449201
5.21425666
5.00155368
4.79606119
4.597473
4.40549775
4.21985816
4.04029028
3.86654275
3.69837618
3.53556248
3.37788435
3.22513464
3.07711586
2.93363971
2.79452657
2.65960511
2.5287118
2.40169059
2.2783925
2.15867527
2.04240305
1.92944605

376
377
378
379
380
381
382
383
384
385
386
387
388
389
390
391
392
393
394
395
396
397
398
399

0.26834014
0.26639424
0.26444834
0.26250243
0.26055653
0.25861062
0.25666472
0.25471882
0.25277291
0.25082701
0.24888111
0.2469352
0.2449893
0.24304339
0.24109749
0.23915159
0.23720568
0.23525978
0.23331387
0.23136797
0.22942207
0.22747616
0.22553026
0.22358435

0.26648459
0.26453375
0.26258291
0.26063207
0.25868123
0.25673039
0.25477956
0.25282872
0.25087788
0.24892704
0.2469762
0.24502536
0.24307452
0.24112368
0.23917284
0.23722201
0.23527117
0.23332033
0.23136949
0.22941865
0.22746781
0.22551697
0.22356613
0.22161529

2.48655748
2.57121674
2.65818596
2.74751034
2.83923551
2.93340757
3.03007305
3.12927892
3.2310726
3.33550192
3.44261518
3.55246108
3.66508876
3.78054779
3.89888815
4.02016024
4.14441491
4.27170337
4.40207729
4.53558872
4.67229013
4.8122344
4.9554748
5.102065

3.86781251
3.98908096
4.11340352
4.24083629
4.37143599
4.50525988
4.64236585
4.78281234
4.92665839
5.07396363
5.22478827
5.3791931
5.5372395
5.69898943
5.86450544
6.03385067
6.20708884
6.38428426
6.56550182
6.75080701
6.94026587
7.13394509
7.33191188
7.5342341

1.81968027
1.7129872
1.60925357
1.50837107
1.41023614
1.31474975
1.22181712
1.13134761
1.04325444
0.95745455
0.87386844
0.79241996
0.7130362
0.63564728
0.56018629
0.48658907
0.41479416
0.3447426
0.27637789
0.20964583
0.14449443
0.08087382
0.01873612
-0.0419646

Pc

PT
61.4
80.9

diagrama T-XY sistema metanol-etanol

400
398
396

T(K)

394
392
390
388
386
384
382
0

0.2

0.4

0.6

0.8

XA-YA

XA-YA
1
0.8
0.6
YA

YA
2.03877055
2.03918218
2.03913329
2.03860396
2.03757373
2.03602162
2.03392607
2.031265
2.02801574
2.02415507
2.01965919
2.01450373
2.00866374
2.00211368
1.9948274
1.98677819
1.97793871
1.96828103
1.95777662
1.94639632
1.93411038
1.92088842
1.90669946
1.89151187
1.87529345
1.85801133
1.83963205
1.82012153
1.79944504
1.77756727
1.75445226
1.73006346
1.70436368
1.67731513
1.64887941
1.61901751
1.58768982
1.55485613
1.52047563
1.48450693
1.44690805

0.4
0.2
0
0

0.2

0.4

0.6
XA

volatilidad

volatilidad promedio

0.8

1.40763642
1.36664893
1.32390185
1.27935095
1.23295141
1.18465786
1.13442442
1.08220466
1.02795164
0.97161791
0.91315552
0.852516
0.78965044
0.72450943
0.65704311
0.58720116
0.51493283
0.44018695
0.36291191
0.28305571
0.20056596
0.11538987
0.02747431
-0.06323422

1.52119943
1.51768002
1.51421591
1.51080638
1.50745071
1.50414816
1.50089805
1.49769967
1.49455234
1.49145537
1.4884081
1.48540987
1.48246002
1.4795579

1.49971014

metanol-etanol

XA
YA

0.8

Series1

YA
0.001
0.01
0.02
0.05
0.1
0.15
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
0.95
1

regla de la palanca
-0.998
-1.98380567
-6.4
3.62903226
1.56862745
1.17449664
0.95238095
0.60606061
0.29498525
0
-0.27855153
-0.53475936
-0.75376884
-0.91954023
-0.97192225
-1

T(C)
0
0.253
0.425
0.624
0.755
0.798
0.815
0.83
0.839
0.849
0.859
0.874
0.898
0.935
0.963
1

100
91.7
86.6
75.7
66.6
63.4
62.2
61
60.4
60
59.5
58.9
58.2
57.5
57
56.5
acetona

diagrama T-XY sistema acetona

1 atm)
150
T(C)

XA

100
50
0
0

0.2

0.4

0.6
XA-YA

B
6.30

C
0.26

D
-1.25E-04

2.04E-08

cp acetona
72.41

agua

B
32.24

cp agua
33.62

C
0.00

D
1.06E-05

-3.60E-09

sistema acetona-agua (a
1 atm)

XA
YA
0.6

0.8