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9701 CHEMISTRY
9701/04
This mark scheme is published as an aid to teachers and students, to indicate the requirements of the
examination. It shows the basis on which Examiners were initially instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners meeting before marking began. Any
substantial changes to the mark scheme that arose from these discussions will be recorded in the published
Report on the Examination.
All Examiners are instructed that alternative correct answers and unexpected approaches in candidates
scripts must be given marks that fairly reflect the relevant knowledge and skills demonstrated.
Mark schemes must be read in conjunction with the question papers and the Report on the Examination.
CIE will not enter into discussion or correspondence in connection with these mark schemes.
CIE is publishing the mark schemes for the June 2005 question papers for most IGCSE and GCE Advanced
Level and Advanced Subsidiary Level syllabuses and some Ordinary Level syllabuses.
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Grade thresholds for Syllabus 9701 (Chemistry) in the June 2005 examination.
maximum
mark
available
Component 4
60
45
40
22
The thresholds (minimum marks) for Grades C and D are normally set by dividing the mark
range between the B and the E thresholds into three. For example, if the difference between
the B and the E threshold is 24 marks, the C threshold is set 8 marks below the B threshold
and the D threshold is set another 8 marks down. If dividing the interval by three results in a
fraction of a mark, then the threshold is normally rounded down.
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June 2005
GCE A LEVEL
MARK SCHEME
MAXIMUM MARK: 60
SYLLABUS/COMPONENT: 9701/04
CHEMISTRY
Paper 4 (Structured Questions A2 Core)
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Page 1
(a)
Mark Scheme
A LEVEL JUNE 2005
(i)
(ii)
(iii)
Syllabus
9701
Paper
4
Ammeter/galvanometer
[1]
[1]
[1]
Volume/amount of hydrogen/gas
[1]
Time
[1]
Current/amps/ammeter reading
(ignore extra measurements)
[1]
[1]
(i)
F=Lxe
[1]
(ii)
[1]
(a)
[1]
Part (a): [1]
(b)
(i)
[1]
[1]
[1]
(ii)
Rate = k [propanone][CN-]
(iii)
Mechanism B (or A see grid below), with the first (or second
see grid below) step being the slow step,
[1]
[1]
[1]
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Page 2
(a)
Mark Scheme
A LEVEL JUNE 2005
(i)
(ii)
Syllabus
9701
Paper
4
[1]
[1]
[1]
[1]
Part (a): [5]
(b)
[1]
Part (b): [1]
(c)
[1]
Mr(2CO2) = 2 x 44 = 88
88
= 47.7%
184.4
Allow 48%. Also allow 48.8% if Mr = 184
% loss in mass = 100 x
(e.c.f. in 184.4)
[1]
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Page 3
(a)
Mark Scheme
A LEVEL JUNE 2005
Syllabus
9701
Paper
4
(i)
(ii)
[1]
(i)
(ii)
[1]
[1]
[1]
[1]
[1]
(i)
(ii)
(e)
Reagent: I2 + OH-
[1]
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Page 4
Mark Scheme
A LEVEL JUNE 2005
Syllabus
9701
Ka = [RCO2-][H+]/[RCO2H]
(a)
Paper
4
[1]
Part (a): [1]
(b)
(i)
The more chlorine atoms in the molecule, the stronger the acid,
[1]
(iii)
[1]
pH = -log10(0.0118)
1.93
[1]
1.26
Allow 1.3
e.c.f.
[1]
Part (b): [6]
(c)
(i)
[1]
(ii)
[1]
Either:
or:
or:
or:
or:
add Br2(aq)
phenol decolourises it, or gives a white ppt.
add FeCl3(aq) phenol give a purple colour
add NaOH(aq) phenol dissolves
add UI solution phenol goes yellow/orange (A stays green)
add diazoniumto solution in OHphenol gives orange/red colour
(in each case, A give no reaction)
or:
or:
or:
or:
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Page 5
(a)
Mark Scheme
A LEVEL JUNE 2005
Syllabus
9701
Paper
4
(i)
[1]
(ii)
HNO3 + H2SO4
[1]
[1]
NO2+
[1]
(iii)
NO2
H
etc.
NO2
or
[1]
H+
[1]
Part (a): [6]
(b)
(i)
Reduction
[1]
(ii)
[1]
Part (b): [2]
(c)
PCl5/PCll3/SOCll2/POCl3
(+ heat)
aq negates
[1]
Part (c): [1]
(d)
(i)
(ii)
[1]
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