Вы находитесь на странице: 1из 59

Cálculo auxiliar: DIFERENÇA DE PROPRIEDADES (VAPOR SAT.

) USANDO EDE-SOAVE
R=83,14
T=300 K
P=9,9742 bar
Po=0,001 bar
Zv=0,825506813
a=9515535,869
b=7,543801116
alpha=1,007077971
A=a*alpha=9582886,56
A=a*alpha=(1+0,71684247*(1-(T/369.85)^0,5))^2
Vv=2064,305
> 0.825506813-1;
-0.174493187
INTEGRAL PARA AVALIAR G-Go/RT:
> int(-.174493187/P, P=0.001..9.9742);
-1.606690871
Iln(P/Po):
> ln(9.9742/0.001);
9.207757038
(G-Go)/RT:
> -1.606690871+9.207757038;
7.601066167
Z=Z(P,V(T),T)
fw= 0.71684247
dZ/dT)p:
> Z := V/(V-b)-((((1+0.71684247-0.71684247*(T/369.85)^(1/2)))^2)*V)/
(R*T*(V^2+b*V));
V ( 1.71684247 −0.03727442185 T )2 V
Z := −
V −b R T ( V 2 +b V )
> diff(Z,T);
0.03727442184 ( 1.71684247 −0.03727442185 T)V
( 3/2 )
RT ( V 2 +b V )
( 1.71684247 −0.03727442185 T )2 V
+
R T 2 ( V 2 +b V )
VALOR DE (dZ/dT)p em : a*alpha, Vv, R, T e b:
> DZ:=(A,V,R,T,b)->.3727442184e-1*(1.71684247-.3727442185e-
1*T^(1/2))*V/R/T^(3/2)/(V^2+b*V)+(1.71684247-.3727442185e-
1*T^(1/2))^2*V/R/T^2/(V^2+b*V);
0.03727442184 ( 1.71684247 −0.03727442185 T)V
DZ := ( A, V, R, T, b ) → ( 3/2 )
RT ( V 2 +b V )
( 1.71684247 −0.03727442185 T )2 V
+
R T 2 ( V 2 +b V )
VALOR:
> DZ(9582886.56,2064.305,83.14,300,7.543801116);
>
0.2404364616 10 -11 ( 1.71684247 −0.03727442185 300 ) 300
+0.6450441071 10 -10 ( 1.71684247 −0.03727442185 300 ) 2
> evalf(%);
0.1186322610 10 -9
-9
(dZ/dT)p= 0.1186322610 10
INTEGRAL PARA AVALIAR (S-So)/R:
> int(((1-0.825506813-300*(.1186322610e-9))/P),P=0.001..9.9742);
1.606690543
(S-So)/RT:
> 1.606690543-ln(9.9742/0.001);
-7.601066495