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CHEMISTRY LEARNING CHECK

Chapter 04

Chemistry ( First Paper)


( Multiple Choice Questions)

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Which one of the following factor affects enthalpy? -i) Nature of element ii)
Quantity of the reactant iii) Distribution of element; which one is correct?
a) i b)ii c) i,ii d) i and iii
If the heat of combustion of methane is -800 kJmol-1 then what amount of methane
will be required to get 1600 kj of heat?
a. 16g b. 24g c. 32g
d.48g
Heat of formation for element is--a) 0 b) +ve c) -ve d) infinite
Heat of neutralization is - i) always exothermic ii)for strong acid-base is -57.3
Kj iii) non spontaneous; which one is correct? a) i b) ii c) I and ii d) I and iii
Characteristics of exothermic reaction- i)H=-ve ii) spontaneous iii) heat is
evolved; which one is correct?
a. i
b) ii
c.iii d. I , ii , iii
Heat of reaction for the reaction between HF and NaOH is
-- a. 52kj b. -57kj c. -68kj d.-92kj
Which one of the following factor does not influence heat of reaction?
a. Atomic structure b. Quantity c. Position d. Allotropy
What is the pH of 0.05M H2SO4 ? (A) 0 (B) 1 (C) 2 (D) 4
pH of 0.1M CH3COOH( ka= 1.8x10-5)?
(a) 1.87
(b) 2.87
(c) 3.43
(d) 5.9
Strongest halogen acid is a) HF b) HCl c) HBr d) HI
pH of 0.01M NaOH =? a) 2 b)8 c) 12 d) 14
If Phenolphthelein is added to the solution of NaOH then what colour will be
observed?
A) Red b) Blue c) Pink d) Colourless
What amount of 0.3M NaOH will be required to neutralize 30mL0.3M H2SO4 ?
A) 15 b) 30 c) 60 d) 90
If Phenolphthalein is added to the mixture of 10 mL 0.1M NaOH and 20 mL
0.1M HCl then it will form colour. A) Red b) Blue c) Pink d) Colourless
Which one of the following metal cannot displace H of HCl?
A) Zn b) Ca c) Au d) K
pH of a solution is 3, then [H+]=?
(a) 110-2 (b) 110-3 (c) 110-7
(d) 210-8
Which one of the following catalyst is used in the conversion of sulphur dioxide
to sulphur tri oxide?
(a) Fe powder (b) MnO2 (c) V2O5 (d) H3PO4
kp = kc,when n=? a.0 b.1c. 2 d.3
N2(g) + 3H2 (g) = 2NH3; unit of kc for the reaction isa) mol/L b) L/mol c) mol/L2 d) L2/mol2

BIPLOB DEB, FACULTY, DEPT.OF CHEMISTRY, NOTRE DAME COLLEGE, DHAKA. (01711220991)

CHEMISTRY LEARNING CHECK

Chapter 04

20. Pressure effect is not observed for the reaction


a. I2(g) + H2(g)=2HI(g) b.2SO2 (g) + O2(g) = 2SO3(g)
c. N2 (g) + 3H2(g) = 2NH3(g)
d. PCl3 (g) + Cl2(g) = PCl5(g)
21. N2 (g) + 3H2(g) = 2NH3(g);H=-92 kJ
i) exothermic reaction ii) reversible iii) volume compresses; which one is
correct?( a). i
(b). i ,ii (c). iii
(d). i, ii ,iii
22. Rateof reaction increases with the increase in temperature becausei) Ea decreases ii) collision increases iii) activated species increases; which one is
correct? a) i b) ii c) iii d) i, ii and iii
23. Rate of reaction is controlled by- i) Surface area ii) Concentration iii) nature of
reactant; which one is correct? (a). i (b). ii (c). iii (d).i,ii,iii
24.If the concentration at equilibrium for H2 , I2 and HI are 10, 5 and 5 mol/L then for
the dissociation of HI find out kc? (a) 0.5 (b) 2 (c) 10 (d) 25
25. What amount of lime will be obtained if 10g CaCO3 is heated?
A) 4.0 b) 5.6 c) 10 d) 15
26. Which one of the following factor does not affect equilibrium position?
a) Temperature b) Concentration c) Catalyst d) Pressure
27. Energy of activation-i) Controls rate of reaction ii) collosion between the particles
supplies Ea iii) Proportional to rate of reaction; which one is correct?
A) I b) I and ii c) I and iii d) ii and iii
2SO2 (g) + O2(g) = 2SO3(g)+ 192kj ; Considering the given reaction answer
question 28-29:
28. The reaction is- a) Endothermic b) Exothermic c) Temperature effect is not
present d) Decomposition reaction.
29. If pressure is increased for the above reaction then equilibrium position i)goes
back ii) moves right iii) remain unchanged; which one is correct?
a. I b. ii c. iii d. ii and iii
30. Catalyst - i) Controls reaction rate ii) does not affect equilibrium process iii)
decreases reaction rate; which one is correct? A) i b) ii c) I and ii d) I,ii and iii
31. If 10% PCl5 dissociates to give PCl3 and Cl2 and the total pressure is 10 atm then
Kp a) 0.1 b) 0.001 c) 0.0001 d) 0.00001
32. If pressure is increased fro the association of PCl5 then the equilibrium position
moves towards-i) right ii) left iii) forward; which one is correct?
a) i b) ii c) iii d) I and iii
33. Heighest pH is observed in
(a) 0.1M HCl(b) 0.2M H2SO4 (c) 0.01M NaOH (d) 1M NaCl

34. For exothermic reaction , if temperature is increased at equilibrium then kc-

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CHEMISTRY LEARNING CHECK

Chapter 04

(a) increases (b) decreases (c) remain unchanged (d) will be zero.
35. What amount of heat is required to increase the temperature of 100g water from 40C to

140C? (a) 0 cal (b) 10 cal (c) 100 cal (d) 1000 cal.
36. If the heat of reaction of HCl and HF with NaOH are -57.3and -68.3 KJmol-1 then what
will be the heat of hydration ? (a) -125.6 (b) -11 (c) +11 (d) + 47
37.
logkp
1/T
st

It is for - (a) zero order reaction (b) 1 order reaction (c) exothermic (d) endothermic
38. If [OH-] is 8.2x10-4 then pH=?

(a) 3.09 (b) 8.91 (c) 9.4 (d) 10.91.

39. If the internal energy of reactant is greater than that of product then H will
be (a) 0 (b) +ve (c) -ve (d) incomplete.
40. Green solvent is a) Water b) CO2 c) CCl4 d) C6H6
41.If n is 0.5 then at what K temperature kp and kc will be 40.5 and 5.5?
(a) 388 (b) 456 (c) 661.3 (d) 756.6.
42. Green house factor of NOx is a) 1 b) 60 c) 160 d) 240
43.Which one of the following acid is the strongest ?
(a) HNO3 (b) HOCl (b) H3BO3 (d) HClO4
44. What number of moles of oxygen will be required to burn 1 mole of Benzene?
(a) 6 (b) 7.5 (c) 15 (d) 30
45.If 10% of 0.1M acetic acid dissociates then what will be the acid dissociation constant?
(a) 0.1 (b) 0.01 (c) 0.001 (d) 0.0001
46. What amount of heat will be evolved if 46g ethanol is burnt to raise the temperature of
1kg water by 20C? (a) 4.2 kJ (b) 8.4 kJ (c) 13.6 kJ (d) 840 J
47. What amount of 1M NaOH will be needed to neutralized the mixture of 20mL 0.15M
HCl and 10 mL 0.1M H2SO4? (a) 2 (b) 3 (c) 4 (d) 5
48. If 20mL 0.25M NaOH solution is added to 100mL 0.25M HCOOH then the resulting
solution will be known as- (a) Basic (b) Neutral (c) Buffer (d) Normal solution.
49. H=? + PV (a) T (b) E (c) t (d) R
50. Heat of reaction is independent of reaction path is the concept of
(a) Laplaces law (b) Lavoisier law (c) Hesss law (d) Rate law

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CHEMISTRY LEARNING CHECK

Chapter 04

51.In which pH range strong acid and strong base changes their colour?
(a) 3-8 (b) 6-8 (c) 10-12 (d) 12-14
52. If kp for the dissociation for N2O4 is 0.08 atm and partially pressure of N2O4 is 0.8 atm
then the partialpressure of NO2 is a) 0.15 (b) 0.20 (c) 0.25 (d) 0.35
53. If temperature is increased for 2NH3= N2 + 3H2 system then the position of
equilibrium will (a) move towards right (b) remain unchanged (c) move towards left
(d) diminished.
54. Example of heterogeneous equilibrium is(a) 2NH3 (g) = N2(g) + 3H2(g)

(b) 2HI (g) = H2(g) + I2(g)


-

(c) CH3COOH (aq) = CH3COO (aq) + H (aq) (d) AgCl (s) = Ag + (aq) + Cl- (aq)
55. kp and kc will be same for
(a) 2NH3 (g) = N2(g) + 3H2(g) (b) 2HI (g) = H2(g) + I2(g)
(c) CH3COOH (aq) = CH3COO-(aq) + H+(aq) (d) COCl2 (s) = CO (g) + Cl2 (g)
56. Catalyst used in the preparation of nitric acid commercially by Ostwald process is (a)
MnO2 (b ) V2O5 (c) Fe powder (d) Pt + Rh
57. Positive catalyst ----- the Ea value. i. increases ii. Decreases iii) does not affect; which
one is correct? (a) I (b) ii (c) iii ( d) I, ii
58. Find out the pH of the buffer solution formed by 0.1M acetic acid and 0.1m sodium
acetate mixture?[ka= 1.8x10-5] (a) 4.54 (b) 4.34 (c) 4.74 (d) 5.24

59.

1
3
N 2 ( g ) H 2 ( g ) NH3(g) unit of kc is
2
2

(a) mol/L (b) L/mol (c) (mol/L)2 (d) (mol/L)3


60. Give an example of equilibrium process which can be made
reversible?............................................................................................................

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