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The Onion diagram

diagram

Reactor

Heat exchanger network I


Composite curves

Separation &
recycle
Heat exchange
network
Utilities
(Linnhoff et al., 1982)
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Lecture outline

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Recommended texts

 Single heat transfer unit vs. a


network (multiple units)
 Heat transfer composite curves
 Hot & cold utility targets
 The famous name pinch

analysis

 Smith, R. (2005). Chemical Process Design and Integration. New York: John

Wiley & Sons (heat exchanger network synthesis).


 Linnhoff, B., Townsend, D. W., Boland, D., Hewitt, G. F., Thomas, B. E.
A., Guy, A. R., & Marshall, R. H. (1982). A User Guide on Process
Integration for the Efficient Use of Energy. Rugby: IChemE (latest edition
by Ian Kemp).
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Evolution of heat recovery


pinch analysis

Some important terms

1970s

Minimum hot and cold utility targeting

1983

The pinch design method (PDM)

1984

Surface area targeting

 Stream to be cooled
 Sources of heat

Heat integration for batch processes

1990

Energy-area trade off (Supertargeting)

1993

Distillation column integration

1993

Total site analysis

Target T

 Stream to be heated
 Sinks of heat

Target T
Cold stream

 Supply temp initial T


 Target temp final T

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2 stream heat recovery

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Supply T
Hot stream

 Cold streams

1989

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 Hot streams

Supply T

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2 stream heat recovery

Steam

Type

Supply temp,
TS (C)

Target temp, TT
(C)

H
(MW)

Steam

Type

Supply temp,
TS (C)

Target temp, TT
(C)

H
(MW)

Cold

40

110

14

Cold

40

110

14

Hot

160

40

12

Hot

160

40

12

QHmin = 3

 Utility available for use:


 Steam @ 180C
 Cooling water @ 20C

QCmin = 1
QREC = 11

 Without heat recovery:


 Heat Stream 1 with steam: 14 MW
 Cold Stream 2 with cooling water: 12 MW

 Comment: high energy cost!


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Tmin = 10C
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A more complex problem

Larger value of Tmin

Feed 2

 Important features:

 Energy targets:

 Vertical shifting is prohibited


 Horizontal shifting is allowed

230C

Reactor 2

140C

 Minimum hot utility: QHmin


 Minimum cold utility: QCmin

180C

Feed 1
20C

Reactor 1

Product 2

200C

80C

250C

Off gas, 40C

40C

Q = mC p T = mC p (TT TS )

QHmin = 4

Product 1, 40C

Supply
Target
H Heat capacity
temp,
temp,
flowrate, CP
(MW) (MW.K-1)
TS (C)
TT (C)
1. Reactor 1 feed
Cold
20
180
32.0
0.20
2. Reactor 1 product
Hot
250
40
31.5
0.15
3. Reactor 2 feed
Cold
140
230
27.0
0.30
4. Reactor 2 product
Hot
200
80
30.0
0.25
Note: Heat capacity flowrate, CP = m.Cp

QCmin = 2

Steam

QREC = 10

Tmin = 20C
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Type

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Hot composite curve

Cold composite curve

T (C)

T (C)

30.0

H (MW)

61.5
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48
61.5

7.5 H (MW)

CP

0 .3

32

27

H (MW)

24

59
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.5
=0

20

20
31.5

CP

=
CP

40

0 .1

40

180
140

140

80

230

CP

80

0.3

0.

CP

CP

180

.4
=0

CP
=

CP

2
0.

230

CP

200

T (C)

0.
2

200

CP
=

250

0.1
5

250

0.1
5

T (C)

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20

15 H (MW)

59
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Hot & cold composite curves

With larger Tmin


QHmin = 7.5

T (C)
Tmin = 10C
250
230
Pinch
QHmin = 11.5

Tmin = 10C

QCmin = 10

40
20

Tmin = 20C
QCmin = 10

QREC = 51.1

QHmin = 7.5

H (MW)
QCmin = 14

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Tmin & economic tradetrade-off


T

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A note on Tmin
 Care should be taken not to ignore practical
constraints in setting Tmin

 To achieve pure Tmin requires heat exchangers


that exhibit pure countercurrent flow
H

Cost
Total

 Shell-and-tube: not possible  Tmin < 10C should be


avoided
 Plate heat exchanger: Tmin ~ 5C or less

Energy
Capital

Q = UATmin

Tmin
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Additional task

The heat recovery pinch

 Proof that the CP for composite curve is the


summation of CP of individual streams.

QHmin

T (C)

 Locate the new energy targets for the following


value of Tmin:

Pinch
Heat
sink

 30C
 50C

Heat
source
Tmin

H (MW)

QCmin

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Possible heating

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Impossible heating

T (C)

T (C)

Impossible

Possible
Pinch

Pinch

Heat
source

Heat
source

H (MW)

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H (MW)

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Heat transfer across pinch

Cold above the pinch

QHmin +XP

T (C)

XP

QHmin +XP

T (C)

Heat
sink

Heat
sink

Heat
source

Heat
source

H (MW)

QCmin+XP

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 To achieve energy targets, must not transfer heat


across the pinch by:
 Process-process heat transfer
 Inappropriate use of utility

Heat
sink

DONT COLD ABOVE THE PINCH!


DONT HEAT BELOW THE PINCH!

Heat
source

H (MW)

QCmin+XP

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Heuristic
QHmin

XP

H (MW)

QCmin

Heat below the pinch


T (C)

XP

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