ORGANIC CHEMISTRY TEST: BOARD EXAM PREP

Time: 2 HOURS

1. What is the type of hybridization of each carbon atom in the following compounds? [4]
(a) Chloroform

(b) (CH3)2CO

(c) CH3CN

(d) CH3CH = CHCN

2. How many and bonds are present in each of the following molecules? [4]
(a) but-3-yne-1-ene
(b) CH2=C=CHCH3
3. Write the IUPAC Names of the following: [6]

4. Draw the position isomers of the following compounds [6]

5. Identify whether the following are aromatic, anti-aromatic or non-aromatic. [8]

6. What are enantiomers and what are diastereomers? [2]

7. What is the reagent(s) used in Aromatization of alkanes and isomerisation of alkanes? [4]
8. What is syn gas? How is it produced? Give one utility of syn gas [3]
9. What happens when acetylene is passed through a red-hot iron tube? [3]

10. Write the products of the following reactions: [7*5]

a. But-1-ene reacts with acidic KMno4
b. Propene reacts with ozone followed by Zn and Water.
c. 1-chloropropane reacts with Sodium in dry ether
d. Sulfuric acid is added to propene
e. HBr is added to but-1-ene in presence of peroxide
f.

2-chlorobutane reacts with alcoholic KOH

g. Phenol reacts with CH3Cl in presence of AlCl3

11. Draw the resonance forms of Phenol and Buta-1,3-diene. [6]

12. Give examples of three +M groups and three M groups. [3]
13. Draw the geometrical isomers of pent-2-ene and label them as cis or trans. [3]
14. Draw the conformational isomers of ethane by using newmann projections and label the
conformers with their names. [4]
15. Give the structures of compounds A to D