Mass and Energy With Recycle

Components
Isobutylene (C4H8)
O2
H2O
MAL (C4H6O)
MAA (C4H6O2)
AA (C2H4O2)
CO
CO2
Xylene
MeOH
H2SO4
MMA (C5H8O2)
MW
56 kg/kmol
32 kg/kmol
18 kg/kmol
70 kg/kmol
86 kg/kmol
60 kg/kmol
28 kg/kmol
44 kg/kmol
106 kg/kmol
32 kg/kmol
98 kg/kmol
100 kg/kmol
Unit Specification
1) R-101
Stoichiometry
C4H8
1
0.99
O2
1
O2
1
O2
3
O2
3
O2
5
Selectivity
MAL
2
0.85
0.84
MAL
1
0.08
MAL
1
0.04
MAL
1
0.04
3) V-101
Efficiency
0.9
Conversion
2) R-102
Stoichiometry
Conversion
Selectivity
Side reaction 1
Selectivity
Side reaction 2
Selectivity
Side reaction 3
4) C-101
Recovery of MAL
0.995
5) V-102
Recovery of MAA + AA (light)
0.95
6) C-102
Recovery of xylene + AA (top)
7) R-103
Stoichiometry
Conversion
MAA
1
0.9
8) C-103
Recovery of H2SO4 (bottom)
0.995
9) C-104
Fractional side withdrawal
Recovery of MMA (bottom)
Purity of MMA (bottom)
0.255
0.995
0.999
10) V-103
Efficiency
Basis of calculation
Feed condition
Production of MMA
Annual capacity
Plant capacity
Stream ID
Temperature
Pressure
Vapor Fraction
Mass Flow
Isobutylene (C4H8)
O2
H2O
MAL (C4H6O)
MAA (C4H6O2)
AA (C2H4O2)
CO
CO2
Xylene
MeOH
H2SO4
MMA (C5H8O2)
Total Mass Flow
MeOH
1
0.9
7.15
1 to 2
6.6039
315
50
deg C
bar
ton isobutylene/hr
C4H8 to O2 (excess oxygen)
ton MMA/hr
day
24
kTA
1
30
1
1.00
2
30
1
1.00
7.15
14.30
ton/hr
7.15
Checking
Mole Flow
Isobutylene (C4H8)
14.30
21.45
127.68
O2
H2O
MAL (C4H6O)
MAA (C4H6O2)
AA (C2H4O2)
CO
CO2
Xylene
MeOH
H2SO4
MMA (C5H8O2)
Total Mole Flow
446.88
kmol/hr
127.68
446.88
Checking
574.55
Mass Balance on Each Unit

R-101
In
Stream
Component
Isobutylene (C4H8)
O2
H2O
MAL (C4H6O)
Total
Mass Balance (ton/hr)
Mass Flow Rate Mole Flow Rate

(ton/hr)
(kmol/hr)
7.15
127.68
7.15
1
Mass Fraction
1.00
127.68
1.00
21
E-101
Inlet
3
Stream
Component
Isobutylene (C4H8)
O2
H2O
MAL (C4H6O)
Total

(ton/hr)
(kmol/hr)
0.07
10.26
2.28
8.85
21.45
Mass Fraction
1.28
320.47
126.40
126.40
574.55
0.00
0.48
0.11
0.41
1.00
21.45
E-102
Inlet
4
Stream
Component
Isobutylene (C4H8)

(ton/hr)
(kmol/hr)
0.07
1.28
Mass Fraction
0.00
O2
H2O
MAL (C4H6O)
Total
10.26
2.28
8.85
21.45
320.47
126.40
126.40
574.55
0.48
0.11
0.41
1.00
21.45
R-102
Inlet
7
Stream
Component
Isobutylene (C4H8)
O2
H2O
MAL (C4H6O)
MAA (C4H6O2)
AA (C2H4O2)
CO
CO2
Total

(ton/hr)
(kmol/hr)
Mass Fraction
0.07
10.26
2.63
10.22
1.28
320.47
146.11
146.02
0.00
0.44
0.11
0.44
23.18
613.88
1.00
23.18
E-103
Inlet
8
Stream
Component
Isobutylene (C4H8)
O2
H2O
MAL (C4H6O)
MAA (C4H6O2)
AA (C2H4O2)
CO
CO2
Total

(ton/hr)
(kmol/hr)
0.07
6.36
3.34
1.53
8.97
0.60
0.56
1.75
23.18
Mass Fraction
1.28
198.84
185.83
21.90
104.25
9.93
19.86
39.72
581.61
0.00
0.27
0.14
0.07
0.39
0.03
0.02
0.08
1.00
23.18
V-101
Inlet
9
Stream
Component
Isobutylene (C4H8)
O2

(ton/hr)
(kmol/hr)
0.07
6.36
1.28
198.84
Mass Fraction
0.00
0.27
H2O
MAL (C4H6O)
MAA (C4H6O2)
AA (C2H4O2)
CO
CO2
Total
3.34
1.53
8.97
0.60
0.56
1.75
23.18
185.83
21.90
104.25
9.93
19.86
39.72
581.61
0.14
0.07
0.39
0.03
0.02
0.08
1.00
23.18
C-101
In
Stream
Component
Isobutylene (C4H8)
O2
H2O
MAL (C4H6O)
MAA (C4H6O2)
AA (C2H4O2)
CO
CO2
Total
11
(ton/hr)
(kmol/hr)
0.06
5.73
0.33
1.38
0.90
0.06
0.50
1.57
10.53
Mass Fraction
1.15
178.96
18.58
19.71
10.43
0.99
17.87
35.74
283.44
0.01
0.54
0.03
0.13
0.09
0.01
0.05
0.15
1.00
10
E-104
Inlet
13
Stream
Component
H2O
MAL (C4H6O)
Total

(ton/hr)
(kmol/hr)
0.35
1.37
1.73
Mass Fraction
19.71
19.61
39.33
0.21
0.79
1.00
1.73
E-105
Inlet
10
Stream
Component
Isobutylene (C4H8)
O2
H2O
MAL (C4H6O)
MAA (C4H6O2)

(ton/hr)
(kmol/hr)
0.01
0.64
3.01
0.15
8.07
0.13
19.88
167.25
2.19
93.83
Mass Fraction
0.00
0.05
0.24
0.01
0.64
AA (C2H4O2)
CO
CO2
Total
0.54
0.06
0.17
12.64
8.94
1.99
3.97
298.17
0.04
0.00
0.01
1.00
12.64
M-101
In
Stream
Component
Isobutylene (C4H8)
O2
H2O
MAL (C4H6O)
MAA (C4H6O2)
AA (C2H4O2)
CO
CO2
Xylene
Total
15
(ton/hr)
(kmol/hr)
Mass Fraction
0.01
0.64
3.01
0.15
8.07
0.54
0.06
0.17
0.13
19.88
167.25
2.19
93.83
8.94
1.99
3.97
0.00
0.05
0.24
0.01
0.64
0.04
0.00
0.01
12.64
298.17
1.00
32
V-102
Inlet
19
Stream
Component
Isobutylene (C4H8)
O2
H2O
MAL (C4H6O)
MAA (C4H6O2)
AA (C2H4O2)
CO
CO2
Xylene
Total

(ton/hr)
(kmol/hr)
0.01
0.64
3.01
0.15
8.07
10.72
0.06
0.17
9.95
32.78
Mass Fraction
0.13
19.88
167.25
2.19
93.83
178.72
1.99
3.97
93.83
561.79
0.00
0.02
0.09
0.00
0.25
0.33
0.00
0.01
0.30
1.00
32.78
P-101
Inlet
21
Stream
Component

(ton/hr)
(kmol/hr)
Mass Fraction
Isobutylene (C4H8)
O2
H2O
MAL (C4H6O)
MAA (C4H6O2)
AA (C2H4O2)
CO
CO2
Xylene
Total
0.00
0.00
0.00
0.00
0.00
0.00
0.00
7.67
10.19
0.00
0.00
9.95
27.80
0.00
89.14
169.79
0.00
0.00
93.83
352.75
0.00
0.28
0.37
0.00
0.00
0.36
1.00
27.80
C-102
Inlet
22
Stream
Component
Isobutylene (C4H8)
O2
H2O
MAL (C4H6O)
MAA (C4H6O2)
AA (C2H4O2)
CO
CO2
Xylene
Total

(ton/hr)
(kmol/hr)
Mass Fraction
0.00
0.00
0.00
0.00
0.00
0.00
0.00
7.67
10.19
0.00
0.00
9.95
27.80
0.00
89.14
169.79
0.00
0.00
93.83
352.75
0.00
0.28
0.37
0.00
0.00
0.36
1.00
27.80
E-106
Inlet
23
Stream
Component
MAA (C4H6O2)
AA (C2H4O2)
Xylene
Total

(ton/hr)
(kmol/hr)
0.00
10.19
9.95
20.13
Mass Fraction
0.00
169.79
93.83
263.62
0.00
0.51
0.49
1.00
20.13
T-101
Inlet
24
Stream
Component

(ton/hr)
(kmol/hr)
Mass Fraction
MAA (C4H6O2)
AA (C2H4O2)
Xylene
Total
7.67
0.00
0.00
7.67
89.14
0.00
0.00
89.14
1.00
0.00
0.00
1.00
7.67
P-102
Inlet
25
Stream
Component
MAA (C4H6O2)
AA (C2H4O2)
Xylene
Total

(ton/hr)
(kmol/hr)
7.67
0.00
0.00
7.67
Mass Fraction
89.14
0.00
0.00
89.14
1.00
0.00
0.00
1.00
7.67
E-107
Inlet
26
Stream
Component
MAA (C4H6O2)
AA (C2H4O2)
Xylene
Total

(ton/hr)
(kmol/hr)
7.67
0.00
0.00
7.67
Mass Fraction
89.14
0.00
0.00
89.14
1.00
0.00
0.00
1.00
7.67
R-103
Stream
Component
H2O
MAA (C4H6O2)
AA (C2H4O2)
Xylene
MeOH
H2SO4
MMA (C5H8O2)
Total
27
(ton/hr)
(kmol/hr)
Mass Fraction
7.67
0.00
0.00
89.14
0.00
0.00
1.00
0.00
0.00
7.67
89.14
1.00
E-108
Inlet
Stream
Component
H2O
MAA (C4H6O2)
AA (C2H4O2)
Xylene
MeOH
H2SO4
MMA (C5H8O2)
Total
32
(ton/hr)
(kmol/hr)
1.61
0.85
0.00
0.00
1.43
8.74
8.95
21.59
Mass Fraction
89.54
9.90
0.00
0.00
44.84
89.14
89.54
322.95
0.07
0.04
0.00
0.00
0.07
0.40
0.41
1.00
21.59
E-109
Inlet
34
Stream
Component
H2O
MAA (C4H6O2)
AA (C2H4O2)
Xylene
MeOH
H2SO4
MMA (C5H8O2)
Total

(ton/hr)
(kmol/hr)
1.56
0.00
0.00
0.00
1.10
0.04
6.86
9.57
Mass Fraction
86.82
0.05
0.00
0.00
34.38
0.43
68.64
190.32
0.16
0.00
0.00
0.00
0.11
0.00
0.72
1.00
9.57
E-110
Inlet
39
Stream
Component
H2O
MAA (C4H6O2)
MeOH
H2SO4
MMA (C5H8O2)
Total

(ton/hr)
(kmol/hr)
0.41
0.00
0.36
0.01
2.27
3.06
Mass Fraction
22.72
0.01
11.38
0.11
22.72
56.94
0.13
0.00
0.12
0.00
0.74
1.00
3.06
C-103 & C-104 & V-103 (red-loop)

Stream
Inlet
33
Component
H2O
MAA (C4H6O2)
MeOH
H2SO4
MMA (C5H8O2)
Total

(ton/hr)
(kmol/hr)
1.61
0.85
1.43
8.74
8.95
21.59
Mass Fraction
89.54
9.90
44.84
89.14
89.54
322.95
0.07
0.04
0.07
0.40
0.41
1.00
21.59
Input
Plant Capacity
Recycle Stream
MAL
1
H2O
1
MAA
2
AA
1
CO2
2
CO
4
H2O
3
CO2
4
H2O
3
H2O
1
MMA
1
H2O
1
3
395
1
1.00
4
561.28
3.7
1.00
5
350
3.7
1.00
0.07
10.26
2.28
8.85
0.07
10.26
2.28
8.85
21.45
21.45
hr
6 (13)
350
3.7
1.00
7
350
3.7
1.00
0.07
10.26
2.28
8.85
0.35
1.37
0.07
10.26
2.63
10.22
21.45
1.73
23.18
21.45
1.28
23.18
1.28
1.28
1.28
320.47
126.40
126.40
320.47
126.40
126.40
320.47
126.40
126.40
19.71
19.61
320.47
146.11
146.02
574.55
574.55
574.55
39.33
613.88
574.55
613.88
Inlet
Mole Fraction
1.00
Mass Flow Rate

(ton/hr)
Mole Flow Rate

(kmol/hr)
14.30
14.30
1.00
2
Mass Fraction
Mole Fraction
446.88
1.00
1.00
446.88
1.00
1.00
21.45
Outlet
4
Mole Fraction
Mass Flow Rate

(ton/hr)
Mole Flow Rate

(kmol/hr)
Mass Fraction
Mole Fraction
0.00
0.56
0.22
0.22
1.00
0.07
10.26
2.28
8.85
21.45
1.28
320.47
126.40
126.40
574.55
0.00
0.48
0.11
0.41
1.00
0.00
0.56
0.22
0.22
1.00
21.45
Outlet
5
Mole Fraction
Mass Flow Rate

(ton/hr)
Mole Flow Rate

(kmol/hr)
Mass Fraction
Mole Fraction
0.00
0.07
1.28
0.00
0.00
0.56
0.22
0.22
1.00
10.26
2.28
8.85
21.45
320.47
126.40
126.40
574.55
0.48
0.11
0.41
1.00
0.56
0.22
0.22
1.00
21.45
Outlet
8
Mole Fraction
0.00
0.52
0.24
0.24
1.00
Mass Flow Rate

(ton/hr)
Mole Flow Rate

(kmol/hr)
Mass Fraction
Mole Fraction
0.07
6.36
3.34
1.53
8.97
0.60
0.56
1.75
23.18
1.28
198.84
185.83
21.90
104.25
9.93
19.86
39.72
581.61
0.00
0.27
0.14
0.07
0.39
0.03
0.02
0.08
1.00
0.00
0.34
0.32
0.04
0.18
0.02
0.03
0.07
1.00
23.18
Outlet
9
Mole Fraction
Mass Flow Rate

(ton/hr)
Mole Flow Rate

(kmol/hr)
Mass Fraction
Mole Fraction
0.00
0.34
0.32
0.04
0.18
0.02
0.03
0.07
1.00
0.07
6.36
3.34
1.53
8.97
0.60
0.56
1.75
23.18
1.28
198.84
185.83
21.90
104.25
9.93
19.86
39.72
581.61
0.00
0.27
0.14
0.07
0.39
0.03
0.02
0.08
1.00
0.00
0.34
0.32
0.04
0.18
0.02
0.03
0.07
1.00
23.18
Outlet
10
Mole Fraction
Mass Flow Rate

(ton/hr)
Mole Flow Rate

(kmol/hr)
Mass Fraction
Mole Fraction
0.00
0.34
0.01
0.64
0.13
19.88
0.00
0.05
0.00
0.07
0.32
0.04
0.18
0.02
0.03
0.07
1.00
3.01
0.15
8.07
0.54
0.06
0.17
12.64
167.25
2.19
93.83
8.94
1.99
3.97
298.17
0.24
0.01
0.64
0.04
0.00
0.01
1.00
0.56
0.01
0.31
0.03
0.01
0.01
1.00
23.18
Inlet
12
Mole Fraction
Mass Flow Rate

(ton/hr)
Mole Flow Rate

(kmol/hr)
Mass Fraction
Mole Fraction
0.35
19.71
1.00
1.00
0.35
19.71
1.00
1.00
0.00
0.63
0.07
0.07
0.04
0.00
0.06
0.13
1.00
10.89
Outlet
6
Mole Fraction
Mass Flow Rate

(ton/hr)
Mole Flow Rate

(kmol/hr)
Mass Fraction
Mole Fraction
0.50
0.50
1.00
0.35
1.37
1.73
19.71
19.61
39.33
0.21
0.79
1.00
0.50
0.50
1.00
1.73
Outlet
15
Mole Fraction
Mass Flow Rate

(ton/hr)
Mole Flow Rate

(kmol/hr)
Mass Fraction
Mole Fraction
0.00
0.07
0.56
0.01
0.31
0.01
0.64
3.01
0.15
8.07
0.13
19.88
167.25
2.19
93.83
0.00
0.05
0.24
0.01
0.64
0.00
0.07
0.56
0.01
0.31
0.03
0.01
0.01
1.00
0.54
0.06
0.17
12.64
8.94
1.99
3.97
298.17
0.04
0.00
0.01
1.00
0.03
0.01
0.01
1.00
12.64
Inlet
18
Mole Fraction
Mass Flow Rate

(ton/hr)
Mole Flow Rate

(kmol/hr)
Mass Fraction
Mole Fraction
0.00
10.19
0.00
169.79
0.00
0.51
0.00
0.64
9.95
20.13
93.83
263.62
0.49
1.00
0.36
1.00
0.00
0.07
0.56
0.01
0.31
0.03
0.01
0.01
1.00
32.78
Outlet
20
Mole Fraction
0.00
0.04
0.30
0.00
0.17
0.32
0.00
0.01
0.17
1.00
Mass Flow Rate

(ton/hr)
Mole Flow Rate

(kmol/hr)
Mass Fraction
Mole Fraction
0.01
0.64
3.01
0.15
0.40
0.54
0.06
0.17
0.13
19.88
167.25
2.19
4.69
8.94
1.99
3.97
0.00
0.13
0.60
0.03
0.08
0.11
0.01
0.04
0.00
0.10
0.80
0.01
0.02
0.04
0.01
0.02
4.98
209.03
1.00
1.00
32.78
Outlet
22
Mole Fraction
Mass Flow Rate

(ton/hr)
Mole Flow Rate

(kmol/hr)
Mass Fraction
Mole Fraction
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.25
0.48
0.00
0.00
0.27
1.00
0.00
7.67
10.19
0.00
0.00
9.95
27.80
0.00
89.14
169.79
0.00
0.00
93.83
352.75
0.00
0.28
0.37
0.00
0.00
0.36
1.00
0.00
0.25
0.48
0.00
0.00
0.27
1.00
27.80
Outlet
23
Mole Fraction
Mass Flow Rate

(ton/hr)
Mole Flow Rate

(kmol/hr)
Mass Fraction
Mole Fraction
0.00
10.19
0.00
169.79
0.00
0.51
0.00
0.64
9.95
20.13
93.83
263.62
0.49
1.00
0.36
1.00
0.00
0.00
0.00
0.25
0.48
0.00
0.00
0.27
1.00
27.80
Outlet
17
Mole Fraction
Mass Flow Rate

(ton/hr)
Mole Flow Rate

(kmol/hr)
Mass Fraction
Mole Fraction
0.00
0.64
0.36
1.00
0.00
10.19
9.95
20.13
0.00
169.79
93.83
263.62
0.00
0.51
0.49
1.00
0.00
0.64
0.36
1.00
Mass Fraction
Mole Fraction
20.13
Outlet
25
Mole Fraction
Mass Flow Rate

(ton/hr)
Mole Flow Rate

(kmol/hr)
1.00
0.00
0.00
1.00
7.67
0.00
0.00
7.67
89.14
0.00
0.00
89.14
1.00
0.00
0.00
1.00
1.00
0.00
0.00
1.00
7.67
Outlet
26
Mole Fraction
Mass Flow Rate

(ton/hr)
Mole Flow Rate

(kmol/hr)
Mass Fraction
Mole Fraction
1.00
0.00
0.00
1.00
7.67
0.00
0.00
7.67
89.14
0.00
0.00
89.14
1.00
0.00
0.00
1.00
1.00
0.00
0.00
1.00
7.67
Outlet
27
Mole Fraction
Mass Flow Rate

(ton/hr)
Mole Flow Rate

(kmol/hr)
Mass Fraction
Mole Fraction
1.00
0.00
0.00
1.00
7.67
0.00
0.00
7.67
89.14
0.00
0.00
89.14
1.00
0.00
0.00
1.00
1.00
0.00
0.00
1.00
7.67
Inlet
28
Mole Fraction
Mass Flow Rate

(ton/hr)
Mole Flow Rate

(kmol/hr)
Mass Fraction
Mole Fraction
4.28
133.71
1.00
1.00
4.28
133.71
1.00
1.00
1.00
0.00
0.00
1.00
21.59
Outlet
33
Mole Fraction
Mass Flow Rate

(ton/hr)
Mole Flow Rate

(kmol/hr)
Mass Fraction
Mole Fraction
0.28
0.03
0.00
0.00
0.14
0.28
0.28
1.00
1.61
0.85
0.00
0.00
1.43
8.74
8.95
21.59
89.54
9.90
0.00
0.00
44.84
89.14
89.54
322.95
0.07
0.04
0.00
0.00
0.07
0.40
0.41
1.00
0.28
0.03
0.00
0.00
0.14
0.28
0.28
1.00
21.59
Outlet
35
Mole Fraction
Mass Flow Rate

(ton/hr)
Mole Flow Rate

(kmol/hr)
Mass Fraction
Mole Fraction
0.46
0.00
0.00
0.00
0.18
0.00
0.36
1.00
1.56
0.00
0.00
0.00
1.10
0.04
6.86
9.57
86.82
0.05
0.00
0.00
34.38
0.43
68.64
190.32
0.16
0.00
0.00
0.00
0.11
0.00
0.72
1.00
0.46
0.00
0.00
0.00
0.18
0.00
0.36
1.00
9.57
Outlet
40
Mole Fraction
Mass Flow Rate

(ton/hr)
Mole Flow Rate

(kmol/hr)
Mass Fraction
Mole Fraction
0.40
0.00
0.20
0.00
0.40
1.00
0.41
0.00
0.36
0.01
2.27
3.06
22.72
0.01
11.38
0.11
22.72
56.94
0.13
0.00
0.12
0.00
0.74
1.00
0.40
0.00
0.20
0.00
0.40
1.00
3.06
30
Mole Fraction
Mass Flow Rate

(ton/hr)
Mole Flow Rate

(kmol/hr)
Mass Fraction
Mole Fraction
0.28
0.03
0.14
0.28
0.28
1.00
0.01
0.85
0.01
8.69
0.04
9.60
0.45
9.85
0.22
88.69
0.45
99.66
0.00
0.09
0.00
0.91
0.00
1.00
0.00
0.10
0.00
0.89
0.00
1.00
````
8
350
3.7
1.00
9
85
1
0.48
10
60
1
0.09
11
60
1
0.89
0.07
6.36
3.34
1.53
8.97
0.60
0.56
1.75
0.07
6.36
3.34
1.53
8.97
0.60
0.56
1.75
0.01
0.64
3.01
0.15
8.07
0.54
0.06
0.17
0.06
5.73
0.33
1.38
0.90
0.06
0.50
1.57
23.18
23.18
12.64
10.53
23.18
23.18
23.18
1.28
1.28
0.13
12
4
1
0.00
0.35
0.35
10.89
1.15
198.84
185.83
21.90
104.25
9.93
19.86
39.72
198.84
185.83
21.90
104.25
9.93
19.86
39.72
19.88
167.25
2.19
93.83
8.94
1.99
3.97
178.96
18.58
19.71
10.43
0.99
17.87
35.74
581.61
581.61
298.17
283.44
581.61
581.61
581.61
Mass Flow Rate

(ton/hr)
0.07
10.26
2.28
8.85
21.45
Outlet
3
Mole Flow Rate
Mass Fraction
(kmol/hr)
1.28
0.00
320.47
0.48
126.40
0.11
126.40
0.41
574.55
1.00
21.45
19.71
19.71
303.15
Mole Fraction
0.00
0.56
0.22
0.22
1.00
Outlet
11
Mass Flow Rate
(ton/hr)
Mole Flow Rate

(kmol/hr)
Mass Fraction
Mole Fraction
0.06
5.73
1.15
178.96
0.01
0.54
0.00
0.63
0.33
1.38
0.90
0.06
0.50
1.57
10.53
18.58
19.71
10.43
0.99
17.87
35.74
283.44
0.03
0.13
0.09
0.01
0.05
0.15
1.00
0.07
0.07
0.04
0.00
0.06
0.13
1.00
23.18
Outlet
13
Mass Flow Rate
(ton/hr)
Mole Flow Rate

(kmol/hr)
14
Mass Fraction
Mole Fraction
0.35
1.37
19.71
19.61
0.21
0.79
0.50
0.50
1.73
39.33
1.00
1.00
Mass Flow Rate

(ton/hr)
0.06
5.73
0.33
0.01
0.90
0.06
0.50
1.57
9.16
10.89
Outlet
19
Mass Flow Rate
(ton/hr)
Mole Flow Rate

(kmol/hr)
Mass Fraction
Mole Fraction
0.01
0.64
3.01
0.15
8.07
10.72
0.06
0.17
9.95
32.78
0.13
19.88
167.25
2.19
93.83
178.72
1.99
3.97
93.83
561.79
0.00
0.02
0.09
0.00
0.25
0.33
0.00
0.01
0.30
1.00
0.00
0.04
0.30
0.00
0.17
0.32
0.00
0.01
0.17
1.00
32.78
Outlet
21
Mass Flow Rate
(ton/hr)
Mole Flow Rate

(kmol/hr)
Mass Fraction
Mole Fraction
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
7.67
10.19
0.00
0.00
9.95
27.80
0.00
89.14
169.79
0.00
0.00
93.83
352.75
0.00
0.28
0.37
0.00
0.00
0.36
1.00
0.00
0.25
0.48
0.00
0.00
0.27
1.00
32.78
Outlet
24
Mass Flow Rate
(ton/hr)
Mole Flow Rate

(kmol/hr)
Mass Fraction
Mole Fraction
7.67
0.00
89.14
0.00
1.00
0.00
1.00
0.00
0.00
7.67
0.00
89.14
0.00
1.00
0.00
1.00
27.80
Outle
32
31
Mass Flow Rate
(ton/hr)
Mole Flow Rate

(kmol/hr)
Mass Fraction
Mole Fraction
Mass Flow Rate

(ton/hr)
0.01
0.85
0.00
0.00
0.01
8.74
0.04
9.64
0.45
9.85
0.00
0.00
0.22
89.14
0.45
100.11
0.00
0.09
0.00
0.00
0.00
0.91
0.00
1.00
0.00
0.10
0.00
0.00
0.00
0.89
0.00
1.00
1.61
0.85
0.00
0.00
1.43
8.74
8.95
21.59
21.59
Outlet
37
38
Mass Flow Rate

(ton/hr)
Mole Flow Rate

(kmol/hr)
Mass Fraction
Mole Fraction
Mass Flow Rate

(ton/hr)
1.19
0.00
1.38
0.00
2.08
4.65
66.04
0.00
43.27
0.01
20.78
130.10
0.26
0.00
0.30
0.00
0.45
1.00
0.51
0.00
0.33
0.00
0.16
1.00
0.05
0.00
0.01
0.03
6.60
6.69
21.59
13
56.77
1
0.00
0.35
1.37
1.73
14
51.57
1
0.89
15
40
1
0.09
0.06
5.73
0.33
0.01
0.90
0.06
0.50
1.57
0.01
0.64
3.01
0.15
8.07
0.54
0.06
0.17
9.16
12.64
1.15
0.13
10.89
16
40
1
0.00
17 (23)
74.92
1
1.00
0.00
10.19
0.00
9.95
0.00
20.13
19.71
19.61
39.33
303.15
178.96
18.58
0.10
10.43
0.99
17.87
35.74
263.82
19.88
167.25
2.19
93.83
8.94
1.99
3.97
298.17
0.00
169.79
0.00
93.83
0.00
263.62
14
Mole Flow Rate
(kmol/hr)
Mass Fraction
Mole Fraction
1.15
178.96
18.58
0.10
10.43
0.99
17.87
35.74
263.82
0.01
0.63
0.04
0.00
0.10
0.01
0.05
0.17
1.00
0.00
0.68
0.07
0.00
0.04
0.00
0.07
0.14
1.00
Outlet
32
Mole Flow Rate
(kmol/hr)
Mass Fraction
Mole Fraction
89.54
9.90
0.00
0.00
44.84
89.14
89.54
322.95
0.07
0.04
0.00
0.00
0.07
0.40
0.41
1.00
0.28
0.03
0.00
0.00
0.14
0.28
0.28
1.00
21.59
38
41
Mole Flow Rate

(kmol/hr)
Mass Fraction
Mole Fraction
Mass Flow Rate

(ton/hr)
Mole Flow Rate

(kmol/hr)
2.60
0.04
0.21
0.33
66.04
69.22
0.01
0.00
0.00
0.00
0.99
1.00
0.04
0.00
0.00
0.00
0.95
1.00
0.37
0.00
0.04
0.01
0.23
0.64
20.45
0.01
1.14
0.10
2.27
23.97
18
40
1
0.00
19
63.42
1
0.05
20
45
1
0.12
21
45
1
0.00
22
45.18
3
0.00
0.01
0.64
3.01
0.15
0.40
0.54
0.06
0.17
0.00
0.00
9.95
0.01
0.64
3.01
0.15
8.07
10.72
0.06
0.17
9.95
0.00
7.67
10.19
0.00
0.00
9.95
0.00
0.00
0.00
0.00
7.67
10.19
0.00
0.00
9.95
20.13
32.78
4.98
27.80
27.80
32.78
32.78
32.78
0.13
0.13
0.00
10.19
27.80
0.00
0.00
19.88
167.25
2.19
4.69
8.94
1.99
3.97
93.83
19.88
167.25
2.19
93.83
178.72
1.99
3.97
93.83
263.62
561.79
209.03
561.79
561.79
561.79
0.00
169.79
0.00
0.00
89.14
169.79
0.00
0.00
93.83
0.00
0.00
0.00
89.14
169.79
0.00
0.00
93.83
352.75
352.75
352.75
41
Mass Fraction
Mole Fraction
0.57
0.00
0.06
0.02
0.35
1.00
0.85
0.00
0.05
0.00
0.09
1.00
23
82.01
1
1.00
24
173.13
1.5
0.00
25
150.06
1
0.00
26
150.93
6.8
0.00
27
55
6.8
0.00
0.00
10.19
7.67
0.00
7.67
0.00
7.67
0.00
7.67
0.00
9.95
0.00
0.00
0.00
0.00
20.13
7.67
7.67
7.67
7.67
27.80
7.67
7.67
0.00
169.79
89.14
0.00
89.14
0.00
89.14
0.00
89.14
0.00
93.83
0.00
0.00
0.00
0.00
263.62
89.14
89.14
89.14
89.14
352.75
89.14
89.14
28
55
6.8
0.00
29
55
6.8
0.00
4.28
0.00
4.28
0.00
30
359.64
1.5
0.00
31
55
6.8
0.00
32
55
6.8
0.00
0.01
0.01
1.61
0.85
0.00
0.85
0.00
0.85
0.00
0.00
0.01
8.69
0.04
9.60
0.00
0.01
8.74
0.04
9.64
0.00
1.43
8.74
8.95
21.59
21.59
21.59
133.71
0.00
133.71
0.00
0.45
0.45
89.54
9.85
0.00
9.85
0.00
9.90
0.00
0.00
0.22
88.69
0.45
99.66
0.00
0.22
89.14
0.45
100.11
0.00
44.84
89.14
89.54
322.95
322.95
322.95
C-104 & V-103

C-103 & C-104 & V-103
33
54.82
1
0.00
34
66.63
1
0.65
35
75
1.5
0.18
36
50
1
1.00
37
67.41
1
0.84
1.61
1.56
1.56
0.04
1.19
0.85
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
1.43
8.74
8.95
21.59
0.00
1.10
0.04
6.86
9.57
0.00
1.10
0.04
6.86
9.57
0.33
0.00
2.04
2.41
1.38
0.00
2.08
4.65
21.59
19.17
**not considered
89.54
86.82
86.82
2.27
66.04
9.90
0.00
0.05
0.00
0.05
0.00
0.00
0.00
0.00
0.00
0.00
44.84
89.14
89.54
322.95
0.00
34.38
0.43
68.64
190.32
0.00
34.38
0.43
68.64
190.32
0.00
10.24
0.01
20.45
32.97
0.00
43.27
0.01
20.78
130.10
322.95
289.98
223.29
322.95
223.29
322.95
0.00
0.00
89.09
44.62
0.45
89.09
89.09
44.62
0.45
89.09
0.00
0.00
0.00
0.00
0.00
**not considered
38
99.24
1
0.00
39
75.57
1
0.00
40
50
1
0.00
41
50
1
0.00
0.05
0.41
0.41
0.37
0.00
0.00
0.00
0.00
0.01
0.03
6.60
6.69
0.36
0.01
2.27
3.06
0.36
0.01
2.27
3.06
0.04
0.01
0.23
0.64
2.60
22.72
22.72
20.45
0.04
0.00
0.01
0.00
0.01
0.00
0.01
0.00
0.00
0.21
0.33
66.04
69.22
0.00
11.38
0.11
22.72
56.94
0.00
11.38
0.11
22.72
56.94
0.00
1.14
0.10
2.27
23.97
Basis of calculation (ton/hr)

2
4
6
8
10
12
Targeted plant capacity (kTA)
Feed required
Conversion of Oxidation of Isobutylene

0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
1
Conversion of Oxidation of Methacrolein, MAL
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
1
Conversion of Esterification of Methacrylic Acid with MeOH

0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
1
Plant capacity (kTA)

13.9285
27.8571
41.7856
55.7141
69.6426
83.5712
50
7.15
Mass Flow Rate of MMA (ton/hr)

0.6653
1.3306
1.9959
2.6612
3.3266
3.9919
4.6572
5.3225
5.9878
6.6531
3.4569
4.7306
5.3930
5.7990
6.0734
6.2711
6.4205
6.5373
6.6310
6.7080

6.3064
6.4610
6.5142
6.5412
6.5574
6.5683
6.5761
6.5820
6.5866
6.5902
Feed vs Plant Capacit

20
10
Feed (ton/hr)
0
10.0000
f(x) = 0.1435902062x - 1.45038928587789E-015

R = 1
20.0000
30.0000
40.0000
50.0000
Plant Capacity (kTA)
Components
Flow Rate (ton/hr)
Flow Rate (ton/yr)
7.15
14.30
0.35
0.00
4.28
0.00
54054
108108
2682.4176798452
0
32346.3806620267
0
6.60
49925.5205272984
Total Reactants Price

(RM/yr)
279533304.465012
279533304.465012
279533304.465012
279533304.465012
279533304.465012
279533304.465012
279533304.465012
279533304.465012
279533304.465012
279533304.465012
Mass Flow Rate of

MMA (ton/hr)
0.6653
1.3306
1.9959
2.6612
3.3266
3.9919
4.6572
5.3225
5.9878
6.6531
Conversion of Oxidation of Methacrolein, Total Reactants Price

MAL
(RM/yr)
Mass Flow Rate of

MMA (ton/hr)
Reactants
Isobutylene (C4H8)
O2
H2O
Xylene
MeOH
H2SO4
Product
MMA (C5H8O2)
Conversion of Oxidation of Isobutylene

0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
1
0.1
0.2
0.3
279533304.465012
279533304.465012
279533304.465012
3.4569
4.7306
5.3930
0.4
0.5
0.6
0.7
0.8
0.9
1
279533304.465012
279533304.465012
279533304.465012
279533304.465012
279533304.465012
279533304.465012
279533304.465012
5.7990
6.0734
6.2711
6.4205
6.5373
6.6310
6.7080
Conversion of Esterification of
Methacrylic Acid with MeOH
Total Reactants Price

(RM/yr)
Mass Flow Rate of

MMA (ton/hr)
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
1
279533304.465012
279533304.465012
279533304.465012
279533304.465012
279533304.465012
279533304.465012
279533304.465012
279533304.465012
279533304.465012
279533304.465012
6.3064
6.4610
6.5142
6.5412
6.5574
6.5683
6.5761
6.5820
6.5866
6.5902
eed vs Plant Capacity
89E-015
40.0000
50.0000
60.0000
70.0000
80.0000
90.0000
Plant Capacity (kTA)
Price (RM/ton)
Price (RM/yr)
Total Price (RM/yr)
2300
1149.05
0.76
3277.66
957.93
159.03
124324200
124221497.4
2038.6374366824
0
30985568.4275753
0
279533304.465012
9760
487273080.346433
487273080.346433
Price of MMA
(RM/yr)
49090318.0179
98180636.0358
147270954.0536
196361272.0715
245451590.0894
294541908.1073
343632226.1252
392722544.1430
441812862.1609
490903180.1788
Economic potential
(RM/yr)
-230442986.4471
-181352668.4293
-132262350.4114
-83172032.3935
-34081714.3756
15008603.6423
64098921.6602
113189239.6780
162279557.6959
211369875.7138
Mass Flow Rate of

MMA (ton/hr)
Economic potential
(RM/yr)
255066453.0950
349052505.0994
397928274.6061
-24466851.3700
69519200.6344
118394970.1411
300000000.0000
200000000.0000
100000000.0000
Economic potential (RM/yr)
0.0000
-100000000.0000
0.2
-200000000.0000
-300000000.0000
Con
300000000.0000
250000000.0000
200000000.0000
150000000.0000
100000000.0000
50000000.0000
0.0000
-50000000.0000 0
-100000000.0000
0.2
200000000.0000
150000000.0000
427885413.6425
448127163.6314
462720273.1981
473739682.1790
482354929.6927
489275420.9543
494956452.2309
148352109.1774
168593859.1664
183186968.7331
194206377.7140
202821625.2277
209742116.4893
215423147.7659
Mass Flow Rate of

MMA (ton/hr)
Economic potential
(RM/yr)
465324076.1492
476729907.2886
480656775.4608
482644609.3413
483845067.9301
484648718.8521
485224390.2888
485657080.9727
485994156.0086
486264148.9715
185790771.6842
197196602.8236
201123470.9957
203111304.8763
204311763.4651
205115414.3871
205691085.8238
206123776.5077
206460851.5436
206730844.5065
100000000.0000
50000000.0000
0.0000
-50000000.0000 0
0.2
-100000000.0000
Con
300000000.0000
250000000.0000
200000000.0000
150000000.0000
100000000.0000
50000000.0000
0.0000
0
0.2
Con
r)
r)
90.0000
300000000.0000
200000000.0000
100000000.0000
0.0000
-100000000.0000
0.2
0.4
0.6
0.8
1.2
0.6
0.8
1.2
-200000000.0000
-300000000.0000
Conversion
300000000.0000
250000000.0000
200000000.0000
150000000.0000
100000000.0000
50000000.0000
0.0000
-50000000.0000 0
-100000000.0000
0.2
0.4
r)
r)
200000000.0000
150000000.0000
100000000.0000
50000000.0000
0.0000
-50000000.0000 0
0.2
0.4
0.6
0.8
1.2
0.6
0.8
1.2
-100000000.0000
Conversion
300000000.0000
250000000.0000
200000000.0000
150000000.0000
100000000.0000
50000000.0000
0.0000
0
0.2
0.4
Conversion
Stream 1
Temperature (C)
Pressure (bar)
Vapor Fraction
Component
Isobutylene (C4H8)
Total
30.00
1.00
1.00
Mass Flow Rate (ton/hr)
7.15
7.15
Stream 2
Temperature (C)
Pressure (bar)
Vapor Fraction
Component
O2
Total
30.00
1.00
1.00
14.30
14.30
Stream 3
Temperature (C)
Pressure (bar)
Vapor Fraction
Component
Isobutylene (C4H8)
O2
H2O
MAL (C4H6O)
Total
395.00
1.00
1.00
0.07
10.26
2.28
8.85
21.45
Stream 4
Temperature (C)
Pressure (bar)
Vapor Fraction
Component
Isobutylene (C4H8)
O2
H2O
MAL (C4H6O)
Total
561.28
3.70
1.00
0.07
10.26
2.28
8.85
21.45
Stream 5
Temperature (C)
Pressure (bar)
Vapor Fraction
Component
Isobutylene (C4H8)
350.00
3.70
1.00
0.07
O2
H2O
MAL (C4H6O)
Total
10.26
2.28
8.85
21.45
Stream 6
Temperature (C)
Pressure (bar)
Vapor Fraction
Component
H2O
MAL (C4H6O)
Total
350.00
3.70
1.00
0.35
1.37
1.73
Stream 7
Temperature (C)
Pressure (bar)
Vapor Fraction
Component
Isobutylene (C4H8)
O2
H2O
MAL (C4H6O)
Total
350.00
3.70
1.00
0.07
10.26
2.63
10.22
23.18
Stream 8
Temperature (C)
Pressure (bar)
Vapor Fraction
Component
Isobutylene (C4H8)
O2
H2O
MAL (C4H6O)
MAA (C4H6O2)
AA (C2H4O2)
CO
CO2
Total
350.00
3.70
1.00
0.07
6.36
3.34
1.53
8.97
0.60
0.56
1.75
23.18
Stream 9
Temperature (C)
Pressure (bar)
Vapor Fraction
Component
85.00
1.00
0.48
Isobutylene (C4H8)
O2
H2O
MAL (C4H6O)
MAA (C4H6O2)
AA (C2H4O2)
CO
CO2
Total
0.07
6.36
3.34
1.53
8.97
0.60
0.56
1.75
23.18
Stream 10
Temperature (C)
Pressure (bar)
Vapor Fraction
Component
Isobutylene (C4H8)
O2
H2O
MAL (C4H6O)
MAA (C4H6O2)
AA (C2H4O2)
CO
CO2
Total
60.00
1.00
0.09
0.01
0.64
3.01
0.15
8.07
0.54
0.06
0.17
12.64
Stream 11
Temperature (C)
Pressure (bar)
Vapor Fraction
Component
Isobutylene (C4H8)
O2
H2O
MAL (C4H6O)
MAA (C4H6O2)
AA (C2H4O2)
CO
CO2
Total
60.00
1.00
0.89
0.06
5.73
0.33
1.38
0.90
0.06
0.50
1.57
10.53
Stream 12
Temperature (C)
Pressure (bar)
Vapor Fraction
Component
4.00
1.00
0.00
H2O
Total
0.35
0.35
Stream 13
Temperature (C)
Pressure (bar)
Vapor Fraction
Component
H2O
MAL (C4H6O)
Total
56.77
1.00
0.00
0.35
1.37
1.73
Stream 14
Temperature (C)
Pressure (bar)
Vapor Fraction
Component
Isobutylene (C4H8)
O2
H2O
MAL (C4H6O)
MAA (C4H6O2)
AA (C2H4O2)
CO
CO2
Total
51.57
1.00
0.89
0.06
5.73
0.33
0.01
0.90
0.06
0.50
1.57
9.16
Stream 15
Temperature (C)
Pressure (bar)
Vapor Fraction
Component
Isobutylene (C4H8)
O2
H2O
MAL (C4H6O)
MAA (C4H6O2)
AA (C2H4O2)
CO
CO2
Total
40.00
1.00
0.09
0.01
0.64
3.01
0.15
8.07
0.54
0.06
0.17
12.64
Stream 16
Temperature (C)
Pressure (bar)
40.00
1.00
Vapor Fraction
Component
Xylene
Total
0.00
0.00
0.00
Stream 17
Temperature (C)
Pressure (bar)
Vapor Fraction
Component
MAA (C4H6O2)
AA (C2H4O2)
Xylene
Total
74.92
1.00
1.00
0.00
10.19
9.95
20.13
Stream 18
Temperature (C)
Pressure (bar)
Vapor Fraction
Component
MAA (C4H6O2)
AA (C2H4O2)
Xylene
Total
40.00
1.00
0.00
0.00
10.19
9.95
20.13
Stream 19
Temperature (C)
Pressure (bar)
Vapor Fraction
Component
Isobutylene (C4H8)
O2
H2O
MAL (C4H6O)
MAA (C4H6O2)
AA (C2H4O2)
CO
CO2
Xylene
Total
63.42
1.00
0.05
0.01
0.64
3.01
0.15
8.07
10.72
0.06
0.17
9.95
32.78
Stream 20
Temperature (C)
Pressure (bar)
Vapor Fraction
45.00
1.00
0.12
Component
Isobutylene (C4H8)
O2
H2O
MAL (C4H6O)
MAA (C4H6O2)
AA (C2H4O2)
CO
CO2
Total

0.01
0.64
3.01
0.15
0.40
0.54
0.06
0.17
4.98
Stream 21
Temperature (C)
Pressure (bar)
Vapor Fraction
Component
Isobutylene (C4H8)
O2
MAL (C4H6O)
MAA (C4H6O2)
AA (C2H4O2)
CO
CO2
Xylene
Total
45.00
1.00
0.00
0.00
0.00
0.00
7.67
10.19
0.00
0.00
9.95
27.80
Stream 22
Temperature (C)
Pressure (bar)
Vapor Fraction
Component
Isobutylene (C4H8)
O2
MAL (C4H6O)
MAA (C4H6O2)
AA (C2H4O2)
CO
CO2
Xylene
Total
45.18
3.00
0.00
0.00
0.00
0.00
7.67
10.19
0.00
0.00
9.95
27.80
Stream 23
Temperature (C)
Pressure (bar)
Vapor Fraction
82.01
1.00
1.00
Component
MAA (C4H6O2)
AA (C2H4O2)
Xylene
Total

0.00
10.19
9.95
20.13
Stream 24
Temperature (C)
Pressure (bar)
Vapor Fraction
Component
MAA (C4H6O2)
AA (C2H4O2)
Xylene
Total
173.13
1.50
0.00
7.67
0.00
0.00
7.67
Stream 25
Temperature (C)
Pressure (bar)
Vapor Fraction
Component
MAA (C4H6O2)
AA (C2H4O2)
Xylene
Total
150.06
1.00
0.00
7.67
0.00
0.00
7.67
Stream 26
Temperature (C)
Pressure (bar)
Vapor Fraction
Component
MAA (C4H6O2)
AA (C2H4O2)
Xylene
Total
150.93
6.80
0.00
7.67
0.00
0.00
7.67
Stream 27
Temperature (C)
Pressure (bar)
Vapor Fraction
Component
MAA (C4H6O2)
AA (C2H4O2)
Xylene
Total
55.00
6.80
0.00
7.67
0.00
0.00
7.67
Stream 28
Temperature (C)
Pressure (bar)
Vapor Fraction
Component
MeOH
Total
55.00
6.80
0.00
4.28
4.28
Stream 29
Temperature (C)
Pressure (bar)
Vapor Fraction
Component
H2SO4
Total
55.00
6.80
0.00
0.00
0.00
Stream 30
Temperature (C)
Pressure (bar)
Vapor Fraction
Component
H2O
MAA (C4H6O2)
AA (C2H4O2)
Xylene
MeOH
H2SO4
MMA (C5H8O2)
Total
359.64
1.50
0.00
0.01
0.85
0.00
0.00
0.01
8.69
0.04
9.60
Stream 31
Temperature (C)
Pressure (bar)
Vapor Fraction
Component
H2O
MAA (C4H6O2)
AA (C2H4O2)
Xylene
MeOH
H2SO4
MMA (C5H8O2)
Total
55.00
6.80
0.00
0.01
0.85
0.00
0.00
0.01
8.74
0.04
9.64
Stream 32
Temperature (C)
Pressure (bar)
Vapor Fraction
Component
H2O
MAA (C4H6O2)
AA (C2H4O2)
Xylene
MeOH
H2SO4
MMA (C5H8O2)
Total
55.00
6.80
0.00
1.61
0.85
0.00
0.00
1.43
8.74
8.95
21.59
Stream 33
Temperature (C)
Pressure (bar)
Vapor Fraction
Component
H2O
MAA (C4H6O2)
AA (C2H4O2)
Xylene
MeOH
H2SO4
MMA (C5H8O2)
Total
54.82
1.00
0.00
1.61
0.85
0.00
0.00
1.43
8.74
8.95
21.59
Stream 34
Temperature (C)
Pressure (bar)
Vapor Fraction
Component
H2O
MAA (C4H6O2)
AA (C2H4O2)
Xylene
MeOH
H2SO4
MMA (C5H8O2)
Total
66.63
1.00
0.65
1.56
0.00
0.00
0.00
1.10
0.04
6.86
9.57
Stream 35
Temperature (C)
Pressure (bar)
75.00
1.50
Vapor Fraction
Component
H2O
MAA (C4H6O2)
AA (C2H4O2)
Xylene
MeOH
H2SO4
MMA (C5H8O2)
Total
0.18
1.56
0.00
0.00
0.00
1.10
0.04
6.86
9.57
Stream 36
Temperature (C)
Pressure (bar)
Vapor Fraction
Component
H2O
MAA (C4H6O2)
MeOH
H2SO4
MMA (C5H8O2)
Total
50.00
1.00
1.00
0.04
0.00
0.33
0.00
2.04
2.41
Stream 37
Temperature (C)
Pressure (bar)
Vapor Fraction
Component
H2O
MAA (C4H6O2)
MeOH
H2SO4
MMA (C5H8O2)
Total
67.41
1.00
0.84
1.19
0.00
1.38
0.00
2.08
4.65
Stream 38
Temperature (C)
Pressure (bar)
Vapor Fraction
Component
H2O
MAA (C4H6O2)
MeOH
H2SO4
MMA (C5H8O2)
99.24
1.00
0.00
0.05
0.00
0.01
0.03
6.60
Total
6.69
Stream 39
Temperature (C)
Pressure (bar)
Vapor Fraction
Component
H2O
MAA (C4H6O2)
MeOH
H2SO4
MMA (C5H8O2)
Total
75.57
1.00
0.00
0.41
0.00
0.36
0.01
2.27
3.06
Stream 40
Temperature (C)
Pressure (bar)
Vapor Fraction
Component
H2O
MAA (C4H6O2)
MeOH
H2SO4
MMA (C5H8O2)
Total
50.00
1.00
0.00
0.41
0.00
0.36
0.01
2.27
3.06
Stream 41
Temperature (C)
Pressure (bar)
Vapor Fraction
Component
H2O
MAA (C4H6O2)
MeOH
H2SO4
MMA (C5H8O2)
Total
50.00
1.00
0.00
0.37
0.00
0.04
0.01
0.23
0.64
Mole Flow Rate (kmol/hr)

127.68
127.68
Mass Fraction
1.00
1.00

446.88
446.88
Mass Fraction
1.00
1.00

1.28
320.47
126.40
126.40
574.55
Mass Fraction
0.00
0.48
0.11
0.41
1.00

1.28
320.47
126.40
126.40
574.55
Mass Fraction
0.00
0.48
0.11
0.41
1.00

1.28
Mass Fraction
0.00
320.47
126.40
126.40
574.55
0.48
0.11
0.41
1.00

19.71
19.61
39.33
Mass Fraction
0.21
0.79
1.00

1.28
320.47
146.11
146.02
613.88
Mass Fraction
0.00
0.44
0.11
0.44
1.00

1.28
198.84
185.83
21.90
104.25
9.93
19.86
39.72
581.61
Mass Fraction
0.00
0.27
0.14
0.07
0.39
0.03
0.02
0.08
1.00
Mass Fraction
1.28
198.84
185.83
21.90
104.25
9.93
19.86
39.72
581.61
0.00
0.27
0.14
0.07
0.39
0.03
0.02
0.08
1.00

0.13
19.88
167.25
2.19
93.83
8.94
1.99
3.97
298.17
Mass Fraction
0.00
0.05
0.24
0.01
0.64
0.04
0.00
0.01
1.00

1.15
178.96
18.58
19.71
10.43
0.99
17.87
35.74
283.44
Mass Fraction
0.01
0.54
0.03
0.13
0.09
0.01
0.05
0.15
1.00
Mass Fraction
19.71
19.71
1.00
1.00

19.71
19.61
39.33
Mass Fraction
0.21
0.79
1.00

1.15
178.96
18.58
0.10
10.43
0.99
17.87
35.74
263.82
Mass Fraction
0.01
0.63
0.04
0.00
0.10
0.01
0.05
0.17
1.00

0.13
19.88
167.25
2.19
93.83
8.94
1.99
3.97
298.17
Mass Fraction
0.00
0.05
0.24
0.01
0.64
0.04
0.00
0.01
1.00

0.00
0.00
Mass Fraction
#DIV/0!
#DIV/0!

0.00
169.79
93.83
263.62
Mass Fraction
0.00
0.51
0.49
1.00

0.00
169.79
93.83
263.62
Mass Fraction
0.00
0.51
0.49
1.00

0.13
19.88
167.25
2.19
93.83
178.72
1.99
3.97
93.83
561.79
Mass Fraction
0.00
0.02
0.09
0.00
0.25
0.33
0.00
0.01
0.30
1.00

0.13
19.88
167.25
2.19
4.69
8.94
1.99
3.97
209.03
Mass Fraction
0.00
0.13
0.60
0.03
0.08
0.11
0.01
0.04
1.00

0.00
0.00
0.00
89.14
169.79
0.00
0.00
93.83
352.75
Mass Fraction
0.00
0.00
0.00
0.28
0.37
0.00
0.00
0.36
1.00

0.00
0.00
0.00
89.14
169.79
0.00
0.00
93.83
352.75
Mass Fraction
0.00
0.00
0.00
0.28
0.37
0.00
0.00
0.36
1.00

0.00
169.79
93.83
263.62
Mass Fraction
0.00
0.51
0.49
1.00

89.14
0.00
0.00
89.14
Mass Fraction
1.00
0.00
0.00
1.00

89.14
0.00
0.00
89.14
Mass Fraction
1.00
0.00
0.00
1.00

89.14
0.00
0.00
89.14
Mass Fraction
1.00
0.00
0.00
1.00

89.14
0.00
0.00
89.14
Mass Fraction
1.00
0.00
0.00
1.00

133.71
133.71
Mass Fraction
1.00
1.00

0.00
0.00
Mass Fraction
#DIV/0!
#DIV/0!

0.45
9.85
0.00
0.00
0.22
88.69
0.45
99.66
Mass Fraction
0.00
0.09
0.00
0.00
0.00
0.91
0.00
1.00

0.45
9.85
0.00
0.00
0.22
89.14
0.45
100.11
Mass Fraction
0.00
0.09
0.00
0.00
0.00
0.91
0.00
1.00

89.54
9.90
0.00
0.00
44.84
89.14
89.54
322.95
Mass Fraction
0.07
0.04
0.00
0.00
0.07
0.40
0.41
1.00

89.54
9.90
0.00
0.00
44.84
89.14
89.54
322.95
Mass Fraction
0.07
0.04
0.00
0.00
0.07
0.40
0.41
1.00

86.82
0.05
0.00
0.00
34.38
0.43
68.64
190.32
Mass Fraction
0.16
0.00
0.00
0.00
0.11
0.00
0.72
1.00

86.82
0.05
0.00
0.00
34.38
0.43
68.64
190.32
Mass Fraction
0.16
0.00
0.00
0.00
0.11
0.00
0.72
1.00

2.27
0.00
10.24
0.01
20.45
32.97
Mass Fraction
0.02
0.00
0.14
0.00
0.85
1.00

66.04
0.00
43.27
0.01
20.78
130.10
Mass Fraction
0.26
0.00
0.30
0.00
0.45
1.00

2.60
0.04
0.21
0.33
66.04
Mass Fraction
0.01
0.00
0.00
0.00
0.99
69.22
1.00

22.72
0.01
11.38
0.11
22.72
56.94
Mass Fraction
0.13
0.00
0.12
0.00
0.74
1.00

22.72
0.01
11.38
0.11
22.72
56.94
Mass Fraction
0.13
0.00
0.12
0.00
0.74
1.00

20.45
0.01
1.14
0.10
2.27
23.97
Mass Fraction
0.57
0.00
0.06
0.02
0.35
1.00
Mole Fraction
1.00
1.00
Mole Fraction
1.00
1.00
Mole Fraction
0.00
0.56
0.22
0.22
1.00
Mole Fraction
0.00
0.56
0.22
0.22
1.00
Mole Fraction
0.00
0.56
0.22
0.22
1.00
Mole Fraction
0.50
0.50
1.00
Mole Fraction
0.00
0.52
0.24
0.24
1.00
Mole Fraction
0.00
0.34
0.32
0.04
0.18
0.02
0.03
0.07
1.00
Mole Fraction
0.00
0.34
0.32
0.04
0.18
0.02
0.03
0.07
1.00
Mole Fraction
0.00
0.07
0.56
0.01
0.31
0.03
0.01
0.01
1.00
Mole Fraction
0.00
0.63
0.07
0.07
0.04
0.00
0.06
0.13
1.00
Mole Fraction
1.00
1.00
Mole Fraction
0.50
0.50
1.00
Mole Fraction
0.00
0.68
0.07
0.00
0.04
0.00
0.07
0.14
1.00
Mole Fraction
0.00
0.07
0.56
0.01
0.31
0.03
0.01
0.01
1.00
Mole Fraction
#DIV/0!
#DIV/0!
Mole Fraction
0.00
0.64
0.36
1.00
Mole Fraction
0.00
0.64
0.36
1.00
Mole Fraction
0.00
0.04
0.30
0.00
0.17
0.32
0.00
0.01
0.17
1.00
Mole Fraction
0.00
0.10
0.80
0.01
0.02
0.04
0.01
0.02
1.00
Mole Fraction
0.00
0.00
0.00
0.25
0.48
0.00
0.00
0.27
1.00
Mole Fraction
0.00
0.00
0.00
0.25
0.48
0.00
0.00
0.27
1.00
Mole Fraction
0.00
0.64
0.36
1.00
Mole Fraction
1.00
0.00
0.00
1.00
Mole Fraction
1.00
0.00
0.00
1.00
Mole Fraction
1.00
0.00
0.00
1.00
Mole Fraction
1.00
0.00
0.00
1.00
Mole Fraction
1.00
1.00
Mole Fraction
#DIV/0!
#DIV/0!
Mole Fraction
0.00
0.10
0.00
0.00
0.00
0.89
0.00
1.00
Mole Fraction
0.00
0.10
0.00
0.00
0.00
0.89
0.00
1.00
Mole Fraction
0.28
0.03
0.00
0.00
0.14
0.28
0.28
1.00
Mole Fraction
0.28
0.03
0.00
0.00
0.14
0.28
0.28
1.00
Mole Fraction
0.46
0.00
0.00
0.00
0.18
0.00
0.36
1.00
Mole Fraction
0.46
0.00
0.00
0.00
0.18
0.00
0.36
1.00
Mole Fraction
0.07
0.00
0.31
0.00
0.62
1.00
Mole Fraction
0.51
0.00
0.33
0.00
0.16
1.00
Mole Fraction
0.04
0.00
0.00
0.00
0.95
1.00
Mole Fraction
0.40
0.00
0.20
0.00
0.40
1.00
Mole Fraction
0.40
0.00
0.20
0.00
0.40
1.00
Mole Fraction
0.85
0.00
0.05
0.00
0.09
1.00
Components
Isobutylene (C4H8)
O2
H2O
MAL (C4H6O)
MAA (C4H6O2)
AA (C2H4O2)
CO
CO2
Xylene
MeOH
H2SO4
MMA (C5H8O2)
State
Gas
Gas
Liquid
Gas
Gas
Liquid
Liquid
Gas
Gas
Gas
Liquid
Liquid
Gas
Liquid
Liquid
T in K
Energy Balance
input
phase change
recycle stream
Reference T
Stream ID
Temperature
Pressure
Vapor Fraction
25
deg C
K
bar
Mole Flow
Isobutylene (C4H8)
O2
H2O
MAL (C4H6O)
MAA (C4H6O2)
AA (C2H4O2)
CO
CO2
Xylene
MeOH
H2SO4
MMA (C5H8O2)
Total Mole Flow
kmol/hr
Specific Enthalpy
Isobutylene (C4H8)
O2
H2O
MAL (C4H6O)
MAA (C4H6O2)
AA (C2H4O2)
CO
CO2
Xylene
MeOH
H2SO4
MMA (C5H8O2)
Total Specific Enthalpy
MJ/kmol
Energy Flow
Isobutylene (C4H8)
O2
H2O
MAL (C4H6O)
MAA (C4H6O2)
AA (C2H4O2)
CO
CO2
Xylene
MeOH
H2SO4
MMA (C5H8O2)
Total Energy Flow
Energy Balance of Each Unit
MJ/hr
R-101 PBR
Inlet
Stream
Temperature (oC)
Pressure (bar)
Mass Balance
Molar Flow Rate (kmol/hr)
Enthalpy (MJ/kmol)
Energy Flow (MJ/hr)
Total Energy Flow (MJ/hr)
Heat Duty (MJ/hr)
Power Requirement (kW)
1
30.00
1.00
7.15
21.45
127.68
1.62
206.71
272.43
-34901.12
-
E-101 Compressor
Stream
Temperature (oC)
Pressure (bar)
Mass Balance
Enthalpy (MJ/kmol)
Energy Flow (MJ/hr)
Heat Duty (MJ/hr)
Inlet
3
395.00
1.00
21.45
21.45
574.55
-243.66
-34628.68
-34628.68
4590.03
1275.01
E-102 Heat exchanger

Stream
Temperature (oC)
Pressure (bar)
Mass Balance
Enthalpy (MJ/kmol)
Energy Flow (MJ/hr)
Heat Duty (MJ/hr)
Inlet
4
561.28
3.70
21.45
21.45
574.55
-187.68
-30038.65
-30038.65
-5813.80
-
R-102 PBR
Stream
Temperature (oC)
Pressure (bar)
Inlet
7
350.00
3.70
23.18
Mass Balance
Enthalpy (MJ/kmol)
Energy Flow (MJ/hr)
Heat Duty (MJ/hr)
23.18
613.88
-258.08
-41947.84
-41947.84
-53492.54
-
E-103 Condenser
Inlet
Stream
Temperature (oC)
Pressure (bar)
Mass Balance
Enthalpy (MJ/kmol)
Energy Flow (MJ/hr)
Heat Duty (MJ/hr)
8
350.00
3.70
23.18
23.18
581.61
-1467.23
-95440.38
-95440.38
-18529.14
1.67
V-101 Flash drum

Stream
Temperature (oC)
Pressure (bar)
Mass Balance
Enthalpy (MJ/kmol)
Energy Flow (MJ/hr)
Heat Duty (MJ/hr)
Inlet
9
85.00
1.00
23.18
23.18
581.61
-1713.14
-113969.52
-113969.52
-1080.02
-
C-101 Absorber
Inlet
Stream
Temperature (oC)
Pressure (bar)
Mass Balance
Enthalpy (MJ/kmol)
Energy Flow (MJ/hr)
11
60.00
1.00
10.53
10.89
283.44
-1729.90
-27400.40
-33066.11
Heat Duty (MJ/hr)

-16.80
-

Stream
Temperature (oC)
Pressure (bar)
Mass Balance
Enthalpy (MJ/kmol)
Energy Flow (MJ/hr)
Heat Duty (MJ/hr)
Inlet
13
56.77
1.00
1.73
1.73
39.33
-390.16
-7680.35
-7680.35
1584.97
-

Stream
Temperature (oC)
Pressure (bar)
Mass Balance
Enthalpy (MJ/kmol)
Energy Flow (MJ/hr)
Heat Duty (MJ/hr)
Inlet
10
60.00
1.00
12.64
12.64
298.17
-1729.90
-87649.14
-87649.14
-604.43
-
M-101 Mixer
Inlet
Stream
Temperature (oC)
Pressure (bar)
Mass Balance
Enthalpy (MJ/kmol)
Energy Flow (MJ/hr)
Heat Duty (MJ/hr)
15
40.00
1.00
12.64
32.78
298.17
-1742.96
-88253.58
-172612.94
1635.75
0.10
V-102 Extractor
Stream
Inlet
19
Temperature (oC)
Pressure (bar)
Mass Balance
Enthalpy (MJ/kmol)
Energy Flow (MJ/hr)
Heat Duty (MJ/hr)
63.42
1.00
32.78
32.78
561.79
-1745.79
-170977.19
-170977.19
-1290.92
-
P-101 Pump
Stream
Temperature (oC)
Pressure (bar)
Mass Balance
Enthalpy (MJ/kmol)
Energy Flow (MJ/hr)
Heat Duty (MJ/hr)
Inlet
21
45.00
1.00
27.80
27.80
352.75
-1477.09
-116678.43
-116678.43
0.00
0.53
C-102 Distillation column

Stream
Temperature (oC)
Pressure (bar)
Mass Balance
Enthalpy (MJ/kmol)
Energy Flow (MJ/hr)
Heat Duty (MJ/hr)
Inlet
22
45.18
3.00
27.80
27.80
352.75
-1761.27
-116668.76
-116668.76
3509.12
-
E-106 Condenser
Stream
Temperature (oC)
Pressure (bar)
Mass Balance
Enthalpy (MJ/kmol)
Inlet
23
82.01
1.00
20.13
20.13
263.62
-851.91
Energy Flow (MJ/hr)

Heat Duty (MJ/hr)
-82664.45
-82664.45
-296.31
-
T-101 Storage
Stream
Temperature (oC)
Pressure (bar)
Mass Balance
Enthalpy (MJ/kmol)
Energy Flow (MJ/hr)
Heat Duty (MJ/hr)
Inlet
24
173.13
1.50
7.67
7.67
89.14
-801.35
-30495.19
-30495.19
-387.71
-
P-102 Pump
Stream
Temperature (oC)
Pressure (bar)
Mass Balance
Enthalpy (MJ/kmol)
Energy Flow (MJ/hr)
Heat Duty (MJ/hr)
Inlet
25
150.06
1.00
7.67
7.67
89.14
-815.00
-30882.90
-30882.90
0.00
1.21

Stream
Temperature (oC)
Pressure (bar)
Mass Balance
Enthalpy (MJ/kmol)
Energy Flow (MJ/hr)
Heat Duty (MJ/hr)
R-103 CSTR
Inlet
26
150.93
6.80
7.67
7.67
89.14
-814.49
-30868.49
-30868.49
-1498.14
-
Inlet
Stream
Temperature (oC)
Pressure (bar)
Mass Balance
Enthalpy (MJ/kmol)
Energy Flow (MJ/hr)
Heat Duty (MJ/hr)
27
55.00
6.80
7.67
21.59
89.14
-865.35
-32366.63
-139783.29
-3421.64
0.27
E-108 Throttle
Stream
Temperature (oC)
Pressure (bar)
Mass Balance
Enthalpy (MJ/kmol)
Energy Flow (MJ/hr)
Heat Duty (MJ/hr)
Inlet
32
55.00
6.80
21.59
21.59
322.95
-2546.07
-143204.93
-143204.93
-7.90
2.19

Stream
Temperature (oC)
Pressure (bar)
Mass Balance
Enthalpy (MJ/kmol)
Energy Flow (MJ/hr)
Heat Duty (MJ/hr)
Inlet
34
66.63
1.00
9.57
9.57
190.32
-2493.55
-53510.99
-53510.99
-3475.86
-

Stream
Temperature (oC)
Pressure (bar)
Mass Balance
Inlet
39
70.00
1.00
3.06
3.06

Enthalpy (MJ/kmol)
Energy Flow (MJ/hr)
Heat Duty (MJ/hr)
56.94
-2532.50
-17174.36
-17174.36
-130.82
-
C-103 & C-104 & V-103 two distillation boundary

Stream
Temperature (oC)
Pressure (bar)
Mass Balance
Enthalpy (MJ/kmol)
Energy Flow (MJ/hr)
Heat Duty (MJ/hr)
Inlet
33
54.82
1.00
21.59
21.59
322.95
-2546.25
-143212.83
-143212.83
Hf, kJ/mol at 25
1.17
0
-285.84
-241.83
-109.7
-368
-486.18
-438.15
-110.52
-393.5
-25.42
-238.6
-201.2
-811.32
-360
Cp=a+bT+cT2+dT3 , kJ/mol.C at 25
a
0.08288
0.0291
0.0754
0.03346
0.09392
0.14629
0.13664
b
2.56E-04
0.00001158
0.00000688
-5.86E-05
-3.21E-04
0.02895
0.03611
1.34E-01
0.07586
0.04293
0.1391
0.2551
oC
4.11E-06
0.00004233
7.88E-06
0.0001683
0.00008301
1.56E-04
-9.38E-04
298.15 K
1
30
303.15
1
1.00
2
30
303.15
1
1.00
3
395
668.15
1
1.00
127.68
446.88
127.68
446.88
1.62
0.15
1.62
0.15
206.71
65.72
206.71
65.72
1.28
320.47
126.40
126.40
574.55
48.52
11.55
-228.78
-74.95
-243.66
61.95
3701.45
-28918.32
-9473.76
-34628.68
Inlet
Outlet
3
395.00
1.00
21.45
21.45
574.55
-243.66
-34628.68
-34628.68
2
30.00
1.00
14.30
21.45
446.88
0.15
65.72
272.43
Cooling
-
Outlet
4
561.28
3.70
21.45
21.45
574.55
-187.68
-30038.65
-30038.65
4590.03
P1(bar)
Po(bar)
Ti (oC)
To(oC)
Ta(oC)
Ta(K)
Component
Required heat
Outlet
5
350.00
3.70
21.45
21.45
574.55
-258.08
-35852.45
-35852.45
Cooling
-
Outlet
8
350.00
3.70
23.18
Isobutylene
O2
H2O
MAL
23.18
581.61
-1467.23
-95440.38
-95440.38
-53492.54
-
Cooling
Outlet
9
85.00
1.00
23.18
23.18
581.61
-1713.14
-113969.52
-113969.52
Cooling
Outlet
10
60.00
1.00
12.64
11
60.00
1.00
10.53
23.18
298.17
-1729.90
-87649.14
283.44
-1729.90
-27400.40
-115049.54
-1080.02
-
Cooling
Inlet
Outlet
12
4.00
1.00
0.35
13
56.77
1.00
1.73
10.89
10.89
19.71
-287.42
-5665.71
-33066.11
14
51.57
1.00
9.16
39.33
-390.16
-7680.35
263.82
-1735.44
-25402.55
-33082.90
-16.80
-
Outlet
6
350.00
3.70
1.73
1.73
39.33
-309.62
-6095.39
-6095.39
Heating
-
Outlet
15
40.00
1.00
12.64
12.64
298.17
-1742.96
-88253.58
-88253.58
Cooling
-
Inlet
Outlet
18
40.00
1.00
20.13
19
63.42
1.00
32.78
32.78
561.79
-1745.79
-170977.19
-170977.19
32.78
263.62
-872.56
-84359.37
-172612.94
1635.75
Required heat
Outlet
20
21
45.00
1.00
4.98
45.00
1.00
27.80
32.78
209.03
-1739.72
-55589.68
352.75
-1477.09
-116678.43
-172268.11
-1290.92
-
Cooling
Outlet
22
45.18
3.00
27.80
27.80
352.75
-1761.27
-116668.76
-116678.43
Pi(bar)
Po(bar)
Component
MAA (C4H6O2)
AA (C2H4O2)
Xylene
Total
0.00
Outlet
23
82.01
1.00
20.13
24
173.13
1.50
7.67
27.80
263.62
-851.91
-82664.45
89.14
-801.35
-30495.19
-113159.64
3509.12
-
Outlet
17
74.92
1.00
20.13
20.13
263.62
-855.49
-82960.76
-82960.76
Cooling
-
Outlet
25
150.06
1.00
7.67
7.67
89.14
-815.00
-30882.90
-30882.90
-387.71
-
Release to the surrounding
Outlet
26
150.93
6.80
7.67
Pi(bar)
Po(bar)
7.67
Component
89.14
-814.49
-30868.49
-30882.90
MAA (C4H6O2)
AA (C2H4O2)
Xylene
Total
0.00
Outlet
27
55.00
6.80
7.67
7.67
89.14
-865.35
-32366.63
-32366.63
Cooling
-
Inlet
Outlet
28
55.00
6.80
4.28
21.59
133.71
-236.12
-31571.18
-139783.29
31
55.00
6.80
9.64
100.11
-2546.07
-75845.48
-3421.64
Outlet
33
54.82
1.00
21.59
21.59
322.95
-2546.25
-143212.83
-143212.83
-7.90
Outlet
35
75.00
1.50
9.57
9.57
190.32
-2527.53
-56986.84
-56986.84
Cooling
-
Outlet
40
50.00
1.00
3.06
3.06
32
55.00
6.80
21.59
21.59
322.95
-2546.07
-143204.93
-143204.93
56.94
-2551.05
-17305.18
-17305.18
Cooling
-
Outlet
30
359.64
1.50
9.60
37
67.41
1.00
4.65
38
99.24
1.00
6.69
99.66
-2119.47
-70173.60
130.10
-2492.82
-33427.65
21.59
8856.63
-
69.22
-2502.75
-23786.71
-134356.20
Cp=a+bT+cT2+dT3 , kJ/mol.C at 25
c
-1.73E-07
-6.076E-009
d
5.05E-11
1.311E-012
7.604E-009
-3.593E-012
3.58E-07
8.99E-07
3.55E-09
-2.887E-008
5.23E-07
-2.22E-12
7.464E-012
-1.87E-008
-8.03E-012
Reference
http://cccbdb.nist.gov/exp2.asp?casno=4170303
Hf =
Cp =
2.41E-06
4
561.28
834.43
3.7
1.00
5
350
623.15
3.7
1.00
6 (13)
350
623.15
3.7
1.00
1.28
320.47
126.40
126.40
1.28
320.47
126.40
126.40
19.71
19.61
574.55
574.55
39.33
77.00
17.10
-222.45
-59.33
41.45
10.08
-230.44
-79.18
-230.44
-79.18
-187.68
-258.08
-309.62
98.31
5480.29
-28117.51
-7499.74
52.93
3230.78
-29128.17
-10007.99
-4542.47
-1552.92
-30038.65
-35852.45
-6095.39
a
8.29E-02
0.0291
0.03346
0.09392
b
2.56E-04
0.00001158
0.00000688
1.00
3.70
395.00
395.38
395.19
668.34
Cp(kJ/mol) using Ta
c
-1.73E-07
-6.076E-009
7.604E-009
Pi(bar)
Po(bar)
Component
Isobutylene (C4H8)
O2
H2O
MAL (C4H6O)
MAA (C4H6O2)
AA (C2H4O2)
CO
CO2
Total
3.70
1.00
mass flow rate(ton/hr)
mass flow rate(kg/hr)
0.07
6.36
3.34
1.53
8.97
0.60
0.56
1.75
23.18
71.50
6362.96
3344.94
1533.16
8965.92
595.74
556.03
1747.51
23177.76
Release to the surrounding
Component
Isobutylene (C4H8)
O2
H2O
MAL (C4H6O)
MAA (C4H6O2)
AA (C2H4O2)
CO
CO2
Xylene
Total
0.01
0.64
3.01
0.15
8.07
10.72
0.06
0.17
9.95
32.78
7.15
636.30
3010.45
153.32
8069.33
10723.36
55.60
174.75
9945.92
32776.17
Assume adiabatic
1.00
3.00

7.67
10.19
9.95
27.80

7665.86
10187.19
9945.92
27798.98
density
(kg/m3)
1020.00
1050.00
870.00
2940.00
Assume adiabatic
1.00
6.80
density
(kg/m3)
7.67
0.00
0.00
7.67
7665.86
0.00
0.00
7665.86
1020.00
1050.00
870.00
2940.00
Component
H2O
MAA (C4H6O2)
AA (C2H4O2)
Xylene
MeOH
H2SO4
MMA (C5H8O2)
Total

1.61
0.85
0.00
0.00
1.43
8.74
8.95
21.59
Cooling
P1(bar)
Po(bar)
Ti (oC)
To(oC)
Ta(oC)
Ta(K)
Component
H2O
MAA (C4H6O2)
AA (C2H4O2)
Xylene
MeOH
H2SO4
6.80
1.00
55.00
54.72
54.86
328.01
Cp(kJ/mol) using Ta
a
7.54E-02
0.14629
0.13664
1.34E-01
0.07586
0.1391
b
-0.00005859
-0.0003208
7.88E-06
0.0001683
0.0001559
41
50.00
1.00
0.64
23.97
-2551.05
-6968.24
.gov/exp2.asp?casno=4170303
Perry's Handbook
Perry's Handbook
Elementary Principles of Chemical Processes
7
350
623.15
3.7
1.00
8
350
623.15
3.7
1.00
9
85
358.15
1
0.48
10
60
333.15
1
0.09
11
60
333.15
1
0.89
1.28
320.47
146.11
146.02
1.28
198.84
185.83
21.90
104.25
9.93
19.86
39.72
1.28
198.84
185.83
21.90
104.25
9.93
19.86
39.72
0.13
19.88
167.25
2.19
93.83
8.94
1.99
3.97
1.15
178.96
18.58
19.71
10.43
0.99
17.87
35.74
613.88
581.61
581.61
298.17
283.44
41.45
10.08
-230.44
-79.18
41.45
10.08
-230.44
-79.18
-303.50
-425.26
-100.82
-379.57
6.96
1.78
-281.32
-104.06
-358.06
-478.48
-108.77
-391.20
4.44
1.04
-283.20
-106.41
-362.28
-481.81
-109.50
-392.18
4.44
1.04
-283.20
-106.41
-362.28
-481.81
-109.50
-392.18
-258.08
-1467.23
-1713.14
-1729.90
-1729.90
52.93
3230.78
-33670.64
-11560.91
52.93
2004.58
-42822.87
-1734.14
-31641.32
-4222.47
-2002.06
-15075.03
8.88
354.54
-52276.95
-2279.26
-37329.04
-4750.81
-2159.94
-15536.94
0.57
20.59
-47364.52
-233.07
-33992.22
-4305.48
-217.45
-1557.57
5.10
185.28
-5262.72
-2097.62
-3776.91
-478.39
-1957.02
-14018.12
-41947.84
-95440.38
-113969.52
-87649.14
-27400.40
Tref
Tref
25
273.15
a
d
5.05E-11
1.311E-012
-3.593E-012
Cp(J/mol)
4.74E+04
1.16E+04
1.31E+04
3.71E+04
Avg
(gamma)
1.0002
1.0007
1.0006
1.0002
1.0004
K.H. Ludtke, Process Centrifugal Comp

J.M. Smith, H. Van Ness, M.M. Abbott,
mole flow
rate(kmol/hr)
density
(kg/m3)
1.28
198.84
185.83
21.90
104.25
9.93
19.86
39.72
581.61
587.90
1.43
999.84
847.00
1020.00
1050
1.15
1.977
4509.30
volume
(m3/hr)
0.04
5.92
3.35
1.81
8.79
0.57
0.59
W=delV(Po-Pi)
1.18
Ideal gas equation:
22.25
Gas constant:
Note mixture of liquid and gas, take total V
Hayward Gordon Ltd., Mixing Fundamenta
density
(kg/m3)
587.90
1.43
999.84
847.00
1020.00
1050
1.15
1.977
870
5379.30
SG
M/SG
0.59
0.00
1.00
0.85
1.02
1.05
0.00
0.00
0.87
5.38
12.16
445273.57
3010.93
181.01
7911.11
10212.73
48350.11
88392.06
11432.09
614775.76
Average Np:
D:
N:
SG (mix)
volume
(m3/hr)
7.52
9.70
11.43
9.46
Note in liquid form, take total V
volume
(m3/hr)
7.52
0.00
0.00
7.52
Note in liquid form take total V
mass flow
rate(kg/hr)
1611.65
851.29
0.00
0.00
1434.97
8735.52
8953.61
21587.04
6.80
1.00
55.00
54.72
54.86
328.01
Cp(kJ/mol) using Ta
c
3.582E-007
8.985E-007
5.23E-07
density
(kg/m3)
999.84
1020.00
1050
870
791.8
1840
940
7511.64
SG
M/SG
1.00
1.02
1.05
0.87
0.79
1.84
0.94
7.51
1611.91
834.60
0.00
0.00
1812.28
4747.56
9525.12
18531.48
Tref
Tref
d
Cp(J/mol)
2.25E+03
8.84E+03
6.67E+03
1.01E+04
2.03E+02
1.90E+02
(gamma)
1.0037
1.0009
1.0012
1.0008
1.0427
1.0457
12
4
277.15
1
0.00
13
56.77
329.92
1
0.00
14
51.57
324.72
1
0.89
15
40
313.15
1
0.09
16
40
313.15
1
0.00
19.71
19.71
19.61
1.15
178.96
18.58
0.10
10.43
0.99
17.87
35.74
0.13
19.88
167.25
2.19
93.83
8.94
1.99
3.97
0.00
19.71
-287.42
39.33
-283.44
-106.72
263.82
298.17
3.63
0.78
-283.84
-107.20
-363.67
-482.89
-109.75
-392.50
2.54
0.44
-284.71
-108.29
-365.57
-484.34
-110.08
-392.94
0.00
-22.64
-287.42
-5665.71
-390.16
-5587.28
-2093.08
-1735.44
-1742.96
4.17
140.43
-5274.54
-10.57
-3791.48
-479.46
-1961.42
-14029.68
0.32
8.79
-47616.73
-237.18
-34301.43
-4328.14
-218.61
-1560.60
-22.64
0.00
-5665.71
-7680.35
-25402.55
-88253.58
0.00
udtke, Process Centrifugal Compressors, Basics, Function, Operation, Design, Application, 2004
mith, H. Van Ness, M.M. Abbott, Intoduction to Chemical Engineering Thermodynamics, Mc Graw Hill Education, 2005
PV=nRT
8.31E-05
m3.bar/K.mol
d Gordon Ltd., Mixing Fundamentals
http://www.cheresources.com/slurr
1.26
6.56168 ft
100 rpm
0.05
Assume D = 2m
Hayward Gordon Ltd., Mixing Fundamentals
Average Np:
D:
N:
SG (mix)
1.26
3.28084 ft
200 rpm
1.16
25
273.15
17 (23)
74.92
348.07
1
1.00
18
40
313.15
1
0.00
19
63.42
336.57
1
0.05
20
45
318.15
1
0.12
21
45
318.15
1
0.00
0.00
169.79
0.00
169.79
93.83
93.83
0.13
19.88
167.25
2.19
93.83
178.72
1.99
3.97
93.83
0.13
19.88
167.25
2.19
4.69
8.94
1.99
3.97
0.00
0.00
263.62
263.62
561.79
209.03
352.75
3.00
0.59
-284.33
-107.82
-364.75
-483.72
-109.94
-392.75
3.00
0.59
0.00
89.14
169.79
0.00
0.00
93.83
-359.77
-479.84
-365.57
-484.34
-15.88
-22.64
4.78
1.14
-282.94
-106.09
-361.71
-481.36
-109.40
-392.04
-18.16
-855.49
-872.56
-1745.79
-1739.72
-1477.09
0.38
11.73
-47553.68
-236.15
-1711.24
-4322.56
-218.32
-1559.85
0.00
0.00
-55589.68
0.00
-81470.62
0.00
-82234.74
-1490.14
-2124.62
0.61
22.61
-47321.39
-232.36
-33938.68
-86030.10
-217.25
-1557.04
-1703.58
-82960.76
-84359.37
-170977.19
-107.82
-364.75
-483.72
-109.94
-392.75
-21.70
0.00
-32513.50
-82128.71
0.00
0.00
-2036.22
-116678.43
Graw Hill Education, 2005
www.cheresources.com/slurrysgzz.shtml
http://www.cheresources.com/slurrysgzz.shtml
Assume D = 2m
22
45.18
318.33
3
0.00
23
82.01
355.16
1
1.00
24
173.13
446.28
1.5
0.00
25
150.06
423.21
1
0.00
26
150.93
424.08
6.8
0.00
0.00
0.00
0.00
0.00
89.14
169.79
0.00
0.00
93.83
352.75
3.02
0.60
-284.32
-107.80
-364.73
-483.69
-109.93
-392.74
-21.67
-1761.27
0.00
0.00
0.00
0.00
-32510.86
-82124.87
0.00
0.00
-2033.03
-116668.76
0.00
169.79
89.14
0.00
89.14
0.00
89.14
0.00
93.83
0.00
0.00
0.00
263.62
89.14
89.14
89.14
-358.57
-478.88
-342.11
-464.94
-346.46
-468.80
-346.30
-468.66
-14.45
5.71
0.26
0.46
-851.91
-801.35
-815.00
-814.49
0.00
-81308.19
-30495.19
0.00
-30882.90
0.00
-30868.49
0.00
-1356.26
0.00
0.00
0.00
-82664.45
-30495.19
-30882.90
-30868.49
27
55
328.15
6.8
0.00
28
55
328.15
6.8
0.00
29
55
328.15
6.8
0.00
30
359.64
632.79
1.5
0.00
31
55
328.15
6.8
0.00
0.45
0.45
89.14
0.00
9.85
0.00
9.85
0.00
0.00
0.00
0.22
88.69
0.45
99.66
0.00
0.22
89.14
0.45
100.11
-260.61
-283.58
-363.11
-482.45
-301.08
-422.47
-363.11
-482.45
-19.79
60.13
-202.38
-754.74
-238.32
-2119.47
-19.79
-236.12
-806.96
-354.06
-2546.07
-116.67
-126.95
-2965.43
0.00
-3576.32
0.00
0.00
-45.38
-66939.44
-106.69
-70173.60
0.00
-52.94
-71930.76
-158.51
-75845.48
133.71
0.00
89.14
133.71
0.00
-236.12
-806.96
-865.35
-236.12
-806.96
-32366.63
0.00
0.00
-31571.18
0.00
-32366.63
-31571.18
0.00
32
55
328.15
6.8
0.00
33
54.82
327.97
1
0.00
34
66.63
339.78
1
0.65
35
75
348.15
1.5
0.18
36
50
323.15
1
1.00
89.54
89.54
86.82
86.82
2.27
9.90
0.00
9.90
0.00
0.05
0.00
0.05
0.00
0.00
0.00
0.00
44.84
89.14
89.54
322.95
0.00
44.84
89.14
89.54
322.95
0.00
34.38
0.43
68.64
190.32
0.00
34.38
0.43
68.64
190.32
0.00
10.24
0.01
20.45
32.97
-283.58
-283.59
-240.42
-282.07
-283.96
-363.11
-482.45
-363.14
-482.47
-361.17
-480.94
-359.76
-479.83
-363.93
-483.09
-19.79
-236.12
-806.96
-354.06
-2546.07
-19.83
-236.14
-806.99
-354.10
-2546.25
-17.53
-236.66
-805.23
-351.61
-2493.55
-15.87
-236.25
-803.98
-349.78
-2527.53
-20.75
-236.55
-807.70
-355.09
-2551.05
-25390.48
-25391.69
-20872.75
-24488.39
-645.08
-3594.30
0.00
-3594.59
0.00
-17.42
0.00
-17.35
0.00
-0.46
0.00
0.00
-10588.35
-71930.76
-31701.04
-143204.93
0.00
-10589.04
-71933.13
-31704.38
-143212.83
0.00
-8135.90
-349.73
-24135.19
-53510.99
0.00
-8121.88
-349.19
-24010.04
-56986.84
0.00
-2422.21
-9.18
-7260.01
-10336.94
37
67.41
340.56
1
0.84
38
99.24
372.39
1
0.00
39
70
343.15
1
0.00
40
50
323.15
1
0.00
41
50
323.15
1
0.00
66.04
2.60
22.72
22.72
20.45
0.00
0.00
0.04
0.00
0.01
0.00
0.01
0.00
0.01
0.00
0.00
43.27
0.01
20.78
130.10
0.00
0.21
0.33
66.04
69.22
0.00
11.38
0.11
22.72
56.94
0.00
11.38
0.11
22.72
56.94
0.00
1.14
0.10
2.27
23.97
-240.40
-280.24
-282.45
-283.96
-283.96
-361.04
-480.84
-355.60
-476.49
-360.60
-480.50
-363.93
-483.09
-363.93
-483.09
-17.37
-236.62
-805.12
-351.44
-2492.82
-10.91
-235.04
-800.27
-344.20
-2502.75
-16.86
-236.49
-804.73
-350.88
-2532.50
-20.75
-236.55
-807.70
-355.09
-2551.05
-20.75
-236.55
-807.70
-355.09
-2551.05
-15875.57
-729.64
-6416.51
-6450.76
-5805.69
-0.07
0.00
-13.50
0.00
-4.55
0.00
-4.59
0.00
-4.13
0.00
0.00
-10239.46
-10.49
-7302.07
-33427.65
0.00
-48.55
-264.39
-22730.62
-23786.71
0.00
-2690.75
-91.46
-7971.10
-17174.36
0.00
-2691.35
-91.80
-8066.68
-17305.18
0.00
-269.13
-82.62
-806.67
-6968.24
C-102
Dew Point - Top Product (Consider only LK & LLK)
P
T
n
0.00
169.79
93.83
y
0.00
0.64
0.36
MAA
AA
Xylene
y/K
1.0000215886
Bubble Point - Bottom Product (Consider only HK)

P
T
n
89.14
0.00
0.00
x
1.00
0.00
0.00
MAA
AA
Xylene
xK
1.000043913
C-103
P
T
n
89.09
0.05
44.62
0.45
89.09
y
0.40
0.00
0.20
0.00
0.40
H2O
MAA
MeOH
H2SO4
MMA
y/K
1.0001903451
Bubble Point - Bottom Product (Consider only HK & HHK)

P
T
n
0.45
9.85
0.22
88.69
x
0.00
0.10
0.00
0.89
H2O
MAA
MeOH
H2SO4
0.45
0.00
MMA
zK
0.9999806691
C-104
P
T
n
66.04
0.00
43.27
0.01
20.78
y
0.51
0.00
0.33
0.00
0.16
H2O
MAA
MeOH
H2SO4
MMA
y/K
1.0000052901
Bubble Point - Bottom Product (Consider only HK)

P
T
n
2.60
0.04
0.21
0.33
66.04
x
0.04
0.00
0.00
0.00
0.95
zK
H2O
MAA
MeOH
H2SO4
MMA
0.9999034163
1.01325 bar
126.14 C
A
5.37325
4.68206
4.14553
Dew Point
760 mmHg
399.14 K
B
2094.201
1642.54
1474.403
C
-44.514
-39.764
-55.377
Psat
0.5873530522
1.1179835167
0.8663379872
K
0.579672393
1.1033639444
0.8550091164
126.14
1.01325 bar
162.22 C
A
5.37325
4.68206
4.14553
Bubble Point
760 mmHg
435.22 K
B
2094.201
1642.54
1474.403
Dew Point
Psat
1.0132944948
1.6964296762
1.3020219298
K
1.000043913
1.6742459178
1.2849957363
162.22
1.01325 bar
165.13 C
A
3.55959
5.37325
5.15853
9.784
5.37785
C
-44.514
-39.764
-55.377
760 mmHg
438.13 K
B
643.748
2094.201
1569.613
3883
1945.56
C
-198.043
-44.514
-34.846
273
-7.569
Psat
2.4067532548
1.0542542608
3.5482391444
2.512639183
2.3612405536
760
K
2.3752807844
1.040468059
3.5018397675
0.0033061042
2.3303632406
165.13
1.01325 bar
411.71 C
A
3.55959
5.37325
5.15853
9.784
760 mmHg
684.71 K
B
643.748
2094.201
1569.613
3883
C
-198.043
-44.514
-34.846
273
Psat
9.3635177043
8.1830319715
15.5371730704
61.1289760829
760
K
9.2410734807
8.0760246449
15.3339976021
0.0804328633
5.37785
Bubble Point
1945.56
-7.569
Dew Point
12.0792518782
411.71
1.01325 bar
103.82 C
A
3.55959
5.37325
5.15853
9.784
5.37785
12.2393019656
760 mmHg
376.82 K
B
643.748
2094.201
1569.613
3883
1945.56
C
-198.043
-44.514
-34.846
273
-7.569
Psat
0.9595858355
0.3950370016
1.7659157022
0.5941314176
1.1150661091
760
K
0.9470375875
0.389871208
1.7428232936
0.0007817519
1.100484687
103.82
1.01325 bar
97.89 C
A
3.55959
5.37325
5.15853
9.784
5.37785
Bubble Point
760 mmHg
370.89 K
B
643.748
2094.201
1569.613
3883
1945.56
97.89
C
-198.043
-44.514
-34.846
273
-7.569
Psat
0.8480713382
0.3522976765
1.6285245124
0.5038828816
1.0231805207
760
K
0.8369813355
0.3476907738
1.6072287317
0.0006630038
1.0098006619
x
0
0.5837310525
0.416290536
1.0000215886
y
1.000043913
0
0
1.000043913
torr
x
0.1679716958
0.0002130344
0.0570621351
0.6037341446
0.1712093352
1.0001903451
torr
y
0.0415111997
0.7981309352
0.0344978062
0.0715803397
0.0542603884
0.9999806691
torr
x
0.535972891
3.634655845E-006
0.1908464704
0.1280641268
0.1451181672
1.0000052901
torr
y
0.0314829501
0.0001906311
0.0047967458
3.164548126E-006
0.9634299249
0.9999034163
C-102
C-102
C-102 Condensor
Stream
Component
MAA
AA
Xylene
Total
Variance
C-102 Reboiler
Stream
Component
MAA
AA
Xylene
Total
Variance
MAA (C4H6O2)
AA (C2H4O2)
Xylene
C-102 Condensor
Stream
Component
MAA
AA
Xylene
Total
C-102 Reboiler
Stream
Component
MAA
AA
Xylene
Total
C-103
C-103 Condensor
Stream
Component
H2O
MAA
MeOH
H2SO4
MMA
Total
Variance
C-103 Reboiler
Stream
Component
H2O
MAA
MeOH
H2SO4
MMA
Total
Variance
H2O
MAA (C4H6O2)
MeOH
H2SO4
MMA (C5H8O2)
C-103 Condensor
Stream
Component
H2O
MAA
MeOH
H2SO4
MMA
Total
C-103 Reboiler
Stream
Component
H2O
MAA
MeOH
H2SO4
MMA
Total
C-104
C-104 Condensor
Stream
Component
H2O
MAA
MeOH
H2SO4
MMA
Total
Variance
C-104 Reboiler
Stream
Component
H2O
MAA
MeOH
H2SO4
MMA
Total
Variance
H2O
MAA (C4H6O2)
MeOH
H2SO4
MMA (C5H8O2)
C-104 Condensor
Stream
Component
H2O
MAA
MeOH
H2SO4
MMA
Total
C-104 Reboiler
Stream
Component
H2O
MAA
MeOH
H2SO4
MMA
Total
In
23A
Molar Flow rate
Mole Fraction
(kmol/hr)
0.00
631.43
423.05
1054.48
23C
Mass Flow
Rate(ton/hr)
Mass Fraction
Molar Flow rate

(kmol/hr)
0.00
37.89
44.84
82.73
0.00
0.46
0.54
1.00
0.00
461.64
329.22
790.87
0.00
0.60
0.40
1.00
82.73
0.00
In
24A
Molar Flow rate
Mole Fraction
(kmol/hr)
222.85
0.00
0.00
222.85
24B
Mass Flow
Rate(ton/hr)
Mass Fraction
Molar Flow rate

(kmol/hr)
19.17
0.00
0.00
19.17
1.00
0.00
0.00
1.00
133.71
0.00
0.00
133.71
1.00
0.00
0.00
1.00
19.17
0.00
Liquid
Liquid
Liquid
-368
-486.18
-25.42
0.14629
0.13664
1.34E-01
-5.86E-05
-3.21E-04
7.88E-06
3.58E-07
8.99E-07
5.23E-07
In
23A
23C
Molar Flow rate

(kmol/hr)
Specific
Enthalpy
(MJ/kmol)
Energy Flow
(MJ/hr)
Molar Flow rate

(kmol/hr)
0.00
631.43
423.05
1054.48
-357.54
-478.06
-13.23
-848.83
0.00
-301862.69
-5597.90
-307460.59
0.00
461.64
329.22
790.87
Molar Flow rate

(kmol/hr)
222.85
0.00
0.00
222.85
In
24A
Specific
Energy Flow
Enthalpy
(MJ/hr)
(MJ/kmol)
-342.30
-76282.63
-465.12
0.00
5.47
0.00
-801.95
-76282.63
24B
Molar Flow rate
(kmol/hr)
133.71
0.00
0.00
133.71
In
34A
34C
Molar Flow rate

(kmol/hr)
Mole Fraction
Mass Flow
Rate(ton/hr)
Mass Fraction
Molar Flow rate

(kmol/hr)
201.61
0.19
82.84
404.87
203.78
893.29
0.23
0.00
0.09
0.45
0.23
1.00
3.63
0.02
2.65
39.68
20.38
66.35
0.04
0.00
0.03
0.48
0.25
0.80
112.52
0.14
38.22
404.42
114.69
670.00
66.35
0.00
In
30A
30B
Molar Flow rate

(kmol/hr)
Mole Fraction
Mass Flow
Rate(ton/hr)
Mass Fraction
Molar Flow rate

(kmol/hr)
6.65
129.16
5.38
99.39
0.03
0.52
0.02
0.40
0.12
11.11
0.17
9.74
0.01
0.50
0.01
0.44
6.21
119.31
5.16
10.70
8.56
249.15
0.03
1.00
0.86
22.00
0.04
1.00
8.11
149.49
22.00
0.00
Liquid
Gas
Liquid
Gas
Liquid
-285.84
-241.83
-368
-201.2
-811.32
0.0754
0.03346
0.14629
0.04293
0.1391
0.00000688
-5.86E-05
0.00008301
1.56E-04
7.604E-009
3.58E-07
-1.87E-008
Liquid
-360
0.2551
-9.38E-04
2.41E-06
In
34A
34C
Molar Flow rate

(kmol/hr)
Specific
Enthalpy
(MJ/kmol)
Energy Flow
(MJ/hr)
Molar Flow rate

(kmol/hr)
201.61
0.19
82.84
404.87
203.78
893.29
-282.25
-360.16
-198.96
-804.33
-350.30
-1996.01
-56903.58
-69.22
-16482.78
-325650.07
-71383.91
-470489.56
112.52
0.14
38.22
404.42
114.69
670.00
In
30A
30B
Molar Flow rate

(kmol/hr)
Specific
Enthalpy
(MJ/kmol)
Energy Flow
(MJ/hr)
Molar Flow rate

(kmol/hr)
6.65
129.16
5.38
99.39
8.56
249.15
-230.44
-303.50
-182.49
-756.61
-244.27
-1717.31
-1533.18
-39200.94
-982.02
-75201.91
-2090.72
-119008.78
6.21
119.31
5.16
10.70
8.11
149.49
In
37A
Molar Flow rate
Mass Flow
Mole Fraction
(kmol/hr)
Rate(ton/hr)
763.36
0.53
13.74
0.00
0.00
0.00
291.57
0.20
9.33
166.63
0.12
16.33
209.58
0.15
20.96
1431.15
1.00
60.36
60.36
37C
Mass Fraction
0.23
0.00
0.15
0.27
0.35
1.00
Molar Flow rate

(kmol/hr)
697.32
0.00
248.30
166.62
188.80
1301.05
0.00
In
38A
38B
Molar Flow rate

Mole Fraction
(kmol/hr)
Mass Flow
Rate(ton/hr)
Mass Fraction
Molar Flow rate

(kmol/hr)
17.82
0.13
2.52
0.33
0.03
0.00
0.00
0.00
0.32
0.01
0.08
0.03
0.01
0.00
0.00
0.00
15.22
0.09
2.32
0.00
531.68
552.48
0.96
1.00
53.17
53.61
0.99
1.00
465.64
483.26
53.61
0.00
Liquid
Gas
Liquid
Gas
Liquid
Liquid
-285.84
-241.83
-368
-201.2
-811.32
-360
0.0754
0.03346
0.14629
0.04293
0.1391
0.2551
0.00000688
-5.86E-05
0.00008301
1.56E-04
-9.38E-04
7.604E-009
3.58E-07
-1.87E-008
2.41E-06
In
37A
37C
Molar Flow rate

(kmol/hr)
Specific
Enthalpy
(MJ/kmol)
Energy Flow
(MJ/hr)
Molar Flow rate

(kmol/hr)
763.36
0.00
291.57
166.63
209.58
1431.15
-282.19
-360.03
-198.93
-804.21
-350.13
-1995.49
-215412.87
-1.77
-58001.60
-134006.01
-73381.73
-480803.98
697.32
0.00
248.30
166.62
188.80
1301.05
In
38A
38B
Molar Flow rate

(kmol/hr)
Specific
Enthalpy
(MJ/kmol)
Energy Flow
(MJ/hr)
Molar Flow rate

(kmol/hr)
17.82
0.13
2.52
0.33
531.68
552.48
-239.46
-356.33
-197.85
-800.93
-345.21
-1939.78
-4267.05
-46.35
-499.56
-265.83
-183540.31
-188619.10
15.22
0.09
2.32
0.00
465.64
483.26
Out
23C
23
Mole Fraction
Mass Flow
Rate(ton/hr)
Mass Fraction
0.00
0.58
0.42
1.00
0.00
27.70
34.90
62.60
0.00
0.44
0.56
1.00
Molar Flow rate

Mole Fraction
(kmol/hr)
0.00
169.79
93.83
263.62
0.00
0.64
0.36
1.00
82.73
0.00
Out
24B
24
Mole Fraction
Mass Flow
Rate(ton/hr)
Mass Fraction
1.00
0.00
0.00
1.00
11.50
0.00
0.00
11.50
1.00
0.00
0.00
1.00
Molar Flow rate

Mole Fraction
(kmol/hr)
89.14
0.00
0.00
89.14
1.00
0.00
0.00
1.00
19.17
0.00
Tref
25 oC
298.15 K
Out
23C
23
Specific
Enthalpy
(MJ/kmol)
Energy Flow
(MJ/hr)
Molar Flow rate

(kmol/hr)
Specific
Enthalpy
(MJ/kmol)
-358.57
-478.88
-14.45
-851.91
0.00
-221073.54
-4758.76
-225832.31
0.00
169.79
93.83
263.62
-358.57
-478.88
-14.45
-851.91
Out
Specific
Enthalpy
(MJ/kmol)
-342.11
-464.94
5.71
-801.35
24B
Energy Flow
(MJ/hr)
-45744.79
0.00
0.00
-45744.79
Specific
Enthalpy
(MJ/kmol)
-342.11
-464.94
5.71
-801.35
Molar Flow rate

(kmol/hr)
89.14
0.00
0.00
89.14
24
Out
34C
34
Mole Fraction
Mass Flow
Rate(ton/hr)
Mass Fraction
Molar Flow rate

(kmol/hr)
Mole Fraction
0.17
0.00
0.06
0.60
0.17
1.00
2.03
0.01
1.22
39.63
11.47
54.36
0.03
0.00
0.02
0.63
0.18
0.87
89.09
0.05
44.62
0.45
89.09
223.29
0.40
0.00
0.20
0.00
0.40
1.00
66.35
0.00
Out
30B
30
Mole Fraction
Mass Flow
Rate(ton/hr)
Mass Fraction
Molar Flow rate

(kmol/hr)
Mole Fraction
0.04
0.80
0.03
0.07
0.11
10.26
0.17
1.05
0.01
0.83
0.01
0.08
0.45
9.85
0.22
88.69
0.00
0.10
0.00
0.89
0.05
1.00
0.81
12.40
0.07
1.00
0.45
99.66
0.00
1.00
22.00
0.00
Tref
-3.593E-012
-8.03E-012
25 oC
298.15 K
Out
34C
34
Specific
Enthalpy
(MJ/kmol)
Energy Flow
(MJ/hr)
Molar Flow rate

(kmol/hr)
Specific
Enthalpy
(MJ/kmol)
-282.70
-361.17
-199.26
-805.23
-351.61
-1999.96
-31809.38
-51.54
-7616.43
-325655.46
-40325.12
-405457.94
89.09
0.05
44.62
0.45
89.09
223.29
-240.42
-361.17
-236.66
-805.23
-351.61
-1995.09
Out
30B
30
Specific
Enthalpy
(MJ/kmol)
Energy Flow
(MJ/hr)
Molar Flow rate

(kmol/hr)
Specific
Enthalpy
(MJ/kmol)
-230.09
-301.08
-181.81
-754.74
-238.32
-1706.04
-1427.82
-35923.29
-937.64
-8076.20
-1933.09
-48298.05
0.45
9.85
0.22
88.69
0.45
99.66
-260.61
-301.08
-202.38
-754.74
-238.32
-1757.13
Out
37C
Mole Fraction
0.54
0.00
0.19
0.13
0.15
1.00
Mass Flow
Rate(ton/hr)
12.55
0.00
7.95
16.33
18.88
55.71
37
Molar Flow rate
Mole Fraction
(kmol/hr)
66.04
0.51
0.00
0.00
43.27
0.33
0.01
0.00
20.78
0.16
130.10
1.00
60.36
Mass Fraction
0.23
0.00
0.14
0.29
0.34
1.00
0.00
Out
38B
38
Mole Fraction
Mass Flow
Rate(ton/hr)
Mass Fraction
Molar Flow rate

Mole Fraction
(kmol/hr)
0.03
0.00
0.00
0.00
0.27
0.01
0.07
0.00
0.01
0.00
0.00
0.00
2.60
0.04
0.21
0.33
0.04
0.00
0.00
0.00
0.96
1.00
46.56
46.92
0.99
1.00
66.04
69.22
0.95
1.00
53.61
0.00
Tref
25 oC
298.15 K
-3.593E-012
-8.03E-012
Out
37C
37
Specific
Enthalpy
(MJ/kmol)
Energy Flow
(MJ/hr)
Molar Flow rate

(kmol/hr)
Specific
Enthalpy
(MJ/kmol)
-282.64
-361.04
-199.22
-805.12
-351.44
-1999.45
-197092.79
-1.71
-49465.75
-134145.57
-66353.20
-447059.01
66.04
0.00
43.27
0.01
20.78
130.10
-240.40
-361.04
-236.62
-805.12
-351.44
-1994.61
Out
38B
38
Specific
Enthalpy
(MJ/kmol)
Energy Flow
(MJ/hr)
Molar Flow rate

(kmol/hr)
Specific
Enthalpy
(MJ/kmol)
-239.31
-355.60
-197.64
-800.27
-344.20
-1937.02
-3641.39
-32.76
-458.18
-1.22
-160272.11
-164405.67
2.60
0.04
0.21
0.33
66.04
69.22
-280.24
-355.60
-235.04
-800.27
-344.20
-2015.35
23
Mass Flow
Rate(ton/hr)
Mass Fraction
0.00
10.19
9.95
20.13
0.00
0.51
0.49
1.00
24
Mass Flow
Rate(ton/hr)
Mass Fraction
7.67
0.00
0.00
7.67
1.00
0.00
0.00
1.00
reflux ratio
L
3 (from aspen)
790.84801084
boilup ratio
a
1.5 (assume)
133.70693065
23
23B
Energy Flow
(MJ/hr)
Molar Flow rate

(kmol/hr)
Specific
Enthalpy
(MJ/kmol)
Energy Flow
(MJ/hr)
0.00
-81308.19
-1356.26
-82664.45
0.00
631.43
423.05
1054.48
-358.40
-478.75
-14.25
-851.40
0.00
-302295.74
-6029.24
-308324.98
24
Energy Flow
(MJ/hr)
-30495.19
0.00
0.00
-30495.19
34
Mass Flow
Rate(ton/hr)
Mass Fraction
1.60
0.00
1.43
0.04
8.91
11.99
0.13
0.00
0.12
0.00
0.74
1.00
30
Mass Flow
Rate(ton/hr)
Mass Fraction
0.01
0.85
0.01
8.69
0.00
0.09
0.00
0.91
0.04
9.60
0.00
1.00
reflux ratio
L
3 (from aspen)
669.8717225395
boilup ratio
a
1.5 (assume)
149.4915945482
34
34B
Energy Flow
(MJ/hr)
Molar Flow rate

(kmol/hr)
Specific
Enthalpy
(MJ/kmol)
Energy Flow
(MJ/hr)
-21418.94
-17.88
-10559.24
-358.88
-31324.06
-63679.00
201.61
0.19
82.84
404.87
203.78
893.29
-282.63
-361.00
-199.21
-805.08
-351.39
-1999.31
-56979.59
-69.38
-16502.93
-325953.79
-71605.33
-471111.03
30
Energy Flow
(MJ/hr)
-116.67
-2965.43
-45.38
-66939.44
-106.69
-70173.60
37
Mass Flow
Rate(ton/hr)
1.19
0.00
1.38
0.00
2.08
4.65
38
reflux ratio
L
10 (from aspen)
1301.0403496
boilup ratio
a
6.9825 (assume)
483.31165669
Mass Fraction
0.26
0.00
0.30
0.00
0.45
1.00
Mass Flow
Rate(ton/hr)
Mass Fraction
0.05
0.00
0.01
0.03
0.01
0.00
0.00
0.00
6.60
6.69
0.99
1.00
37
37B
Energy Flow
(MJ/hr)
Molar Flow rate

(kmol/hr)
Specific
Enthalpy
(MJ/kmol)
Energy Flow
(MJ/hr)
-15875.57
-0.07
-10239.46
-10.49
-7302.07
-33427.65
763.36
0.00
291.57
166.63
209.58
1431.15
-282.57
-360.87
-199.17
-804.97
-351.22
-1998.80
-215700.66
-1.77
-58072.62
-134131.11
-73610.05
-481516.22
38
Energy Flow
(MJ/hr)
-729.64
-13.50
-48.55
-264.39
-22730.62
-23786.71
E-201
Stream
Temperature (C)
Temperature (K)
Pressure (atm)
Mass Balance
Molar Flow Rate(kmol/hr)
Enthalpy (MJ/kmol)
Energy Flow (MJ/hr)
Heat Duty (MJ/hr)
Power Requirement
In
23A
88.01
Out
23B
83.01
361.16
356.16
1
82.73
1
82.73
0.00
1054.48
-848.83
-307460.59
-307460.59
-864.39
-
1054.48
-851.40
-308324.98
-308324.98
23D
Molar Flow rate (kmol/hr)
0.00
461.64
329.22
790.87
Specific Enthalpy
Energy Flow (MJ/hr)
(MJ/kmol)
-358.40
-478.75
-14.25
-851.40
0.00
-221010.67
-4692.00
-225702.67
E-203
Stream
Temperature (C)
Temperature (K)
Pressure (atm)
Mass Balance
Enthalpy (MJ/kmol)
Energy Flow (MJ/hr)
Heat Duty (MJ/hr)
Power Requirement
In
34A
72.63
345.78
1
66.35
0.00
893.29
-1996.01
-470489.56
-470489.56
-621.47
-
Out
34B
67.63
340.78
1
66.35
893.29
-1999.31
-471111.03
-471111.03
34D
112.52
0.14
38.22
404.42
114.69
670.00
E-205
Stream
Temperature (C)
Temperature (K)
Pressure (atm)
Mass Balance
Enthalpy (MJ/kmol)
Energy Flow (MJ/hr)
Heat Duty (MJ/hr)
Power Requirement
Specific Enthalpy
Energy Flow (MJ/hr)
(MJ/kmol)
-282.63
-361.00
-199.21
-805.08
-351.39
-1999.31
-31800.90
-51.52
-7614.58
-325594.97
-40300.44
-405362.42
In
37A
73.41
346.56
1
60.36
Out
37B
68.41
341.56
1
60.36
0.00
1431.15
-1995.49
-480803.98
-480803.98
-712.24
-
1431.15
-1998.80
-481516.22
-481516.22
37D
697.32
0.00
248.30
166.62
188.80
1301.05
Specific Enthalpy
Energy Flow (MJ/hr)
(MJ/kmol)
-282.57
-360.87
-199.17
-804.97
-351.22
-1998.80
-197040.21
-1.71
-49453.72
-134120.63
-66312.47
-446928.72
*Cooling
E-202
Stream
Temperature (C)
In
24A
172.13
Temperature (K)
445.28
Pressure (atm)
Mass Flow Rate (ton/
Mass Balance
Molar Flow Rate(kmo
Enthalpy (MJ/hr)
Energy Flow (MJ/hr)
Total Energy Flow (M
Heat Duty (MJ/hr)
Power Requirement
1
19.17
0.00
222.85
-801.95
-76282.63
-76282.63
42.64
-
E-204
*Cooling
Stream
Temperature (C)
Temperature (K)
Pressure (atm)
Mass Balance
Molar Flow Rate(kmol/hr
Enthalpy (MJ/hr)
Energy Flow (MJ/hr)
Total Energy Flow (MJ/h
Heat Duty (MJ/hr)
Power Requirement
In
30A
350
623.15
1
22.00
0.00
249.15
-1717.31
-119008.78
-119008.78
537.14
-
*Cooling
E-206
Stream
Temperature (C)
Temperature (K)
Pressure (atm)
Mass Flow Rate (ton/
Mass Balance
Molar Flow Rate(kmo
Enthalpy (MJ/hr)
Energy Flow (MJ/hr)
Total Energy Flow (M
Heat Duty (MJ/hr)
Power Requirement
In
38A
95
368.15
1
53.61
0.00
552.48
-1939.78
-188619.10
-188619.10
426.72
-
Out
24B
173.13
24
173.13
446.28
446.28
1
11.50
1
7.67
133.71
-801.35
-45744.79
89.14
-801.35
-30495.19
0.00
-76239.99
*heating
-
Out
30B
359.64
632.79
1
12.40
30
359.64
632.79
1
9.60
149.49
-1706.04
-48298.05
99.66
-1757.13
-70173.60
0.00
-118471.65
*heating
-
Out
38B
99.24
372.39
1
46.92
38
99.24
372.39
1
6.69
0.00
483.26
69.22
-1937.02
-2015.35
-164405.67
-23786.71
-188192.38
*heating
-
P-201
In
23C
82.01
Out
23D
83.01
Temperature (K)
355.16
356.16
Pressure (atm)
Mass Balance
Enthalpy (MJ/hr)
Energy Flow (MJ/hr)
Heat Duty (MJ/hr)
Power Requirement
1
263.62
1.1
263.62
Stream
Temperature (C)
0.00
62.60
-851.91
-225832.31
-225832.31
62.60
-851.40
-225702.67
-225702.67
129.63
0.06
Assume adiabatic
Pi(bar)
Po(bar)
Component
MAA (C4H6O2)
AA (C2H4O2)
Xylene
Total
1.00
1.10
mass flow rate(ton/hr) mass flow rate(kg/hr)

0.00
27.70
34.90
62.60
0.00
27698.55
34897.59
62596.14
P-202
Stream
Temperature (C)
Temperature (K)
Pressure (atm)
Mass Balance
Enthalpy (MJ/hr)
Energy Flow (MJ/hr)
Heat Duty (MJ/hr)
Power Requirement
In
34C
66.63
339.78
1
223.29
Out
34D
67.63
340.78
1.1
223.29
0.00
54.36
-1999.96
-405457.94
-405457.94
54.36
-1999.31
-405362.42
-405362.42
95.53
0.10
Assume adiabatic
Pi(bar)
Po(bar)
Component
H2O
MAA (C4H6O2)
MeOH
H2SO4
MMA (C5H8O2)
Total
1.00
1.10

2.03
0.01
1.22
39.63
11.47
54.36
2025.35
12.27
1223.18
39633.59
11468.83
54363.22
P-207
Stream
Temperature (C)
Temperature (K)
Pressure (atm)
Mass Balance
Enthalpy (MJ/hr)
Energy Flow (MJ/hr)
Heat Duty (MJ/hr)
Power Requirement
In
37C
67.41
340.56
1
130.10
Out
37D
68.41
341.56
1.1
130.10
0.00
55.71
-1999.45
-447059.01
-447059.01
55.71
-1998.80
-446928.72
-446928.72
130.29
0.14
Assume adiabatic
Pi(bar)
Po(bar)
Component
H2O
MAA (C4H6O2)
MeOH
H2SO4
MMA (C5H8O2)
Total
1.00
1.10

12.55
0.00
7.95
16.33
18.88
55.71
12551.80
0.41
7945.57
16328.43
18880.46
55706.66
density
(kg/m3)
1020.00
1050.00
870.00
2940.00
volume
(m3/hr)
0.00
26.38
40.11
21.29
density
(kg/m3)
volume
(m3/hr)
999.84
1020.00
791.8
1840
940
5591.64
2.03
0.01
1.54
21.54
12.20
37.32
density
(kg/m3)
999.84
1020.00
791.8
1840
940
5591.64
volume
(m3/hr)
12.55
0.00
10.03
8.87
20.09
51.55
Type of Utilities
Unit
Code
Condenser
Compressor (gas)
Throttle
Mixer
CSTR
P-101
P-102
P-201
P-202
P-203
E-103
E-101
E-108
M-101
R-103
Type of Utilities
Unit
Code
Methane (Fuel Gas)
Reactor
R-101
Pump
Electricity
http://www.engineeringtoolbox.com/steam-heating-systems-d_102.html (classification of low pressu

Type of Utilities (Saturated
Steam)
High Pressure Steam
Type of Utilities
Unit
Code
Heat Exchanger
E-104
E-202
E-204
E-206
Distillation column (reboiler)
Unit
Heat exchanger
Cooling Water
Condenser
Distillation column (condenser)
Code
E-102
E-105
E-109
E-101
E-107
E-103
E-106
E-201
E-203
E-205
Requirement
Type of utility
Cooling
Cooling water
Steam
Fuel Gas
Electricity
Heating
Power
Total amount of utility

(MT/yr)
1,632,744.07
9,056.71
5,022.49
Heat Intergration
Utilities
Flue Gas
Unit
Amount of flue gas produced

per year (MT/yr)
R-101
29,130.42
Unit
Code
Heat Exchanger
E-104
E-202
E-204
E-206
Distillation column
CH4
O2
CO2
H2O
Hf (kJ/mol)
-74.85
0
-393.50
-241.83
fuel gas
Component
CH4
O2
CO2
H2O(vapor)
Temp
oC
oC
oC
oC
delta H
O2
CH4
395.00
1.06E+01
1.27E+01
Power Quantity
kW
Total Electrical Energy

Consumption per year
(kWh/yr)
0.53
1.21
0.06
0.10
0.14
1.67
1,275.01
2.19
0.10
0.27
Total
3,971.28
9,153.94
447.12
783.79
1,082.52
12,613.41
9,639,062.07
16,593.33
752.21
2,054.42
9,686,514.09
Heat Duty, Q
Temperature In (C)
Temperature Out (C)
30.00
395.00
34,901.12
MJ/hr
MJ/yr
Latent Heat of Vaporization

(MJ/MT)
1,584.97
42.64
537.14
426.72
11,982,346.07
322,382.66
4,060,750.90
3,225,994.40
2,163.20
2,163.20
2,163.20
2,163.20
Total
Temperature In (C)
Temperature Out (C)
Delta T
30.00
30.00
30.00
30.00
30.00
30.00
30.00
30.00
30.00
30.00
241.28
50.00
38.37
50.00
125.93
295.00
37.09
35.00
35.00
35.00
211.28
20.00
8.37
20.00
95.93
265.00
7.09
5.00
5.00
5.00
MJ/hr
ml (classification of low pressure steam)

Heat Duty, Q
Total amount of utility

(MT/hr)
Total power requirement

(kWh/yr)
Total power requirement

(kWh)
9,686,514.09
1,281.28
215.97
1.20
0.66
Temperature (C)
395.00
Source of Flue Gas
oC
Inlet Temperature of Flue Gas Amount of flue gas produced

(C)
per year (MT/yr)
R-101
R-101
R-101
R-101
395.00
395.00
395.00
395.00
29,130.42
a
3.43E-02
0.0291
0.03611
0.03346
b
5.47E-05
0.00001158
0.00004233
0.00000688
c
3.66E-09
-6.076E-009
-2.887E-008
7.604E-009
delta H+Hf
O2
CH4
Heat Duty, Q
MJ/yr
Heating Value (kJ/mol)
Heating Value (MJ/MT)
-840.55
52,534.23
Total
263,852,430.70
Amount of steam required per

year (MT/yr)
5,539.18
149.03
1,877.20
1,491.31
9,056.71
Heat Duty, Q
MJ/hr
MJ/yr
Specific Heat Capacity

(MJ/MT.K)
5,813.80
604.43
3,475.86
130.82
1,498.14
18,529.14
296.31
864.39
621.47
712.24
43,952,320.27
4,569,506.10
26,277,464.43
989,005.84
11,325,906.24
140,080,307.26
2,240,084.20
6,534,759.14
4,698,297.18
5,384,545.00
4.19
4.19
4.19
4.19
4.19
4.19
4.19
4.19
4.19
4.19
Total
Amount of steam required per

year (MT/yr)
5,539.18
149.03
1,877.20
1,491.31
d
-1.10E-11
1.311E-012
7.464E-012
-3.593E-012
395.00
1.06E+01
-6.22E+01
Tref
oC
25
Amount of fuel gas required

per year (MT/yr)
5,022.49
5,022.49
Amount of cooling water

required per year (MT/yr)
49,696.32
54,580.82
749,995.70
11,813.26
28,204.56
126,279.25
75,477.74
312,219.74
224,476.69
257,264.45
1,632,744.07
oC

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Components

Mass Balance on Each Unit

Mass Flow Rate Mole Flow Rate

Mass Flow Rate Mole Flow Rate

Mass Flow Rate Mole Flow Rate

Mass Flow Rate Mole Flow Rate

Mass Flow Rate Mole Flow Rate

Mass Flow Rate Mole Flow Rate

Mass Flow Rate Mole Flow Rate

Mass Flow Rate Mole Flow Rate

Mass Flow Rate Mole Flow Rate

Mass Flow Rate Mole Flow Rate

Mass Flow Rate Mole Flow Rate

Mass Flow Rate Mole Flow Rate

Mass Flow Rate Mole Flow Rate

Mass Flow Rate Mole Flow Rate

Mass Flow Rate Mole Flow Rate

Mass Flow Rate Mole Flow Rate

Mass Flow Rate Mole Flow Rate

C-103 & C-104 & V-103 (red-loop)

Mass Flow Rate Mole Flow Rate

Mass Flow Rate

Mole Flow Rate

Mass Flow Rate

Mole Flow Rate

Mass Flow Rate

Mole Flow Rate

Mass Flow Rate

Mole Flow Rate

Mass Flow Rate

Mole Flow Rate

Mass Flow Rate

Mole Flow Rate

Mass Flow Rate

Mole Flow Rate

Mass Flow Rate

Mole Flow Rate

Mass Flow Rate

Mole Flow Rate

Mass Flow Rate

Mole Flow Rate

Mass Flow Rate

Mole Flow Rate

Mass Flow Rate

Mole Flow Rate

Mass Flow Rate

Mole Flow Rate

Mass Flow Rate

Mole Flow Rate

Mass Flow Rate

Mole Flow Rate

Mass Flow Rate

Mole Flow Rate

Mass Flow Rate

Mole Flow Rate

Mass Flow Rate

Mole Flow Rate

Mass Flow Rate

Mole Flow Rate

Mass Flow Rate

Mole Flow Rate

Mass Flow Rate

Mole Flow Rate

Mass Flow Rate