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This document contains a chemistry review with 7 questions and their answers. The questions cover topics like:
1) Calculating pH after adding acids or bases to buffers.
2) Calculating pH and fraction dissociation from Ka values for weak acids/bases.
3) Calculating an equilibrium constant from other given equilibrium constants.
4) Calculating concentration of an analyte using emission spectroscopy after a sample is spiked.
5) Using an internal standard to calculate the concentration of an unknown analyte from signal responses.
This document contains a chemistry review with 7 questions and their answers. The questions cover topics like:
1) Calculating pH after adding acids or bases to buffers.
2) Calculating pH and fraction dissociation from Ka values for weak acids/bases.
3) Calculating an equilibrium constant from other given equilibrium constants.
4) Calculating concentration of an analyte using emission spectroscopy after a sample is spiked.
5) Using an internal standard to calculate the concentration of an unknown analyte from signal responses.
This document contains a chemistry review with 7 questions and their answers. The questions cover topics like:
1) Calculating pH after adding acids or bases to buffers.
2) Calculating pH and fraction dissociation from Ka values for weak acids/bases.
3) Calculating an equilibrium constant from other given equilibrium constants.
4) Calculating concentration of an analyte using emission spectroscopy after a sample is spiked.
5) Using an internal standard to calculate the concentration of an unknown analyte from signal responses.
1) Addition of 0.0125 mol KOH to 150 mL of a 0.150 M HF/0.100 M NaF
buffer results in a pH = ________? The Ka of HF is 6.8 10-4. Answer: 3.61 2) Addition of 0.0125 mol HCl to 150 mL of a 0.150 M formic acid/0.100 M sodium formate buffer results in a pH = ________? The Ka of formic acid is 1.8 104. Answer: 2.60 3) What is the pH of 0.10 M ethylamine solution? What is the fraction of dissociation of ethylamine? The Ka of ethylamine is 2.3 x 10-11. Answer: 5.82; 0.000015 4) What is the pH of 0.15 M NaCN? What is the fraction of dissociation of CN-? The Ka of HCN is 4.9 x 10-10. Answer: 11.24; 0.012 5) If we know the equilibrium constants for the following two reactions: (1) H2O(l) + HNO2 (aq) H3O+(aq) + NO2-(aq), K1 = 4.50 10-4 (2) H3O+(aq) + OH-(aq) 2 H2O(l), K2 = 1.00 1014 What is the equilibrium constant for the reaction? NO2-(aq) + H2O(l) HNO2 (aq) + OH-(aq) Answer: 2.2 x 10-11
6) The concentration of copper in brandy may be measured by atomic
emission spectroscopy using an inductively coupled plasma. After measuring the emission signal from pure brandy, a 50.00 mL aliquot is spiked with 1.00 mL of 100.0 ppm copper standard. The emission signal for the pure sample was 2.11 units, and for the spiked sample it was 6.37 units. Calculate the concentration of copper in the brandy. Answer: 0.962 ppm 7) In the analysis of aspirin, caffeine may be used as an internal standard. A sample containing 5.0 mg/mL of aspirin and 4.0 mg/mL of caffeine gave a signal of 35 mAU for aspirin and a signal of 48 mAU for caffeine, respectively. A 5.0 mL of unknown sample was then spiked with 1.0 mL of 4.0 mg/mL caffeine. The signals for this mixture were 23 mAU for aspirin and 10 mAU. Calculate the concentration of aspirin in the unknown sample. Answer: 3.2 mg/mL