TABLA I MTODO DE MOHR: Valoracin de 100mL de disolucin con 0.02M de anin ClAgNO3 0.24M (Kps=1.

77E-10)
mL disolucin Ag+ 0.24M aadidos
2.50
2.75
3.00
3.25
3.50
3.75
Pto. De Equiv. 4.00
4.25
4.50
4.75
5.00
5.25
5.50
5.75
6.00
6.25
6.50
6.75
7.00

[Cl]t
9.51E-02
9.47E-02
9.42E-02
9.37E-02
9.32E-02
9.28E-02
9.23E-02
9.18E-02
9.14E-02
9.09E-02
9.05E-02
9.00E-02
8.96E-02
8.91E-02
8.87E-02
8.82E-02
8.78E-02
8.74E-02
8.69E-02

[Ag]t
5.85E-06
6.42E-06
6.99E-06
7.55E-06
8.12E-06
8.67E-06
9.23E-02
9.78E-06
1.03E-05
1.09E-05
1.14E-05
1.20E-05
1.25E-05
1.30E-05
1.36E-05
1.41E-05
1.46E-05
1.52E-05
1.57E-05

cin con 0.02M de anin Cl- con

[Cl-]
6.53E-01
4.96E-02
1.44E-01
6.35E-01
4.88E-02
1.41E-01
3.85E-05
4.80E-02
1.39E-01
5.99E-01
4.73E-02
1.37E-01
5.82E-01
4.65E-02
1.35E-01
5.66E-01
4.58E-02
1.33E-01
5.49E-01

p[Ag+]
4.6128
4.5724
4.5357
4.5020
4.4709
4.4420
4.4150
4.3897
4.3659
4.3435
4.3222
4.3021
4.2829
4.2646
4.2472
4.2304
4.2144
4.1991
4.1843

[Cl]t= iniciales/vol
[Ag]t= aadido/vol
4.7000
4.6000
4.5000
4.4000
4.3000
4.2000
4.1000
4.0000
3.9000
0.0000

5.0000

10.0000

15.0000

20.0000

TABLA II MTODO DE FAJ

Vol. AgNO3 aadido (mL)

20.00
99.00
99.50
100.00
100.50
110.00

Column G

15.0000

20.0000

A 20mL:
mmol Cl- = 100mL * 0.100 mmol / mL = 10 mm
mmol Ag+ = 20mL - 0.100 mmol / mL = 2 mmo
Cl- remanente = 10 - 2 = 8 mmol / 120mL = 0.0
pCl= - log 0.0667= 1.18

A 99mL:
mmol Ag+ = 99mL * 0.100 mmol / mL = 9.9 mm
Cl- remanente = 10 - 9.9 = 0.10 mmol / 199mL =
pCl= - log 5.0E-4 = 3.26

A 99.5mL
mmol Ag+ = 99.50mL * 0.100 mmol / mL = 9.95
Cl- remanente = 10 - 9.95 = 0.05 mmol / 199.5m
pCl= - log 2.5E-4 = 3.60

A 100mL, todo el Cl ha reaccionado con Ag

[Cl-] = (Kps)^1/2 = (1.0E-10)^1/2 = 1.0E-5M
pCl = -log 1.0E-5 = 5

A 100.50mL:
mmol Ag+ = 100.50mL * 0.1000 mmol/mL = 10
Ag+ remanente = 10.05 - 10 = 0.05mmol / 200.

[Cl-] = Kps/[Ag+] = 1E-10/ 2.4E-2 = 4.2E-9M

pCl = -log 4.2E-9 = 8.38

A 110mL
mmol Ag+ = 110mL * 0.10000 mmol/mL = 11 m
Ag+ remanente = 11 - 10 = 1 mmol/240mL = 4
[Cl-] = 1E-10 / 4.76E-3 = 2.1E-8M
pCl = -log 2.1E-8 = 7367

TABLA II MTODO DE FAJANS: Valoracin de 100mL de NaCl con de AgNO3 estandarizado

Vol. AgNO3 aadido (mL)
20.00
99.00
99.50
100.00
100.50
110.00

mmol Ag+ Cl-, Ag+ remanente

2.000
8.00
9.900
0.10
9.950
0.05
10.000
0.00
10.050
0.05
11.000
1.00

mL * 0.100 mmol / mL = 10 mmol

mL - 0.100 mmol / mL = 2 mmol
10 - 2 = 8 mmol / 120mL = 0.0667M

mL * 0.100 mmol / mL = 9.9 mmol

10 - 9.9 = 0.10 mmol / 199mL = 5.0E-4M

50mL * 0.100 mmol / mL = 9.950 mmol

10 - 9.95 = 0.05 mmol / 199.5mL = 2.5E-4M

el Cl ha reaccionado con Ag+:

= (1.0E-10)^1/2 = 1.0E-5M

.50mL * 0.1000 mmol/mL = 10.05 mmol

= 10.05 - 10 = 0.05mmol / 200.5mL = 0.02M

[Cl-]
0.0667
5.00E-04
2.50E-04
1.00E-05
4.20E-09
2.10E-08

9.000
8.000
7.000
6.000
5.000

pCl 4.000
3.000
2.000
1.000
0.000
0.00

20.00

40.00

60.00

80.00 100.00 120.00

mL AgNO3

= 1E-10/ 2.4E-2 = 4.2E-9M

mL * 0.10000 mmol/mL = 11 mmol

= 11 - 10 = 1 mmol/240mL = 4.76E-3M
76E-3 = 2.1E-8M

3 estandarizado

00

pCl1.176
3.301
3.602
5.000
8.377
7.678

AgNO3 [M]
KSCN [M]
Vol. Viraje
pClExponential (pCl-)

80.00 100.00 120.00

NO3

TABLA III, MTODO DE VOLHARD: Efecto del ion comun

en solubilidad molar del precipitado
Exceso de [Cl-], M
Solubilidad de AgCl, M
0.1
1.56E-09
0.014
1.56E-08
0.0026
1.56E-07
0.00031
1.56E-06
0.000024
1.56E-05

[Ag+][Cl-] = S^2 = Kps(AgCl) = 1.56E-10

[Ag+] permanece en soln = S(AgCl) = Kps(AgCl) / [Cl-]
0.05M
0.05M
6.3mL

Estandarizacin AgNO3:
1.52gNaCl*1mol AgCl/58.45NaCl = 0.0260molAgCl
0.0260molAgC / 0.0100AgNO3 = 0,26M

Estandarizacin KSCN:
C1V1=C2V2
C2= (0.26mol/L)(0.025L)/(0.0063L) = 1.031M

0.031mol KSCN/1L KSCN * 1mol SCN-/ 1mol KSCN * 6.3E-3 =

KSCN = 1.95E-4

DETERMINACIN DE CLORUROS:
0.026mol Ag - 1.95E-4mol SCN- = 2.58E-2
%Cl = (2.58E-2)(35.45g Cl) / 100mL NaCl =
0.01M X 100% = 0,91%

D: Efecto del ion comun

del precipitado
Exceso de AgCl, M
0.1
0.014
0.0026
0.00031
0.000024

0
2
-20

10

11

-40
-60
-80
Solubilidad s

-100
mL AgNO3

-120
-140
-160
-180
-200
pAg

pCl

pCa
3
4

mL AgNO3
-188
-138

T1
T
T
-184.977007 3.02299318 -3.02299318
-149.318814 -11.3188139 11.3188139

5
6
7
8
9
10

-130
-95
-91
-57
-54
-30

-121.660171
-99.0614138
-79.954437
-63.4032209
-48.8040136
-35.7445777

8.33982925
-4.06141379
11.045563
-6.40322091
5.19598636
-5.74457772

-8.33982925
4.06141379
-11.045563
6.40322091
-5.19598636
5.74457772

11

mL AgNO3

pCl

0mL ------> pCa = -log[Ca+] = -logx1E-1 = 1

50mL
0.12M X 10mL = 12mmol Ca+
mmoles de EDTA aadido-------> 0.1M X 50mL = 5mmol
mmol Ca+ = 12 - 5 = 7mmol
[Ca+] = 7mmol/150mL =0.04M
pCa = -log 4E-2 = 1.40

12
10
8

100mL
[CaY+] = 10mmol/200mL = 0.0500M
[Ca+] = CH4Y = x
[CaY-] = 0.050M - x
0.050/(x)(x) = 1.8E10
x = 1.7E-6M = [Ca+]
pCa = -log 1.7E-6 = 5.77

pCa

6
4
2
0
0

20

40

60

80

mL EDT

150mL
[CaY-] = 10mmol/250mL = 0.0400M
mmol en exceso CH4Y = 0.120M X 150mL - 0.120M X 100mL = 6mmol
C4HY = 6mmol/ 250mL = 0.024M
0.040 / [Ca+][0.024] = 1.8E10
pCa = -log 1.1E10 = 9.95M

Tabla IV: pCa Vs. mL de EDTA aadidos

mL aadidos de EDTA [Ca] presente
0
1
50
0.04M
100
1.7E-6M
150
1.10E+10

pCa
1
1.40
5.77
9.95

12
10
8
pCa

6
pCa

Linear (pCa)

2
0
0

0mL = 6mmol

20

40

60

80
mL EDTA

100

120

140

160

mL

pCa
10
20
30
40
50
60
70
80
90
100
110
120
130
140

1
1.1
1.3
1.5
1.7
1.8
2
2.3
2.5
9
9.3
9.8
9.9
10

pCa

inear (pCa)

Tabla V: pMg Vs. mL de EDTA aadidos

mL aadidos de EDTA
0
50
100
150

[Mg] presente
1
0.001
1.50E-06
1.20E-03

12
10
8
pMg

6
4
2
0
0

20

40

60

80
mL EDTA

100

120

140

160

EDTA aadidos
pMg
1
3.00
5.82
2.92

pCa
Linear (pCa)

80
EDTA

100

120

140

160