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SVPre Broad _ 12th _ Chemistry

TOTAL MARKS: 70
TIME: 2HR 30MIN
Q.1 (i) Define oxidation No. of central atom homoleptic and heteroleptic complexes.
(6 Marks)
2+
(ii)Why is Cr is reducing agent and Mn3+ Oxidising when both have d4 configuration.
(2 Marks)
(iii)Define the preparation of potassium Dichromate from iron chromite ore. What is the effect of
increasing PH on a solution of potassium dichromate?
(2 Marks)
Q.2.(i) Why are pentahalides more covalent than trihalides?
(2 Marks)
(ii) PH3 has lower boiling point than NH3. Why ?
(2 Marks)
(iii) Why is BiH3 the strongest reducing agent amongst all the hydrides of group 15 element?
(2 Marks)
(iv) Prepare dinitrogen with reactions.
(2
Marks)
(v) Why does NH3 act as a lewis base?
(2
Marks)
Q.3 (i) Explain the term Magnetic separation with diagram. (3 Marks)
(ii) Describe the Froth flotation method with diagram. (3 Marks)
(iii) Although Thermodynamically feasible, in practice, magnesium metal is not used for the
reduction of alumina in the metallurgy of aluminium. Why ?
(2 Marks)
(iv) Why is the reduction of a metal oxide easier if the metal formed is in liquid state at the
temperature of reduction?
(2 Marks)
Q.4.(i) In a reaction, 2A Products, the concentration of A decreases from 0.5 mol L -1 in 10
minutes. Calculate the rate during this interval.
(2 Marks)
(ii) Explain the factors influencing the rate of reaction.
(3 Marks)
(iii) Calculate the overall order of a reaction which has the rate expression:
(2 Marks)
(a) Rate= K[A]1/2 [B]3/2
(b) Rate= K[A]3/2 [B]-1
(c) (iv) The initial concentration of N2O5 in the following first order reaction N2O5(g) 2NO2(g) +
1/2O2(g) was 1.24x10-2 mol L-1 at 318K. The concentration of N2 O5 after 60 minutes was
0.20x10-2 mol L-1. Calculate the rate constant of the reaction at 318K.
(3 Marks)
(d) Q.5. Explain the following terms.
(2
Marks each)

(e) (i) Bravais Lattices


(f) (ii) Square close packing
(g) (iii) Packing efficiency

(h) (iv) Interstitial effect


(i) (v)Metal Excess defect

(j) Q.6(i) Calculate the molarity of a solution containing a 5g of a NaOH in 450ml solution.(2
Marks)
(k) (ii) Calculate the mass percentage of Benzene (C 6H6) and Carbon Tetrachloride (CCl4) if 22g
of Benzene is dissolved in 122g of Carbon Tetrachloride.
(2 Marks)
(l) (iii) Define Molarity, Molality and Mole function.
(6 Marks)
(m)
Q.7.(i) Write Galvanic cells half reactions.
(2 Marks)
(n) (ii) Can you store copper sulphate solution a zinc pot.
(2 Marks)
(o) (iii) Calculate the equilibrium constant of the reaction: Cu(S)+2Ag +(aq)Cu2+(aq) + 2Ag(S)
E0 Cell= 0.46V
(3 Marks)
(p) (iv) The cell in the following reaction occurs:
(3 Marks)
3+
(q) 2Fe (aq) + 2I-(aq) 2Fe2+ I2(s)
has E0 cell =0.236V at 298.
(r) Calculate standard Gibbs energy and equilibrium constant of the cell reaction.