Abellar, Rodgie John

Aries, Allen Jerry

Belnas, Katrina Lyn
BSChE-4

Assignment
ChE Thermodynamics 2
January 27,2014

Problem:
Calculate the enthalpy and entropy of saturated isobutene vapor at 360 K from the following
information:
1. compressibility-factor data for isobutene vapor.
2. The vapor pressure of isobutane at 360 K is 15.41 bar.
ig
1
ig
1 1
3. H 0 =18,115.0 J mo l and S 0 =295.976 J mol K
for the ideal gas reference state at
300 K and 1 bar.
4. The ideal-gas heat capacity of interest is:
C igP
3
=1.7765+ 33.037 10 T (T / K )
R
Solution:
Compressibility Factors Z for
Isobutane
P
(bar)
0.1
0.5
2
4
6
8
10
12
14
15.41
R

H
Z
=T
RT
0 T

( ) dPP
P

340 K
0.997
7
0.987
45
0.958
95
0.924
22
0.887
42
0.845
75
0.796
59

350 K
0.997
19
0.988
3
0.962
06
0.930
69
0.898
16
0.862
18
0.821
17
0.773
1

360 K
0.997
37
0.989
07
0.964
83
0.936
35
0.907
34
0.875
86
0.840
77
0.801
03
0.755
06
0.717
27

370 K
0.997
53
0.989
77
0.967
3
0.941
32
0.915
29
0.887
45
0.856
95
0.823
15
0.785
31

380 K
0.997
67
0.990
4
0.969
53
0.945
74
0.922
23
0.897
43
0.870
61
0.841
34
0.809
23

Abellar, Rodgie John

Aries, Allen Jerry
Belnas, Katrina Lyn
BSChE-4
R

S
Z
=T
R
0 T

Assignment
ChE Thermodynamics 2
January 27,2014

dP
dP
(Z1)
P
P P
0

( )

Solving for (Z 1)/ P in every pressure at 360 K:

*Value(s) in parenthesis are

Plotting Z vs .T
At

at each

P=0.1 bar,

Graphing from 350 K to

P
(bar)
0
0.1
0.5
2
4
6
8
10
12
14
15.41

(Z 1)/ P

(bar-1)

(0.031500)
0.026300
0.021860
0.017585
0.015913
0.015443
0.015518
0.015923
0.016581
0.017496
0.018347

found by extrapolation
pressure:

remove decreasing side:

Abellar, Rodgie John

Aries, Allen Jerry
Belnas, Katrina Lyn
BSChE-4

Assignment
ChE Thermodynamics 2
January 27,2014

1
1
f(x) = - 0x^2 + 0x + 0.98
R = 1

1
1
1
Z

1
1
1
1
1
345

350

355

360

365

370

375

380

385

T(K)

P=0.50

At

bar,

0.99
0.99
0.99
0.99

f(x) = - 0x^2 + 0x + 0.92

R = 1

0.99
0.99
Z

0.99
0.99
0.99
0.99
0.99
0.99
335

340

345

350

355

360
T(K)

365

370

375

380

385

Abellar, Rodgie John

Aries, Allen Jerry
Belnas, Katrina Lyn
BSChE-4

Assignment
ChE Thermodynamics 2
January 27,2014

P=2 bar,

At

0.97
0.97
0.97
0.97

f(x) = - 0x^2 + 0x + 0.68

R = 1

0.96
Z

0.96
0.96
0.96
0.96
0.95
0.95
335

340

345

350

355

360
T(K)

At

P=4 bar,

365

370

375

380

385

Abellar, Rodgie John

Aries, Allen Jerry
Belnas, Katrina Lyn
BSChE-4

Assignment
ChE Thermodynamics 2
January 27,2014

0.95
0.95

f(x) = - 0x^2 + 0x + 0.3

R = 1

0.94
0.94
Z

0.93
0.93
0.92
0.92
0.91
335

340

345

350

355

360
T(K)

At

P=6

bar,

365

370

375

380

385

Abellar, Rodgie John

Aries, Allen Jerry
Belnas, Katrina Lyn
BSChE-4

Assignment
ChE Thermodynamics 2
January 27,2014

0.93
0.92

f(x) = - 0x^2 + 0.01x - 0.22

R = 1

0.91

0.9
0.89
0.88
0.87
335

340

345

350

355

360
T(K)

At

P=8

bar,

365

370

375

380

385

Abellar, Rodgie John

Aries, Allen Jerry
Belnas, Katrina Lyn
BSChE-4

Assignment
ChE Thermodynamics 2
January 27,2014

0.91
0.9
0.89

f(x) = - 0x^2 + 0.01x - 0.97

R = 1

0.88
0.87
Z

0.86
0.85
0.84
0.83
0.82
0.81
335

340

345

350

355

360

365

370

375

380

385

T(K)

P=10 bar,

At

0.88
0.86

f(x) = - 0x^2 + 0.01x - 2.16

R = 1

0.84
0.82
Z

0.8
0.78
0.76
0.74
335

340

345

350

355

360
T(K)

365

370

375

380

385

Abellar, Rodgie John

Aries, Allen Jerry
Belnas, Katrina Lyn
BSChE-4

Assignment
ChE Thermodynamics 2
January 27,2014

P=12 bar,

At

12
10
8

6
4
2
0
335

340f(x) =345
R = 0

350

355

360
T(K)

At

P=14

bar,

365

370

375

380

385

Abellar, Rodgie John

Aries, Allen Jerry
Belnas, Katrina Lyn
BSChE-4

Assignment
ChE Thermodynamics 2
January 27,2014

12
10
8

6
4
2
0
335

340f(x) = 345
R = 0

350

355

360

365

370

375

380

T(K)

Differentiating each trend line equation at T =360 K

and dividing each by corresponding

pressure gives:

P
(bar)
0
0.1
0.5
2
4
6
8
10
12
14
15.41

*Value(s) in parenthesis are

( TZ ) / P
P

(1.757
1.700
1.474
1.320
1.342
1.446
1.608
1.838
2.093
2.387

(K-1bar-1)
x
x
x
x
x
x
x
x
x
x

10-4)
10-4
10-4
10-4
10-4
10-4
10-4
10-4
10-4
10-4

(2.594 x 10-4)

found by extrapolation

385

Abellar, Rodgie John

Aries, Allen Jerry
Belnas, Katrina Lyn
BSChE-4

( TZ ) / P

Plotting

Assignment
ChE Thermodynamics 2
January 27,2014

vs.

P :

x=P ,

y=

( TZ ) /P
P

0
0

f(x) = 0x^6 - 0x^5 + 0x^4 - 0x^3 + 0x^2 - 0x + 0

R = 1

0
0
0
0
0

10

12

14

16

18

( TZ ) / P=4.51210

10

P62.3218 108 P5 + 4.6323 107 P 44.5265 106 P3 +2.3141 105 P25.4059

Z
T

( )

dP
=
P P

15.41

( 4.512 1010 P62.3218 108 P5 + 4.6323 107 P 44.5265 106 P 3+2.3141 105 P25.4

Abellar, Rodgie John

Aries, Allen Jerry
Belnas, Katrina Lyn
BSChE-4

Assignment
ChE Thermodynamics 2
January 27,2014

( TZ ) dP= 26.67 10
P

K 1

Graphing (Z 1)/ P vs .

P :

x=P and

y=( Z1)/P

0.04
0.03
0.03
0.02
y

0.02
0.01
0.01
0
0

10
x

12

14

16

18

Abellar, Rodgie John

Aries, Allen Jerry
Belnas, Katrina Lyn
BSChE-4

Assignment
ChE Thermodynamics 2
January 27,2014

0.01758
5

2
2
2
2
2
2
1.41

0.016
0.0155
0.0155
0.016
0.0165
0.0175
0.01834
7

yx
0.03517
0.032
0.031
0.031
0.032
0.035
0.025869

y x=0.255039

= y x=0.2550
(Z1) dP
P
0

H
Z
=T
RT
0 T

( ) dPP
P

H R =R T 2
0

( TZ ) dPP =8.314 ( 360 ) (26.67 10

2

H R =2873.7 J mo l1

S
Z
=T
R

T
0

dP
dP
(Z1)
P
P
P
0

( )

S R =RT
0

Z
T

( )

dP
dP
R ( Z1 )
P
P
P
0

S R =8.314 ( 360 ) ( 26.67 104 ) +(8.314 )(0.2550)

S R =5.862 J mo l1 K1
T

H=H ig0 + CigP dT +H R

T0

360

H=18,115.0+ 8.314 ( 1.7765+33.037 103 T ) dT 2873.7

300

H=21566 J mol
T
ig

ig

S=S 0 + C P
T0

dT
P
R
R ln + S
T
P0

1.7765+33.037 103 T
dT
15.41
() 8.314 ln
5.862
T
1

360

S=295.976+
300

S=269.68 J mol 1 K1

Summary:
H=21570 J mol 1
S=269.7 J mo l1 K1