75

t
1
5
8
10
14
18
22
30
40
52
80
135
210

X
0.05
0.2
0.3
0.35
0.4
0.45
0.5
0.55
0.6
0.65
0.7
0.75
0.77

C
2.128
1.792
1.568
1.456
1.344
1.232
1.12
1.008
0.896
0.784
0.672
0.56
0.5152

t
1
15
30
45
60
75
90
105
120
135
150
210

X
0.06
0.25
0.36
0.44
0.48
0.52
0.55
0.56
0.57
0.59
0.6
0.63

C
2.1056
1.68
1.4336
1.2544
1.1648
1.0752
1.008
0.9856
0.9632
0.9184
0.896
0.8288

t
1
15
30
45
60
75
90
105
135
150

X
0.02
0.15
0.25
0.32
0.36
0.4
0.43
0.45
0.5
0.51

C
2.1952
1.904
1.68
1.5232
1.4336
1.344
1.2768
1.232
1.12
1.0976

log C
0.32797162
0.25333801
0.19534606
0.16316137
0.12839927
0.09061071
0.04921802
0.00346053
-0.04769199
-0.10568394
-0.17263073
-0.25181197
-0.28802415

(-dc/dt)
0.084
0.07466667
0.056
0.028
0.028
0.028
0.014
0.0112
0.00933333
0.004
0.00203636
0.00059733
-

log (-dc/dt)
-1.07572071
-1.12687324
-1.25181197
-1.55284197
-1.55284197
-1.55284197
-1.85387196
-1.95078198
-2.02996322
-2.39794001
-2.69114467
-3.22378325
-

(-dc/dt)
0.0304
0.01642667
0.01194667
0.00597333
0.00597333
0.00448
0.00149333
0.00149333
0.00298667
0.00149333
0.00112
-

log (-dc/dt)
-1.51712642
-1.78445056
-1.92275325
-2.22378325
-2.22378325
-2.34872199
-2.82584324
-2.82584324
-2.52481325
-2.82584324
-2.95078198
-

(-dc/dt)
0.0208
0.01493333
0.01045333
0.00597333
0.00597333
0.00448
0.00298667
0.00373333
0.00149333
0.00149333

log (-dc/dt)
-1.68193667
-1.82584324
-1.9807452
-2.22378325
-2.22378325
-2.34872199
-2.52481325
-2.42790323
-2.82584324
-2.82584324

70
log C
0.32337587
0.22530928
0.15642799
0.09843605
0.06625136
0.03148926
0.00346053
-0.00629931
-0.01628353
-0.03696812
-0.04769199
-0.08155026

65
log C
0.34147409
0.27966694
0.22530928
0.18275693
0.15642799
0.12839927
0.10612287
0.09061071
0.04921802
0.0404441

210

0.55

1.008

0.00346053

Mtodo lineal: T=75C

-0.3

-0.2

0
-0.1-0.5 0

0.1

0.2

0.3

-1
f(x) = 3.9091621142x - 2.0345260945
-1.5
R = 0.9665241243
-2

log(-dC/dt)

-2.5

Column F

-3
-3.5
log (C)

Mtodo lineal: T=70C

0
-0.5

0.05 0.1 0.15 0.2 0.25 0.3 0.35

-1
log(-dC/dt)
-1.5
-2

f(x) = 2.8922978376x - 2.4379028794

R = 0.9809981335

Column F

-2.5
log (C)

Mtodo lineal: T=65C

0
-0.5

0.05 0.1 0.15 0.2 0.25 0.3 0.35 0.4

-1
log(-dC/dt)

-1.5
-2

f(x) = 3.8343560288x - 2.9025835792

R = 0.9571609946

-2.5
-3
log (C)

Column F

-2

R = 0.9571609946

-2.5
-3
log (C)

Column F

Cao

k(75)
k(70)
k(65)

Column F

Column F

Column F

2.24

0.01674107
0.00605867
0.00414541

Column F

t
1
5
8
10
14
18
22
30
40
52
80
135
210

X
0.05
0.2
0.3
0.35
0.4
0.45
0.5
0.55
0.6
0.65
0.7
0.75
0.77

C
2.128
1.792
1.568
1.456
1.344
1.232
1.12
1.008
0.896
0.784
0.672
0.56
0.5152

Ln c
0.75518257
0.58333231
0.44980092
0.37569295
0.29565024
0.20863887
0.11332869
0.00796817
-0.10981487
-0.24334626
-0.39749694
-0.5798185
-0.6632001

t
1
15
30
45
60
75
90
105
120
135
150
210

X
0.06
0.25
0.36
0.44
0.48
0.52
0.55
0.56
0.57
0.59
0.6
0.63

C
2.1056
1.68
1.4336
1.2544
1.1648
1.0752
1.008
0.9856
0.9632
0.9184
0.896
0.8288

Ln c
0.74460046
0.51879379
0.36018876
0.22665737
0.1525494
0.07250669
0.00796817
-0.01450469
-0.0374942
-0.08512225
-0.10981487
-0.18777641

t
1
15
30
45
60
75
90
105
135
150

X
0.02
0.15
0.25
0.32
0.36
0.4
0.43
0.45
0.5
0.51

C
2.1952
1.904
1.68
1.5232
1.4336
1.344
1.2768
1.232
1.12
1.0976

Ln c
0.78627316
0.64395694
0.51879379
0.42081339
0.36018876
0.29565024
0.24435695
0.20863887
0.11332869
0.09312598

1
0.8
0.6
0.4
Ln C

0.2
0
-0.2 0
-0.4
-0.6
-0.8

f(x) = - 0.00359
R ==0.89041072
f(x)
- 0.00413
f(x)
- 0.00627
R ==0.81981299
R = 0.75467758
50

210

0.55

1.008

0.00796817

1
0.8
0.6
0.4
Ln C

0.2
0
-0.2 0

75 C
Linear
(75
C)

f(x) = - 0.0035947239x + 0.635078369

R ==0.8904107208
f(x)
- 0.0041396539x + 0.4947694752
f(x)
- 0.0062785488x + 0.3630777745
R ==0.819812996
R = 0.7546775826
50

100

-0.4
-0.6
-0.8
t (min

150

200

250

Cao

2.24

t
1
5
8
10
14
18
22
30
40
52
80
135
210

X
0.07
0.2
0.3
0.35
0.4
0.45
0.48
0.52
0.53
0.57
0.65
0.73
0.79

C
2.0832
1.792
1.568
1.456
1.344
1.232
1.1648
1.0752
1.0528
0.9632
0.784
0.6048
0.4704

1/C
0.48003072
0.55803571
0.6377551
0.68681319
0.74404762
0.81168831
0.85851648
0.93005952
0.94984802
1.03820598
1.2755102
1.65343915
2.12585034

t
1
15
30
45
60
75
90
105
120
135
150
210

X
0.13
0.27
0.39
0.44
0.48
0.51
0.53
0.55
0.57
0.59
0.6
0.65

C
1.9488
1.6352
1.3664
1.2544
1.1648
1.0976
1.0528
1.008
0.9632
0.9184
0.896
0.784

1/C
0.51313629
0.61154599
0.73185012
0.79719388
0.85851648
0.91107872
0.94984802
0.99206349
1.03820598
1.08885017
1.11607143
1.2755102

2.5
2

f(x) = 0.0071626
R = 0.99144373

1.5
1/C

f(x) = 0.0029
f(x)==0.99073
0.0020
R
R = 0.98789

1
0.5
0
0

50

10

1.4
f(x) = 0.0029755945x
R = 0.9907396379

1.2
1
0.8
0.6
0.4
0.2
0
20

40

60

80

100 1

1.2

t
1
15
30
45
60
75
90
105
135
150

X
0.05
0.17
0.27
0.32
0.36
0.4
0.42
0.44
0.48
0.5

C
2.128
1.8592
1.6352
1.5232
1.4336
1.344
1.2992
1.2544
1.1648
1.12

1/C
0.46992481
0.53786575
0.61154599
0.65651261
0.69754464
0.74404762
0.76970443
0.79719388
0.85851648
0.89285714

f(x) = 0.0020953048x
R = 0.9878905641

0.8
0.6
0.4
0.2
0
20

40

60

80

100

0.4
0.2

210

0.55

1.008

0.99206349

0
20

40

60

80

100

75 C
Linear (75 C)
70 C
Linear (70 C)
65 C

2 orden
2.5
2

f(x) = 0.0071626806x + 0.6616395133

R = 0.9914437327

1.5
1/C

f(x) = 0.0029755945x + 0.6724082086

f(x)==0.9907396379
0.0020953048x + 0.5704679987
R
R = 0.9878905641

1
0.5
0
0

50

100

150

200

250

t (min)

1.4
f(x) = 0.0029755945x + 0.6724082086
R = 0.9907396379

1.2
1
0.8

Column D
0.6

Linear (Column D)

0.4
0.2
0
20

40

60

80

100 120 140 160 180 200 220

1.2
1

f(x) = 0.0020953048x + 0.5704679987

R = 0.9878905641

0.8

Column D

0.6

Linear (Column D)
0.4
0.2
0
20

40

60

80

100 120 140 160 180 200 220

0.4
0.2
0
20

40

60

80

100 120 140 160 180 200 220

Cao

2.24

t
1
5
8
10
14
18
22
30
40
52
80
135
210

X
0.05
0.2
0.3
0.35
0.4
0.45
0.5
0.55
0.6
0.65
0.7
0.75
0.77

C
2.128
1.792
1.568
1.456
1.344
1.232
1.12
1.008
0.896
0.784
0.672
0.56
0.5152

1/C^2
0.22082933
0.31140386
0.40673157
0.47171235
0.55360686
0.65883792
0.79719388
0.98418997
1.24561543
1.62692628
2.21442744
3.18877551
3.76745689

t
1
15
30
45
60
75
90
105
120
135
150
210

X
0.06
0.25
0.36
0.44
0.48
0.52
0.55
0.56
0.57
0.59
0.6
0.63

C
2.1056
1.68
1.4336
1.2544
1.1648
1.0752
1.008
0.9856
0.9632
0.9184
0.896
0.8288

1/C^2
0.22555282
0.35430839
0.48656853
0.63551808
0.73705055
0.86501072
0.98418997
1.02943424
1.07787166
1.1855947
1.24561543
1.45579598

3
4
3
1/C2

X
0.02
0.15
0.25
0.32
0.36
0.4
0.43
0.45
0.5
0.51

C
2.1952
1.904
1.68
1.5232
1.4336
1.344
1.2768
1.232
1.12
1.0976

1/C^2
0.20751611
0.27584563
0.35430839
0.4310088
0.48656853
0.55360686
0.6134148
0.65883792
0.79719388
0.83006443

2
f(x) = 0.0060249482x
R
f(x)==0.957961621
0.0038106486x

R = 0.983948927

0
0

50

100
t

1.6

f(x) = 0.0060249482x + 0.33

R = 0.957961621

1.4
1.2
1
0.8
0.6
0.4
0.2
0
0

t
1
15
30
45
60
75
90
105
135
150

f(x) = 0.0181674593x
R = 0.9577999178

50

100

1.2
1

f(x) = 0.0038106486x + 0.24

R = 0.983948927

0.8
0.6
0.4
0.2
0
0

50

100

0.4
0.2

210

0.55

1.008

0.98418997

0
0

50

100

75 C
Linear (75 C)
70 C
Linear (70 C)
65 C

3er orden
4

f(x) = 0.0181674593x + 0.391772711

R = 0.9577999178

3
1/C2

2
f(x) = 0.0060249482x + 0.336722065
R
f(x)==0.957961621
0.0038106486x + 0.2456364684

R = 0.983948927

0
0

50

100

150

200

250

t (min)

70 C
1.6

f(x) = 0.0060249482x + 0.336722065

R = 0.957961621

1.4
1.2

70 C

Linear (70 C)

0.8
0.6
0.4
0.2
0
0

50

100

150

200

250

65 C
1.2
1

f(x) = 0.0038106486x + 0.2456364684

R = 0.983948927

0.8

65 C
Linear (65 C)

0.6
0.4
0.2
0
0

50

100

150

200

250

0.4
0.2
0
0

50

100

150

200

250

Cao

2.24

k
0.002
0.003
0.007

ln k
1/T
338 -6.2146081 0.00295858
343 -5.80914299 0.00291545
348 -4.96184513 0.00287356

0
0.00284
-1

0.00288

-2
-3
Ln k
-4
-5
-6
-7

f(x) = R = 0.9

0
0.00284
-1

0.00288

0.00292

0.00296

-2
-3

Ln k
-4
-5
-6

f(x) = - 14709.2045174213x + 37.2281891999

R = 0.956832116

-7
1/T

0.003

t
1
5
8
10
14
18
22
30
40
52
80
135
210

X
0.07
0.2
0.3
0.35
0.4
0.45
0.48
0.52
0.53
0.57
0.65
0.73
0.79

C
2.0832
1.792
1.568
1.456
1.344
1.232
1.1648
1.0752
1.0528
0.9632
0.784
0.6048
0.4704

1/Ca

Cateor

0.44842857
0.45642857
0.46242857
0.46642857
0.47442857
0.48242857
0.49042857
0.50642857
0.52642857
0.55042857
0.60642857
0.71642857
0.86642857

2.23000956
2.19092332
2.16249614
2.143951
2.10779886
2.07284572
2.03903292
1.97461213
1.89959294
1.81676616
1.64899882
1.39581256
1.15416323

1/Ca

Cateor

1
15
30
45
60
75
90
105
120
135
150
210

0.13
0.27
0.39
0.44
0.48
0.51
0.53
0.55
0.57
0.59
0.6
0.65

1.9488
1.6352
1.3664
1.2544
1.1648
1.0976
1.0528
1.008
0.9632
0.9184
0.896
0.784

0.44942857
0.49142857
0.53642857
0.58142857
0.62642857
0.67142857
0.71642857
0.76142857
0.80642857
0.85142857
0.89642857
1.07642857

2.22504768
2.03488372
1.86418109
1.71990172
1.5963512
1.4893617
1.39581256
1.31332083
1.24003543
1.17449664
1.11553785
0.92899801

t
1
15
30
45
60
75
90
105
135
150
210

X
0.05
0.17
0.27
0.32
0.36
0.4
0.42
0.44
0.48
0.5
0.55

C
2.128
1.8592
1.6352
1.5232
1.4336
1.344
1.2992
1.2544
1.1648
1.12
1.008

1/Ca
0.45342857
0.55142857
0.65642857
0.76142857
0.86642857
0.97142857
1.07642857
1.18142857
1.39142857
1.49642857
1.91642857

Cateor
2.20541903
1.8134715
1.52339499
1.31332083
1.15416323
1.02941176
0.92899801
0.84643289
0.71868583
0.66825776
0.52180395

3
2
Ca (mol/L) 1
0
0

50

3
2
Ca (mol/L) 1
0
0

3
2
Ca (mol/L) 1
0
0

50

k
0.002
0.003
0.007

75 C
3
2

Conc exp

Ca (mol/L) 1

Conc teorica

0
0

50

100

150

200

250

t (min)

70 C
3
2

Conc exp

Ca (mol/L) 1

Conc teorica

0
0

50

100

150

200

250

t (min)

65 C
3
2

Conc exp

Ca (mol/L) 1

Conc teorica

0
0

50

100

150

t (min)

200

250

1/Cao
338
343
348

0.44642857