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QUESTION 1
PO1, CO1, C3
An isothermic reaction is carried out adiabatically and the CSTR reactor design algorithm is shown as
below:
The reaction is second order in A. The feed which is equimolar in a solvent and A, and its enters the
reactor at a total volumetric flow rate, v0 of 10 dm3/min with the initial concentration of A being 4 M.
The rate constant, k given as 0.1 dm3/mol.min at 380 K. Determine the conversion can be achieved in
600 dm3 CSTR by using the following methods:
a) Graphically
b) False position method with initial guesses of Xl =0.6 and Xu =0.9
c) Secant method with initial estimates of X-1 = 0.6 and X0, =0.9
Iterate until the approximate error falls below 1 %. Find the absolute relative approximate error at the
end of each iteration.
(20 marks)
QUESTION 2
PO1, CO2, C4
A liquid-liquid extraction is used to extract nickel from the aqueous solution into an organic solution.
Table 1 shows the experimental data from the extraction process.
Table 1 Extraction of Nickel
Ni in aqueous phase, a (g/l)
12
16
20
6.3
12
15.5
18.3
21.5
Where g is the amount of nickel in the organic solution and a is the amounts of nickel in the aqueous
solution. Identify the best type of polynomial that fit to these data and determine its polynomial
CHE555 2015
equation. Then estimate the amount of nickel in the organic solution when 25 g/l of nickel is in the
aqueous solution.
(20 marks)
QUESTION 3
PO4, C03, C4
Compare answer from Question 2 with the answer from Excel and Matlab. Write the details command
(Excel and Matlab) and result of this problem.