Amostra

1
1B
2
2B
2C
3
3B
4
5
6
7
7B
8
9

CALIBRAO (g) - DIAN 18/05/15

etOH
Acetaldedo ter
Butanol Isopropanol SOMA
0.5242
0
0
0
0.509
1.0332
1.0224
0
0
0
1.0103
2.0327
0
0.518
0
0
0.5267
1.0447
1.462
0
0
1.447
2.909
0
2.07
0
0
2.03
4.1
0
0
0.5876
0
0.5266
1.1142
0
0
2.024
0
2.018
4.042
0
0
0
0.5297
0.5548
1.0845
1.27
0.16
0.143
0.1284
2.0776
3.779
0.2558
1.2599
0.2511
0.2524
2.0047
4.0239
0.2687
0.2353
1.2142
0.2598
2.006
3.984
0.2595
0.27
1.27
0.2624
1.9906
4.0525
0.3341
0.3489
0.3408
1.5605
2.5211
5.1054
0.643
0.632
0.67
0.634
2.493
5.072

Amostra
1
1B
2
2B
2C
3
3B
4
5
6
7
7B
8
9

CALIBRAO (g) - DIAN 18/05/15

etOH
Acetaldedo ter
Butanol Isopropanol SOMA
50.74%
0.00%
0.00%
0.00%
49.26%
100.00%
50.30%
0.00%
0.00%
0.00%
49.70%
100.00%
0.00%
49.58%
0.00%
0.00%
50.42%
100.00%
0.00%
50.26%
0.00%
0.00%
49.74%
100.00%
0.00%
50.49%
0.00%
0.00%
49.51%
100.00%
0.00%
0.00%
52.74%
0.00%
47.26%
100.00%
0.00%
0.00%
50.07%
0.00%
49.93%
100.00%
0.00%
0.00%
0.00%
48.84%
51.16%
100.00%
33.61%
4.23%
3.78%
3.40%
54.98%
100.00%
6.36%
31.31%
6.24%
6.27%
49.82%
100.00%
6.74%
5.91%
30.48%
6.52%
50.35%
100.00%
6.40%
6.66%
31.34%
6.48%
49.12%
100.00%
6.54%
6.83%
6.68%
30.57%
49.38%
100.00%
12.68%
12.46%
13.21% 12.50%
49.15%
100.00%

rea
Amostra
1
2
3
4
5
6
7
8
9

CALIBRAO
CALIBRAO 19
CALIBRAO 20
CALIBRAO 7
CALIBRAO 8
CALIBRAO 9
CALIBRAO 10
CALIBRAO 28
CALIBRAO 12
CALIBRAO 13
CALIBRAO 14
CALIBRAO 15
CALIBRAO 16
CALIBRAO 17
CALIBRAO 21
CALIBRAO 23
CALIBRAO 24
CALIBRAO 25
CALIBRAO 26

Acetaldedo

51922962 9901233
37920504 22.04%

3778662
4067754
32928638
30552858
5819526
4586655
4938401
5492903
8907674
9297926

204418.7
5.21%
1679930
5.29%
871771.3
16.75%
392091.8
7.52%
275949.9
3.03%

etOH
Isopropanol
58879416 740851.8 64259377 782270.53497
57831694
1.27% 63153080
1.23%
76890246 14029861.28
20.95%
57049026
63090416 4685016.3061
69716030
7.06%
66773325 4474340.4167
73100998
6.40%
41369809 2669128 74838780 5041818.9938
45144526
6.17% 81968989
6.43%
8571396 31652.08 74097206 2178292.1491
8526633
0.37% 71016635
3.00%
6859309 1272747 65742719 11435468.468
5059373 21.36% 49570525
19.83%
7123640 222353.3 65533544 2069164.3595
6809185
3.19% 62607303
3.23%
14914117 219095.3 65835573 999966.15619
15223964
1.45% 67249739
1.50%

Razo (Componente / Isopropanol)

Amostra
1
2
3
4
5
6
7
8
9

CALIBRAO
CALIBRAO 19
CALIBRAO 20
CALIBRAO 7
CALIBRAO 8
CALIBRAO 9
CALIBRAO 10
CALIBRAO 11
CALIBRAO 12
CALIBRAO 13
CALIBRAO 14
CALIBRAO 15
CALIBRAO 16
CALIBRAO 17
CALIBRAO 21
CALIBRAO 23
CALIBRAO 24
CALIBRAO 25
CALIBRAO 26

Acetaldedo

etOH
0.916277 0.000381
0.915738
0.04%

0.675287 0.007486
0.6647
1.12%

0.050491
0.049626
0.444398
0.430221
0.08852
0.092528
0.075357
0.087736
0.135302
0.13826

0.000612
1.22%
0.010024
2.29%
0.002834
3.13%
0.008753
10.73%
0.002091
1.53%

0.552786
0.550751
0.115678
0.120065
0.104336
0.102064
0.108702
0.10876
0.226536
0.22638

0.001439
0.26%
0.003102
2.63%
0.001606
1.56%
4.1E-005
0.04%
0.000111
0.05%

ter

Butanol

45332671 83515724 51922962 37920504

0.6647
42925327 81933499 76890246 57049026 0.675287
51846575 6208943
60627346 11.04%

4142500
4594937
9590806
8341422
48361701
36853935
8188144
7976578
16334710
16783004

319921.6
7.32%
883447.9
9.85%
8137219
19.10%
149599.1
1.85%
316991.6
1.91%

94379246
91184813
5121092
5527556
10069755
11492037
8792637
6555751
54133213
50988037
20531085
21057677

2258805
2.43%
287413.5
5.40%
1005705
9.33%
1581717 5819526 6859309 65742719 48361701 8792637
20.61% 4586655 5059373 49570525 36853935 6555751
2223975
4.23%
372356.7
1.79%

anol)
ter

Butanol

0.821782 0.033836
0.869633
4.00%

0.055352 0.000498
0.056057
0.89%
0.129435 0.00847
0.117457
6.86%
0.735621 0.005547
0.743465
0.75%
0.124946 0.00174
0.127407
1.38%
0.248114 0.001024
0.249562
0.41%

1.413427
1.247381
0.068428
0.067435
0.135899
0.161822
0.133743
0.132251
0.826038
0.81441
0.311854
0.313127

0.117412
8.83%
0.000703
1.03%
0.01833
12.31%
0.001055
0.79%
0.008222
1.00%
0.0009
0.29%

Concentrao

Acetaldedo
Razo
Conc.isopropanol*Comp /
Isopropanol

6.68%
12.46%
31.31%
50.49%

0.0448321392
0.0672307581
0.2178668304
0.3317284904

Concentrao

Etanol
Razo
Conc.isopropanol*Comp /
Isopropanol

6.54%
12.68%
33.61%
50.30%

0.0536926108
0.1113089535
0.3033485698
0.4552775805

f(x) = 0.6775469979x - 0.0055581175

R = 0.9942762976

f(x) = 0.9172168879x - 0.0055651236

R = 0.9999839154

Acetaldedo

Etanol

0.35

0.5
0.45

0.3

0.4

0.25

0.35
0.3

0.2

0.25

0.15

0.2

0.1

0.15
0.1

0.05

0.05
0

0
0

0.1

0.2

0.3

0.4

0.5

0.6

0.1

0.2

0.3

0.4

f(x) = 1.1709673901x - 0.0203316804

R = 0.997258355

ter

0.7
0.6
0.5
0.4
0.3
0.2
0.1
0
0

0.1

0.2

0.3

0.4

ter
Butanol
Razo
Razo
Concentrao Conc.isopropanol*Comp / Concentrao Conc.isopropanol*Comp
Isopropanol
/ Isopropanol
6.83%
13.21%
31.34%
52.74%

0.0623071179
0.1223093975
0.3632655459
0.59

9x - 0.0055651236

6.52%
12.50%
30.57%
48.84%

0.091971801
0.1535958599
0.4050353539
0.6805977924

f(x) = 1.4030074375x - 0.012443256

R = 0.997948746

Etanol

Butanol

0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0.2

0.3

0.4

0.5

0.6

0.0203316804

ter

0.2

0.3

0.4

0.5

0.6

0.1

0.2

0.3

0.4

0.5

0.6

0.6

Amostra
1
2
3
CALIBRAO (g) - DIAN 18/05/15
Amostra etOH Acetaldedo ter
Butanol Isopropanol
1
50.30%
0.00%
0.00%
0.00%
49.70%
2
0.00%
50.49%
0.00%
0.00%
49.51%
3
0.00%
0.00%
52.74%
0.00%
47.26%
4
0.00%
0.00%
0.00%
48.84% 51.16%
5
33.61%
4.23%
3.78%
3.40%
54.98%
6
6.36%
31.31%
6.24%
6.27%
49.82%
7
6.40%
6.66%
31.34%
6.48%
49.12%
8
6.54%
6.68%
6.83%
30.57% 49.38%
9
12.68%
12.46%
13.21% 12.50% 49.15%

Acetaldedo
Etanol
6.68% 0.081546 6.54%
12.46% 0.136781 12.68%
31.31% 0.437309 33.61%
50.49% 0.669994 50.30%

ter
0.108731 6.83%
0.226458 13.21%
0.551769 31.34%
0.916008 52.74%

Butanol
0.126176 6.52%
0.248838 12.50%
0.739543 30.57%
0.845707 48.84%

4
5
6
7
8
9

0.18266
0.31249
0.820224
1.330404

Razo (Componente / Isopropanol)

CALIBRAO
CALIBRAO 19
CALIBRAO 20
CALIBRAO 7
CALIBRAO 8
CALIBRAO 9
CALIBRAO 10
CALIBRAO 11
CALIBRAO 12
CALIBRAO 13
CALIBRAO 14
CALIBRAO 15
CALIBRAO 16
CALIBRAO 17
CALIBRAO 21
CALIBRAO 23
CALIBRAO 24
CALIBRAO 25
CALIBRAO 26

Acetaldedo

etOH
0.916277 0.916008
0.915738
0.04%

ter

0.675287 0.669994
0.6647
1.12%
0.821782 0.845707
0.869633
4.00%

0.050491
0.049626
0.444398
0.430221
0.08852
0.092528
0.075357
0.087736
0.135302
0.13826

0.050058
1.22%
0.437309
2.29%
0.090524
3.13%
0.081546
10.73%
0.136781
1.53%

0.552786
0.550751
0.115678
0.120065
0.104336
0.102064
0.108702
0.10876
0.226536
0.22638

Acetaldedo
Etanol
6.68% 0.040268 6.54%
12.46% 0.067231 12.68%
31.31% 0.217867 33.61%
50.49% 0.331728 50.30%

0.551769
0.26%
0.117872
2.63%
0.1032
1.56%
0.108731
0.04%
0.226458
0.05%

ter
0.053693 6.83%
0.111309 13.21%
0.303349 31.34%
0.455278 52.74%

0.055352
0.056057
0.129435
0.117457
0.735621
0.743465
0.124946
0.127407
0.248114
0.249562

Butanol
0.062307 6.52%
0.122309 12.50%
0.363266 30.57%
0.399703 48.84%

0.055705
0.89%
0.123446
6.86%
0.739543
0.75%
0.126176
1.38%
0.248838
0.41%

0.089723
0.153596
0.405035
0.680598

Butanol

1.413427
1.247381
0.068428
0.067435
0.135899
0.161822
0.133743
0.132251
0.826038
0.81441
0.311854
0.313127

1.330404
8.83%
0.067932
1.03%
0.148861
12.31%
0.132997
0.79%
0.820224
1.00%
0.31249
0.29%

Concentraes
Amostra Acetaldeido
Amostra 1B
Amostra 1B
Amostra 2C
Amostra 2C
Amostra 3B
Amostra 3B
Amostra 4
Amostra 4
Amostra 5
Amostra 5
Amostra 6
Amostra 6
Amostra 7
Amostra 7
Amostra 8
Amostra 8
Amostra 9
Amostra 9

0.00%
0.00%
50.49%
50.49%
0.00%
0.00%
0.00%
0.00%
4.23%
4.23%
31.31%
31.31%
5.91%
5.91%
6.83%
6.83%
12.46%
12.46%

Etanol
50.30%
50.30%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
33.61%
33.61%
6.36%
6.36%
6.74%
6.74%
6.54%
6.54%
12.68%
12.68%

Isopropanol
49.70%
49.70%
49.51%
49.51%
49.93%
49.93%
51.16%
51.16%
54.98%
54.98%
49.82%
49.82%
50.35%
50.35%
49.38%
49.38%
49.15%
49.15%

ter
0.00%
0.00%
0.00%
0.00%
50.07%
50.07%
0.00%
0.00%
3.78%
3.78%
6.24%
6.24%
30.48%
30.48%
6.68%
6.68%
13.21%
13.21%

re
Butanol
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
48.84%
48.84%
3.40%
3.40%
6.27%
6.27%
6.52%
6.52%
30.57%
30.57%
12.50%
12.50%

Acetaldeido
0
0
51922961.8
37920503.5
0
0
0
0
3778662
4092086.8
32928638.1
30552858.2
5957899.6
4820427
4938401.1
5492902.7
8907673.9
9297926

reas
Etanol
58879416.3
57831693.6
0
0
0
0
0
0
41716339.9
45144525.7
8718361.6
8526632.8
8806799.3
7551341.3
7112074.3
6809184.7
14914116.8
15223964.4

Isopropanol
64259377.3
63153079.7
76890245.6
57049025.5
73515145.3
71329985.9
70458877.5
73100998.1
75388012.7
81826734.1
74703279.3
71016635.4
70340493
60001380.2
65533543.6
62607303.3
65835572.9
67249738.6

Razo
ter
0
0
0
0
87768551.9
85085398.7
0
0
4142499.6
4592190.5
9590806.3
8341422.3
49386421.7
40588071
8172538.1
7976578.4
16334710.1
16783003.9

Butanol
0
0
0
0
0
0
94269022.3
91184812.9
5280105.2
5527555.9
10128960.5
11083994.1
11472087.3
10071891.8
54133213.1
51088580.1
20531085.3
21057677.2

Acetaldeido
Etanol
Isopropanol
0
0.9162774178
1
0
0.9157382961
1
0.6752867206
0
1
0.6647002848
0
1
0
0
1
0
0
1
0
0
1
0
0
1
0.0501228493 0.5533550813
1
0.0500091669 0.5517087563
1
0.4407924044 0.1167065446
1
0.4302211451 0.1200652883
1
0.0847008508 0.1252024108
1
0.0803386019 0.1258527933
1
0.0753568452 0.1085257093
1
0.0877358137 0.1087602299
1
0.1353018362 0.2265358399
1
0.1382596601 0.2263795327
1

zo

Fator de Resposta
ter
Butanol
Acetaldeido
Etanol
Isopropanol
ter
Butanol
0
0
#DIV/0! 0.9054333677
1
#DIV/0!
#DIV/0!
0
0
#DIV/0! 0.9049006265
1
#DIV/0!
#DIV/0!
0
0
0.6622377019 #DIV/0!
1
#DIV/0!
#DIV/0!
0
0
0.6518558349 #DIV/0!
1
#DIV/0!
#DIV/0!
1.1938839479
0
#DIV/0!
#DIV/0!
1
1.1903447662 #DIV/0!
1.1928419391
0
#DIV/0!
#DIV/0!
1
1.1893058464 #DIV/0!
0
1.337929664
#DIV/0!
#DIV/0!
1
#DIV/0! 1.4013278792
0
1.2473812297 #DIV/0!
#DIV/0!
1
#DIV/0!
1.306488779
0.0549490489 0.0700390554 0.6508451982 0.9052366276
1
0.798336672 1.1332799186
0.0561209066 0.0675519555 0.6493690318 0.9025433953
1
0.8153622063 1.0930369372
0.1283853452 0.1355892351 0.7013703731 0.9146270916
1
1.0249864656 1.0769244834
0.1174573007 0.1560760241 0.684549829 0.9409495049
1
0.9377405446 1.2396418604
0.7021051402 0.1630936437 0.7220990507 0.9347079868
1
1.1599595711 1.2592988806
0.6764522893 0.167861002 0.6849096281 0.9395634662
1
1.1175780699 1.2961091992
0.1247077092 0.8260382413 0.5445174618 0.8189289603
1
0.9225369887 1.3345241974
0.1274065162 0.8160163017 0.6339660647 0.8206986399
1
0.9425016664 1.3183330332
0.2481137382 0.311853978 0.5337143633 0.8783108068
1
0.9232052976 1.2262649323
0.2495623663 0.3131265286 0.5453818554 0.8777047824
1
0.9285954914 1.2312688264
0.6428290259 0.8804913278
1.0191981611 1.2095974538
9.31%
6.05%
13.79%
10.33%
Terico
0.46
0.53
0.55
0.66
(Referencia
com PI de
F=1)
Terico
(Referecia PI
Isopropanol)

0.8679245283

1.0377358491 1.2452830189

Acetaldeido
Etanol
0
#DIV/0! 0.916007857
0.6699935027 1.12%

0.04%

Isopropanol
1
0.00%

#DIV/0!

0.00%

ter
0

#DIV/0!

#DIV/0!

#DIV/0!

#DIV/0!

0.00% 1.1933629435

#DIV/0!

#DIV/0!

0.00%

0.0500660081 0.16% 0.5525319188

0.21%

0.00% 0.0555349778

1.49%

0.4355067747 1.72% 0.1183859164

2.01%

0.00% 0.122921323

6.29%

0.0825197264 3.74%

0.125527602

0.37%

0.00% 0.6892787148

2.63%

0.0815463295 10.73% 0.1086429696

0.15%

0.00% 0.1260571127

1.51%

0.1367807481 1.53% 0.2264576863

0.05%

0.00% 0.2488380523

0.41%

0.06%
#DIV/0!

Butanol
0

#DIV/0!

#DIV/0!

#DIV/0!

1.2926554468 4.95%
0.0687955055 2.56%
0.1458326296 9.93%
0.1654773228 2.04%
0.8210272715 0.86%
0.3124902533 0.29%

Concentraes
Acetaldeido
0.00%
0.00%
50.49%
50.49%
0.00%
0.00%
0.00%
0.00%
4.23%
4.23%
31.31%
31.31%
5.91%
5.91%
6.83%
6.83%
12.46%
12.46%

Etanol Isopropanol ter

50.30% 49.70%
0.00%
50.30% 49.70%
0.00%
0.00%
49.51%
0.00%
0.00%
49.51%
0.00%
0.00%
49.93% 50.07%
0.00%
49.93% 50.07%
0.00%
51.16%
0.00%
0.00%
51.16%
0.00%
33.61% 54.98%
3.78%
33.61% 54.98%
3.78%
6.36%
49.82%
6.24%
6.36%
49.82%
6.24%
6.74%
50.35% 30.48%
6.74%
50.35% 30.48%
6.54%
49.38%
6.68%
6.54%
49.38%
6.68%
12.68% 49.15% 13.21%
12.68% 49.15% 13.21%

Razo
Butanol
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
48.84%
48.84%
3.40%
3.40%
6.27%
6.27%
6.52%
6.52%
30.57%
30.57%
12.50%
12.50%

Acetaldeido Etanol Isopropanol ter

0
0.916277
1
0
0
0.915738
1
0
0.675287
0
1
0
0.6647
0
1
0
0
0
1
1.193884
0
0
1
1.192842
0
0
1
0
0
0
1
0
0.050123 0.553355
1
0.054949
0.050009 0.551709
1
0.056121
0.440792 0.116707
1
0.128385
0.430221 0.120065
1
0.117457
0.084701 0.125202
1
0.702105
0.080339 0.125853
1
0.676452
0.075357 0.108526
1
0.124708
0.087736 0.10876
1
0.127407
0.135302 0.226536
1
0.248114
0.13826 0.22638
1
0.249562

Butanol
0
0
0
0
0
0
1.33793
1.247381
0.070039
0.067552
0.135589
0.156076
0.163094
0.167861
0.826038
0.816016
0.311854
0.313127

te
Acetaldeido

1.4

0.8

1.2

0.7
0.6
0.5

f(x) = 1.3457058612x - 0.0044947757

R = 0.9969629223

0.8

0.4

0.6

0.3
0.2

0.4

0.1

0.2

0
0.00%

f(x) = 2.3788761276x - 0.02130

R = 0.9965684566

10.00%

20.00%

30.00%

40.00%

50.00%

60.00%

0
0.00%

10.00%

20.00%

Etanol
1
0.9
0.8 f(x) = 1.7722737189x - 0.0013681883
0.7 R = 0.9966648607
0.6
0.5
0.4
0.3
0.2
0.1
0
0.00%
10.00%
20.00%
30.00%
40.00%

30.00

Buta
1.6
1.4
1.2
1

f(x) = 2.6708720402x - 0.0089

R = 0.9980857349

0.8
0.6
0.4
0.2
50.00%

60.00%

0
0.00%

10.00%

20.00%

30.0

ter

61276x - 0.021302755
4566

20.00%

30.00%

40.00%

50.00%

60.00%

Butanol

20402x - 0.0089920724
7349

20.00%

30.00%

40.00%

50.00%

60.00%