PHYPRNI 30 ie [OEE Quiz No. 4 (Part II) Heo lator Solve the following problems: 3 y it 1. A mixture of 50 g methanol Hor and 100 g water is boiled at 100 kPa. (a) Determine the boiling point and composition of the vapor produced. Assume ideal solution. Antoine constants: ‘ A B c methanol 16.5785 3638.27 239.50 (15 pts.) water 16.3872 3885.70 238.17 2. The normal boiling point of decane is 166°C. Calculate the (a) the molar heat of vaporization of decane (b) the vapor pressure of decane at 200°C. (b) the boiling point of decane at 500 mm Hg. (15 pts.) 3. The densities of the solid and liquid phases of a certain pure substance at 5.5 °C are, respectively, 1.132 g em’ and 0.923 g cm”. Its enthalpy of fusion at the same temperature is 15.65 kJ mole. Estimate the melting point of the solid at 1000 atm, ) a) 11000 atm. (1S pts.) fran Bg, ny pine ehctsnen 4. Liquid A which is immiscible with water was steam-distilled giving a 225 mL distillate of which contained 63.4 mL of ‘A. The density of liquid A is 1.86 g/mL. The system was distilled at 740 mm Hg. f Calculate the molecular weight of A (1S pts.) oiling pt + tydem> 90°U CHAOK 5. For the combustion reaction: CsHs (g) + Oz (g) = CO, (g) + H,0 (I) (unbalanced), calculate the (a) non-expansion work (b) and the maximum work that can be obtained from the combustion of 2 moles of propane at 298 K (10 pts.) 49 a a (*)Park 1:14 a é Cpt Qua #4 Name ____ Bernard _Jomari _B- Rarwte _ ee Subject pant Oe Professor —_Dr_Nathaniel__P. Dugos _ ete Date___.__ fell a, 206 Seton rains ag ep | sO(00 be» 0. 21a @ Tig rm zai - ee PS 2 148+ 38% kM ie AT = FS ae e f sa pee TITS = an ites AR im, yr Foss -_—— =O. SoS yOSince decane if a nen polar _vubstance, (Ts) so (44.15). ~ [maar 75 J ) apo presure of decane af 200°C oe Te ay Beye KK T= 4BAS K eA Py = Late Fie 2, a iv) fis ieee ves Aloy ee = ii Sas oy ee See ep ee a ! Van gm /\# we) ew {in Pp, = 08 [n= 2. 0% An ISB. 43mg T Bas : | Tom * 4a. Bio pete6 preg. Dip, 2 Iso kd Vs con? Teche e las s = mM Lt 3 Sato a as ee 7 es b T. 5.5°@ tooo ee P, = latm oa P, + 1000 atm —laing CAepayron “Eauitatn 2 Fs Ps eae u =e (10 =f) ohm + 18.05 KS tn it bv: \, -, : 2 : BN es Cay, > s * oo lows tm] v= 0.2 om = € iz © 1S. 1000 eee Ea (ie -1.) othe. IS. 65 = In oaecee- qu. —_ 194 - me = a5 exp [0+ 103409 Ieee BAS aes) : se OF Teesee eee Paco She Joni “smnsasibla axons sisi 140 mm tg > Pi 4 A Wo. 36 _- _3845-7 Diet > 42 = Bes I ; zo DE A+ TO P’s 94. 390 kPa 5; Pe < Pepe pe Say i 9. 689 ka a PE + 4.539 Pa P+ 94-320 kPa 7-D4.q > 4.339 [Mp REO Gg 94.320 \F./ 12-24 (WRO}(eop > sect eent+ erpansion vec (BG) ae + ThG, oy 5DGe, = = 4(-31-8) + 3 C39) ~ 0 =(-2-9) ba - SV uof : [PS == ae. OF 5)_maimam work (AA) =e bq = BA + bNgkT _ 1 = 2106- = OA seat) | BA + = 2100. 679k) mol DA pr 2 rte oy poepane ae ~ 2100. G7 __bS [4 males 4 ~ [4045 KW | I wole- Cy i : i