Вы находитесь на странице: 1из 18

( )

..
(1 2, 5);
, , ...
( 33, 22);
, ,
( 17, 6)

http://www.sciteclibrary.ru/rus/catalog/pages/6372.html
(TD)
() ,
2-40 . TD 21-23 .
TD
~0,34 /,

- . 2-25
~1
~60 . TD ,

.
TD
25 -
.
: ; ; ; ; .
1.
1.1.
.

.
, ()
() . (Ds)
=4 35 [Kholmanskiy, 2015], .

3-5 ().
20-25 ( 1),
30-40.

.

(PHL) . PHL
, , , ,
. -
. ,
PHL,
.
1.

): (19),
(47), (20),
(21), (47).

PHL ()

( ,

, , ). PHL ,
,
. [, 1985; ,
2013; , 2009, 2010, 2011]

(F), .

1.2.
PHL -
.

.
(s)
[Kholmanskiy, 2014, 2015; Zakharov, 2011,2012]. -
s.
(W6-)
, s (W-, 2)
. [Shimkevich, 2011] W 15-40

10-12 ,

W6-.
- [Kholmanskiy, 2014].
- -

()

D [Kholmanskiy, 2015]. I-
s . D

(),

(D)

(). D 13
21 / D. II- [Kholmanskiy, 2015]. -
. II- 0,6 ~6 /,
(0,18-1,0
/ [Zakharov, 2011]). II-
D , C.

2. W- W6- . a)
12 ,
( ). ) [Shimkevich, 2011]; (
), ( ),
. b)
; ) ; d) ; ) ; f) .

1.3.

PHL

NaCl, (GL), (TG), (DX)


(G) (GA) ( 2).
.
()
.
,
(R) :
R = 1,18 C1/3,
/, R .

(1)

[11] Ds
(tg ) NaCl .
0-20 tg NaCl
(m) 20 . 40
, tg
m 50 . 20
tg , tg W6-.
m 50 s ,
2.
3.11 [, 2015],
tg m=20 20, 30, 50.

(r.u.)

79, 67, 45, .


= 15 /,
D 25-90 [Kholmanskiy, 2015]. ,
tg
- .
tg GL
tg .
[, 2015], GL s
.
GL W6 ( 2).
G (ZG)
~10 [ ., 2005], GA .

tg G G (0,03 /) 35 [, 2015]. G
50 tg W- - 75 .
GA m 25 ,
- .

3.

max

(1

/).

[, 2015].

TD lgm G (1 /) 3.32 [,
2015] ( 3)
: 24 (0-25); 28 (35-70); 26 / (40-20).
TD m, ,
TD m 35-40 [, 2015]. TD m
1,7 G (1 /, R~1 ) TD tg
ZG
s.
[, 2015]
() G 15 .
0,1 2 / 2,5 /.
G R ~2,5-0,87 , ZG
, 12-17 [
., 2005]. (1) R3,
ZG.
, G>2 / ZG

, ZG .
1.4.
GL TG (wt)
PHL .
GL 19-23 / 13-65 wt 30-60%

[Gallina et al. 2008]. TG wt 0-33%


14-16 / 0-100 [Lerbret et al. 2010].
D, ,
21 15-17 / 0-25 25-90, [Kholmanskiy,
2015]. wt TG 33%
, 30 / 66% [Lerbret et al. 2010].
4.

TG

TG/.

[Lerbret et
al. 2010]. (1)
, (2) .
wt 33%.

2 [15],
TG =25, 35, 45
TG/ ( 4). TG
[Lerbret et al. 2010]
TG, .
TG
>0,8 / R<1 . R
, 17
[Gallina et al. 2010].
1.5.
PHL in vivo .
tg 20-25
.
[, 2013], PHL
- . [, 1982]

,
- 7,6,
12,6 /.

[Kholmanskiy et al. 2010]. tg , PHL ,


(, )
20-25 , tg NaCl (0,9%)
[, 2015]. , ,
~20 -.
(, ,
, ) tg PHL 20-25
50 , W- [,
2015]. 50
20 , W6-.

tg

[, 2015],
.
,
HL CF .
36,6
[, 2010].
0,73% NaCl, 0,0530,075% , 1%
. HL
[, 2005]. (~5%)
. L- (
) ~0,08. (~0,8%)
0,82. HL ,
, -,
( ),
.

,
. ,

, .
. ,

PHL

W-

() .
2.


.
GL, (DX) (GE).
100 :
GL 40 ; 0,1 Cl 3,0-4,0; 0,26 NaCl;
DX 10 30000 40000 0,9 NaCl;
G 4 0,9 NaCl.
() (589 )
-3 ( 0,02,
0,04) 10 20 . (r
= 242) ( ), 2-25
- 2015 .

3.
3.1. TD .
, 5,6 ,
GL DX
(||). TDs GL
DX

x~21

~23,

( 6). > , ,
r 5. || 6
GL ~2-3 , 2- .
DX .
TDs < ( 6)
E 0,33 0,36 / GL DX, .
E,
[, 2007].

5. GL (40%, 10 ) DX (10%, 20 )
. 29 .

6. GL (a) DX (b) ( )
( ).
GL .

,
|| 0,1-0,4 ( 7). ||

(),

Ki 3
.
(Ki 4),
|| , Ki
3.

7. GL(40%, 10 )
, , (Ki).

3.2.
TDs GL DX ( 8a,b)
||. TD G
, TD m G (1 /)
3. TD G
300, TD m
G ( 3). G

G,

~0,9 [ ., 1973].
G G ~1 / R~1,2 , ZG
[,

2011],
GE. TDs m GE G.
TDs, ,
GE
ZG.

8.

(40%),
1700-2000, 29-08-2005; b)
(10%), 2000-2300, 14-09-2005; )
(4%), 2000-2200, 01-09-2005.

20

3.3.
PHL
TDs GL DX. 0,33-0,36
/, TDs 0-40

II-.

II-

(OI) (I) - [Pershin,


2008; Zakharov, 2012]. OI/I
3:1. PI

.
OI 0,29 / .
(h) PI
OI 0,38 / [Tikhonov, 2002]. ,
- PI, OI
PI h.
h.
, TD OI
h PHL II.

, (S), -.
W6- W- (4,
~21-25, ~35 ) - -
[Zakharov, 2011].
s
:
S = |Q|/T p(|T|/T),

(2)

|Q| ; p , |T|/ (|-|)/T


<< 1.
|| <35 -
-,

W6- W- OI/PI.
S
Q .
[Dyson et al., 1973].
(2) -
T. ,
Baikal-GVD,
T = 0,020,03 4001000 ,

[ ., 2002]. T

,
TD (45 ) (75 ) [ ., 2008].
-
- s
OI/I [Dyson et al., 1973; Zakharov, 2012].
-
.
s ,
|| 25.
, ~1
W- -.

PHL,

PHL ,

.
.
4. .

() ,
.
20-23 .

,
- .
,



4, 25, 35 [Kholmanskiy, 2015]. ,


[, 2009 ] 40 .

1. .. . .
// http://bsfp.iszf.irk.ru/bsfp2002/articles/Parfenov.htm
2. .. , . Moscow.
1985.
3. .., .., .. , ..,
l

(2005).

http://www.mce.su/archive/doc15592/doc.pdf
4. . ., . ., . .
//
, 52 (2008) 114121. http://www.chem.msu.su/rus/jvho/2008-1/114.pdf
5. . ., ., . .
. 1973.
6. .. , . Moscow.1982.
7. .. ,
. . 2005.
8. .. ,
// . . 30 (2011) 3
9. ..,

, 58 (2013) 159-164

//

10... , // . 3. (2005):
http://fh.kubstu.ru/fams/issues/issue03/st0302.pdf
11..., .. ,
// . 5 (2007) 57
12... ,
// . 3 (2009) 51-62.
http://j-asymmetry.com/2011/12/holmansky_1_2009_1/.
13...,

//

(2010):

http://www.smolensk.ru/user/sgma/MMORPH/N-28-html/kholmanskiy2/kholmanskiy-2.htm
14... , .. ,

//

. 10 (2011);
\http://www.smolensk.ru/user/sgma/MMORPH/N-32html/holmanskiy/holmanskiy.htm
15.M.E. Gallina, L. Comez, S. Perticaroli, et al. Density fluctuations of water
glucose mixtures studied by inelastic ultra-violet scattering // Philosophical
Magazine, 88 (2008) 39913998
16.M. E. Gallina, L. Comez, A. Morresi, et al. Rotational dynamics of trehalose in
aqueous solutions studied by depolarized light scattering // J. Chem. Phys 132
(2010) 214508
17.F. Dyson, E. Montroll, M. Kac, M. Fisher, Stability and Phase Transitions,
Moscow, 1973.
18..S. Kholmanskiy, .Z. Tilov, .Yu. Sorokin, Drying kinetics of plant
products: Dependence on chemical composition // Journal of Food Engineering.
117 (2013) 378382
19.A.S. Kholmanskiy, inetic factor of extreme temperature dependences of the
properties of water // Int. J. Alternat. Energy Ecol. 6 (2014) 6674.

20.. Kholmanskiy, Activation energy of water structural transitions // Journal of


Molecular Structure. 1089 (2015) 124-128
21.A. Lerbret, F. Affouard, P. Bordat, et al. Slowing down of water dynamics in
disaccharide

aqueous

solutions.

(2010)

http://arxiv.org/ftp/arxiv/papers/1005/1005.5327.pdf
22.S.M. Pershin, Coincidence of Rotational Energy of H2O Ortho-Para Molecules
and Translation Energy near Specific Temperatures in Water and Ice // Phys.
Wave Phenom. 16 (2008) 1525.
23.A. Shimkevich, I. Shimkevich, Adv. Condens. Matter Phys. (2011) 5, http://
dx.doi.org/10.1155/2011/871231 (Article ID 871231).
24.V.I. Tikhonov, A.A. Volkov. Separation of water into its ortho and para isomers
// Science. 296 (2002) 2363.
25.S.D.Zakharov, I.V. Mosyagina, The Cluster Structure of Water (review), FIAN.
2011. http://preprints.lebedev.ru/wp-content/uploads/2011/12/35_11_pr.pdf.
26.S.D. Zakharov, Ortho/Para Spin-Isometry Isomerism of H2O Molecules as the
Leading Formation Factor of Two Structural Types in Water. (2012)
http://www.biophys.ru/archive/h2o-00025.pdf