Вы находитесь на странице: 1из 37

total gas flow rate

Flow rate of biomass


gas yield

0
100
200
300
400
500
252.6192 256.0774 260.7143 266.3636 274.4689 284.2461
27.38
27.38
27.38
27.38
27.38
27.38
9.226415 9.352715 9.522071
9.7284 10.02443 10.38152

12
10
8
6
4
2
0
0

100

200

300

400

500

600
700
295.875 308.7957
27.38
27.38
10.80624 11.27815

Row 4

300

400

500

600

700

800

Component
HYDROGEN
WATER
CO
CO2
CH4
O2
S
CL2
C
NITROGEN

0
0.637311
2.38E-01
0.504179
0.433124
3.57E-02
0.00E+00
0
0.00E+00
0
1.524429

100
0.650204
0.22804
0.538025
0.421026
0.034053
0
0
0
0
1.524429

200
0.66686
0.215489
0.584214
0.404207
0.032
0
0
0
0
1.524429

300
0.685054
0.209658
0.625728
0.386365
0.025819
2.17E-23
0
0
0
1.524429

3.372743 3.395776 3.427199 3.457052

25

20

15

Gas composition (%mol)


10

100

200

300

400

500

600

Pre-heating Temperature (oC)

700

400
0.701323
0.216639
0.65596
0.367758
0.014193
9.73E-23
0
0
0
1.524429

500
0.706789
0.227387
0.682921
0.348904
0.006087
6.94E-22
0
0
0
1.524429

600
0.700251
0.242004
0.705619
0.330246
0.002047
7.72E-21
0
0
0
1.524429

700
0.686695
0.258416
0.724884
0.312408
0.000619
1.02E-19
0
0
0
1.524429

25
18.40254
6.863331
14.55833
12.5066
1.030125
0
0
0
0
44.01837

100
19.2781938
6.76125241
15.9521567
12.4831798
1.00964441
0
0
0
0
45.1984969

3.480303 3.496516 3.504597 3.507451

1.26

1.21

Carbon conversion efficiency


m feed,dry
mfeed,wet
45.314
55.6
166.99266158 175.016412

H2
CO
CO2
CH4

400

500

600

700

800

g Temperature (oC)

19.41919
8.304096
13.20357
13.94368
1.328756

19.80219
7.821583
14.33751
13.39414
1.240838

20.20987
7.483651
15.40488
12.81176
1.072096

20.6748294
7.57159594
16.1969184
12.1862972
0.68156651

20.9423813
7.75512547
16.9548781
11.5642322
0.36295502

1.470752 1.381146 1.311914 1.2764668494 1.23518324

200
19.63793
6.345798
17.20413
11.90321
0.942342
0
0
0
0
44.89192

300
19.98873
6.117476
18.25771
11.27349
0.753347
6.32E-022
0
0
0
44.48032

400
20.28673
6.266594
18.97455
10.63791
0.410564
2.81E-021
0
0
0
44.09621

500
20.21409
6.503231
19.53146
9.97863
0.17408
1.99E-020
0
0
0
43.59851

600
19.98094
6.905344
20.13409
9.423235
0.058397
2.20E-019
0
0
0
43.49799

700
19.57817
7.367618
20.66698
8.906981
0.017658
2.92E-018
0
0
0
43.46259

1.14

1.09

1.07

1.03

0.99

0.95

moisture m,gas
Ash
C
18.5 252.6192
0.007
0.506
178.6107 180.0067 178.4522 176.4381 176.0313

175.888

n efficiency

1.60
1.40
1.20
1.00
0.80

H2/CO ratio

H2/CO (Air)

0.60

H2/CO (Air+steam)

0.40
0.20
0.00

100

200

300

400

Pre-heating Temperature (oC)

500

600

600

Air
25.6
45.6
55.6
65.6
75.6
35.6

ER
0.18
0.32
0.39
0.46
0.53
0.25

H2
CO
CO2
CH4
O2
WATER
N2

0.18
0.298068
0.044572
0.350515
0.111252
3.27E-28
0.425778
0.70295

0.25
0.461463
0.158427
0.407714
0.070891
5.49E-26
0.343104
0.976776

0.32
0.566066
0.318744
0.430503
0.048748
8.53E-25
0.282787
1.250603

1.93

2.42

2.90

0.39
0.637314
0.504188
0.433121
0.035675
5.00E-24
0.237686
1.524429

0.46
0.644484
0.61757
0.418736
0.001606
0
0.298653
1.798255

0.53
0.501482
0.621396
0.416511
5.50E-06
3.07E-16
0.444856
2.072082

21.44
0.207429
0.017713
0.312648
0.135555
7.13E-30
0.467811
0.589038

3.37

3.78

4.06

1.73

0.179117
15.41889
2.305687
18.13197
5.754993
1.69E-026
22.02525
36.36322
0
100
6.687329

0.249084
19.08155
6.550974
16.859
2.931346
2.27E-024
14.18736
40.38977
0
100
2.91278

0.319052
19.5367
11.00083
14.85799
1.682432
2.94E-023
9.759871
43.16217
0
100
1.775929

25

20

H2
15

CO

CO2
Syngas Composition (%mol)
CH4
10
5

0.15

0.3

ER

0.45

0.6

0.389019
18.89787
14.95036
12.84307
1.057834
1.48E-022
7.04795
45.20293
0
100
1.264041

0.458986
17.05298
16.34085
11.0797
0.042491
0
7.902332
47.58165
0
100
1.04358

0.528954
12.36294
15.31915
10.26816
0.000136
7.57E-015
10.96696
51.08265
0
100
0.807025

Air
25.6
45.6
55.6
65.6
75.6
35.6

ER
0.18
0.32
0.39
0.46
0.53
0.25

H2
CO
CO2
CH4
O2
WATER
N2

0.04
0.436282
0.345257
0.123402
0.351361
0.082405
0
7.03E-01

0.07
0.586898
0.260224
0.326931
0.364902
0.049614
0
0.976776

0.11
0.680301
0.20037
0.573055
0.344557
0.032839
0
1.250603

2.04

2.57

3.08

0.14
0.686698
0.258412
0.72488
0.312412
0.00062
1.02E-19
1.524429

0.18
0.537805
0.408542
0.730669
0.307242
1.14E-06
2.51E-14
1.798255

0.22
0.417173
0.529176
0.705726
0.332186
1.84E-08
4.82E-11
2.072082

3.51

3.78

4.06

0.179117
17.11794
17.07106
9.609104
0.000316
4.036182
0
34.43037
0
100

0.249084
17.27667
16.38159
9.884393
0.00031
1.93399
0
38.07583
0
100

0.319052
17.41519
15.72854
10.13592
0.000305
1.065608
0
40.58127
0
100

1.002746 1.054639 1.107235

Syngas Composition (%mol)

H2

CO

CH4

S/B

CO2

Column I

0.389019
17.5344
15.11029
10.36474
0.000302
0.017663
2.92E-018
43.46259
0
100

0.458986
17.63609
14.52437
10.57278
0.000299
3.01E-005
6.63E-013
47.54128
0
100

0.528954
17.72188
13.9685
10.76181
0.000296
4.54E-007
1.19E-009
51.08252
0
100

1.160428 1.214241 1.268702

Air
25.6
45.6
55.6
65.6
75.6
35.6

ER
0.18
0.32
0.39
0.46
0.53
0.25

H2
CO
CO2
CH4
O2
WATER
N2

0.18
0.436282
0.345257
0.123402
0.351361
0.082405
0
7.03E-01

0.25
0.586898
0.260224
0.326931
0.364902
0.049614
0
0.976776

0.32
0.680301
0.20037
0.573055
0.344557
0.032839
0
1.250603

2.04

2.57

3.08

0.39
0.686698
0.258412
0.72488
0.312412
0.00062
1.02E-19
1.524429

0.46
0.537805
0.408542
0.730669
0.307242
1.14E-06
2.51E-14
1.798255

0.53
0.417173
0.529176
0.705726
0.332186
1.84E-08
4.82E-11
2.072082

3.51

3.78

4.06

0.179117
21.36903
16.91062
6.044217
17.20958
4.036182
0
34.43037
0
100

0.249084
22.87793
10.14383
12.74415
14.22427
1.93399
0
38.07583
0
100

0.319052
22.07534
6.501873
18.59526
11.18064
1.065608
0
40.58127
0
100

1.263645 2.255355 3.395228

25
20
H2
15

CO

CO2
Syngas Composition (%mol)
CH4
10
5
0
0.15

0.3

ER

0.45

0.389019
19.57827
7.367513
20.66687
8.907092
0.017663
2.92E-018
43.46259
0
100

0.458986
14.21818
10.80081
19.31702
8.122687
3.01E-005
6.63E-013
47.54128
0
100

0.528954
10.28446
13.04564
17.39809
8.189289
4.54E-007
1.19E-009
51.08252
0
100

2.657378 1.316399 0.788345

ER

0.45

0.6

Air
25.6
45.6
55.6
65.6
75.6
35.6

0.436282
0.586898
0.680301
0.686698
0.537805
0.417173

ER
0.18
0.32
0.39
0.46
0.53
0.25

0.345257
0.260224
0.20037
0.258412
0.408542
0.529176

H2
CO
CO2
CH4
O2
WATER
N2

0.123402
0.326931
0.573055
0.72488
0.730669
0.705726

0.3513606
0.3649017
0.3445565
0.3124119
0.3072418
0.3321856

0.18
0.416901
0.356816
0.108633
0.352966
0.086316
1.75E-26
0.70295

0.25
0.569692
0.271942
0.298003
0.373507
0.052357
1.02E-24
0.976776

0.32
0.66454
0.212027
0.531163
0.359674
0.034891
1.03E-23
1.250603

2.02

2.54

3.05

0.082405
0 7.03E-01
0.049614
0 0.976776
0.032839
0 1.250603
0.00062 1.02E-19 1.524429
1.14E-06 2.51E-14 1.798255
1.84E-08 4.82E-11 2.072082

0.39
0.700262
0.241989
0.705599
0.330264
0.002049
7.70E-21
1.524429

0.46
0.55097
0.395374
0.717497
0.320412
2.84E-06
3.62E-15
1.798255

0.53
0.427068
0.519281
0.695831
0.342081
3.78E-08
1.07E-11
2.072082

3.50

3.78

4.06

0.179117
20.59196
17.62421
5.365688
17.434
4.263388
8.65E-025
34.72075
0
100

0.249084
22.40872
10.69679
11.72191
14.69181
2.05947
4.01E-023
38.4213
0
100

0.319052
21.76752
6.945099
17.39864
11.7814
1.142882
3.37E-022
40.96445
0
100

1.168391 2.094901 3.134228

25
20
H2
15

CO

CO2
Syngas Composition (%mol)
CH4
10
5
0
0.15

0.3

ER

0.45

0.389019
19.98127
6.904919
20.13356
9.423747
0.058462
2.20E-019
43.49805
0
100

0.458986
14.56625
10.45267
18.9688
8.470886
7.50E-005
9.57E-014
47.54132
0
100

0.528954
10.5284
12.8017
17.15415
8.433227
9.31E-007
2.63E-010
51.08252
0
100

2.893773 1.393543 0.822422

ER

0.45

0.6

Air
25.6
45.6
55.6
65.6
75.6
35.6

ER
0.18
0.32
0.39
0.46
0.53
0.25

0.397091
0.552018
0.648422
0.70679
0.565211
0.43777

H2
CO
CO2
CH4
O2
WATER
N2

0.368519
0.283859
0.223855
0.227378
0.381123
0.508578

0.0949523
0.2703861
0.4906645
0.6829043
0.7032369
0.6851286

0.18
0.397091
0.368519
0.094952
0.353955
0.09037
9.56E-27
0.70295

0.25
0.552018
0.283859
0.270386
0.381357
0.055236
6.45E-25
0.976776

0.32
0.648422
0.223855
0.490665
0.374009
0.037036
6.90E-24
1.250603

2.01

2.52

3.02

0.353955
0.381357
0.374009
0.348917
0.334667
0.352783

0.09037
0.055236
0.037036
0.006091
7.48E-06
8.07E-08

9.56E-27
6.45E-25
6.90E-24
6.93E-22
4.65E-16
2.17E-12

0.39
0.70679
0.227378
0.682904
0.348917
0.006091
6.93E-22
1.524429

0.46
0.565211
0.381123
0.703237
0.334667
7.48E-06
4.65E-16
1.798255

0.53
0.43777
0.508578
0.685129
0.352783
8.07E-08
2.17E-12
2.072082

3.50

3.78

4.06

0.179117
19.77706
18.35403
4.729087
17.62866
4.500844
4.76E-025
35.01032
0
100

0.249084
21.90866
11.26589
10.73117
15.13542
2.192232
2.56E-023
38.76662
0
100

0.319052
21.43836
7.40116
16.22252
12.36562
1.224493
2.28E-022
41.34785
0
100

1.077532 1.944691 2.896622


0.70295
0.976776
1.250603
1.524429
1.798255
2.072082

25
20
H2
15

CO

CO2
Syngas Composition (%mol)
CH4
10
5
0
0.15

0.3

ER

0.45

0.389019
20.21415
6.503005
19.53104
9.979005
0.174192
1.98E-020
43.59861
0
100

0.458986
14.94279
10.07595
18.59185
8.84778
0.000198
1.23E-014
47.54144
0
100

0.528954
10.79225
12.53786
16.8903
8.697074
1.99E-006
5.35E-011
51.08252
0
100

3.108432 1.483015 0.860773

ER

0.45

0.6

Air
25.6
45.6
55.6
65.6
75.6
35.6

ER
0.18
0.32
0.39
0.46
0.53
0.25

H2
CO
CO2
CH4
O2
WATER
N2

0.18
0.376846
0.380372
0.082342
0.354333
0.094565
0
0.70295

0.25
0.53402
0.295871
0.244345
0.388372
0.058229
0
0.976776

0.32
0.631943
0.235849
0.451666
0.387511
0.039278
0
1.250603

1.99

2.50

3.00

0.39
0.701322
0.216639
0.655958
0.36776
0.014194
0
1.524429

0.46
0.580586
0.365722
0.687809
0.350082
2.09E-05
5.27E-17
1.798255

0.53
0.449318
0.497031
0.673581
0.364331
1.79E-07
4.06E-13
2.072082

3.48

3.78

4.06

0.179117
18.92361
19.10065
4.134882
17.79307
4.74866
0
35.29912
0
100

0.249084
21.38123
11.84613
9.783124
15.54972
2.33139
0
39.1084
0
100

0.319052
21.08691
7.869898
15.07134
12.93062
1.310654
0
41.73057
0
100

0.990731 1.804912 2.679439

25
20
H2
15

CO

CO2
Syngas Composition (%mol)
CH4
10
5
0
0.15

0.3

ER

0.45

0.389019
20.15118
6.22471
18.84772
10.5669
0.407847
0
43.80164
0
100

0.458986
15.34936
9.668846
18.1841
9.255372
0.000552
1.39E-015
47.54177
0
100

0.528954
11.07692
12.25318
16.60562
8.981755
4.42E-006
1.00E-011
51.08252
0
100

3.237288 1.587507 0.904004

ER

0.45

0.6

Air
25.6
45.6
55.6
65.6
75.6
35.6

ER
0.18
0.32
0.39
0.46
0.53
0.25

H2
CO
CO2
CH4
O2
WATER
N2

0.18
0.356354
0.392276
0.070882
0.354111
0.098859
0
0.70295

0.25
0.515475
0.308121
0.219592
0.394623
0.061377
0.00E+00
0.976776

0.32
0.615083
0.248017
0.414223
0.400149
4.16E-02
0.00E+00
1.250603

1.98

2.48

2.97

0.39
0.685054
0.209658
0.625728
0.386365
0.025819
2.17E-23
1.524429

0.46
0.596992
0.349234
0.671239
0.366611
6.17E-05
5.29E-18
1.798255

0.53
0.461767
0.484581
0.66113
0.376781
4.17E-07
6.93E-14
2.072082

3.46

3.78

4.06

0.179117
18.03929
19.85774
3.588155
17.92576
5.004448
0
35.58461
0
100

0.249084
20.81918
12.44447
8.868963
15.93815
2.478895
0
39.45034
0
100

0.319052
20.71195
8.351572
13.94831
13.4744
1.401656
0
42.11211
0
100

0.908426 1.672967 2.480007

25
20
H2
15

CO

CO2
Syngas Composition (%mol)
CH4
10
5
0
0.15

0.3

0.45
ER

0.389019
19.81612
6.064648
18.10005
11.17614
0.746841
6.26E-022
44.09621
0
100

0.458986
15.78344
9.233146
17.74642
9.692558
0.00163
1.40E-016
47.5428
0
100

0.528954
11.38384
11.94625
16.29868
9.288689
1.03E-005
1.71E-012
51.08253
0
100

3.26748 1.709433 0.952921

0.45
ER

0.6

Air
25.6
45.6
55.6
65.6
75.6
35.6

ER
0.18
0.32
0.39
0.46
0.53
0.25

H2
CO
CO2
CH4
O2
WATER
N2

0.18
0.335545
0.404284
0.06048
0.353308
0.10326
0
0.70295

0.25
0.496417
0.320579
0.196231
0.400074
0.064676
0
0.976776

0.32
0.597784
0.26039
0.378312
0.411918
0.044088
0
1.250603

1.96

2.45

2.94

0.39
0.666871
0.215481
0.584243
0.404196
0.031999
0
1.524429

0.46
0.614384
0.331578
0.65332
0.384398
0.000194
4.64E-19
1.798255

0.53
0.4752
0.471147
0.647695
0.390215
1.01E-06
1.07E-14
2.072082

3.43

3.78

4.06

0.179117
17.12116
20.62857
3.085992
18.0275
5.268823
0
35.86796
0
100

0.249084
20.22269
13.05952
7.993921
16.29793
2.634733
0
39.7912
0
100

0.319052
20.31141
8.847481
12.85423
13.99608
1.498005
0
42.49279
0
100

0.829973 1.548501 2.295728

25
20
H2
15

CO

CO2
Syngas Composition (%mol)
CH4
10
5
0
0.15

0.3

0.45
ER

0.389019
19.45807
6.287353
17.04715
11.7937
0.93366
0
44.48007
0
100

0.458986
16.24439
8.76697
17.27386
10.16354
0.005119
1.23E-017
47.54612
0
100

0.528954
11.71499
11.61508
15.96748
9.619888
2.50E-005
2.64E-013
51.08254
0
100

3.094795 1.852908 1.008602

0.45
ER

0.6

Air
25.6
45.6
55.6
65.6
75.6
35.6

ER
0.18
0.32
0.39
0.46
0.53
0.25

H2
CO
CO2
CH4
O2
WATER
N2

0.18
0.31438
0.416437
0.051075
0.351934
0.107766
0
0.70295

0.25
0.476737
0.333311
0.174179
0.404734
0.06815
0
0.976776

0.32
0.57993
0.273043
0.343811
0.422842
0.046688
0
1.250603

1.94

2.43

2.92

0.39
0.650211
0.228034
0.538044
0.421019
0.034052
0
1.524429

0.46
0.632143
0.312922
0.633766
0.403503
0.000642
3.58E-20
1.798255

0.53
0.489745
0.456599
0.633144
0.404765
2.60E-06
1.48E-15
2.072082

3.40

3.78

4.06

0.18
16.17
21.42
2.63
18.10
5.54
0.00
36.15
0.00
100.00
0.75

0.25
19.59
13.69
7.16
16.63
2.80
0.00
40.13
0.00
100.00
1.43

25
20
H2
15

CO

CO2
Syngas Composition (%mol)
CH4
10
5
0
0.15

0.3

ER

0.45

0.6

0.32
19.88
9.36
11.79
14.50
1.60
0.00
42.87
0.00
100.00
2.12

0.39
19.15
6.72
15.84
12.40
1.00
0.00
44.89
0.00
100.00
2.85

0.46
16.72
8.28
16.76
10.67
0.02
0.00
47.56
0.00
100.00
2.02

0.53
12.07
11.26
15.61
9.98
0.00
0.00
51.08
0.00
100.00
1.07

Un-preheating
Preheating
Preheating+Steam

S/B
0.04
0.07
0.11
0.14
0.18
0.22

1
2
3
4
5
6

H2
17.12
17.28
17.42
17.53
17.64
17.72

CO2
9.61
9.88
10.14
10.36
10.57
10.76

20.00
18.00
16.00
14.00
12.00
10.00
8.00
6.00
4.00
2.00
0.00
0.00

0.05

0.10

0.15

0.20

CO
17.07
16.38
15.73
15.11
14.52
13.97

CH4
0.00032
0.00031
0.00031
0.00030
0.00030
0.00030

TEM Gasifier
918.68
915.38
911.93
908.47
905.01
901.55

H2
CO2
CO
CH4

0.15

0.20

0.25

H2/CO
1.00
1.05
1.11
1.16
1.21
1.27

S/B=0.04, Prethreat 500, S=1kg/h


HYDROGEN
0.60
WATER
0.45
CO
0.60
CO2
0.34
CH4
0.00
O2
0.00
S
0.00
CL2
0.00
C
0.00
NITROGEN
1.52
total
3.52
S/B=0.04, Prethreat 100, S=1kg/h
HYDROGEN
0.6599699
WATER
0.6185711
CO
0.5435247
CO2
0.3956498
CH4
1.12E-05
O2
0
S
0
CL2
0
C
0
NITROGEN
1.5244295
total
3.7421561

hreat 500, S=1kg/h


17.12
12.90
17.07
9.61
0.00
0.00
0.00
0.00
0.00
43.31
100.00

S/B=0.07, Prethreat 500, S=1kg/h


HYDROGEN
0.62
17.28
WATER
0.49
13.82
CO
0.59
16.38
CO2
0.35
9.88
CH4
0.00
0.00
O2
0.00
0.00
S
0.00
0.00
CL2
0.00
0.00
C
0.00
0.00
NITROGEN
1.52
42.63
total
3.58
100.00

eat 100, S=1kg/h


17.636086
16.529805
14.524373
10.572776
0.0002989
0
0
0
0
40.736661
100

S/B=0.04, Prethreat 100, S=1kg/h


HYDROGE 0.67301739 17.721876153
WATER
0.66103188 17.40627402
CO
0.53047693 13.968504522
CO2
0.40869751 10.761812048
CH4
1.13E-05 0.000296419
O2
0
0
S
0
0
CL2
0
0
C
0
0
NITROGEN 1.52442948 40.141236838
total
3.797664447
100

S/B=0.04, Prethreat 100,


HYDROGE
WATER
CO
CO2
CH4
O2
S
CL2
C
NITROGE
total

/B=0.04, Prethreat 100, S=1kg/h


0.63237 17.41519
0.535154 14.73792
0.571125 15.72854
0.36805 10.13592
1.11E-05 0.000305
0
0
0
0
0
0
0
0
1.524429 41.98212
3.631139
100

S/B=0.04, Prethreat 100, S=1kg/h


HYDROGE 0.646432 17.5344
WATER
0.576601 15.64025
CO
0.557063 15.11029
CO2
0.382111 10.36474
CH4
1.11E-05 0.000302
O2
0
0
S
0
0
CL2
0
0
C
0
0
NITROGE 1.524429 41.35002
total
3.686648
100

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