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Jeager lecture
ABSTRACT
The contribution deals with possibilities of metallographical identification of crack types in steel structures.
The main features of cracks predominately in welded joints are illustrated on real cases of breakdowns.
Keywords: Crack types, Welded joints, Steel structures, Case studies, Cold cracking, Fatigue cracks,
LME, SSCC
1. INTRODUCTION
The welded joints are most critical places of steel structures due to high residual stresses and stress
concentration ( constructional and structural notches) and due to possible cracking originated from welding
process.
In service, cracks can easily propagate, either suddenly (brittle fracture) or gradually (fatigue, creep or
corrosion). It is very important to distinguish the crack types, as different measures are often taken to
eliminate the various cracks, for instance to eliminate hot cracking usually lower welding heat input is
required, but this is unfavorable for cold cracking. In such cases microfractographical analysis gives us a
very useful tool.
solidification cracks, which are formed during solidification in the weld metal, and are most often
orientated towards the weld axis, in the direction of columnar crystals, they are of typical
interdendritic character (Fig. 1)
liquation cracks, which are formed in the underbead zone of the base metal, or in multi-pass
weld of the weld metal
polygonization cracks, which are formed in the lower temperature zone (800 1100C), in the
heat affected zone and the weld metal
If hot cracks are open (i. e. on the surface) they can generally be distinguished from other types of cracks by
their oxidized black and brown tinged surface. This is more difficult with closed cracks. Hot cracks are
usually shorter and more laminated than other types, and they are always of intercrystalline character. The
residues both of solidified liquid film in the form of eutectic secondary phases (Fig. 2) and of round grains
with typical soliditied bridges between them in the case of soluble lower temperature elements (Fig. 3) can
be detected on the surfaces of solidification and liquation cracks. The surfaces of polygonization cracks are
pure, and without secondary phases. Closed hot cracks which are not opened to air are characterized by
thermal faceting of their surface (Fig. 4), which is present at above 900C as a result of metal ion
evaporation into vacuum and this unambiguously differentiates hot cracks from lower temperature ones.
Table 1 - Chemical composition of plates in S530Q steel and MMAW and SAW weld metals
(wt%)
Specimen
h
(mm)
Mn
Si
Cr
Mo
Ni
Cu
Ti
Se
PM
20
35
0,152
0,161
1,51
1,33
0,35
0,28
1,47
1,44
0,55
0,51
0,12
0,24
0,07
0,06
0,0028
0,0030
0,01
0,01
0,0054
0,0101
0,015
0,0135
0,819
0,791
20
35
0,096
0,067
1,47
1,24
0,47
0,43
0,61
0,39
0,47
0,43
1,26
1,21
0,02
0,05
MMAW
WM
SAW
WM
Table 2 Chemical composition [wt %] and mechanical properties of the 15 G2S steel
C
0,14-0,15
Mn
1,37-1,45
Si
1,07-1,08
P
0,014
S
0,029
Re [MPa]
Rm [MPa]
A5 [%]
387 404
591 - 612
22 - 27
Cr
Ni
0,06
0,05
ChV FATT
(50J.cm-2)
+ 140 C
Cu
0,08
Ti
0,032
Upper shelf
55 J.cm-2
a)
b)
th
The last case of failure did not happen during pipeline service. It appeared at construction (laying) of 4
transmission line OD 1420 x 18.6 mm made of X-70 steel grade spirally welded pipes.
During bending of pipes on site a few pipes cracked along the spiral welds. The cracks in length up to 1 m
always appeared in the same distance from the pipe end (Fig. 21). The crack occurrence corresponded with
appearance of a cold impression on the outer spiral weld reinforcement (Fig. 22 and 23). It was found that
such impression was formed due to incorrectly installed supporting steel rollers in the furnace used for pipe
insulation. In this furnace the pipes are flame heated prior to PE insulation up to 300 0C, whereas they
rotate (about 70 revolutions) on the rollers. In certain period of manufacture some pairs of rollers were taken
out for the repair, and therefore the pipe weight (about 12 tons) was supported by the remaining pair (in
11.5 m distance). Since all inspections of pipes were performed prior to pipe insulation, such impression
could not be revealed.
This finding resulted in repeated ultrasonic inspection of all bent pipes manufactured in that period
(about 300 pipes). The problem was, that the concerned pipes were already distributed in the section about
150 km long, which was already buried under the soil.
C
Material
15Mo3
1.4462
ER
309Mo
Mn
Si
Cr
Ni
Mo
Nb
22
24
5,45
14,2
0,12
3,04
2,74
0,53
0,13
0,135
-
The working medium of air cooler consisted of hydrogen (up to 70%), hydrocarbons (up to 28%)
and hydrogen sulphide, water and other admixtures. The working pressure was 13,48 MPa and working
temperature 50 to 122oC.
After about three weeks of service a leakage of the working medium through the welds was
observed.
The cross section of a specimen extracted from the defective weld is shown in Fig.25. It is evident
that a single pass weld is concerned. The crack propagated to weld metal in normal direction to surface
(Fig.26). The arrows indicate the initiation points of short crack. The weld metal exhibited martensitic
structure (Fig.27). Chemical microanalysis (EDX) of the weld metal revealed its considerable dilution by
the tubeplate material:
element
wt%
Cr
10,03
Ni
6,42
Mo
1,55
As it is evident also from Fig.25 about 60% of the tubeplate material and only about 15% of the tube
material fused into the weld metal. Based upon the calculated chromium and nickel equivalents (the
content of non-analyzed elements was assessed approximately by the dilution degree) ECr = 11,9 and
ENi = 10,2 plotted in the Schaeffler diagram, the weld metal structure was expected to be martensitic
with a small proportion of austenite which well agrees with the morphological determination of the
structure as well as with hardness measurements.
a)
b)
HV5
Location
weld metal
tube BM
tube HAZ
tubeplate - BM
tubeplate - HAZ
412 435
248 262
257 262
152 165
322 381
From the viewpoint of SSCC the hardness should not exceed the values of HV 248 according to
NACE standard for low alloy steels (for duplex steels, the hardness limit is higher, namely HV 285).
Unacceptable hardness was observed also in the heat affected zone of the tubeplate which was
mostly bainitic with some martensitic islands.
The performed analyses have shown, that the specific joint configuration and restricted welding
condition (access though a hole 25 mm in diameter on the opposite wall) resulted in undesired weld
metal dilution by the tubeplate material leading to weld metal with a martensitic structure which is
usually extremely susceptible to sulphide stress corrosion cracking. It was actually the main reason for
necessity to repair all tube and tubeplate welded joints, including the joints where no corrosion cracking
was observed yet.
During the repair of air cooler, besides the martensitic weld metal also the hardened heat
affected zones of the tubeplate and tube ends (made of a duplex steel which is incapable to
withstand the repeated heating) had to be removed. Thus the repair of all 3240 welded joints in
tube tubeplate connections of the air cooler was a really demanding job.
The repair procedure of air cooler was carried out in the following steps [2]:
a) removal of all original welds by use of a special tool,
b) removal of all tubes from the air cooler plug headers,
c) dehydrogenization of the plug headers by tempering,
d) machining of grooves in the tubeplate bores, serving for tube end expanding by rolling with
a special roller,
e) buttering beads of Ni-base alloy were deposited on the outs around the bore ends by use
of a special welding procedure,
f) all butters were machined to the required shape,
g) HAZ on the tubes were cut off (shortened by 10 mm),
h) the buttering welds were tempered,
i) the air cooler plugs were assembled with the tubes into the sections,
j) tube to tubeplate welds were fabricated by use of Inconel electrodes and the leakage test
was performed,
k) rolling expansions of tube to tubeplate by a special roller,
l) pressure test of tube sections was performed
5.2 Welded joint failure of austenitic creep resisting Cr-Mn steel [3]
In the hydrogenation fuel refining process, the hydrogen and hydrogen sulphide mixture attacks the material
of the radiation pipes (219 x 14 mm, seamless) which are subjected to temperatures ranging between 350
and 400C. The newly developed chromium manganese austenitic steel (08Mn18Cr11V0,6) is concerned
see Table 5. It belonged to the so-called economical austenitic steels in which nickel, which was lacking at
the time, was replaced by manganese as a cheaper alternative.
The pipe failed in the heat affected zone (HAZ) of the circumferential welded joint near the fusion line.
Cracks propagated from the inner surface, through the whole cross section, to the outer pipe surface (Fig.
28 cross section). A more detailed picture shows that intercrystalline stress corrosion cracking was
involved (Fig. 29).
A whole network of cracks of similar character, which propagated from the fusion line into the parent
metal, could be observed on the inner side of the circumferential joint (Fig. 30). Weld metal fabricated by
ERNiCr-3 electrode did not exhibit any corrosion attack traces .
Mn
Si
Cr
0,05 0,08
17,0 20,0
0,25 1,0
9,5 11,5
0,45 0,75
max. 0,045
max. 0,035
Figure 29 Intercrystalline
character of crack in pipe wall (x 50)
EDX energy dispersion analysis of the corrosion products on the intercrystalline surface of the fractured
crack (Fig. 31) showed increased S and partially also Cl contents, which proves the corroding effect of
polythionic acids and chloride ions. Sulphur and chlorine can originate from the raw material (MONA gas
and H2 circulation gas) but also from the technological process of catalyst regeneration.
It can be assumed that the intercrystalline corrosion attack was caused by a condensate of polythionic acids
which were formed by the conjoined effect of sulphides, humidity and air oxygen during equipment
shutdowns. The condensate itself was a consequence of the improper N2-filling up process of the furnace at
beginning of the shutdown. According to the operator, 11 major overhauls and about 20 catalyst
regenerations have been performed on the furnace during its 14 years of service.
As this Cr-Mn steel has Cr content just on the limit of passive state and it easily sensitive to intercrystalline
corrosion, it was recommended that the entire Cr-Mn steel piping system to be replaced by Cr-Ni (AISI 321)
steel which has a proven track record in similar applications. In addition, it was recommended that more
careful inspections be carried out while in shutdown mode (e. g. blowing of the furnace by nitrogen).
Location
BM
WM
As delivered
306, 289, 306
321, 332, 336
The easiest way how to distinguish proper state of the thermowells is detection by a magnet (ferromagnetic
martensite or paramagnetic austenite)
6. CONCLUSIONS
The paper dealt with main metallurgical features of cracks in the welded joints, which where illustrated on
selected real cases of breakdowns. To distinguish the crack types and to know their causes is very
important for adoption of proper measures at their remedy.
REFERENCES
[1] Bernasovsk, P. Boansk, J.: Welding and technological causes of breakdown of the lock gate of waterwork chamber on Danube river, JOM-10
Conference , Helsingor, May 2001
[2]
[3]
[4]